Oxford Cambridge and RSA

AS Level Chemistry A (H032)

A Level Chemistry A (H432)

Data Sheet
* 3 4 1 0 7 4 0 6 7 4 *

INSTRUCTIONS
• Do not send this Data Sheet for marking. Keep it in the centre or recycle it.
Chemistry A

INFORMATION
• This document has 4 pages.

Copyright Information
OCR is committed to seeking permission to reproduce all third-party content that it uses in its assessment materials. OCR has attempted to identify and contact all copyright
holders whose work is used in this paper. To avoid the issue of disclosure of answer-related information to candidates, all copyright acknowledgements are reproduced in
the OCR Copyright Acknowledgements Booklet. This is produced for each series of examinations and is freely available to download from our public website (www.ocr.org.
uk) after the live examination series.
If OCR has unwittingly failed to correctly acknowledge or clear any third-party content in this assessment material, OCR will be happy to correct its mistake at the earliest
possible opportunity.
For queries or further information please contact The OCR Copyright Team, The Triangle Building, Shaftesbury Road, Cambridge CB2 8EA.
OCR is part of the Cambridge Assessment Group; Cambridge Assessment is the brand name of University of Cambridge Local Examinations Syndicate (UCLES), which is
itself a department of the University of Cambridge.

© OCR 2020 [601/5256/4] Chemistry A

DC (LK) 203564 CST263
 2

General Information

Molar gas volume = 24.0 dm3 mol−1 at room temperature and pressure, RTP

Avogadro constant, NA = 6.02 × 1023 mol−1

Specific heat capacity of water, c = 4.18 J g−1 K−1

Ionic product of water, K w = 1.00 × 10−14 mol2 dm−6 at 298 K

1 tonne = 106 g

Arrhenius equation: k = Ae–Ea/RT or ln k = −Ea/RT + ln A

Gas constant, R = 8.314 J mol−1 K−1

Characteristic infrared absorptions in organic molecules

Bond Location Wavenumber / cm−1

C–C Alkanes, alkyl chains 750–1100
C–X Haloalkanes (X = Cl, Br, I) 500–800
C–F Fluoroalkanes 1000–1350
C–O Alcohols, esters, carboxylic acids 1000–1300
C=C Alkenes 1620–1680
Aldehydes, ketones, carboxylic acids, esters,
C=O 1630–1820
amides, acyl chlorides and acid anhydrides
aromatic Several peaks in range
Arenes
C=C 1450–1650 (variable)
−
C=N Nitriles 2220–2260
C–H Alkyl groups, alkenes, arenes 2850–3100
O–H Carboxylic acids 2500–3300 (broad)
N–H Amines, amides 3300–3500
O–H Alcohols, phenols 3200–3600

© OCR 2020 Chemistry A

 13C NMR chemical shifts relative to TMS
C Cl
C Br
C
C C
C N
C C
C O C
C O C C
C C

220 200 180 160 140 120 100 80 60 40 20 0

δ / ppm
1H NMR chemical shifts relative to TMS

O H N H

CH

HC O O
O O
HC Cl HC C
C C C C HC R
HC Br
OH H H HC N

12 11 10 9 8 7 6 5 4 3 2 1 0
δ / ppm

Chemical shifts are variable and can vary depending on the solvent, concentration and substituents. As a result, shifts may be outside the ranges
indicated above.
OH and NH chemical shifts are very variable and are often broad. Signals are not usually seen as split peaks.
Note that CH bonded to ‘shifting groups’ on either side, e.g. O–CH2–C=O, may be shifted more than indicated above.
© OCR 2020 Chemistry A
 The Periodic Table of the Elements

(1) (2) (3) (4) (5) (6) (7) (0)

1 Key 18
1 atomic number 2
H Symbol He
hydrogen name helium
1.0 2 relative atomic mass 13 14 15 16 17 4.0
3 4 5 6 7 8 9 10
Li Be B C N O F Ne
lithium beryllium boron carbon nitrogen oxygen fluorine neon
6.9 9.0 10.8 12.0 14.0 16.0 19.0 20.2
11 12 13 14 15 16 17 18
Na Mg Al Si P S Cl Ar
sodium magnesium aluminium silicon phosphorus sulfur chlorine argon
23.0 24.3 3 4 5 6 7 8 9 10 11 12 27.0 28.1 31.0 32.1 35.5 39.9
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
potassium calcium scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc gallium germanium arsenic selenium bromine krypton
39.1 40.1 45.0 47.9 50.9 52.0 54.9 55.8 58.9 58.7 63.5 65.4 69.7 72.6 74.9 79.0 79.9 83.8
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
rubidium strontium yttrium zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium indium tin antimony tellurium iodine xenon
85.5 87.6 88.9 91.2 92.9 95.9 101.1 102.9 106.4 107.9 112.4 114.8 118.7 121.8 127.6 126.9 131.3
55 56 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
Cs Ba • 57–71 Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
caesium barium lanthanoids hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon
132.9 137.3 178.5 180.9 183.8 186.2 190.2 192.2 195.1 197.0 200.6 204.4 207.2 209.0
87 88 104 105 106 107 108 109 110 111 112 114 116
Fr Ra Rf Db Sg Bh Hs Mt Ds Rg Cn Fl Lv
francium radium actinoids rutherfordium dubnium seaborgium bohrium hassium meitnerium darmstadtium roentgenium copernicium flerovium livermorium
•• 89–103

57 58 59 60 61 62 63 64 65 66 67 68 69 70 71
La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
lanthanum cerium praseodymium neodymium promethium samarium europium gadolinium terbium dysprosium holmium erbium thulium ytterbium lutetium
152.0
• 138.9 140.1 140.9 144.2 144.9 150.4 157.2 158.9 162.5 164.9 167.3 168.9 173.0 175.0

89 90 91 92 93 94 95 96 97 98 99 100 101 102 103

Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
actinium thorium protactinium uranium neptunium plutonium americium curium berkelium californium einsteinium fermium mendelevium nobelium lawrencium
232.0 238.1
••
© OCR 2020 Chemistry A