Exam 3 CHEM 1100 /1110 Fall 2017

1. In the reaction, K2SO4(aq) + Ba(NO3)2(aq)  BaSO4(s) + 2 KNO3(aq), which ions are the spectator ions?
A. Ba2+ and K+
B. Ba2+ and NO3–
C. Ba2+ and SO42–
D. K+ and SO42–
E. K+ and NO3–

2. Which is the net ionic equation for the reaction which takes place when HClO3(aq) is added to KOH(aq)?

A. H+(aq) + OH– (aq)  H2O(l)

B. H+(aq) + KOH(aq)  K+(aq) + H2O(l)
C. HClO3(aq) + K+(aq)  KClO3(aq) + H+(aq)
D. HClO3(aq) + KOH(aq)  KClO3(aq) + H2O(l)
E. HClO3(aq) + OH– (aq)  ClO3– (aq) + H2O(l)

3. Which compound is soluble in water?

A. AgBr
B. BaSO4
C. CaCO3
D. MgCl2
E. PbCO3

4. If 50.0 mL of 6.50 M H2SO4 is diluted to give a 1.30 M solution of H2SO4, what is the final volume of the
diluted acid?
A. 25.0 mL
B. 1.30 102 mL
C. 135 mL
D. 2.50102 mL
E. 3.00 L

5. What is the molar concentration of the H+ ion if the OH– ion concentration in an aqueous solution at 25.0 °C is
3.4 × 10–3 M?
A. 3.4 × 10–17 M
B. 2.9 × 10–12 M
C. 6.6 × 10–10 M
D. 5.8 × 10–9 M
E. 2.9 × 10–3 M

6. A 100.0 mL sample of a 0.200 M aqueous solution of K2CrO4 was added to 100.0 mL of a 0.100 M aqueous
solution of BaCl2. The mixture was stirred and the precipitate was collected, dried carefully, and weighed.
How many grams of precipitate should be obtained? The reaction is shown below:

K2CrO4(aq) + BaCl2(aq)  BaCrO4(s) + 2 KCl(aq)

A. 2.05 g
B. 2.53 g
C. 5.07 g
D. 6.16 g
E. 7.60 g

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Exam 3 CHEM 1100 /1110 Fall 2017
7. When 25.0 mL of sulfuric acid solution was completely neutralized in a titration with 18.3 mL of 0.050 M
NaOH(aq) solution. The unbalanced equation for the reaction is:

NaOH(aq) + H2SO4(aq)  Na2SO4(aq) + H2O(l)

What was the molarity of the sulfuric acid solution?

A. 0.0100
B. 0.0148
C. 0.0183
D. 0.0325
E. 0.0366

8. What is the reducing agent in the following the redox redox below?

C4H10(g) + Cr2O72– (aq) + H+(aq)  H6C4O4(aq) + Cr3+(aq) + H2O(l)

A. C4H10(g)
B. Cr2O72– (aq)
C. Cr3+(aq)
D. H+(aq)
E. H6C4O4(aq)

9. Balance the half-reaction, Cl2O7  HClO, taking place in acidic media. How many electrons are needed to
balance the half reaction?
A. 2 electrons, left side
B. 3 electrons, right side
C. 6 electrons, right side
D. 8 electrons, left side
E. 12 electrons, left side

10. What is the sum of ALL the coefficients in the equation after balancing of the following redox reaction?

OH– + Bi2O3(s) + OCl– (aq)  Cl– (aq) + BiO3–(aq) + H2O

A. 6
B. 8
C. 9
D. 10
E. 14

11. A 4.98 g sample of aniline (C6H5NH2, molar mass = 93.13 g/mol) was combusted in a bomb calorimeter with a
calorimeter constant of 4.25 kJ/°C. What is the ΔE°comb for aniline if the temperature of the calorimeter rose
from 29.5°C to 69.8°C?

A. –7.81 × 103 kJ/mol

B. –3.20 × 103 kJ/mol
C. –1.71 × 103 kJ/mol
D. +1.71 × 103 kJ/mol
E. +7.81 × 103 kJ/mol

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Exam 3 CHEM 1100 /1110 Fall 2017
12. Which of the following signs on q and w represent a system that is doing work on the surroundings but gains
heat from the surroundings?
A. q=–,w=–
B. q = +, w = +
C. q = –, w = +
D. q = +, w = –
E. None of these represent the system referenced above.

13. For a change in a system that takes place at constant pressure, which statement below is true?
A. ΔE = qp
B. ΔH = ΔE
C. ΔH = qp – PΔV
D. ΔH = ΔE – qp
E. ΔH = qp

14. A 113.25 g sample of gold is initially at 100.0 °C. It gains 20.00 J of heat from its surroundings. What is its final
temperature? (The specific heat of gold is 0.129 J g–1 °C–1)
A. –101.4 °C
B. –98.6 °C
C. 96.6 °C
D. 98.6 °C
E. 101.4 °C

15. What is the enthalpy change, H, for the reaction, N2(g) + 2 H2(g)  N2H4(l), given the following
thermochemical equations:

N2H4(l) + O2(g)  2 H2O(l) + N2(g) H = –622.0 kJ

H2(g) + ½ O2(g)  H2O(l) H = –285.9 kJ
A. –151.7 kJ
B. –236.2 kJ
C. +106.1 kJ
D. +50.2 kJ
E. +567.4 kJ

16. What is the BEST estimate for the molar heat of combustion (Hcombustion) of methanol (CH3OH)?

CH3OH(l) + O2(g)  CO2(g) + H2O(g) Bond Bond Energy

A. +30 kJ (kJ/mol)
B. –655 kJ C–H 413
C. +715 kJ C=O 799
D. –3466 kJ O=O 498
E. +6277 kJ H–O 467
C–C 347
C–O 358

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Exam 3 CHEM 1100 /1110 Fall 2017
17. What is the heat of formation (H˚f) of KCl(s)? (Hint: Use the H°(kJ)
data given to construct a Born-Haber cycle.) K(s) → K(g) 89
K(g) → K⁺(g) + e⁻ 418
A. –1119 kJ
Cl2(g) → 2 Cl(g) 244
B. –997 kJ
Cl(g) + e⁻ → Cl⁻(g) –349
C. –437 kJ
KCl(s) → K⁺(g) + Cl⁻(g) 717
D. +158 kJ
E. +631 kJ

18. The standard enthalpy of combustion for xylene, C8H10(l), is –3908 kJ mol–1. What is the standard enthalpy of
formation of C8H10(l), in kJ mol–1?
A. –669.5 kJ H°f(kJ)
B. +3228.6 kJ H2O(l) –285.9 kJ mol–1
C. –3228.6 kJ CO2(g) –393.5 kJ mol–1
D. +4587.4 kJ
E. +8485.5 kJ

19. In an open-end mercury manometer measurement, the level in the end of the tube connected to the gas
container, measured 76.2 cm above the U-neck, while the level in the open end (to the atmosphere) was 23.8
cm above the U-neck. The outside air pressure in the laboratory was measured as 754 torr. What is the
pressure in the gas container?
A. 230 torr
B. 236 torr
C. 241 torr
D. 246 torr
E. 1278 torr

20. A sample of a gas occupies a volume of 1.820 L at STP. What pressure would it exert if it is transferred to a
1.425-L vessel in which its temperature is raised to 25.2 °C?
A. 0.7168 atm
B. 0.8552 atm
C. 1.169 atm
D. 1.278 atm
E. 1.395 atm

21. What is the total pressure exerted by a gaseous mixture that consists of 8.00 g of methane and 8.00 g of ethane,
C2H6, in a 3.50-L container maintained at 35.20 °C?
A. 0.286 atm
B. 0.631 atm
C. 2.51 atm
D. 5.53 atm
E. 30.7 atm

22. The average speed at which a nitrogen molecule effuses at 30.0 °C is 480 m/s. What should the average speed
at which a butene molecule (C4H8) effuses at the same temperature?
A. 120 m s-1
B. 170 m s-1
C. 240 m s-1
D. 339 m s-1
E. 679 m s-1

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Exam 3 CHEM 1100 /1110 Fall 2017
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23. How many liters of pure oxygen gas, measured at 45.2 C and 104.0 kPa, are required for the complete
combustion of 5.60 L of acetaldehyde gas (C2H4O), measured under the same conditions of temperature and
pressure?
A. 4.93 L
B. 12.3 L
C. 14.0 L
D. 14.8 L
E. 16.8 L

24. A sample of hydrogen gas was collected by displacement of water in a large gas buret. The total pressure in the
buret was measured as 764.2 torr, the temperature was 23.0 °C, and the buret contained 511 mL of the collected
gas. How much hydrogen was collected? (At 23.0 °C, the vapor pressure of water is 21.1 torr.)
A. 0.0191 mol
B. 0.0206 mol
C. 0.0211 mol
D. 0.0215 mol
E. 0.0217 mol

25. At what pressure will 1.00 mole of CH4 be in a 10.0-L container at 298 K assuming CH4 is a REAL GAS? (The
van der Waals constants for CH4 are a = 2.253 L2 atm mol-2, b = 0.04278 L mol-1.)
A. 0.440 atm
B. 2.43 atm
C. 2.28 atm
D. 2.51 atm
E. 24.5 atm

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