FIITJEE

ALL INDIA TEST SERIES

CONCEPT RECAPITULATION TEST – II
JEE (Advanced)-2019
PAPER – 2

ANSWERS, HINTS & SOLUTIONS

Physics PART – I

SECTION – A
1. ABCD
Sol. Charge on capacitor at time t is
q  Q0 cos t
1
Where  
LC

At t  ,q  0
2

 t LC
2
By conservation of energy
Q20 1 2
 Limax
2C 2
Q
 imax  0
LC

2. ACD
Sol. Apply Gauss law and property of conductor.

3. AD
GM
Sol. V [3R2  r 2 ], inside the earth.
2R3

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AITS-CRT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 2

4. ABCD
Sol. Let elongation in spring A, B and C be x1, x2 and x3 respectively.
Considering spring forces and constraint relations
x2 = 4x3 …(i)
x2 = 2x1 …(ii)
and x1 + 2x2 + x3 = x …(iii)
2
  4 1
 x1    x ; x 2    x ; x 3    x
 11   11   11 
 x
Also, F = 2K  
 11 
11m
 T  2
2k

5. AB
Sol. For microwaves,
c 3  108
  = 300 m.
f 106
x = d sin 
2 2
= d sin  = (150 sin ) =  sin 
 300
  sin  
I  I0 cos2  
 2 

6. ABC
2 2 2 2
Sol. T=  ; R= (1)2  (1)2 T =
10 5 5
2

H=
 2 
1
2g 10

7. C
Sol. Optical path difference at any point P on the screen, (P) = S2P–S1P – ( – 1)t and the

intensity on the screen, at point P = 4Io × cos2  P .


8. A
Sol. (A) A  B : V , P constant  T, U and W is –ve, Q < 0, U < 0
(B) B  C : V is same, P  T , U, Q < 0, U < 0
No work is done.
(C) C  D : V   T, U > 0, Q > 0, W > 0
(D) D  A : V decrease so W < 0
 TD = T A  U = 0
and then Q < 0

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 3 AITS-CRT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/19

9. B
12.5  12.3  11.8  12.4  12.2  12.6
Sol. Mean value  = 12.3
6
x1  .......  x 6
Mean absolute error =
6
Mean absolute error
Relative error =
Mean value
10. D
Sol. According to Lenz’s law induced current flows in such a way that it is opposing the
change in magnetic flux.

SECTION – D

11. 00028.00
2m1m2 g 2  2  5  9.8
Sol. T=  = 28 N
m1  m2 7
2kg
5kg

12. 00000.10
1 1 1
Sol. Given, mv 2  mu (1  0.19)  mu2 (0.81)
2 2 2
 v = 0.9 u
v
  0.10
u

13. 00000.09
Sol.  = vB = 3 × 106 × 10 × 3 × 10–9 = 9 × 10–2  0.09 V

14. 00000.23
velocity in air
Sol. 
velocity in medium

15. 00001.00
Sol. The shape of water layer between the two plates T
is shown in the figure.
Thickness d of the film = 0.12 mm = 0.012 cm. d
2R
d
Radius R of cylindrical face  .
2
T
F = T(2l) = P  l  2R 
T
P
R
T 2T
Pressure difference across the cylindrical surface   .
R d

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AITS-CRT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 4

Area of each plate wetted by water = A.

Force F required to separate the two plates is given by
2T 2  75  8
F = pressure difference  area  A  1N
d 0.012

16. 00008.00
4 1 2 2
Sol. 
3 4

17. 00000.00
 
Sol. dw  E.dr  0

18. 00004.00
2 2
2 R R R  R
R (O)      ( )     
Sol. Xcm = 2 2 2  2
2 2
2 R R
R      ( )  
2 2

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 5 AITS-CRT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/19

Chemistry PART – II

SECTION – A

19. ABD
Sol. O2 contains unpaired electron in -antibonding M.O and N2 in 2p orbital N22 contains
unpaired electron in -antibonding M.OS.

20. ABC
Sol. Rate = k[X][Y]0  2  10-8 = k[0.1] [0.1]0  k = 2  10–7s–1.

21. ABD
Sol. When Cl is directly attached to benzene, +R effect of chlorine is observed. Which
increases the bond order of C – Cl bond.

22. BCD
Sol. Elimination takes place in option(A).

23. AC
Sol. Azeotropic mixture has fixed composition.

24. ACD
Sol.  
a  2 rNa  rCl  2  95  181  552pm

25. B

Sol. 2LiOH   Li2O  H2O

26. C
Sol. In E2 mechanism, loss of Hydrogen takes place from that carbon atoms which are
adjacent to the carbon atoms that hold chlorine. Carbocations are formed in E1
mechanism.

27. D
Sol. H2O/H


 CH3 COOH  NH4 H O
CH3CO 2 O   2 CH3COOH
2

CH3CONH2

H2 O/OH
  CH3 COO   NH3

28. A
Sol. Fact based

SECTION – D

29. 00400.00
Sol. K P1  pSO2  pSO3  900

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AITS-CRT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 6

pSO2  pSO3  30 cm of Hg
p2SO3 30
K P2  2
  25  10 4
p SO2  p O2 30  pO2
1
pO2   400 cm of Hg
25  104

30. 00208.30
Sol. Ksp = 4s3 = 4  10–3
 s = 10-1 = 0.1 mol L–1
In 10 L  1 mole dissolves
Mass of 1 mole = 208.3 g

31. 00138.00
Sol. P = K2CO3, Q = O2, R = KOH, S = H2O2. Heaviest product is K2CO3.

32. 00157.00
Sol. Cl

P = CH3 - CH - CH3

33. 00175.50
Sol. The product is Cl  CH2  CH  CH2COCl
Cl
34. 00226.50
Sol. The complex is [Cr(NH3)4Cl2]Cl.

35. 95735.71
V2 1/ 10
Sol. W = -2.303nRT log = -2.303  1  8.314  5000  log = 95735.71
V1 1

36. 00390.55

Sol.  0
CH COOH 
 0
m Ca  CH3 COO 2  2 m0 HCl   m0 CaCl2 
m 3
2
200.8  2  425.95   271.6
  390.55
2

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 7 AITS-CRT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/19

Mathematics PART – III

SECTION – A
37. ACD
 2 4 8 
Sol. tan  2 tan  4 tan  8 cot  cot tan
7 7 7 7 7

tan   2 tan 2  4 tan 4  8 cot 8  cot  [ when   ]
7
1  cos 2  
(a) cos ec 2  cot 2   cot   cot (where   )
sin 2 7 7
  
(b) tan  cot  2cot
14 14 7
2  
sin 2 sin cos
(c) 7  7 7  cot 
2  7
1  cos 2 sin2
7 7
 2    
 1  cos   cos 2cos2  cos

 7  7 7 7
(d)   cot
      7
2 sin cos  sin 2 sin  cos  1
7 7 7 7 7 

38. ABCD
sec x tan x cos x sin x
Sol. (a) We have f  x    , g x  
cos x cot x sec x cos ec x
k
Clearly both f  x  and g  x  are identical functions as x  k I .
2
2
(b) As x 2  4x  5   x  2   1  0
Hence f  x   1 x  R .
 
Also cos2 x  sin2  x    0
 2
Hence g  x   1 x  R g.
 f  x  and g  x  are identical.

ln x 2  3x  3 
(c) f  x   e
2
 3 3
As x 2  3x  3   x     0  x  R .
 2 4
2
Hence f  x   x  3x  3  x  R
 f  x  k is identical to g  x 
sin x cos x 2 cos2 x
(d) We have f  x    , g x 
sec x cos ec x cot x
k
Clearly both f  x  and g  x  are identical functions as x  k I .
2

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AITS-CRT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 8

39. AC
Sol. Differential coefficient of f  x  w.r.t. y
x 1 
sin1 x  2 at x  it is –2
x 2
 
f 0   2;f ' 0   2  
 f is not derivable at x = 0

x
–1 1 O 1 1
2 2
40. ABC
/ 2

 cos   sin x  dx
2
Sol. I1 
0
b b

 f  x  dx   f a  b  x  dx
a a
/ 2

 cos   cos x  dx
2
I1 
0
On adding
/ 2

 cos   sin x   cos   cos x  dx

2 2
2I1 
0
/ 2
  
  2 cos  2  .cos  2 cos 2x  dx  0
0

I1  0 ……..(i)
 /2  /2
 
I2   cos   1  cos 2x  dx    cos   cos 2x  dx 
0  0 

1
 cos   cos t  dt [Put 2x  t ]
2 0
 /2
2
 cos   cos t  dt  I3
2 0
 I2  I3  0 …….(ii)
Hence, I1  I2  I3  0

41. BCD
Sol. Domain is x  R
2
Also f  x   cos  tan1  sin    
 
where cot   x
2
   1  
 cos  tan 1    
 2
   1 x   

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 9 AITS-CRT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/19

 1  x2 
2 y
2 1
  cos   where tan    
1  x2  2  x 2  (0, 1)

1  x2 1
g x  2
 1
2x 2  x2
1  2x
(0, 1/2)
Range is  , 1 ; f '  x   2
 2  
2  x2  x
Hence f '  0   0 0
Also lim f  x   1
x 
Hence (B), (C), (D)

42. ABC
sin x
Sol. f x 
x

43. A
Sol. (P) Let S  cos   cos 2  cos 4  .....  cos10
2 sin .S  2 sin  cos   cos 2  .....  cos10
2 sin 6 cos 5 sinn cosm
S 
2 sin  sin 
 n  6 and m  5

4
(Q) E  9x sin x 
x sin x
[Note that x sin x  0 in  0,   ]
2
 2 
E   3 x sin x    12
 x sin x 

 Emin  12 which occurs when 3x sin x  2
2
 x sin x 
3

[Note that x sin x is continuous at x = 0 and attains the value which is greater
2
2  2
than at x  , hence it must take the in  0,   ]
3 2 3

 2 1
(R) f  x   2   sin x  2   
 2
 M  19 and m  3
M  8 19  8
Hence  9
m 3

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AITS-CRT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 10

3
(S) tan9 
4
3 4
sin9  ; cos 9 
5 5
3 4
Now given 
sin3 cos 3

2
 3 cos 3  4 sin 3 
2 sin 3 cos 3
3 4 
10  cos   sin 3 
 5 5 

sin 6
 sin 9 3  cos 9 sin 3  sin  9  3 
 10    10  10
 sin 6  sin 6

44. B
f  3 cosh  4 sin h  2   f 1  0 
Sol. (P) lim  0 form 

h 0 f 3eh  5 sec h  4  f 2
    
 3 sin h  4 cosh  f '  3 cos h  4 sinh  2  4 f ' 1 4  6
 lim    4
h 0
3e h
 5 sec h tan h f ' 3e  5 sec h  4  h
 3 f ' 2 3  2
f  2a  h   f  2a 
(Q) f '  2a    lim  4 (Given)
h0 h
f  2a  h   f  2a 
Now f '  2a    lim
h 0 h
f  2a  h   f  2a 
 lim ( f is even function)
h 0 h
f  2a  h   f  2a 
 lim
h 0 h
 f ' 2a   4  
 f  x   f  4a  x   x   2a, 4a 
Put x  2a  h, we get f  2a  h   f  2a  h 

(R) We have F  x   f e x  
 F'x  e x
f ' e  x

And G  x   e 
f x

G '  x   e  f '  x 
f x

f ' 0  e 
f 0
G'  0 
 
F ' 0  e0 f ' e0  
f 0 
f ' 0 e 3e3
  3
f ' 1 e3

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 11 AITS-CRT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/19

(S)  Number of points of non – differentiability =2 y  2x  1 y = x

(0, 1)

(1, 1)

y = cos x

x
O (0, 0) x=x1 x=1 
2
f(x) is non – derivable at
2 points x=x1 and x=1

45. C
Sol. f  x   ln x  kx 2  0
ln x
k 
x2
n x
Consider g  x   as shown
x2
y

1
y
2e
x
1 e
 e –1

46. D
2 y
Sol. (P) f  x   e sgn x  e x
When x0 f 0  2
2
When x0 f  x   e  ex
1 2
When x0  ex
f  x  (0, 1+e)
e
(0, 2)
Hence, f  x  is many – one and neither odd nor
even.  1
 0, 1  
 e

(0, 0) x
O

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AITS-CRT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 12

(Q) Df :1  x 2  0
x 2  1  0  x   1, 1
 x 4  when x   1,1 is equal to 0.
1
 f x 
1  x2
Hence, f  x  f is even and many – one.
 x 4  x 2  1
(R) f  x   x 4  1   2 
 x  x 1 
 x 4  1  x2  x  1

 x 4  x2  x  2  x x3  x  1  2 
Hence, f  x  is many – one and neither odd nor even.
(S) f  x   x  3x 3  5x 5  .....  101x101
Clearly f  x  is an odd function.
Now, f '  x   0  x  R
 f 'x  0 x R
Hence, f  x  f is one – one function

SECTION – D

47. 00000.25
Sol. Put x sin y  y cos y  t and after rearrangement put sin y  z

48. 00000.50
Sol. Above sequence is in A.P.
x1  1 x 2  3 x  2009
  ..................... 1005 k
x1 x2 x1005

k 
 x1  1   x 2  3   ......  x1005  2009 
x1  x 2 .............x1005
2
1005  x 21  41
k  1 
2010 x 21
82
 x 21 
1005

49. 00007.56
Sol. Let   d, ,   d are roots
 3  a (1)
3 2  d2  b (2)
1
 
  2  d2  (3)
9

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 13 AITS-CRT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/19

a2
From (1) and (2), d2  b
3
Put d2 in (3) to get
2a3  9ab  1  4

50. 00000.22
Sol. Let number of marbles are
Red = a, White = b, Blue = c, Green = d
C4 b  C3  b  c   C4  abcd
a a a

   
T T T T
abc  d
where T  C4
a3 a2 a 1
solving, b  ,c ,d
4 3 2
N is max when a = 95
 Nmax  196

51. 00000.50
 6 27  1
Sol. 9A 2  6A  I   B
 10 1
2
  3A  I  81
 3A  I  9 (1)
a b 
Let A   
c d 
 g  ad  bc   18 or 0 (using equation 1)
Since A  0
 ad  bc  2  A  2

52. 00000.30
100
 k  100
Sol. Let S     Ck
k 0  k  1 



100  k  1  1
 100 C   100 100  100 100 Ck
k  Ck   
k 0  k  1  k 0  k 0 k  1
1 100  101 100 
 2100   Ck 
101 k  0  k  1 
100
1
 2100   101
Ck 1
101 k  0
 2101  1  101 2100  2101  1 99 2
2100    
100
1  

 101  101 101



a 2100  b (Given)
c

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AITS-CRT-II (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 14

So, a  99, b  1, c  101

Hence,  a  b  c least  99  1  101  201 .

53. 00000.14
 9 7 
Sol. Let l  lim   ……(i)
x 1 1  x

9
1  x7 
1  9x 9 7x 7 
Put x  , we get l  lim    ………(ii)
y x 1 1  x 9 1  x7 

 On adding equation (i) and (ii), we get
2l  9  7  2
l1
tan x  sin x
Common ratio  lim 3
x 0 ln 1  x 

tan x  sin x
 lim 3
x 0
3 ln 1  x  
x  
 x 
tan x 1  cos x  1
 lim 2

x 0 x 2

54. 00000.25
p pq
Sol. Since f is injective Sp 
r qr
 pq  pr  rp  rq
 2pr  q p  r  ………..(i)
q r
Also,   p,r,q are in G.P.
r p
So, let r  pa, q  pa2 , where a is the common ratio of G.P.
Therefore from equation (i), we get
2.p.pa  pa 2  p  pa 
 2  a2  a
 a2  a  2  0
  a  2  a  1  0
 a  2,1
So,  p,  2p, 4p  and (p, p, p)
(But common ratio = a= 1, is not possible as p, q, r are non – zero distinct quantities.)
Also, p  q  r  6 [As g  x   px 2  qx  r passes through M (1, 6)]
 p  4p  2p  6
 p2
Hence q  4p  4  2   8

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