ALL INDIA TEST SERIES

OPEN TEST

JEE (Advanced)-2021
PAPER –2
TEST DATE: 24-01-2021

ANSWERS, HINTS & SOLUTIONS

Physics PART – I

SECTION – A

1. A, B, C
F dv
Sol.  .
A dy

2. B, C
Sol. mg  FB  6rv 
gr 2
 v 
9
1
mgH FBH +Wf = mv 2  0
2

3. A, C, D
3v
Sol. f P
4
3v 3  330
 
4f 4  550 x=0 x=
9
 m  45cm
20
The amplitude of pressure variation in the pipe is
a  | P0 sinkx |

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AITS-OT (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021 2

 3 
a  P0 sin  x
 2 
at x = /2
 3  P0
a  P0 sin   
 4  2
The maximum pressure at the middle of the pipe
 P 
  P0  0 
 2 
The maximum pressure at the closed end of the pipe = P0  P0 

4. A, B
dV 2
Sol.  
VdT T
dv dT
  2
V T
 V  kT 2
i.e. PV1/ 2  constant
R
C = CV +  C  CV  2R
 1
1  
 2

5. B, C, D
4m m
Sol. T  2  4
g K
2 A  g
g gT 2 4mg
A  
2
4 2 K
4mg
Equilibrium compression X0 
K

6. B, C, D
hc
Sol. eV0  

 1240 
  1.5  eV
 400 
 V0  1.6volt
1240
For B, V0   2  1.1 volt
400
Energy is equally distributed through out spectrum but for B,  th  620 nm for photo electric
effect in metal B range of spectrum is 400 nm to 620 nm.

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 3 AITS-OT (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021

SECTION – B

7. 3
Sol. =i+e–A
30 = 60 + e  30 30
 e = 0  ray is perpendicular on the second surface of
prism, so that r=30 60
o
30
sin60
  3
sin30

8. 6
Sol. Angular velocity about centre of mass is same.
So that Where rA  rB  d
v A  rA m r m r A A B B
v B  rB d
1  rA 
mB v B2 7
k e B 
 2 6d
k e A  1  rB 
mA v 2A 7
2
2
 6d 

2 MS  7 
 6
12 MS  d 2
7 
 

9. 5
 2BA
Sol. eav = 
t t
eav t
B
2A
20  103  0.2
= 5
2  4  10 4

10. 9
Sol. F - N = ma B

1 N
80 -  6g = ma ma
3 1
Ma =60 C
A  0
 mg
  F
ma cos   mg sin   0
2 2
 tan  =1 N A
 =45

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AITS-OT (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021 4

11. 5
Sol. The equation of process A  B is dT
Sign scheme for
 2P  dV
P    0  V  5P0
 V0  +ve ve
 2P0  2  5P0  V0 5 2V0
T   V   V V0
 nRV0   nR  4
dT  4P0  5P0
  V 
dV  nRV0  nR
pdV Sign scheme for C
Now, C  CV 
ndT +ve ve +ve
3R  5P V  2P0 V 
C  R 0 0  V0 5 2V0
2  5P0 V0  4P0 V  V0 25V0
4
R  25V0  16V  16
C  
2  5V0  4V 
Hence the heat is absorbed by the gas
25
from V0 to V0
16
Hence the process changes from
endothermic to exothermic at the
 25V0 
volume  
 16 

12. 4
Sol. Q = Q0 cos t
i = Q0  sin t
Q0 Q0  1  
= .sin   8L0 r 
n 0Lr L.8  0 r  L.8  r 4 
 0 
Q0 1
= 
L.80r 2
n=4

SECTION – C

13. 00006.25
Sol. Vsep = e Vapp V2
V1 – V2 = e(V1 +V2)
V1
4
V0  1  e   V2 1  e  V0
5
V0 1  e  5 37
   6.25
V2 1 e 4

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 5 AITS-OT (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021

14. 00014.14
Sol.  ax = 0
a = g sin 30
 y 
v  u  at
 x
v  5iˆ  (5ˆj)1
 5iˆ  5ˆj  m / s
v2 52  52
R   14.14m
an 
5/ 2  y 30

15. 00001.73
Sol. induced emf × P
e  Bv × × ×
  PQ  2 10  5 2 2
  10 3  × × × ×
B
e = 1.73 volt × C
V
× ×

× x × ×
× × ×

16. 00003.25
Sol. When it is at 45 from horizontal N

  m2 2 
mg cos 45    m  N
4  12 16 
45
12g

7 2
24g
Conservation of energy gives : 2  mg
7 2
 
N  mgsin 45  m  2 
 4
  4mg
mg cos 45  N = m     N 
 4  7 2
By solving   3.25

17. 00002.50
Sol. COM V1
4  2.5 = 4 VC + 4 V1
 Vc + V1 = 2.5
COAM VC
1 1 1 
4  2.5  = 4  V1  + [2  2 ( )2]
2 2 2

 2.5 = V1 +
2
Vsep = e Vapp

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AITS-OT (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021 6

1 1
VC +   V1   2.5
2 2
 2.5
 VC   V1 
2 2
2.5 2.5
By solving equation,   2.5 rad / s, VC  m / s, V1  m/s
2 2
Loss of energy = K e i  K e f   3.12 J

18. 00038.46
Sol. V = 2.5  60 = 150 volt
I  IR2  IL2  15.25
V 150
Z   38.46
I 15.25

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 7 AITS-OT (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021

Chemistry PART – II

SECTION – A
19. A, B, C
Sol. (A) K 2  Zn  ClBr  CNNO2   has four constitutional isomers and each one is chiral.
(B) 2+ has one chiral centre and hence it exists as a pair of enantiomer.
Me
N N
Pt
H
N N
3
(C) Co  ox F 2  Cl2   it has three geometrical isomers and one of them is chiral. So, total
stereoisomers are 4.
(D) K 3 FeF6  is a colourless complex

20. B, D
Sol. (A) Increasing order of stability of conformers of cyclohexane is
chair > twist boat > boat > half-chair
(B) Gauche conformer of 2-fluoroethanol is more stable due to intramolecular hydrogen
bonding than its anti conformer.
(C) OH O OH NH2 CH O
NaOBr OH
CH C NH2  CH N C O  

Hoffmann Bromamide 

Major 
(D) During ozonolysis, cross-ozonides are also formed.
21. B, C, D
Sol. (A)
H3C CHO
H3C CH3
 


CH3 CHO
Major product 
(B) O O
O CH3
C CuLi
 2
dil. OH

Retro aldol


O H

Major product 
(C) O O O

i OH  dilute 

  H O
 
3

 2
 CO

CH2 C C OEt COOH

EtO
O
O C C O O Major product 
Et
O OEt

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AITS-OT (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021 8

(D) Br
Br Br
C
Br

N N N
H H

Mg / Ether

N
HO O N
MgBr
Conc. H2 SO4

Major product 

22. A, B, C, D
Sol. (A) H3PO4  PO34  H2PO4  HPO24
Initial m. mol 10 10 0 0
m.mol. after neutralization 0 0 10 10
So, pH  pK a  8 Buffer 
2
(B) H3PO4  H PO 
2

4 PO 3
4

10  10  10 

H3PO4  PO34  H2PO4  HPO24
Initial m. mol 10 10 10 0
After neutralization 0 0 20 10
Again it is a buffer
HPO24   10
pH  pK a  log  8  log  7.70
2 H2PO2 

20
(C) H3PO4  PO  3
4 H PO 
2
2
4 HCl
10  10  10  10 
 PO34  HCl  HPO24  Cl
10 10 0 0
0 0 10 10
2 
 H3PO4  HPO 4 
 2H2PO 4

10 10 10
0 0 30
pK a  pK a38
So, pH  1
 5.5
2

2 2
(D) pH will remain same as in option (B).

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 9 AITS-OT (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021

23. A, C, D
Sol. Formula of ideal solid ‘x’ = AB3
Tf  i  k f  m
0.60  1000
0.2976  1.6  1.86 
m x  100
 mx  60 g / mole
a o
rA 3  rB  a  2A
2

60  1
 Density (d)   12.5 g / cm3
6  10  8  1024
23

0.60
Total number of unit cells = Total number of molecules of AB3   6  1023  6  1021
60
 If there are 12% cation vacancies it means formula of defected solid would be A 0.88B3.00
36
So, %A 4  ions   100  40.9%
88

24. A, C
Sol. Gas is undergoing free expansion, so, process is irreversible adiabatic as well as isothermal.
V
Ssyst  nRn 2
V1
2.73Vi
 nRn
Vi
= nR
PV
Ssyst  i i

Ti

SECTION – B

25. 0
Sol. Species Geometry Hybridization d-orbitals involved
I.  VO  acac 2  Square pyramidal dsp3 dx2  y 2
II. Fe  CO 5  Trigonal bi-pyramidal dsp3 dz2
III. PtCl4  Square planar dx2  y 2
2
dsp2
IV. K 4 Fe  CN6  Octahedral d2 sp3 d x 2  y 2 , dz 2
V. IF7  Pentagonal bi- sp3 d3 dx2  y2 , dz2 and dxy
pyramidal
So, x = 3, y = 4 and z = 1

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AITS-OT (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021 10

26. 8
Sol. OAc

H O
OAc OAc
H

OAc O
OAc H
O
H H

OAc H H OAc
H H

H OAc

27. 5
Sol. RH2  Ca2  
 RCa  2H
3  10 4 M
3
So, Ca 2    10 4 M
2
3
So, mass of CaCO3 present in 1 L hard water   10 4  100  1.5  10 2 g
2
1.5  102
So, degree of hardness of water   106  10 g
1500
So, degree of hardness = 10 ppm.
So, 2x = 10 and x = 5.

28. 5
Sol. Only, reaction II, IV, V, VI, VII will give tert-butyl benzene as the major product.

29. 6
Sol. Only KNO3 , Ag2 O, KClO3 , HgO, NaNO3 and H2O2 will decompose on heating to give O2 as the
only gaseous product.

30. 9
Sol. O
C2H5 CH3
H5C6 S N ; C H NH ; C H  CH ; C H  CH  C  C  H;
6 5 2 6 5 3 6 5
O C2H5
C 6 H5

; C6H5  NO2 are insoluble in aq. NaOH and rest are soluble.
OH

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 11 AITS-OT (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021

SECTION – C

31. 00001.48
11a
Sol. The 4th nearest distance in CsCl structure  d1  
2
5a
and the 5th nearest distance in NaCl structure  d2  
2
d1 11
  2.2  1.48
d2 5

32. 00004.60
Sol. 

Mg NH4 PO4   2  3
 Mg  NH4  PO 4
K sp  Mg2   NH24  PO34  … (1)
Now,
H3PO4  H2O   
 H2PO4  H3 O ;

pK a1  2.2


H2PO4  H2O  2 
 HPO4  H3 O ; pK a2  7.2


and HPO24  H2O  3 
 PO4  H3 O ; pK a3  12.4
from the above data, it is very much clear that at pH = 10, the main component is HPO24 .
Let, the solubility of Mg NH4  PO4 be ‘S’ mol dm-3, then
S  Mg2    HPO42  … (2)
PO34   H3 O   K a3  HPO 24  
K a3   3
or PO 4   … (3)
HPO24   H3 O  
So, from Eq. (1), (2) and (3), we get
S
K sp  NH4   S  K a 
3 H3 O 
1/2
NH4   K a  S 2  K sp  H3 O  
S    
K sp  3

H3 O    NH4  K a 
   3 
1
So, p  S   pK sp  pH  log10 NH4   pK a 
 
2 3 

1
p S  12.6  10  1  12.4 
2
p(S) = 4.60

33. 00001.33
Sol. In solid truncated cube, each vertex becomes a triangular face and each square face becomes an
octagonal face.

34. 00004.50
Sol. y = 0, x = 9

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AITS-OT (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021 12

35. 00007.00
Sol.
O
||
H3O conc. H SO
CH2  C  CH2  CH  C  CH3 

2 4

 X
 Y
36. 00006.75
Sol. Wt. of pay load  80  103 g
nRT
80  103  0  100  x   1.25  x
P
 x  26.8  27
So, minimum number of balloon required is 27.

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 13 AITS-OT (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021

Mathematics PART – III

SECTION – A

37. A, B, C, D
Sol. 1, 2, 3, ..... n are in H.P.
2 1 1
So,   for k = 2, 3, ....., n – 1
k k 1 k 1

38. B, C, D
Sol. bn 1  an  bn  c n
cn 1  bn1
an 1  bn  cn
 bn1  an1  an
an1  2  an  an1 
r 2  2r  2  0
2 48
r  1 3
2

   
n n
an  A 1  3  B 1 3 put a1 = 1, a2 = 2
1 1
A and B  
2 3 2 3

39. A, C
Sol. (x2 – 3x)2 + x2 – 3x + a = 0

40. A, B, C
n  n 
Sol.  A    f i f r   f r  f  j    f r 
2
ij
2
 A ij  A2 = (tr(A))A

r 1  r 1 

41. A, B
Sol. 12  OI12  R2  2r1R

42. A, B, C, D
7
C1  6! 4 7
Sol. (A)  C4  2  7 C7
3! 3! 2!

SECTION – B

43. 5
Sol. The equation of circle will be (x – 1)(x – 8) + y2 + y = 0 will touch y = x
 = 17, 1 as ordinate of P is positive so  = 1
x2 + y2 – 9x + y + 8 = 0
81 1 50 5
r  8  
4 4 2 2

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AITS-OT (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021 14

44. 0
x
t10  1
Sol. Let h  x   t
0
10 2
 t 1
dt  x 2  x

x10  1 x2
h  x   10 2
 2x  1 =
 2x  0
x  x 1 x  x2  1 10

 h(x) decreases in (0, ), h(0) = 0 so no positive real root of the equation

45. 2
1  /2
Sol. Put x = sin , then  0
f  x  dx   f  sin   cos d
0
..... (1)

1  /2
Put x = cos , 
0
f  x  dx   f  cos  sin d
0
..... (2)

1  /2 1

Adding equation (1) and (2), we get 2 f  x  dx  
0

0
1 dx ,  f  x  dx  4
0

46. 3
1 1
Sol. 
0
f   x  dx  f 1  f  0   1 =  1  x
0
2 1/ 4 1  x 2 1/ 4 f   x  dx (C.S. inequality)

1 1
1 2 1 2
 
  1  x 2 
1/2
dx 
  
 1  x 2 1/2 f   x 2 dx

 

0  0 
1
1
  1  x
0
2 1/2  f   x  2 dx 
ln 1  2 

47. 0
 1
 1  1  x 
tan1  x   tan  3 
1
Sol.   tan
 3  
 2 3 
 1
6  6 x  6 
  tan1  x 
 6    3
 2 3 
 1
6 x 
1 tan1  x2
 
 2 3 
32 2 32 2 32 2
1 1
 
1
x 22
dx  
1
f   x  dx  
1
2
x 1
dx

3 2 2
1 x 
tan1  f  3  2 3   tan1  3  2 2  
2 2 1 4

48. 1
14
r
Sol. sin 15  4   214  sin  4  15 
r 0

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 15 AITS-OT (Paper-2)-PCM(Sol.)-JEE(Advanced)/2021

SECTION – C

49. 00000.25
Sol. N is mid-point of OH

IH2 + IO2 = 2ON2 + 2IN2 I O

N
H

50. 00125.00
Sol. a3 cos 3B + 3a2b cos(A – 2B) + 3ab2 cos(2A – B) + b3 cos(2A) = Real part of (ae–iB + beiA)3
 a b 
= ((a cos B + b cos A) + i(a sin B – b sin A))3 = c 3 .   
 sin A sinB 

51. 00007.20
Sol. G(4, 3.2) G(4, 4)
Tangents of A and B will intersect at corresponding directrix. So A
E and F lies on directrix x = 4. ES is perpendicular to AB where E(4, 2)
P

S is focal chord, also FSG is also S
2 F(4, –2)
B

52. 00017.00
Sol.  z  2i 4  1  i z2 z1
 2k /4 
i 
z  2i   2  e 
1/4 4 
2i
Put k = 0, 1, 2, 3
4 1 1 17


2
Minimum value of z  zi = 4  2 8  2 8 28 z3 z1
i1

53. 00000.50
2 4 6 8
 1  1  1 1 1
Sol. PA     2    4    8    ..... 
 
2  
2  
2  
2 2

54. 00005.00
 k k2 
n  2
 3  1
1 5
Sol. lim
n
 

k 1 
n
k k
n
2


=
2 
 x  x 2  dx =
12
 1  2  3  1 
0
 n n 

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