Ion Exchange Softening
Ion Exchange Softening
1|Page
A variety of techniques are marketed to manage hardness minerals. This NebGuide
focuses on the ion exchange softening process which remains the most commonly
used technique for managing hard water in residential settings.
The ion exchange water softening process can remove nearly all calcium and
magnesium from source water. Softeners may also remove as much as 5-10 ppm
(parts per million; ppm is equal to milligrams per liter, or mg/L) of iron and
manganese. Consumers can check the water softener’s manufacturer’s rating for
removal of these contaminants. Concentrations of iron and manganese greater than the
softener’s removal rating may require pretreatment such as greensand filters (see
NebGuide G1280 Drinking Water: Iron and Manganese) to increase the lifespan of
the softener.
Water Testing
Regardless of which water treatment system is considered, the water first should be
tested to determine which contaminants are present. Public water systems routinely
are tested for contaminants. Water utilities are required to publish Consumer
Confidence Reports (CCRs), which inform consumers on the source of the water,
concentration of contaminants present, potential health effects of those contaminants,
and methods of treatment used by the utility. Depending on the population served by
the water utility, CCRs may be mailed, published in newspapers, or posted on the
Internet, but a copy of it can be obtained by contacting the local water utility. Public
supplies must conform to federal standards established by the Safe Drinking Water
Act. If contaminants exceed the Maximum Contaminant Level (MCL), the water must
be treated by the water supplier to correct the problem and/or another source of
potable water must be provided.
2|Page
In contrast, monitoring private water systems is the consumer’s responsibility.
Therefore, contamination is more likely to go undetected in a private water supply.
Knowing which contaminants may be present should guide the testing, since it’s not
economically feasible to test for all possible contaminants. Know which contaminants
are present, their concentrations, and reasons for removal (i.e., health risks, tastes or
odors, etc.) prior to selecting treatment methods or equipment. Refer to NebGuide
G907 Drinking Water: Testing for Quality for testing information.
Testing laboratories, some city-county health departments, and some water treatment
equipment dealers can test water for hardness. In addition, a variety of test kits and
dip strips are available for hardness testing outside of a laboratory environment. When
using these tests, users should understand the nature of the test and the accuracy of the
test results. While some may provide accurate and reliable measurements from which
decisions can be made, others may not. Greater reliability and accuracy can be
expected with laboratory testing. In situations where considerable investment is
necessary to correct a problem, verification of the severity of the problem by an
approved laboratory is advisable.
Water hardness is often expressed as grains of hardness per gallon of water (gpg) or
milligrams of hardness per liter of water (mg/L). Table I, adapted from the Water
Quality Association (WQA), shows hardness classifications. Hardness ions are
typically combined with sulfate, chloride, carbonate, or bicarbonate ions. For
consistency, concentrations are generally converted to the equivalent concentration as
calcium carbonate (CaCO3) and expressed in terms of hardness as calcium carbonate.
3|Page
Treatment Principles
Household water softeners are ion exchange devices. Ion exchange involves removing
the hardness ions calcium and magnesium and replacing them with non-hardness ions,
typically sodium supplied by dissolved sodium chloride salt, or brine. The softener
contains a microporous exchange resin, usually sulfonated polystyrene beads that are
supersaturated with sodium to cover the bead surfaces. As water passes through this
resin bed, calcium and magnesium ions attach to the resin beads and the loosely held
sodium is released from the resin into the water. The softening process is illustrated
in Figure 1.
After softening a large quantity of hard water the beads become saturated with
calcium and magnesium ions. When this occurs, the exchange resin must be
regenerated, or recharged. To regenerate, the ion exchange resin is flushed with a salt
brine solution (Figure 1). The sodium ions in the salt brine solution are exchanged
with the calcium and magnesium ions on the resin and excess calcium and magnesium
is flushed out with wastewater.
4|Page
Frequency of the regeneration or recharge cycle depends on the hardness of the water,
the amount of water used, size of the softener, and capacity of the resins. Sixty to 120
minutes generally are required for the brine to pass through the unit and flush the tank
before soft water is available again.
Through the softening process, sodium is added to water at a rate of about 8 mg/L for
each grain per gallon (gpg) of hardness. After treatment, water that was 10 gpg of
hardness will have about 80 mg/L of sodium. This means that for every liter (0.26
gallon) of water intake, there would be 80 mg of sodium intake. People on restricted
sodium diets due to health reasons should account for increased intake through
softened water and consult their physician. Drinking and cooking with softened water
is often avoided by having a cold water line to the kitchen tap that bypasses the water
softener. This provides hard water for drinking, cooking and other uses.
It is not recommended to repeatedly use softened water for plants, lawns or gardens
due to the sodium content.
Equipment
Ion exchange water softeners can be classified as one of four different types:
5|Page
All types of softeners must be correctly installed and monitored for proper operation.
If an automatic or DIR unit appears to use more salt than expected or water is not
softened, have a service provider check the unit settings. The amount of salt used for
softening depends on the number of people in the household, daily water usage,
softener capacity, and water hardness. The appropriate size of water softener depends
on several factors including the water hardness level, daily water use and water flow
rate.
Types of Salt
There are different types of salt available for water softeners. The choice depends
upon the type of water softener and manufacturer design. Softeners are designed to
use specific types of salt so it is important to follow manufacturer’s recommendations
regarding the salt type.
Compressed salt has undergone an evaporation and compression process that yields
small particles referred to as pellets, nuggets, or beads. A variety of grades and
formulations are available on the market. Products designed to manage iron (rust) may
contain food-grade additives, such as citric acid. Compressed salt is sized according to
manufacturer’s specifications. The majority of softeners are designed for this type of
salt.
Salt blocks for use in some softener brine tanks look similar to those used for
livestock feeding. Blocks for livestock feeding, however, may contain additives
incompatible with water softener units. Block salt should be used only in those units
specifically designed for this form of salt. It should be high-grade evaporated salt
without additives.
Rock salt may have high levels of soluble or insoluble impurities. If the impurities are
calcium or magnesium salts, they may significantly reduce the effectiveness of the
regeneration process and plug valves. Rock salt is only an option if suggested by the
manufacturer and only those averaging less than 1 percent impurities should be used.
In certain situations, potassium chloride may be used for softener regeneration instead
of sodium chloride. Potassium chloride can be more costly and more difficult to
obtain than sodium chloride, however. Potassium chloride also adheres more strongly
to the resin. This can reduce the exchange efficiency compared to sodium chloride and
require more potassium chloride. Substituting potassium chloride for sodium chloride
may be appropriate if health or environmental reasons necessitate restricting sodium;
a water treatment professional should be consulted regarding this option.
Maintenance
6|Page
Maintenance of water softening equipment is somewhat dependent on the type of
softener. Some degree of monitoring or managing the regeneration process is
generally required. The softener must be kept regenerated to avoid hard water flowing
into pipes and appliances. Regeneration does place additional load on a septic system.
Approximately 50 gallons of water (roughly equal to that required for a load of
laundry using an older washing machine, or two loads using a newer high-efficiency
washing machine) is used to regenerate a water softener. Also, certain situations such
as high concentrations of iron or manganese in the water can affect the exchange
capacity of the resin. In this case the resin may eventually need to be cleaned or
replaced. A water treatment professional should be consulted for guidance on cleaning
or replacing the resin.
The brine tank requires periodic checking and cleaning. How frequently you clean it
depends on the type and amount of salt and characteristics of the water being treated.
Inspect the tank for scale build-up. The brine valve and float assembly, if used, should
also be cleaned and inspected at least once a year.
Excess iron (above 5 ppm) or hydrogen sulfide in the water can reduce the
effectiveness of the water softener. The water should be tested for these contaminants
and proper pre-softening equipment installed if required. NebGuides G1280 Drinking
Water: Iron and Manganese and G1275 Drinking Water: Sulfur (Sulfate and
Hydrogen Sulfide) discuss these contaminants. Sediment in the water can also reduce
the effectiveness of the softener. The NebGuide G1492 Drinking Water Treatment:
Sediment Filtration discusses options for sediment removal.
Selection Requirements
Federal, state, or local laws do not regulate water softening home systems. The
industry is self-regulated. The NSF (formerly the National Sanitation Foundation) and
the Water Quality Association (WQA) evaluate performance, construction,
advertising, and operation manual information. The NSF program establishes
performance standards that must be met for endorsement and certification. The WQA
program uses the same NSF standards and provides equivalent American National
Standards Institute (ANSI) accredited product certifications. WQA certified products
carry the Water Quality Association Gold Seal. Though these certifications and
7|Page
validations should not be the only criteria for choosing a water softening system, they
are helpful to ensure effectiveness of the system.
Summary
Drinking water treatment by water softening (ion exchange) is one option for the
homeowner in treating water problems. Calcium and magnesium ions in water
decrease the effectiveness of most cleaning tasks and can cause film and scale buildup
in and on plumbing and fixtures. Water softening is an effective method for reducing
the calcium and magnesium mineral ions from the water. It can also reduce iron and
manganese concentrations. Selection of an ion exchange water softening unit should
be based on water analysis and assessment of the individual homeowner’s needs and
situation. Regular maintenance of the unit is a critical factor in maintaining
effectiveness of the unit. NSF and the WQA test and certify products and this
certification can help guide selection.
Acknowledgment
9|Page
Contaminants removed by the water softening (ion exchange) process
The ion exchange water softening process can remove nearly all calcium and
magnesium from source water. Softeners may also remove as much as 5-10 ppm
(parts per million; ppm is equal to milligrams per liter, or mg/L) of iron and
manganese. Consumers can check the water softener’s manufacturer’s rating for
removal of these contaminants. Concentrations of iron and manganese greater than the
softener’s removal rating may require pretreatment such as greensand filters (see
NebGuide G1280 Drinking Water: Iron and Manganese) to increase the lifespan of
the softener.
Water Testing
Regardless of which water treatment system is considered, the water first should be
tested to determine which contaminants are present. Public water systems routinely
are tested for contaminants. Water utilities are required to publish Consumer
Confidence Reports (CCRs), which inform consumers on the source of the water,
concentration of contaminants present, potential health effects of those contaminants,
and methods of treatment used by the utility. Depending on the population served by
the water utility, CCRs may be mailed, published in newspapers, or posted on the
Internet, but a copy of it can be obtained by contacting the local water utility. Public
supplies must conform to federal standards established by the Safe Drinking Water
Act. If contaminants exceed the Maximum Contaminant Level (MCL), the water must
be treated by the water supplier to correct the problem and/or another source of
potable water must be provided.
Testing laboratories, some city-county health departments, and some water treatment
equipment dealers can test water for hardness. In addition, a variety of test kits and
dip strips are available for hardness testing outside of a laboratory environment. When
using these tests, users should understand the nature of the test and the accuracy of the
test results. While some may provide accurate and reliable measurements from which
decisions can be made, others may not. Greater reliability and accuracy can be
expected with laboratory testing. In situations where considerable investment is
necessary to correct a problem, verification of the severity of the problem by an
approved laboratory is advisable.
Water hardness is often expressed as grains of hardness per gallon of water (gpg) or
milligrams of hardness per liter of water (mg/L). Table I, adapted from the Water
Quality Association (WQA), shows hardness classifications. Hardness ions are
typically combined with sulfate, chloride, carbonate, or bicarbonate ions. For
consistency, concentrations are generally converted to the equivalent concentration as
calcium carbonate (CaCO3) and expressed in terms of hardness as calcium carbonate.
Treatment Principles
Household water softeners are ion exchange devices. Ion exchange involves removing
the hardness ions calcium and magnesium and replacing them with non-hardness ions,
typically sodium supplied by dissolved sodium chloride salt, or brine. The softener
11 | P a g e
contains a microporous exchange resin, usually sulfonated polystyrene beads that are
supersaturated with sodium to cover the bead surfaces. As water passes through this
resin bed, calcium and magnesium ions attach to the resin beads and the loosely held
sodium is released from the resin into the water. The softening process is illustrated
in Figure 1.
After softening a large quantity of hard water, the beads become saturated with
calcium and magnesium ions. When this occurs, the exchange resin must be
regenerated, or recharged. To regenerate, the ion exchange resin is flushed with a salt
brine solution (Figure 1). The sodium ions in the salt brine solution are exchanged
with the calcium and magnesium ions on the resin and excess calcium and magnesium
is flushed out with wastewater.
Frequency of the regeneration or recharge cycle depends on the hardness of the water,
the amount of water used, size of the softener, and capacity of the resins. Sixty to 120
minutes generally are required for the brine to pass through the unit and flush the tank
before soft water is available again.
12 | P a g e
Through the softening process, sodium is added to water at a rate of about 8 mg/L for
each grain per gallon (gpg) of hardness. After treatment, water that was 10 gpg of
hardness will have about 80 mg/L of sodium. This means that for every liter (0.26
gallon) of water intake, there would be 80 mg of sodium intake. People on restricted
sodium diets due to health reasons should account for increased intake through
softened water and consult their physician. Drinking and cooking with softened water
is often avoided by having a cold-water line to the kitchen tap that bypasses the water
softener. This provides hard water for drinking, cooking and other uses.
It is not recommended to repeatedly use softened water for plants, lawns or gardens
due to the sodium content.
Equipment
Ion exchange water softeners can be classified as one of four different types:
All types of softeners must be correctly installed and monitored for proper operation.
If an automatic or DIR unit appears to use more salt than expected or water is not
softened, have a service provider check the unit settings. The amount of salt used for
softening depends on the number of people in the household, daily water usage,
13 | P a g e
softener capacity, and water hardness. The appropriate size of water softener depends
on several factors including the water hardness level, daily water use and water flow
rate.
Types of Salt
There are different types of salt available for water softeners. The choice depends
upon the type of water softener and manufacturer design. Softeners are designed to
use specific types of salt so it is important to follow manufacturer’s recommendations
regarding the salt type.
Compressed salt has undergone an evaporation and compression process that yields
small particles referred to as pellets, nuggets, or beads. A variety of grades and
formulations are available on the market. Products designed to manage iron (rust) may
contain food-grade additives, such as citric acid. Compressed salt is sized according to
manufacturer’s specifications. The majority of softeners are designed for this type of
salt.
Salt blocks for use in some softener brine tanks look similar to those used for
livestock feeding. Blocks for livestock feeding, however, may contain additives
incompatible with water softener units. Block salt should be used only in those units
specifically designed for this form of salt. It should be high-grade evaporated salt
without additives.
Rock salt may have high levels of soluble or insoluble impurities. If the impurities are
calcium or magnesium salts, they may significantly reduce the effectiveness of the
regeneration process and plug valves. Rock salt is only an option if suggested by the
manufacturer and only those averaging less than 1 percent impurities should be used.
In certain situations, potassium chloride may be used for softener regeneration instead
of sodium chloride. Potassium chloride can be more costly and more difficult to
obtain than sodium chloride, however. Potassium chloride also adheres more strongly
to the resin. This can reduce the exchange efficiency compared to sodium chloride and
require more potassium chloride. Substituting potassium chloride for sodium chloride
may be appropriate if health or environmental reasons necessitate restricting sodium;
a water treatment professional should be consulted regarding this option.
Maintenance
14 | P a g e
into pipes and appliances. Regeneration does place additional load on a septic system.
Approximately 50 gallons of water (roughly equal to that required for a load of
laundry using an older washing machine, or two loads using a newer high-efficiency
washing machine) is used to regenerate a water softener. Also, certain situations such
as high concentrations of iron or manganese in the water can affect the exchange
capacity of the resin. In this case the resin may eventually need to be cleaned or
replaced. A water treatment professional should be consulted for guidance on cleaning
or replacing the resin.
The brine tank requires periodic checking and cleaning. How frequently you clean it
depends on the type and amount of salt and characteristics of the water being treated.
Inspect the tank for scale build-up. The brine valve and float assembly, if used, should
also be cleaned and inspected at least once a year.
Excess iron (above 5 ppm) or hydrogen sulfide in the water can reduce the
effectiveness of the water softener. The water should be tested for these contaminants
and proper pre-softening equipment installed if required. NebGuides G1280 Drinking
Water: Iron and Manganese and G1275 Drinking Water: Sulfur (Sulfate and
Hydrogen Sulfide) discuss these contaminants. Sediment in the water can also reduce
the effectiveness of the softener. The NebGuide G1492 Drinking Water Treatment:
Sediment Filtration discusses options for sediment removal.
Selection Requirements
Federal, state, or local laws do not regulate water softening home systems. The
industry is self-regulated. The NSF (formerly the National Sanitation Foundation) and
the Water Quality Association (WQA) evaluate performance, construction,
advertising, and operation manual information. The NSF program establishes
performance standards that must be met for endorsement and certification. The WQA
program uses the same NSF standards and provides equivalent American National
Standards Institute (ANSI) accredited product certifications. WQA certified products
carry the Water Quality Association Gold Seal. Though these certifications and
validations should not be the only criteria for choosing a water softening system, they
are helpful to ensure effectiveness of the system.
15 | P a g e
Other important guidelines are discussed in NebGuide G1488 Drinking Water
Treatment: What You Need to Know When Selecting Water Treatment Equipment. The
NebGuide series on drinking water treatment focuses on contaminants most likely to
be encountered in Nebraska drinking water supplies. Some water supplies may
contain contaminants not addressed in this series, such as cryptosporidium, giardia,
hexavalent chromium and others.
Summary
Drinking water treatment by water softening (ion exchange) is one option for the
homeowner in treating water problems. Calcium and magnesium ions in water
decrease the effectiveness of most cleaning tasks and can cause film and scale buildup
in and on plumbing and fixtures. Water softening is an effective method for reducing
the calcium and magnesium mineral ions from the water. It can also reduce iron and
manganese concentrations. Selection of an ion exchange water softening unit should
be based on water analysis and assessment of the individual homeowner’s needs and
situation. Regular maintenance of the unit is a critical factor in maintaining
effectiveness of the unit. NSF and the WQA test and certify products and this
certification can help guide selection.
Acknowledgment
16 | P a g e