SAFETY DATA SHEET

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Trade name or designation PPC5TF4-Black
of the mixture
Registration number -
Synonyms None.
Product code S0000105689
Issue date 23-February-2018
Version number 01
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Plastic Resin
Uses advised against None known.
1.3. Details of the supplier of the safety data sheet
Supplier
Company name Washington Penn Plastic Co. Inc.
Address Audia Plastics, S.R.O.
Voderady 426
919 42 Voderady
SK
Division Corporate Headquarters EU
Telephone Phone 00421.33.323.8001
Fax 00421.33.323.8054
e-mail [email protected]
Contact person Michael Griffith
1.4. Emergency telephone Emergency telephone 1-800-424-9300
number
Emergency telephone 1-703-527-3887

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
The mixture has been assessed and/or tested for its physical, health and environmental hazards and the following classification
applies.
Classification according to Regulation (EC) No 1272/2008 as amended
This mixture does not meet the criteria for classification according to Regulation (EC) 1272/2008 as amended.
Hazard summary Not classified for health hazards. However, occupational exposure to the mixture or substance(s)
may cause adverse health effects.
2.2. Label elements
Label according to Regulation (EC) No. 1272/2008 as amended
Hazard pictograms None.
Signal word None.
Hazard statements The mixture does not meet the criteria for classification.
Precautionary statements
Prevention Observe good industrial hygiene practices.
Response Wash hands after handling.
Storage Store away from incompatible materials.
Disposal Dispose of waste and residues in accordance with local authority requirements.
Supplemental label information 98 % of the mixture consists of component(s) of unknown long-term hazards to the aquatic
environment. 97 % of the mixture consists of component(s) of unknown acute oral toxicity. 98 % of
the mixture consists of component(s) of unknown acute hazards to the aquatic environment. 98 %
of the mixture consists of component(s) of unknown acute dermal toxicity.
2.3. Other hazards None known.

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SECTION 3: Composition/information on ingredients
3.2. Mixtures
General information
Chemical name % CAS-No. / EC REACH Registration No. INDEX No. Notes
No.

magnesium silicate (free from 40 - < 50 14807-96-6 - -

asbestos), non-respirable 238-877-9
Classification: -

1-Propene, polymer with ethene 30 - < 40 9010-79-1 - -

-
Classification: -

1-Propene, homopolymer 20 - < 30 9003-07-0 - -

-
Classification: -

Other components below reportable levels 3-<5

List of abbreviations and symbols that may be used above
#: This substance has been assigned Union workplace exposure limit(s).
M: M-factor
PBT: persistent, bioaccumulative and toxic substance.
vPvB: very persistent and very bioaccumulative substance.
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

SECTION 4: First aid measures

General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.
4.1. Description of first aid measures
Inhalation Move to fresh air. Call a physician if symptoms develop or persist.
Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists.
Eye contact Rinse with water. Get medical attention if irritation develops and persists.
Ingestion Rinse mouth. Get medical attention if symptoms occur.
4.2. Most important symptoms Exposure may cause temporary irritation, redness, or discomfort.
and effects, both acute and
delayed
4.3. Indication of any Treat symptomatically.
immediate medical attention
and special treatment needed

SECTION 5: Firefighting measures

General fire hazards No unusual fire or explosion hazards noted.
5.1. Extinguishing media
Suitable extinguishing Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
media
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
5.2. Special hazards arising During fire, gases hazardous to health may be formed.
from the substance or mixture
5.3. Advice for firefighters
Special protective Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
equipment for firefighters
Special fire fighting Use water spray to cool unopened containers.
procedures
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
For non-emergency Keep unnecessary personnel away. For personal protection, see section 8 of the SDS.
personnel

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 For emergency responders Keep unnecessary personnel away. Use personal protection recommended in Section 8 of the
SDS.
6.2. Environmental precautions Avoid discharge into drains, water courses or onto the ground.
6.3. Methods and material for Stop the flow of material, if this is without risk. Following product recovery, flush area with water.
containment and cleaning up
6.4. Reference to other For personal protection, see section 8 of the SDS. For waste disposal, see section 13 of the SDS.
sections

SECTION 7: Handling and storage

7.1. Precautions for safe Avoid prolonged exposure. Observe good industrial hygiene practices.
handling
7.2. Conditions for safe Store in original tightly closed container. Store away from incompatible materials (see Section 10
storage, including any of the SDS).
incompatibilities
7.3. Specific end use(s) Not available.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Occupational exposure limits
Czech Republic. OELs. Government Decree 361
Components Type Value Form

1-Propene, homopolymer TWA 5 mg/m3 Dust.

(CAS 9003-07-0)
Latvia. OELs. Occupational exposure limit values of chemical substances in work environment
Components Type Value Form

1-Propene, homopolymer TWA 5 mg/m3 Dust.

(CAS 9003-07-0)
Lithuania. OELs. Limit Values for Chemical Substances, General Requirements
Components Type Value
1-Propene, homopolymer TWA 10 mg/m3
(CAS 9003-07-0)
Biological limit values No biological exposure limits noted for the ingredient(s).
Recommended monitoring Follow standard monitoring procedures.
procedures
Derived no effect levels Not available.
(DNELs)

Predicted no effect Not available.

concentrations (PNECs)

8.2. Exposure controls

Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level.
Individual protection measures, such as personal protective equipment
General information Personal protection equipment should be chosen according to the CEN standards and in
discussion with the supplier of the personal protective equipment.
Eye/face protection Wear safety glasses with side shields (or goggles).
Skin protection
- Hand protection Wear appropriate chemical resistant gloves.
- Other Wear suitable protective clothing.
Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
Hygiene measures Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.
Environmental exposure Environmental manager must be informed of all major releases.
controls

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SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance
Physical state Solid.
Form Solid. Solid
Colour Not available.
Odour Not available.
Odour threshold Not available.
pH Not available.
Melting point/freezing point Not available.
Initial boiling point and boiling Not available.
range
Flash point Not available.
Evaporation rate Not available.
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
(%)
Flammability limit - upper Not available.
(%)
Vapour pressure Not available.
Vapour density Not available.
Relative density Not available.
Solubility(ies)
Solubility (water) Not available.
Solubility (other) Not available.
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Explosive properties Not explosive.
Oxidising properties Not oxidising.
9.2. Other information
Density 1,23 g/cm3 estimated
Specific gravity 1,23 estimated

SECTION 10: Stability and reactivity

10.1. Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
10.2. Chemical stability Material is stable under normal conditions.
10.3. Possibility of hazardous No dangerous reaction known under conditions of normal use.
reactions
10.4. Conditions to avoid Contact with incompatible materials.
10.5. Incompatible materials Strong oxidising agents.
10.6. Hazardous Carbon monoxide. Irritating and/or toxic fumes and gases may be emitted upon the product's
decomposition products decomposition.

SECTION 11: Toxicological information

General information Occupational exposure to the substance or mixture may cause adverse effects.
Information on likely routes of exposure
Inhalation Prolonged inhalation may be harmful.
Skin contact No adverse effects due to skin contact are expected.
Eye contact Direct contact with eyes may cause temporary irritation.
Ingestion May cause discomfort if swallowed. However, ingestion is not likely to be a primary route of
occupational exposure.

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Symptoms Exposure may cause temporary irritation, redness, or discomfort.
11.1. Information on toxicological effects

Acute toxicity Not known.

Skin corrosion/irritation Due to partial or complete lack of data the classification is not possible.
Serious eye damage/eye Due to partial or complete lack of data the classification is not possible.
irritation
Respiratory sensitisation Due to partial or complete lack of data the classification is not possible.
Skin sensitisation Due to partial or complete lack of data the classification is not possible.
Germ cell mutagenicity Due to partial or complete lack of data the classification is not possible.
Carcinogenicity Due to partial or complete lack of data the classification is not possible.
IARC Monographs. Overall Evaluation of Carcinogenicity
magnesium silicate (free from asbestos), non-respirable 2B Possibly carcinogenic to humans.
(CAS 14807-96-6)
3 Not classifiable as to carcinogenicity to humans.
Reproductive toxicity Due to partial or complete lack of data the classification is not possible.
Specific target organ toxicity - Due to partial or complete lack of data the classification is not possible.
single exposure
Specific target organ toxicity - Due to partial or complete lack of data the classification is not possible.
repeated exposure
Aspiration hazard Due to partial or complete lack of data the classification is not possible.
Mixture versus substance No information available.
information
Other information Not available.

SECTION 12: Ecological information

12.1. Toxicity Based on available data, the classification criteria are not met for hazardous to the aquatic
environment.
12.2. Persistence and No data is available on the degradability of this product.
degradability
12.3. Bioaccumulative potential No data available.
Partition coefficient Not available.
n-octanol/water (log Kow)
Bioconcentration factor (BCF) Not available.
12.4. Mobility in soil No data available.
12.5. Results of PBT Not available.
and vPvB
assessment
12.6. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Residual waste Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
EU waste code The Waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Disposal methods/information Collect and reclaim or dispose in sealed containers at licensed waste disposal site.
Special precautions Dispose in accordance with all applicable regulations.

SECTION 14: Transport information

ADR
14.1. UN number UN3077
14.2. UN proper shipping Environmentally hazardous substance, solid, n.o.s.
name
14.3. Transport hazard class(es)
Class 9
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 Subsidiary risk -
Label(s) 9
Hazard No. (ADR) 90
Tunnel restriction code E
14.4. Packing group III
14.5. Environmental hazards Yes
14.6. Special precautions Read safety instructions, SDS and emergency procedures before handling.
for user
RID
14.1. UN number UN3077
14.2. UN proper shipping Environmentally hazardous substance, solid, n.o.s.
name
14.3. Transport hazard class(es)
Class 9
Subsidiary risk -
Label(s) 9
14.4. Packing group III
14.5. Environmental hazards Yes
14.6. Special precautions Read safety instructions, SDS and emergency procedures before handling.
for user
ADN
14.1. UN number UN3077
14.2. UN proper shipping Environmentally hazardous substance, solid, n.o.s.
name
14.3. Transport hazard class(es)
Class 9
Subsidiary risk -
Label(s) 9
14.4. Packing group III
14.5. Environmental hazards Yes
14.6. Special precautions Read safety instructions, SDS and emergency procedures before handling.
for user
IATA
14.1. UN number UN3077
14.2. UN proper shipping Environmentally hazardous substance, solid, n.o.s.
name
14.3. Transport hazard class(es)
Class 9
Subsidiary risk -
14.4. Packing group III
14.5. Environmental hazards Yes
ERG Code 9L
14.6. Special precautions Read safety instructions, SDS and emergency procedures before handling.
for user
Other information
Passenger and cargo Allowed with restrictions.
aircraft
Cargo aircraft only Allowed with restrictions.
IMDG
14.1. UN number UN3077
14.2. UN proper shipping ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., MARINE POLLUTANT
name
14.3. Transport hazard class(es)
Class 9
Subsidiary risk -
14.4. Packing group III
14.5. Environmental hazards
Marine pollutant Yes
EmS F-A, S-F
14.6. Special precautions Read safety instructions, SDS and emergency procedures before handling.
for user
14.7. Transport in bulk Not applicable.
according to Annex II of Marpol
and the IBC Code
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ADN; ADR; IATA; IMDG; RID

Marine pollutant

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations
Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I and II, as amended
Not listed.
Regulation (EC) No. 850/2004 On persistent organic pollutants, Annex I as amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 1 as amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 2 as amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 3 as amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex V as amended
Not listed.
Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry, as amended
Not listed.
Regulation (EC) No. 1907/2006, REACH Article 59(10) Candidate List as currently published by ECHA
Not listed.
Authorisations
Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorization, as amended
Not listed.
Restrictions on use
Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as amended
Not listed.
Directive 2004/37/EC: on the protection of workers from the risks related to exposure to carcinogens and mutagens at
work, as amended.
Not listed.
Other EU regulations
Directive 2012/18/EU on major accident hazards involving dangerous substances, as amended
Not listed.
Other regulations Pregnant women should not work with the product, if there is the least risk of exposure. The
product is classified and labelled in accordance with Regulation (EC) 1272/2008 (CLP Regulation)
as amended. This Safety Data Sheet complies with the requirements of Regulation (EC) No
1907/2006, as amended.
National regulations Follow national regulation for work with chemical agents. Young people under 18 years old are not
allowed to work with this product according to EU Directive 94/33/EC on the protection of young
people at work, as amended.

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15.2. Chemical safety No Chemical Safety Assessment has been carried out.
assessment

SECTION 16: Other information

List of abbreviations Not available.
References Not available.
Information on evaluation The classification for health and environmental hazards is derived by a combination of calculation
method leading to the methods and test data, if available.
classification of mixture
Full text of any H-statements None.
not written out in full under
Sections 2 to 15
Revision information None.
Training information Follow training instructions when handling this material.
Disclaimer Washington Penn Plastic Co. Inc. cannot anticipate all conditions under which this information and
its product, or the products of other manufacturers in combination with its product, may be used. It
is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the
product, and to assume liability for loss, injury, damage or expense due to improper use. The
information in the sheet was written based on the best knowledge and experience currently
available.

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