Lecture 17+18
Lecture 17+18
Boiling Curve
Interface Evaporation (region I) with
no bubble formation
Boiling takes place in a thin layer of liquid which
adjoins the heated surfaces.
Liquid in the immediate vicinity of the wall
become superheated i.e,temp of liq exceeds sat
temp at a given pressure.
The superheated liq rises to the liq –vap interface
where evaporation takes place.
The fluid motion is determined primarily by free
convection effects.
Heat .tr. Rate increases, but gradually ,with
growth in a temp excess.
Nucleate Boiling
When liq overheated in relation to sat
temp, vapor bubbles are formed at certain
favorable spots called nucleation or active
sites at wall surface irregularities, air
bubbles, particles of dust.
Bubbles grow to certain size influenced by
pressure, temp and surface tension at liq-
vap interface.
Following steps occur-
Bubbles forms & collapse on surface itself
Bubbles form but get condensed in liq after detaching
from the surface
Bubbles form, break away from heated surface with
increasing frequency and intensity. The liq is however
quite hot and bubbles donot condense in it. They rise to
the surface & are directly expelled to vapor space and
helps in rapid evaporation
Bubble growth & nucleate boiling
Bubble formation in nucleate boiling is
greatly influenced by the nature &
condition of heating surface and surface
tension at solid-liq interface.
Surface tension-wetting capability of
surface with liq & that influences the
angle of contact between bubble & solid
surface. Any contamination will influence
wetting characteristic.
A second difficulty appears if bubble doesn’t
leave the surface once it is formed
An important factor in detachment is interfacial
tension between liq & heating surface
If interfacial tension large, bubble tends to
spread along the surface forming a blanket
If interfacial tension low, bubble will pinch off
easily.
Pl (𝑃𝑣 −𝑃𝑙 )𝜋𝑟 2 = 2𝜋𝑟𝜎
σ σ 2𝜎
or(𝑃𝑣 −𝑃𝑙 ) =
𝑟
To find the dependence of pressure
Pv
on equilibrium temp when 2 phase
r
coexist, Clapeyron Equation used
𝑑𝑃 𝑃𝑣 λ
=
𝑑𝑇 𝑅𝑣 𝑇𝑣 2
(𝑃𝑣 −𝑃𝑙 ) 𝑃𝑣 λ
=
(𝑇𝑣 −𝑇𝑠𝑎𝑡 ) 𝑅𝑣 𝑇𝑣 2
2𝜎 𝑅𝑣 𝑇𝑣 2
(𝑇𝑣 −𝑇𝑠𝑎𝑡 ) =
𝑟 𝑃𝑣 λ
A bubble of radius r will grow if
Tl-Tsat>Tv- Tsat
Otherwise it will collapse
Nucleate Pool Boiling is influenced by the following
factors:
I. Material, shape, condition of surface(rough
surface better than smooth)
II. Pressure: Temp diff between heating surface
and bulk and hence the rate of bubble growth
affected by pressure. Maximum allowable
heat flux for boiling liquid increases with
pressure until critical pressure is reached and
thereafter it declines.
III. Liquid property: Bubble size increase with
viscosity. With increase in bubble size the
frequency of bubble formation decreases that
results in reduced heat transfer
Film Boiling
Bubble formation is rapid.
Soon it forms a blanket over heating surface &
prevent the incoming fresh liquid from taking
their place.
Insulating effect of the vapor film(low K)
overshadows the beneficial effect of liq agitation
& consequently heat flux drops with growth in
excess temp.
0.5 0.25
𝑄 𝑔 (𝜌𝑙 − 𝜌𝑣 ) 𝜎
= 0.09 𝜌𝑣 λ
𝐴 𝑚𝑖𝑛
𝜌𝑙 + 𝜌𝑣 𝑔(𝜌𝑙 − 𝜌𝑣 )
Spherical bubbles of 3mm dia are observed in the
bulk fluid boiling of water at std. atm. Press.
Assuming pure water vap in the bubble & vap press
equal to 101.325 kN/m2, calculate temp of vapor
2𝜎 𝑅𝑣 𝑇𝑣 2
(𝑇𝑣 −𝑇𝑠𝑎𝑡 ) =
𝑟 𝑃𝑣 λ
r=3/2 = 1.5mm, σ = 0.058N/m
Rv= R/M = 8314/18 = 461
Pv= 101.325kN/m2
λ = 2255kJ/kg
Tsat = 100oC
Tv = 100.257oC
An electric wire of 1.25mm dia & 250 mm long is laid
horizontally & submerged in water at 7bar. The wire has
an applied voltage of 2.2V& carries a current of 130A. If
the surface of the wire is maintained at 200oC, make
calculations for the heat flux & boiling heat transfer
coeff. (Tsat at 7 bar = 165oC)
0.25 0.5
𝑄 𝜌𝑙 − 𝜌𝑣 𝜌𝑙
= 0.81 ρ𝑣 λ 𝜎𝑔
𝐴 𝑚𝑎𝑥
𝜌𝑣 2 𝜌𝑣 + 𝜌𝑙
𝜌𝑙 =959.52kg/m3, 𝜌𝑣 = 0.597kg/m3
λ = 2.257x 106 J/kg, 𝜎 = 0.0533N/m
𝑄
= 1.48 x 106 J/s-m2
𝐴 𝑚𝑎𝑥
Electric Energy = V x I = 195V w
A= πdl
= 9.42 x 10 -4 m2
Voltage = 7.15V