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Samarpan Iit Jee: Class XI

This document contains a 10 question practice test on quantum numbers and atomic orbitals. The questions cover topics like the relationship between different quantum numbers, allowed quantum number values for different orbitals, degeneracy of atomic orbitals, and determining electron configurations based on quantum numbers.

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Cheryl Chaudhari
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299 views

Samarpan Iit Jee: Class XI

This document contains a 10 question practice test on quantum numbers and atomic orbitals. The questions cover topics like the relationship between different quantum numbers, allowed quantum number values for different orbitals, degeneracy of atomic orbitals, and determining electron configurations based on quantum numbers.

Uploaded by

Cheryl Chaudhari
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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SAMARPAN IIT JEE

Class XI
Time: 30 min
DPP No: 04 Marks: 35

Q.1 If an electron has spin quantum number of + and magnetic quantum number of –1 it cannot
be present in
(A) f-orbital (B) d-orbital (C) p-orbital (D) s-orbital [3]

Q.2 Principal, azimuthal and magnetic quantum numbers are respectively related to [3]
(A) size, shape and orientation (B) shape, size and orientation
(C) size, orientation and shape (D) none of these

Q.3 Consider the ground state of Cr (Z = 24). The numbers of electrons with the azimuthal
quantum numbers l = 1 and 2 respectively are [3]
(A) 16 and 4 (B) 12 and 5 (C) 12 and 4 (D) 16 and 5

Q.4 Degenerate atomic orbitals have [3]


(A) equal energy (B) nearly equal energy
(C) different energy (D) none of the above

Q.5 When the quantum number n,l,m,s are represented by 3,3,2,+1/2, the symbolism for the
electron is [3]
(A) 3s (B) 3d
(C) 3f (D) impossible set of quantum number

Q.6 For a 6s electron the values of n,l,m,s respectively could be: [3]
(A) 6,4,4,+1/2 (B) 1,0,0,+1/2 (C) 6,1,0,+1/2 (D) 6,0,0, +1/2

Q.7 Any p-orbital can accomodate up to [3]


(A) four electrons (B) Two electrons in parallel spin
(C) Six electrons (D) Two electrons with opposite spin

Q.8 Which one of the following sets of quantum numbers (n,l,m,s) represents an impossible
arrangement? [3]
(A) 3,2,–2,+1/2 (B) 4,0,0,+1/2 (C) 3,2,–3,+1/2 (D) 5,3,0,–1/2

Q.9 Match the column: [6]


(‘l’ and ‘m’ are respectively the azimuthal and magnetic quantum numbers)
Column-I Column-II
(A) Total number of values of (l) for a (P) 0, 1, 2, .................(n–1)
shell
(B) Values of (l) for a shell (Q) +l, .....+2, +1, 0, –1, –2, .......–l
(C) Total number of values of (m) for a (R) (2l + 1)
subshell
(D) Values of (m) for a subshell (S) n

Q.10 Imagine a universe in which the four quantum no. can have the same possible values as in our
universe except that angular quantum no. (l) can have integral values from 0, 1, 2 .... n + 1.
[5]

(a) Find the no. of electron n = 1 & 2 shell.

(b) Predict the electronic configuration for elements with atomic no. 15 & 25 using aufbau
(n + l) rule.

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