Scribd
Upload
73 views

Answer: Step 1

The document is a multi-step chemistry problem involving calculations of mole fractions, enthalpies, temperatures, and partial molar properties of components in a binary liquid mixture. Specifically, it involves calculating the mole fractions, enthalpies, and temperature of input and output streams in an adiabatic mixing process, as well as the partial molar enthalpy and volume of one component in the mixture. Diagrams and equations are provided to work through the various calculation steps.

Uploaded by

cj
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
73 views

Answer: Step 1

The document is a multi-step chemistry problem involving calculations of mole fractions, enthalpies, temperatures, and partial molar properties of components in a binary liquid mixture. Specifically, it involves calculating the mole fractions, enthalpies, and temperature of input and output streams in an adiabatic mixing process, as well as the partial molar enthalpy and volume of one component in the mixture. Diagrams and equations are provided to work through the various calculation steps.

Uploaded by

cj
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 4

4/8/2021 https://fkchegg.com/cg23/?auth=eyJhbGciOiJIUzI1NiIsInR5cCI6IkpXVCJ9.

eyJ1dWlkIjoiOTc4MDQ3MDI1OTYxMC0xNzg4MDUwMyIsImlh…

Join here! for free Chegg Unlocks WallStreetBets - Discord Server (https://fkchegg.com/wsb/). ×

Question

Answer
Step 1
a)

Step 2
Calculate the number of moles in the binary mixture .

Here, number of moles of species 1 is , and number of moles of species 2 is .

Substitute for , and for .

Step 3
Calculate the mole fraction of species 1 .

Substitute for and for .

Calculate the mole fraction of species 2 .

Substitute for and for .

Step 4
Express the reported molar enthalpy of liquid mixture.

…… (1)

Here, temperature is T.

Step 5
https://fkchegg.com/cg23/?auth=eyJhbGciOiJIUzI1NiIsInR5cCI6IkpXVCJ9.eyJ1dWlkIjoiOTc4MDQ3MDI1OTYxMC0xNzg4MDUwMyIsImlhdCI6MTYxN… 1/4
4/8/2021 https://fkchegg.com/cg23/?auth=eyJhbGciOiJIUzI1NiIsInR5cCI6IkpXVCJ9.eyJ1dWlkIjoiOTc4MDQ3MDI1OTYxMC0xNzg4MDUwMyIsImlh…

Substitute 0.5 for , 0.5 for , for T and calculate the enthalpy of stream a .

Substitute 0.5 for , 0.5 for , for T and calculate the enthalpy of stream b .

Step 6
Express the energy balance equation for adiabatic process.

Here, flow rate of moles of stream a is , flow rate of moles of stream b is , flow rate of moles of output mixture
is , and enthalpy of output mixture is .

Substitute for , for , for , for , for ,


for , 0.8 for , and 0.2 for .

Hence, the temperature of the outlet stream is .

Step 7
b)

Express the enthalpy of the binary mixture .

Substitute for h, for , for , for .

https://fkchegg.com/cg23/?auth=eyJhbGciOiJIUzI1NiIsInR5cCI6IkpXVCJ9.eyJ1dWlkIjoiOTc4MDQ3MDI1OTYxMC0xNzg4MDUwMyIsImlhdCI6MTYxN… 2/4
4/8/2021 https://fkchegg.com/cg23/?auth=eyJhbGciOiJIUzI1NiIsInR5cCI6IkpXVCJ9.eyJ1dWlkIjoiOTc4MDQ3MDI1OTYxMC0xNzg4MDUwMyIsImlh…

…… (2)

Step 8
Differentiate Equation (2) partially with respect to and calculate the partial molar enthalpy of species 1 .

…… (3)

Step 9
Substitute for T, and 0.5 for both and .

Step 10
Hence, the partial molar enthalpy of species 1 is .

https://fkchegg.com/cg23/?auth=eyJhbGciOiJIUzI1NiIsInR5cCI6IkpXVCJ9.eyJ1dWlkIjoiOTc4MDQ3MDI1OTYxMC0xNzg4MDUwMyIsImlhdCI6MTYxN… 3/4
4/8/2021 https://fkchegg.com/cg23/?auth=eyJhbGciOiJIUzI1NiIsInR5cCI6IkpXVCJ9.eyJ1dWlkIjoiOTc4MDQ3MDI1OTYxMC0xNzg4MDUwMyIsImlh…

Step 11
c)

Step 12
In Equation (2), substitute 1 for , 0 for and calculate the partial molar volume of species 1 at infinite dilution
.

Substitute for T.

Hence, the partial molar volume of species 1 at infinite dilution is .

https://fkchegg.com/cg23/?auth=eyJhbGciOiJIUzI1NiIsInR5cCI6IkpXVCJ9.eyJ1dWlkIjoiOTc4MDQ3MDI1OTYxMC0xNzg4MDUwMyIsImlhdCI6MTYxN… 4/4

You might also like