Appendix E: Antoine

Coefficients

The constants in the table below are used to model the relationship between vapor
pressure and temperature, through
B
log10 P sat 5 A 2
T1C
where P sat is expressed in mm Hg and T is expressed in degrees Celsius.

Name Structure A B C T Range

Acetic acid CH3COOH 7.38782 1533.313 22.309 Liquid
Acetone (CH3)2CO 7.11714 1210.595 229.664 Liquid
Acetonitrile CH3CN 7.11988 1314.4 230 Liquid
Acetylene C2H2 9.1402 1232.6 280.9 2130 to 283
7.0999 711.0 253.4 282 to 272
Benzene C6H6 9.1064 1885.9 244.2 212 to 3
6.90565 1211.033 220.790 8 to 103
Benzyl alcohol C6H5CH2OH 7.19817 1632.593 172.790 122 to 205
Biphenyl (C6H5)2 7.24541 1998.725 202.733 69 to 271
Bromochloromethane CH2BrCl 6.49606 942.267 192.587 16 to 68
1,3-Butadiene C4H6 7.03555 998.106 245.233 280 to 262
6.84999 930.546 238.854 258 to 15
n-butane C4H10 6.80896 935.86 238.73 277 to 19
1-butanol C4H9OH 7.47680 1362.39 178.77 15 to 131
2-butanol C4H9OH 7.47431 1314.19 186.55 25 to 120
1-Butene C4H8 6.79290 908.80 238.54 282 to 13
Chloroethane C2H5Cl 6.98647 1030.01 238.61 256 to 12.2
Chloroform CHCl3 6.4934 929.44 196.03 235 to 61
Chloromethane CH3Cl 7.09349 948.58 249.34 275 to 25
Cyclohexane C6H12 6.84130 1201.53 222.65 20 to 81
Diethyl ketone C5H10O 6.85791 1216.3 204

Ethanol C2H5OH 8.32109 1718.10 237.52 22 to 100

(Continued)

741

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742 Fundamentals of Chemical Engineering Thermodynamics

Name Structure A B C T Range

Ethyl acetate CH3COOCH2CH3 7.10179 1244.95 217.88 15 to 76

Ethyl benzene C8H10 6.95719 1424.255 213.21 26 to 164
n-Heptane C7H16 6.89677 1264.90 216.54 22 to 124
n-Hexane C6H14 6.87601 1171.17 224.41 225 to 92
Hexfluorobenzene C6F6 7.03295 1227.98 215.49 5 to 114
Methanol CH3OH 7.89750 1474.08 229.13 214 to 65
7.97328 1515.14 232.85 64 to 110
2-Methyl-1-propanol (CH3)2CHCH2OH 7.32705 1248.48 172.92 20 to 115
n-Octane C8H18 6.91868 1351.99 209.15 19 to 152
n-Pentane C5H12 6.85296 1064.84 233.01 250 to 58
Phenol C6H5OH 7.1330 1516.79 174.95 107 to 182
Propane C3H8 6.80338 804.00 247.04 2108 to 225
1-Propanol C3H7OH 7.84767 1499.21 204.64 2 to 120
2-Propanol C3H7OH 8.11778 1580.92 219.61 0 to 101
Toluene C6H5CH3 6.95464 1344.800 219.48 6 to 137
Water* H2O 8.01195 1698.785 231.04 5 to 150
o-Xylene C8H10 6.99891 1474.679 213.69 32 to 172
m-Xylene C8H10 7.00908 1462.266 215.11 28 to 166
p-Xylene C8H10 6.99052 1453.430 215.31 27 to 166

Based on data from James G. Speight, Lange’s Handbook of Chemistry, 16th ed., McGraw-Hill, 2005, except as noted.
*
Fit to data from steam tables

Copyright 2015 Cengage Learning. All Rights Reserved. May not be copied, scanned, or duplicated, in whole or in part. Due to electronic rights, some third party content may be suppressed from the eBook and/or eChapter(s).
Editorial review has deemed that any suppressed content does not materially affect the overall learning experience. Cengage Learning reserves the right to remove additional content at any time if subsequent rights restrictions require it.