SAFETY DATA SHEET aan gy? APCODUR HB ZP PRIMER - GREY ee SECTION 1: Identification of the substance/mixture and of the company/ undertaking Product name ? APCODUR HB ZP PRIMER - GREY Product code : 17130607 Other means of Not available, identification Identified uses » Paint Uses advised against : Do not use for any purpose other than the one for which itis intended. Manufacturer : Asian Paints PPG Pvt. Ltd, 6A, Shantinagar, Santacruz East, Mumbai 400055 Supplier : Asian Paints PPG Pvt. Ltd, 6A, Shantinagar, Santacruz East, ‘Mumbai 400055 ‘e-mail address of person: [email protected] responsible for this SDS Emergency telephone + 022 ~ 62182649 (10 am to 7 pm except on Sunday & National Holiday) number (with hours of 022 - 62182700 (Weekdays - 7 pm to 10 am ; Active 24 hrs on Sunday) operation) SECTION 2: Hazards identification Classification of the substance or mixture Product definition : Mixture: Classification of the : FLAMMABLE LIQUIDS - Category 3 substance or mixture ACUTE TOXICITY (inhalation) - Category 4 ‘SKIN CORROSIONIIRRITATION - Category 2 ‘SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 SKIN SENSITIZATION - Category 1 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 AQUATIC HAZARD (LONG-TERM) - Category 2 The product is classified as hazardous according to Regulation (EC) 1272/2008 as amended. 81.2 percent ofthe misture consists of components) of unknown oa tax 81.2 percent of the misture consists of componeni(s) af unknown dermal oxi 851.2 percent ofthe misture consists of components) af unknown inhalation laxity Contains 51 % of components with unknown hazards tothe aquatic environment ‘See Section 11 for more detailed information on health effects and symptoms, Label elements Signal word : Danger Hazard statements + H226 - Flammable liquid and vapor. H332 - Harmful if inhaled H318 - Causes serious eye damage. H315 - Causes skin irtation H317 - May cause an allergic skin reaction, H373 - May cause damage to organs through prolonged or repeated exposure. H411 - Toxic to aquatic life with long lasting effects. Precautionary statementsDate ofissue/Dato of revision 15 October 2020 29 SECTION 2: Hazards identification Prevention P280 - Wear protective gloves, Wear protective clothing, Wear eye or face protection. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. 273 - Avoid release to the environment, P260 - Do not breathe vapor. Response : P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing, P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing, Rinse skin with water. P305 + P310 - IF IN EYES: Immediately call a POISON CENTER or physician. Storage Not applicable. isposal + P501 - Dispose of contents and container in accordance with all local, regional, national and international regulations. Other hazards which do: None known. not result in classification SECTION 3: Composition/information on ingredients ‘Substancelmixture = Mixture Productiingredient name % CAS# fethyibonzene 225 - 538 700-414 reaction product: bisphenol-A-(epichlorhydrin); epoxy resin 10 25068-286 (number average molecular weight < 700) butan-1-o1 5 71-36-3 titanium dioxide 5 13463-67-7 Jo-ryiene 3 95-476 pylene 50.3 1330-20-7 zine bis(orthophosphate) 50.3 7779-90-0 ‘There are no additional ingredients present which, according to Regulation (EC) 1272/2008 as amended and in the concentrations applicable, are classified as hazardous to health or the environment, or have been assigned a workplace ‘exposure limit and hence require reporting in this section, Occupational exposure limits, i available, are listed in Section 8. SECTION 4: First measures Description of first aid measures Eye contact : Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for atleast 10 minutes. Chemical burns must be treated promptly by a physician Inhalation : Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing, If'itis suspected that fumes are stil present, the rescuer should wear an appropriate mask or selt- contained breathing apparatus. If not breathing, if breathing Is regular or if respiratory arrest occurs, provide artficial respiration or oxygen by trained personnel. Itmay be dangerous to the person providing aid to give mouth-to-mouth resuscitation If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway, Loosen tight clothing such as a collar, tie, belt or waistband, contact : Get medical attention immediately. Call a poison center or physician. Wash with plenty of soap and water. Remove contaminated clothing and shoes, Wash Contaminated clothing thoroughly with water before removing i, or wear gloves, Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. in the event of any complaints or symptoms, avoid further exposure, Wash clothing before reuse. Clean shoes thoroughly before reuse.Date of esuerDate of rvision 15 October 2020 a9 SECTION 4: First aid measures Ingestion 7 Gat medical altention immediately. Call a polson center or physician. Wash out mouth with water. Remove dentures ff any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. if material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway, Loosen tight clothing such as a collar, tie, belt or waistband, Most important symptoms and effects, both acute and delayed Potential acute health effects Eye contact + Causes serious eye damage. Inhalation : Harmful if inhaled. Skin contact : Causes skin irritation, May cause an allergic skin reaction. Ingestion + No known significant effects or crtical hazards. Over-exposure signs/symptoms Eye contact : Adverse symptoms may include the following: pain watering redness Inhalation : No specific data. Skin contact : Adverse symptoms may include the following: pain or irtation redness blistering may occur Ingestion : Adverse symptoms may include the following: stomach pains Indication of any immediate medical attention and special treatment needed Notes to physician : Treat symptomatically, Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments No specific treatment. Protection of first-aiders __:No action shall be taken involving any personal risk or without suitable training. If itis suspected that fumes are stil present, the rescuer should wear an appropriate mask ‘r self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. [SECTION 5: Firefighting measures Extinguishing medi Suitable extinguishing + Use dry chemical, CO2, water spray (fog) or foam, media Unsuitable extinguishing: Do not use water jet media ‘Special hazards arising from the substance or mixture Hazards from the : Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In substance or mixture a fire or if heated, a pressure increase will occur and the container may burst, with the Fisk of a subsequent explosion. The vaporigas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material mustDate of esuerDate of rvision 15 October 2020 43 SECTION 5: Firefighting measures Hazardous combustion products Advice for firefighters Special protective actions for fire-fighters Special protective equipment for fire-fighters © Decomposition products may include the following materials: carbon dioxide carbon monoxide halogenated compounds metal oxide/oxides + Prompily isolate the scene by removing all persons from the vicinity ofthe incident if there is a fire, No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-expased containers cool : Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-plece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents. SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures: For non-emergency personnel For emergency responders + Avoid : No action shall be taken involving any personal risk or without suitable training, Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide adequate ventilation, Wear appropriate respirator when ventilation is inadequate, Put on appropriate personal protective equipment. + If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials, See also the information in "For non-emergency personn .ersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soll or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage. Methods and materials for containment and cleaning up ‘Small spill Large spill Reference to other sections Stop leak if without risk. Move containers from spill area. Use spark-proof tools and fexplosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or f water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an cffluent treatment plant or proceed as follows. Contain and collect spillage with non- combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. : See Section 1 for emergency contact information. ‘See Section 8 for information on appropriate personal protective equipment. ‘See Section 13 for additional waste treatment information.Date ofissue/Date of revision 15 October 2020 a3 SECTION 7: Handling and storage Precautions for safe handling Protective measures Advice on general ‘occupational hygiene Conditions for safe storage, including any : Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing, Do not breathe vapor cf mist. Do not ingest. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the criginal container or an approved alternative made from a compatible material, kept tightly closed when not in use, Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilaling, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. : Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures, Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well ventilated area, away from incompatible materials (see Section 10) and food and drink, Store locked up. Eliminate all ignition sources, Separate from oxidizing materials. Keep container tightly closed and sealed untl ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers, Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials, before handling or use. SECTION 8: Exposure controls/personal protection Control parameters ‘Occupational exposure limits, Productiingredient name Exposure limit values ethylbenzene onylene vylene [EU OEL (Europe, 2/2017). Absorbed through skin. Notes: list of lindicative occupational exposure limit values TWA: 100 ppm 8 hours. ‘TWA: 442 mgim? 8 hours. STEL: 200 ppm 15 minutes. STEL: 884 mgim? 15 minutes, IEU OEL (Europe, 2/2017). Absorbed through skin. Notes: list of lindicative occupational exposure limit values TWA: 50 ppm 8 hours. TWA: 221 mglm? 8 hours. STEL: 100 ppm 15 minutes, STEL: 442 mgim? 15 minutes. IEU OEL (Europe, 2/2017). Absorbed through skin. Notes: list of lindicative occupational exposure limit values TWA: 50 ppm 8 hours. ‘TWA: 221 mgim? 8 hours. STEL: 100 ppm 15 minutes, STEL: 442 mgim? 15 minutes. ethylbenzene |AGGIH TLV (United States, 3/2017). TWA: 20 ppm 8 hours. OSHA PEL 1989 (United States, 3/1989). ‘TWA: 100 ppm 8 hours. ‘TWA: 435 mgim? 8 hours. STEL: 125 ppm 15 minutes. STEL: 545 mgim? 15 minutes.Date ofissue/Date of revision 15 October 2020 ana SECTION 8: Exposure controls/personal protection epoxy resin butan-t-ol titanium dioxide NIOSH REL (United States, 10/2016). TWA: 100 ppm 10 hours. ‘TWA: 435 mgim? 10 hours. STEL: 125 ppm 15 minutes. STEL: 545 mgim? 15 minutes. OSHA PEL (United States, 6/2016). TWA: 100 ppm 8 hours. ‘TWA: 435 mgim? 8 hours. crystalline silica, respirable powder OSHA PEL Z3 (United States, 6/2016). Notes: 250/(%Si02+5) TWA: 250 mppef | (%Si02+5) 8 hours. Form: Respirable JOSHA PEL Z3 (United States, 6/2016). Notes: 10/(SiO2+2) TWA: 10 mglm*/ (6Si02+2) 8 hours, Form: Respirable JOSHAPEL 1989 (United States, 3/1989). Notes: as quartz TWA: 0.1 mg/m*, (as quartz) 8 hours. Form: Respirable dust JOSHAPEL (United States, 6/2016). "TWA: 50 ugim? 8 hours. Form: Respirable dust JACGIH TLV (United States, 3/2017). ‘TWA: 0.025 mgim® 8 hours. Form: Respirable fraction |NIOSH REL (United States, 10/2016). TWA: 0.05 mgim? 10 hours. Form: respirable dust reaction product: bisphenol-A-(epichlorhydrin); [None. |ACGIH TLV (United States, 3/2017). ‘TWA: 20 ppm 8 hours. OSHA PEL 1989 (United States, 3/1989). Absorbed through skin. CEIL: 50 ppm CEIL: 150 mg/m? NIOSH REL (United States, 10/2016). Absorbed through skin. CEIL: 50 ppm CEIL: 150 mg/m? OSHA PEL (United States, 6/2016) TWA: 100 ppm 8 hours. ‘TWA: 300 mg/m? 8 hours. ACGIH TLV (United States, 3/2017). TWA: 10 mg/m? 8 hours. OSHA PEL 1989 (United States, 3/1989). ‘TWA: 10 mg/m? 8 hours, Form: Total dust OSHA PEL (United States, 6/2016). TWA: 15 mg/m? 8 hours. Form: Total dust Recommended monit. procedures Exposure controls Appropriate engineering controls Individual protection measures + Ifthis product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures andlor the necessity to use respiratory protective equipment. Reference should be made to monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres - Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy) European Standard EN 14042 (Workplace atmospheres - Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents) European Standard EN 482 (Workplace atmospheres - General requirements for the performance of procedures for the measurement of chemical agents) Reference to national guidance documents for methods for the determination of hazardous substances will also be required. : Use only with adequate ventilation, Use process enclosures, local exaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limit, Use explosion-proof ventilation equipment.Date of esuerDate of rvision 15 October 2020 ms SECTION 8: Exposure | controls/personal protection Hygiene measures ‘Skin protection Hand protection Body protection Other skin protection Respiratory protection Environmental exposure controls. = Wash hands, forearms and face thoroughly after handling chemical products, before ‘eating, smoking and using the lavatory and at the end of the working period ‘Appropriate techniques should be used to remove potentially contaminated clothing, Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location, : Safety eyewear complying with an approved standard should be used when a risk ‘assessment indicates this is necessary to avoid exposure to liquid splashes, mists, {gases or dusts. If contact is possible, the following protection should be worn, Unless the assessment indicates a higher degree of protection: chemical splash ‘goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be Tequired instead. : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products ifa risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, ‘check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear antistatic protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Refer to European Standard EN 1149 for further information on material and design requirements and test methods, Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product, : Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fiting, training, and other important aspects of use. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. SECTION 9: Phy: ‘al and chemical proper Information on basic physical and chemical properties Physical state Color Oder Odor threshold pH Melting pointifreezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Upperllower flammabil explosive limits Vapor pressure Vapor density Liquid: : Not available. 2 Not available. : 2.3 ppm : Not applicable. : Not available. : Not available. : Closed cup: >26°C [Abel's close cup] 2 >4 (Butyl Acetate = 1) : Not available. 2 Lower: 0.8% Upper: 6.7% : 1.3 kPa [room temperature] : 3.7 [Air= 1]Date ofissue/Date of revision 15 October 2020 ang SECTION 9: Physical and chemical properties Relative density : 127 Solubility(ies) + Not available. Not available. Auto-ignition temperature : 432°C Decomposition temperature: Not available. Viscosity Not available, Explosive properties : Not available. Oxidizing properties : Not available. Other information Solubility in water Not available. SECTION 10: Stability and reactivity Reactivity + No specific test data related to reactivity available for this product or its ingredients. Chemical stability + The productis stable. Possibility of hazardous: Under normal conditions of storage and use, hazardous reactions will not occur. reactions Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, dri, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas, Incompatible materials : Reactive or incompatible with the following materials: oxidizing materials Hazardous decomposition: Under normal conditions of storage and use, hazardous decomposition products products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Product/ingredient name Result Species Dose Exposure ethylbenzene ILD50 Dermat Rabbit >5000mgikg | ILDS0 Oral Rat 3500 mgikg | butan-1-ol ILC50 inhalation Vapor Rat 24000 mgim?—_|4 hours ILD50 Dermal Rabbit 3400 mgikg ——|- ILD50 Oral Rat 790 mg/kg - o-fene ILD50 Oral Rat 3567 mgikg | vylene ILC50 Inhalation Gas. Rat 5000 ppm 4 hours ILD50 Oral Rat }4300 mgikg | Conclusion/Summary __: Not available. Acute toxicity estimates Route ATE value Oral [8073.3 maka Dermal 17860.5 mg/kg Inhalation (vapors) 12.7 mg niGorrosionDate ofissue/Date of revision 15 October 2020 ng SECTION 11: Toxicological information Product/ingredient name Result Species | Score | Exposure | Observation ethylbenzene Byes Severe irtant Rabbit ~ 500 Imitigrams ‘Skin - Mid irtant Rabbit - — fatnours 15 | - mitigrams reaction product: bisphenol- | Eyes - Mid irtant Rabbit = ftoo : /A-{epichlorhydrin}; epoxy Imiligrams resin (number average molecular weight s 700) ‘Skin - Moderate iritant Rabbit - [24 hours 600 | - microliters ‘Skin - Severe iritant Rabbit - — fethours2 | - mitigrams butan-t-ol Eyes - Severe irtant Rabbit - — fahours2 | - Imiligrams Eyes - Severe irritant Rabbit - — fo.o0s' - Miiters Skin - Moderate iitant Rabbit - f24hours 20. |- mitigrams titanium dioxide ‘Skin - Mild iritant Human | __{72 hours 300 | - IMicrograms intermittent ryfene Eyes - Mid iritant Rabbit - [87 milligrams | - Eyes - Severe irritant Rabbit + febhourss | - Imitigrams ‘Skin - Mid irtant Rat - |hours6o | - microliters ‘Skin - Moderate iritant Rabbit - [24 hours 500 | - nitigrams ‘Skin - Moderate iritant Rabbit = fto0 Percent | - Conclusion/Summary + Notavailable. Sonsitization Conclusion/Summary _—: ‘Notavailable. Mutagenicity Conclusion/Summary _—: ‘Notavailable. Carcinogenicity Conclusion/Summary _—: ‘Notavailable. Reproductive toxicity Conclusion/Summary _: ‘Notavailable. Teratogenicity Conclusion/Summary _—:-Notavailable. cific target organ toxicity (single exposure Productingredient name Category Route of | Target organs exposure utan-t-ol [Category3 __[Notapplicable, Respiratory tact irtation and Narcotic effects Specific target organ toxicity (repeated exposure) Productingredient name Category Route of | Target organs exposure ethylbenzene [Category2 __[Notdetermined [nearing organs Aspiration hazard Product/ingredient name Result ethylbenzene ‘ASPIRATION HAZARD - Category 1Date ofissue/Date of revision 15 October 2020 1013 SECTION 11: Toxicological information Information on the likely: Not available. routes of exposure Potential acute health eff Eye contact : Causes serious eye damage. Inhalation : Harmful if inhaled. Skin contact : Causes skin irritation, May cause an allergic skin reaction. Ingestion No known significant effects or critical hazards. ‘Symptoms related to the physical, chemical and toxicological characteristics Eye contact : Adverse symptoms may include the following: pain watering redness. Inhalation + No specific data. ‘Skin contact : Adverse symptoms may include the following: pain or iritation redness blistering may occur Ingestion : Adverse symptoms may include the following: stomach pains Delayed and immediate effects and also chronic effects from short and long term exposure ‘Short torm exposure Potential immediate Not available. effects Potential delayed effects: Not available. Lona term exposure Potential immediate : Not available. effects Potential delayed effects: Not available. Potential chronic health effects Not available. Conclusion/Summary Not available. General : May cause damage to organs through prolonged or repeated exposure, Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. Carcinogenicity + No known significant effects or critical hazards. Mutagenicity Teratogenicity + No known significant effects or critical hazards. + No known significant effects or critical hazards. Developmental effects No known significant effects or crtical hazards. Fertility effects + No known significant effects or critical hazards. Other information Not available. SECTION 12: Ecological information Toxicity