Chemistry Atomic Structure
Chemistry Atomic Structure
ATOMIC STRUCTURE
LATEST SYLLABUS- Key Concepts /Concerns
Atoms, Molecules and Radicals
An atom is the smallest particle of an element.
.It is not capable of independent existence
he propertics of an element depend upon the atoms constitutingit.
A molcule is the smallest particle of an element or compound, capable of independent existence, Ito
one or more than one atom of the same or different elements.
Aradical is a single atom of an element or a group of atoms of different elements behaving as single uni
Itconsists
with a charge on group. t
and
Atomicity (no.of atoms in an entity) of elements and compounds - mono atomic, di atomic, tri atomic, Pols.
Aociate the first 20 elements in the periodic table with their names and symbols yat
Valecy is the combining capacity of an element or the number of Inydogern atoms with which it combines orrenl
Learning Outcomes:
detine atom, molecule and radical;
eplacs
discuss the significance of valencyofelements and radicals;
define valency in tems of number of hydrogen atoms combined or replaced by one atom ot the elementg
apply the definition based on hydrogen atom to find out the valency of other elements and radicals;
Correlate the valency of the elements with
group number of periodic table.
[RADICALS|
It is the basic unit of matter.
An atom is the smallest particle of an element -
not capable of independent existence.
An element is made up of - only one kind of atoms.
Properties of an element - depend upon the atoms constitutingit
A molecule - is capable of independent existence & retains the characteristics of the substana
A molecule- is formed when atoms of the -
O2 H +
+H H,O
oxygen molecule water molecule
RADICAL
A radical is a single atom of an element or a group of atoms of different element
behaving as a single unit and with a - charge on the group.
A radical takes part - unsplit in a chemical reaction &t retains its identity.
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B .ATOM
Term, Structure & Modern Periodic Table
1 . ATOM- Term
1e Smallest particle of an
element - which is
atom is not made up of - only one kund of aro
An capable of
independent existence
The properties ot an
elemnt
depend upon - the atons constituling i.
ATOM- Basic structure
2.
e - electron
9p
PROTON
10n
NUCLEUS - contains NEUTRON
NUCLEUS
P-protons ELECTRON
An atom n neutrons
p-proton-has a jositTOediange |+1; e-electron has anegative charge[-1; n-neutron -has no cHauge
3.MODERN PERIODIC TABLE
Mendeleff [1869| - Classified elements systematically in a table c a l l e d - Moden Periodic Table|
GROUP GROUP
GROUP | GROUP GROUP GROUP GROUP GROUF
2 ATOMIC NUMBER
13 14 15 16 1 7 18
IAIIA IIIA IVA VA VIA VIIA 0
N Symbol of element
PERIOD
H MASS NUMBER Nitrogen
14 Ke
1
Myodrogen Heliem
PERIOD 10
Be F Ne
2 Lithlum Berylium Soron
N
Carbenitrogan Orygen Fivorine Heon
9 12 14 16 19 20
In the Modern Periodic Table - atoms of all elements are arranged according to their
increasing order of - atomic numbers
Z 6 =
6
Carbon atom Atomic number of carbon is 6.
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of structure of
atom
Brief history of discovery
ATOM Ancient views
1. STRUCTURE OF THE ATOM as Dalton's
thtomic tha
-
represented at.
Goldstein [1898)
Protons
Discovery of
-
Rutherford [1911]
Atonic nucleus
Discovery of
-
concluded that
Studied the atomic model &
a centrally
located 'nucle -
that
Studied the atomic model & concluded
in the nucleus of the atom are present
-
Further studies by Bohr led to the discovery of the moderm atomic theoy.
O L E C U L E Term, molecules of element, molecules of compounds
term
MOL
LECULE - The
1 . Atoms o f the same element or dfferent elements
a -
molecule'
to form
bine
H CI
H CI
Chlorine Hydrogen chloride
Oxygen Oxvgen Hydrogen molecule
atom molecule atom atom
Hydrogen atom H H
Nitrogen molecule
Nitrogen atom N N
3. MOLEcULE OF A - Compound
A molecule of a a compound -
is formed from -
Hydrogen [2 atoms| H
Oxygen [1 atom1 H
Water molecule
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MOLECULE Atomicity
ATOMICITY The term
of an element.
lt is the number of atoms present in a - molecule
1. MONOATOMIC MOLECULE
knowm as
one aton is monoatos:
-
mic moleg
eg. Noble gases
Xenon
Helium Neon Argon Krypton Radon
Kr Xe
He Ne Ar Rn
eg. Metals
Iron
Potassium Sodium Calcium Magnesiunm
Fe
Copper
Na Ca Mg Cu
K
2. DIATOMIC MOLECULE
element composed of
-
two atoms is known as diatom1C mole
A molecule of an
A molecule of a n
Ozone-O3
OzoneO3
4. POLYATOMIC MOLECULES
three atons is known
as -
polyatomic mola
of- more than
element composed
Amolecule of an Sulphur - Octatomic
Phosphorus - Tetratomic
S
S
S
Sulphur-S8
Phosphorus - P4
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p.RADICALs
- Term
R A D I C A L
1 .RAL
A m m o n i u m
NH 1 atom of nitrogen; 4 atoms of hydrogen
RADICAL
-
Types
3.
Radicals are of two
types
-
Negative radical
N H
H H
ONS
exist as ions
Ina salt the positive & negative parts
-
C Hydrogen chloride
'HCT
Naleney
de hChlorne
SO Sulphuric acid
Sulphate
-
HO
Three atoms of hydrogen - "3H One atom of nitrogen N Ammonia
NH Nitrogn
Valency of some elements which do not combine with hydrogen - then becomes
the combining power of the element with an element whose valency is known.
eg Magnesium combines with oxvgen - forming magnesium oxide
hence valency of nnagnesiun1 is
-MgO
- Two.
Valency of oxygen is two
Chemical combinations:
Chlorine Hydrogen Hydrogen chloride HCI
1 atom 1 atom 1 molecule
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yALENCYC CHART of elements &
radicals
.VALEN
NCIES
Of commor elements - for reference
Monovalent Divalent
Trivalent Tetravalent
K1 Calcium Ca2
/Polassiunm Aluminium A
Sodium
Nal+
Magnesium Mg*
Zinc Zn2
Copper1 1
Cul+ Copper [11] Cu2
Iron i Fe2 Iron [I1] Fe3+
Hydrogen Hl+
H Lead [I1] Pb2 Pb4+
Lead [IV
CI Oxygen 02
Nitrogen N3- Carbon
C h l o r i n e
loxide nitride
jchloride)
B r o m i n e
Br Sulphur S2
bromide
sulphide]
Iodine
iodide
Of radicals
VALENCIES
2.
Monovalent Divalent Trivalent
Ammonium NH
Bicarbonate HCO Carbonate co Phosphate PO
Bisulphite HSO Sulphite so3
Bisulphate HSO Sulphate so
Nitrate NO
Hydroxide OH
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CHEMICAL FORMULAS From symbols & valencies
F.
-
.
It is the representation of a substance by means
No. of atoms of
Substance Symbols each element present
1 atom of-i Chen
orm
Sodium chloride Na (sodiun], CI |dhlorine (chloride)]1 atom of - Na, C
writing Method of
2. CHEMICAL FORMULA
SYMBOL VALE
.To write a chemical formula you should know- lof the element/ radicall of the
he eleme
ent| ta
Step 1 Write eachsymbol uwith its valency
Step I1 -
Radical Formula
Compound Element
. A.Umbols && formulas of the reactants & products involved in the reactio
-
th
chorthand torm -
DILUTE
HYDROCHLORIC ACID
Sodium chloride + Water
NaCl+ H,O
SODIUM
HYDROXIDE
Reactants Products
NaOH + HC NaCl+H,O
REACTANTS PRODUCTS
1 atom of Cl chlorine
1 atom of CI - chlorine
element of reactant/s No. of atoms of each element of product/s.
No. of atoms of each
Therefore the above equation is said to be a 'balanced equation'
a molecular equation:
can be represented by a word equation &
The above reaction Sodium hydroxide +hydrochloric acid sodium chloride + water
Word equation:
Molecular equation: NaOH HCI NaCl +H,O
An equation must be balanced to comply with the 'law of conservation of natter'|
chemical reaction.
which states that matter is neither created nor destroyed during a
Balancing an equation
o
H. PERIODIC TABLE - Names & symbols of first twenty ol.
PLRIOD 19 20
K Ca I:lec. Config. 2,6
Potevelm Calclum
Z P Ino. of electrons]
39 40 atomic no. Ino, of protons
NAMES, SYMBOLS & VALENCY Of the first twenty elements in the modern periodic t
Atomic
Metal, Non-metal
NAME SYMBOL Valency or Gas [noble gas
No. [Z]
H +1 Non-metal
HYDROGEN Noble gas
HELIUM He
Li 3 Metal
LITHIUM Metal
Be 4
BERYLLIUM Metalloid
B 5 3
BORON 6 4 Non-metal
CARBON
NITROGEN N
Non-metal
gas
8 Non-metal gas
OXYGEN Non-metal
FLUORINE F 9 Igas
Ne 10 Noble gas
NEON Na 11 1t Metal
SODIUM Metal
MAGNESIUM Mg 12
ALUMINIUM Al 13 3t Metal
Si 14 4 Metalloid
SILICON
15 3 Non-metal
PHOSPHORUS 13.51
SULPHUR S 16 Non-metal
CI 17 Non-metal
CHLORINE
ARGON Ar 18 0 Noble gas
POTASSIUM K 19 Metal
CALCIUM Ca 20 2 Metal
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group number
P E R I O D I C
I C
T A B L E
-
PERIOD
TABLE - Group number & valency
ERIODIC
Showing elements - atomic number - 1 to 20
T h p e r o d i c t a b l e
GROUPGROUPGROUP
GOU
GROUP GROUT 18
16
GROUPP
9
At. No. 11 18
13 16
Ar
AI Si
PERIOD
Na Mg
Sodium Magnesium
Aluminium Saicon Phorphorus
31
Sulphur Chlerine
32 35.5
Argon
40
3 27 28
23 24
11p
12n
PERIOD 199
Potassium Calcium
39 40
Elec. Config. 2,8,1
Croup
electrons in the outer shell of all elements
in a group - is the same
Number of
same
in the s a m e group of the periodic table have
-
Valency Valency
Valency
Elements
Lithium Li 1 Beryllium Be 2 Fluorine F
Chlorine CI
11
Sodium Na 1 Magnesium Mg 2 1
2t Bromine Br
Potassium K 1 Calcium Ca
Highly reactive non-metals
Highly reactive metals Less reactive metals
Properties Good conductors of Bad or non-conductors of
Good conductors of
-
or
of electrons a n atom can
.Valency - is also the number of the nearest noble gas.
electronic configuration
-
so as to achieve stable
lon formed Nearest noble gas Valency
Nal+ [2, 8] Neon [Ne] [2, 8] 1
Na [2, 8, 1]
CI [2, 8, 71 +
el e Cil [2, 8, 8] Argon[Ar] |2, 8, 8] 1
53
EXERCISE
Atomic Structure
of the
eaning of term atom
a b] molecule cl
-
meaning
the
S t a t e
radical -
State
she
the
main
points
main points of contradiction of Dalton's atomic theory by the Modern Atomic Iheory.
the same elem
ement or different elements combine to form a molecule'.
oms of
5. ATOo examples each of - a atoms of the same element bl atoms of different elements
the term
6. Explain the -
10. Name the cation and the anion in the salt - calcium sulphate.
12. Give the symbol and valency of the following elements & radicals.
al potassium b] sodium c] hydrogen d] calcium e] aluminium f] magnesium gl zinc
h] chlorine [chloride] i] sulphur [sulphide] j] nitrogen [nitride] k] oxygen [oxide]
ammonium m] bicarbonate n] nitrate o bisulphate pl bisulphite q] hydroxide
rcarbonate s sulphate t sulphite
13. Give an example of three elements exhibiting variable valency.
14. State what is meant by the term - 'chemical formula'. Give the chemical formula of -
e5
OBJECTIVE TYPE QUESTIONS
Atomic Structure
retaine
characteristics of the substance.
difterent elements beha
of a group of atoms of
3. An elementary particle of matter
-
aving
single unit with charge on the group.
revoive.
around the nucleus of an atom in which electrons
4.Imaginary path
5. The term for the combining capacity of an element or the number ot hydrogen atom
which it combines or replaces.
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