Name: Erwin Golovashkin Date: 8/10/2020

Student Exploration: Collision Theory

NCVPS Chemistry Fall 2014
Vocabulary: activated complex, catalyst, chemical reaction, concentration, enzyme, half-life,
molecule, product, reactant, surface area

Prior Knowledge Questions (Do these BEFORE using the Gizmo.)

1. Suppose you added a spoonful of sugar to hot water and another to ice-cold water. Which

type of water will cause the sugar to dissolve more quickly? Hot Water

2. Suppose you held a lighted match to a solid hunk of wood and another match to a pile of

wood shavings. Which form of wood will catch fire more easily? Wood shavings

Gizmo Warm-up
A chemical reaction causes the chemical compositions
of substances to change. Reactants are substances that
enter into a reaction, and products are substances
produced by the reaction. The Collision Theory Gizmo™
allows you to experiment with several factors that affect
the rate at which reactants are transformed into products
in a chemical reaction.

You will need blue, green, and orange markers or colored

pencils for the first part of this activity.

1. Look at the key at the bottom of the SIMULATION pane. In the space below, draw the two
reactants and two products of this chemical reaction.

Reactants: Products:
A

B
A B
2. Click Play ( ). What do you see? Reactant A, Product A and Product B are moving
around while Reactant B is staying still. The Reactants then decrease with the products
increasing.
 Get the Gizmo ready:
Activity A:  Click Reset ( ).
 Check that the Reactant concentration is set to
Temperature
1.0 mol/L, the Catalyst concentration is set to
0.00 mol/L, and the Surface area is Minimum.

Question: How does temperature affect the rate of a chemical reaction?

1. Observe: Select the ANIMATION tab. View the animation with No catalyst selected.

What do you see? Reactant A reacts with Reactant B to form Product A and B.

When two reactant molecules meet, they form a temporary structure called an activated
complex. The activated complex breaks up into the product molecules.

2. Observe: Return to the CONTROLS pane. Set the Temperature to 0 °C and the Simulation
speed to its maximum setting. Click Play.

A. Describe the motions of the molecules. As they bounce their speed increases but
when they are not, their speed dramatically falls.

B. Now set the Temperature to 200 °C. How does increasing the temperature affect

the motions of the molecules? They bounce faster and collide more often causing a

increase in speed.

C. What do you notice about the chemical reaction at the higher temperature? The rate
increases.

3. Interpret: Select the GRAPH tab. Click the zoom out button ( ) until you can see the whole

graph. What does this graph show? How many reactants and products there are, and how

at the beginning there are more reactants but then later on more products.

4. Predict: How do you think temperature will affect the rate of a chemical reaction? When
temperature increases the rate also increases.

(Activity A continued on next page)

Activity A (continued from previous page)

5. Gather data: Click Reset. A useful way to compare reaction rates is to record the time
required for half of the reactants to react, called the half-life of the reaction. With the
Temperature set to 200 °C, click Play. Click Pause ( ) when the number of reactant
molecules is 10. Record the half-life time in the first space of the table below.

Trial 200 °C 150 °C 100 °C 50 °C

1 360 480 2098 2658
2 622 684 1038 5332

Mean half-life 8:11 min. 9:42 min. 26:8 min. 66:35 min.

Repeat the experiment at different temperatures to complete the table. (Note: To get exact
times, you can refer to the TABLE tab.)
1:2
Minute:Seconds
6. Calculate: Calculate the mean half-life for each temperature. Fill in these values above.

(Hint: To get an exact mean, first convert each time to seconds by multiplying the minutes
value by 60 and adding this to the seconds. To find the mean in seconds, add up the two
times and divide by two. Convert the answer back to minutes and seconds.)

7. Analyze: What do your results indicate? They indicate as the temperature decreases the
time increases for the chemical reaction to occur at the half life. Therefore the rate
decreased as the temperature decreased.

8. Draw conclusions: For two molecules to react, they must collide at just the right angle and
with enough energy to break the original bonds and form new ones. Based on these facts,
why does the reaction tend to go more quickly at higher temperatures?

Because when the temperature is higher, the molecules move faster leading to higher
chances of them hitting at the right angle.

9. Apply: Paper must be heated to 234 °C to begin reacting with oxygen. This can be done by
putting the paper over a flame. Why do you think the paper must be heated to start burning?
Because it needs a bit of time to react or in order for the molecules to hit each other at the
right angle.
 Get the Gizmo ready:
Activity B:
 Click Reset.
Surface area and  Check that the Catalyst concentration is set to
concentration 0.00 mol/L and the Surface area is Minimum.
 Set the Temperature to 200 °C.

Introduction: Reaction rates are also influenced by surface area and concentration. The
surface area of a solid is a measure of how much of the solid is exposed to other substances.
The concentration of a substance is a measure of how many molecules of that substance are
present in a given volume.

Question: How do surface area and concentration affect reaction rates?

1. Observe: Change the Surface area from Minimum to Maximum. How does this change
the amount of Reactant B molecules that are exposed to Reactant A?
The amount of reactants react quicker with the products and more of Reactant B are
exposed to Reactant A, leading to 2:24 minutes and 6 reactants and 14 products.
2. Predict: How do you think increasing the surface area will affect the rate of the reaction?

It will increase the rate.

3. Gather data: Set the Reactant concentration to 2.0 mol/L. Use the Gizmo to measure
the half-life of the reaction for each surface area setting. (There will now be 20 reactant
molecules left at the half-life.) Then, calculate the mean half-life for each setting.

Trial Minimum surface area Maximum surface area

1 232 1:00
2 300 :42
Mean half-life 4:26 0:51

4. Analyze: What do your results indicate? That when we increase the surface area the rate of
the reaction increases.

5. Explain: Why does the reaction proceed more quickly when the surface area is
increased?

Because when you increase the surface area, you increase the chance for exposing the
reactant to the other reactant.
(Activity B continued on next page)
Activity B (continued from previous page)

6. Observe: Click Reset. Move the Reactant concentration slider back and forth. What do
you notice?

The reactants positions changes and the amount of reactants decrease. The rate decreases as
you slide it closer to zero.

7. Predict: How will increasing the reactant concentration affect the rate of the reaction?
Why?

It’ll increase the rate of the reaction as when there are more reactants there is a better chance
of them being to exposed to each other and have a chance at reacting.
8. Gather data: Make sure the Temperature is 200 °C and the Surface area is Maximum.
Use the Gizmo to measure the half-life for each given reactant concentration. (Note that the
number of reactant molecules changes with each concentration.) Calculate the means.

Trial 0.4 mol/L 0.8 mol/L 1.2 mol/L 1.6 mol/L 2.0 mol/L
1 10:00 2:54 1:58 1:08 1:10
2 8:30 2:04 2:26 1:18 :46
Mean half-life 9:15 2:58 2:12 1:23 :58

9. Compare: If possible, find the mean times for each concentration for your entire class.
What is the mean class time for a concentration of 0.4 mol/L? How about for 2.0 mol/L?

Mean for 0.4 mol/L: 9:15 Mean for 2.0 mol/L: :58

10. Analyze: What do these results indicate? That has the reactant concentration increases the
rate increases and the time decreases.

11. Apply: Hydrochloric acid reacts with the mineral calcite to produce carbon dioxide gas,
water, and calcium chloride. Based on what you have learned in activity A and activity B,
what are three things you could do to make the reaction occur more quickly?
Increase the temperature, surface area and concentration.
 Activity C: Get the Gizmo ready:
Catalysts  Click Reset ( ).

Introduction: A catalyst is a substance that helps a chemical reaction to proceed. The catalyst
molecules are not changed by the reaction and can be reused over and over again.

Question: How do catalysts affect the rate of a chemical reaction?

1. Observe: Select the ANIMATION tab. Select With catalyst, and observe.

A. What do you see? Reactants get into a catalyst and that’s where the transferring of
atoms goes on.

B. Why do you think the shape of a catalyst is important? Because it is what tells you
what atom is transferred.

Many catalysts have a special shape that allows them to bind to specific reactant molecules.

2. Predict: How do you think catalysts will affect the rate of a chemical reaction? Increase
the rate.

3. Gather data: On the CONTROLS pane, set the Reactant concentration to 2.0 mol/L, the
Surface area to Maximum, and the Temperature to 50 °C. Measure the half-life for each
given catalyst concentration. Calculate the means.

Catalyst concentration
Trial
0.00 mol/L 0.05 mol/L 0.10 mol/L 0.15 mol/L
1 35:02 4:46 2:06 1:12
2 28:02 3:10 2:30 1:11

Mean half-life 31:32 3:58 2:18 1:11

4. Analyze: What do your results indicate? When you increase the concentration of
catalysts you then also increase the number of reactions and decrease the time.
(Activity C continued on next page)
Activity C (continued from previous page)

5. Explore: Set the Catalyst concentration to 0.00 mol/L and the Temperature to 0 °C.
Click Play, wait for 10 minutes of simulated time, and click Pause.

A. What happens? 6 products form

B. Click Reset, set the Catalyst concentration to 0.25 mol/L, and click Play. After 10

simulated minutes, click Pause. What happens now? 38 products formed

C. Why do you think the catalysts allowed the chemical reaction to take place at 0 °C?

Because of added energy.

6. Draw conclusions: What is the usefulness of catalysts? They increase the reaction rate.
7. Apply: Most of the chemical reactions inside your body rely on protein catalysts called
enzymes to take place. For example, the enzyme pepsin helps to break down protein
molecules in your stomach. What might happen if your stomach stopped producing pepsin?

The proteins we try to digest would not be broken down within the confines of our stomach.