Gen David CHM 101 PDF..-1
Gen David CHM 101 PDF..-1
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NOTE: QUESTION NO 10 SHOULD BE TREATED AS
THE ERROR THAT ARE NOT SUSCEPTIBLE TO MATHEMATICAL TREATMENT ARE
DETERMINATE ERROR (THIS SHOULD BE CHANGED IN GEN DAVID MANUAL)
1. One of the following is use of electrolysis
(a). Electroplating (b). Purification of metals (c). Manufacture of chlorine (d). Tin plating (e). All of the above
Answer:- E
2. Convert 6.3056 to 3 significant figure
(a). 6.32 (b). 6.31 (c). 6.34 (d). 6.30
Answer: B
3. Mn + 𝑍𝑛2+ → 𝑀𝑛2+ + Zn
Which of this in the equation oxidised?
(a). Z𝑛2+ (b). 𝑀𝑛2+ (c). Mn (d). Zn
Answer: C
4. In adding electron to the product side, the equation is said to be (a). Reduction (b). Addition (c). Oxidation (d).
Substitution s
Answer: C
5. What is the oxidation number of oxygen in peroxide?
(a). +1 (b). – 1 (c). +2 (d). – 2
Answer: B
6. Which of the following compound conduct electricity least
(a). Zinc (ii) Tetraoxosulphate vi (b). Ammonia (c). Sodium chloride (d). Sugar
Answer: D
7. Who discovered planetary model of atom? (a). J J. Thompson (b). Rutherford (c). Chadwick (d). John Dalton
Answer: B
8. Addition of electronegativity element is?
(a). Oxidation (b). Reduction (c). Redox (d). Substitution
Answer: A
9. If A and B are both gases, Ma and Mb are their masses respectively and Ea. and Eb are their velocity, which of
the following is true?
(a). Ea.> 𝐸𝑏 (𝑏). 𝐸𝑎 < 𝐸𝑏 (𝑐). 𝐸𝑎 = 𝐸𝑏 (𝑑). 𝐸𝑎 ≠ 𝐸𝑏
Answer: C
10. Which of the following is not susceptive to mathematical treatment?
(a). Methodical (b). Determinate (c). Constant (d). Systematic
Answer: B
11. During purification of copper, what is the anode reaction?
(a). Oxidation occurs/loss of electrons
(b).Reduction occurs/gain of electrons
(c). Oxidation occurs because there is gain of electrons
(d). Reduction occurs because there is loss of electrons
Answer: A
12. 𝑀𝑛𝑂4− is
(a). Reducing agent (b). Oxidising agent (c). Redox (d). None of the above
Answer: B
13. Equal volume of hydrogen gas and oxygen gas diffuses through a porous pot for 24s and 98s respectively,
calculate the relative between molar mass of hydrogen and oxygen gas
144 2401 576 144
(a). (𝑏). (𝑐). (𝑑).
2401 144 2401 9604
Answer: A
14. Who discovered atom
(a). Millikan (b). Rutherford (c). Chadwick (d). John Dalton
Answer: D
15. Calculate the time taken for 6.36g of copper (ii) tetraoxosulphate vi of the current of 10A (Cu = 63.5g/mol,
F=96500)
(a). 33.24min (b). 32.22min (c). 33.22min (d). 32.24min
Answer: B
16. Given a mean of 27.99 and the true value of 34.75. Calculate the relative error (a). – 0.195 (b). – 0.230 (c). –
0.994 (d). – 0.115
Answer: A
17. Atomic theory was supported by except (a). Law of multiple proportion (b). Law of definite proportion (c).
Frosh law (d). Proust’s law
Answer: C
18. Find the root mean square velocity of 8.7˚C, Molecular mass = 63.0Kg/mol
(a). 10.56m/s (b). 11.57m/s (c). 10.50m/s (d). 11.50m/s
Answer: A
19. Find the mean of 27.37, 27.87, 27.35, 27.45, 45.30, 11.00
(a). 20.50 (b). 27.5 (c). 27.51 (d). 20.51
Answer: C
20. How many mole of copper will be deposited in 1 faraday of copper II tetraoxosulphate (vi)
(a). 2 (b). 1 (c). 3 (d). 4
Answer: B
21. Which of this reaction is an oxidising agent
𝑀𝑛𝑂4− + 8𝐻 + → 𝑀𝑛2+ + 4𝐻2 O
(a). 𝑀𝑛𝑂4− (b). 𝑀𝑛2+ (c). 𝐻2 𝑂 (d). 𝑆𝑂42−
Answer: A
22. The mass number is the same thing as
(a). Proton number (b). Nucleon number (c). Electron number (d). Neutron number
Answer: B
23. What is the oxidation number of Mn in 2Mn𝑂4−
(a). +4 (b). +3 (c). +2 (d). +7
Answer: D
24. The oxidation number of carbon in 𝐶2 𝑂42−
(a). +3 (b). – 2 (c). – 1 (d). +2
Answer: A
25. The mean of the following CHM experiment
23.49, 24.69, 20.49, 62.54, 21.00
(a). 30.44 (b). 22.42 (c). 40.44 (d). 30.33
Answer: B
26. Accuracy is estimated in one of following
(a). Absolute error (b). Standard error (c). Probable error (d). Standard deviation
Answer: A
27. Round off 58.3 + 0.039 – 25.92 to 3 significant figure
(a). 32.41 (b). 32.42 (c). 32.4 (d). 22.4
Answer: C
28. Oxidation number of hydrogen is – 1 in which of the following
(a). NAOH (b). 𝐻2 𝑂2 (C). 𝑁𝑎 𝐻 (D). 𝐻2 𝑆𝑂4
Answer: C
29. Which of the following discovered electron
(a). Chadwick (b). Dalton (c). J.J Thompson (d). Millikan
Answer: C
30. Which of the scientist named electron
(a). G.J Stoney (b). J.J Thompson (c). Millikan (d). Chadwick
Answer: A
31. The scientist that calculate proton charge to mass ratio is
(a). J.J Thompson (b). G.J Stoney (c). Millikan (d). Chadwick
Answer: A
32. Oxidation is the addition of hydrogen and reduction is the addition of oxygen (a). True (b). False (c). None of the
above (d) all of the above
Answer: B
33. One of the following is not relate to precision
(a). Average deviation (b). Standard deviation (c). Probable error (d). Standard error
Answer: D
34. Which of the following is not an example of an electrolyte
(a).𝑁𝑎 𝑐𝑙 (b). Sugar solution (c). Acidified water (d). 𝐻2 𝑆𝑂4
Answer: B
35. Oxidation is the gain of electron while reduction is loss of electron
(a). True (b). False (c). I don’t know (d). A and B
Answer: B
36. Electron was discovered by who?
(a). Sir J.J Thompson (b). Isaac John Dalton (c). John Dalton (d).Chadwick
Answer: A
37. 4𝑀𝑛𝑂2 − + O𝐻 + → 𝑀𝑛2+ +𝐻2 𝑂
What is the change in the number of oxidation of Mn
(a). +4> +2 (b). +6 > +2 (𝑐). +8 > +2 (𝑑). +3 > +2
Answer: D
38. _____is the degree of closeness between replicate set of measurement or analysis
(a). Accuracy (b). Data (c). Precision (d). Error
Answer: C
39. Oxidation number of Na of NaOH is
(a). +2 (b). +1 (c). +3 (d). – 1
Answer: B
40. Who was the first person to invest mass spectrometer?
(a). Chadwick (b). Francis Aston (c). J.J Thompson (d). John Dalton
Answer: B
41. Which of the following is an Oxidizing Agent in the equation below 𝑀𝑛𝑂4− + 𝐹𝑒 2+ → 𝑀𝑛2+ + 𝐹𝑒 3+
(a). 𝑀𝑛𝑂4− (b). 𝐹𝑒 2+ (𝑐). 𝑀𝑛2+ (d). 𝐹𝑒 3+
Answer: A
42. Where does hydrogen said to be – 1
(a). Halides (b). Hydride (c). Peroxide (d). Hydroxyl
Answer: B
43. Oxidation is the addition of electropositive elements and reduction is the removal of electronegative elements
(a). True (b). False (c). I don’t know (d). None of the above
Answer: B
44. The oxidation of elements in its neutral state is
(a). +2 (b). – 2 (c). +1 (d). 0
Answer: D
45. X = equal volume of all gases at the same temperature and pressure contain an equal number of molecules
Y = number of molecules in one of gas of 6.0255× 1022
Which of the above is correct?
(a). X and Y(b). X only (c). Y only (d). X and Y are incorrect
Answer: B
46. Find the oxidation number of chromium in the oxidising agent 𝐾2 𝐶𝑟2 𝑂7
(a). +5 (b). +3 (c). +4 (d). +6
Answer: D
47. What is the oxidation number of hydrogen?
(a). – 1 (b). +2 (c). +1 (d). – 2
Answer: C
48. How many atom of copper are present in 35.4g of copper (Cu = 63.5)
(a). 3.35 × 1023 atoms (b). 3.02 × 1022 atoms (c). 3.35 × 1022 atoms (d). 3.35 × 1021 atoms
Answer: A
49. Convert 6.36500 to 3 significant figure
(a). 6.36 (b). 6.37 (c). 6.33 (d). 6.35
Answer: B
50. The oxidation number of oxygen in Hydrogen peroxide is
(a). +2 (b). –2 (c). +1 (d) –1
Answer: D
51. A boy measured the mass of a ball as 52.63g and the actual mass of the ball is 58.78g calculate the percentage
relative error
(a). –10.3% (b). –10.5% (c). –10.7% (𝑑). −10.13%
Answer: B
52. Precision is refer to as
(a). Measurement that are within 1 min (b). Highly accurate data (c). Level of measurement and exactness of
description in a data (d). Logical accuracy
Answer: C
53. Find the mean deviation of 4.31, 3.20, 4.09, 11.09, 3.02, 4.30 and 5.06 (a). 0.54 (b). 0.52 (c). 0.20 (d). 0.30
Answer: A
54. Who proposed atomic theory?
(a). James Chadwick (b). G.J Stoney (c). John Dalton (d). J.J Thompson
Answer: C
55. Oxidation number of Mn changes from ______to ______in the following reaction 2𝑀𝑛𝑂4− + 𝐶𝑂 + 14𝐻 + →
2𝑀𝑛2+ + 𝐶𝑂2 + 7𝐻2 𝑂
(a). +4 → +2 (𝑏). +7 → +2 (𝑐). +5 → +2 (𝑑). +2 → +7
Answer: B
56. The root mean square error of a cyanide in cassava is 0.45g, the mean of cyanide is 6.38.what is the variance of
the cyanide
(a). 0.2025 (b). 0.2051 (c). 0.0001 (d). 0.3594
Answer: A
57. Which of the following is the least conductor of electricity
(a). ZnS𝑂4 (𝑏). 𝐻𝐶𝑙 (𝑐). 𝑁𝐻3 (𝑑). 𝑁𝑎𝐶𝑙
Answer: C
58. Two samples A and B have a mass of Ma and Mb, kinetic energy Ea. and Eb where T is the temperature of the
gases, which of the following is correct
(a). Ea≠ 𝐸𝑏 (𝑏). 𝐸𝑎 = 𝐸𝑏 (𝑐). 𝐸𝑎 < 𝐸𝑏 (𝑑). 𝐸𝑎 > 𝐸𝑏
Answer: B
59. The addition of higher electronegativity elements is (a). Oxidation (b). Reduction (c). None of the above (d).
Redox
Answer: A
60. A scientist measured an object to have a mean of 6.36 while the value is 6.20. Calculate the percentage relative
error. (a). 3.57% (𝑏). 4.76% (𝑐). 2.58% (𝑑). 5.91%
Answer: C
61. In the purification of copper. What is the cathode half reaction?
(a).𝐶𝑢2+ + 2𝑒 − = 𝐶𝑢 (b). 𝐶𝑢2+ + 2𝑒 − = 2𝐶𝑢 (c).Cu→ 𝐶𝑢 2+ + 2𝑒 − (𝑑). 𝐶𝑢2+ + 2𝑒 − → 𝐶𝑢2+
Answer: A
62. _________is the electronic configuration of 17?𝐶𝑙
(a). 1𝑆 2 2𝑆 2 3𝑃6 4𝑆 2 4𝑃6 (𝑏). 1𝑠 2 2𝑝3 3𝑝4 4𝑠 6 (c). 1𝑠 2 2𝑠 2 2𝑝6 3𝑠 2 3𝑝5 (𝑑). 1𝑠 2 2𝑆 2 2𝑃6 3𝑆 2 3𝑃6
Answer: C
63. All these are basic law upon stoichiometry except
(a). Law of conservation of mass (b). Law of definite proportion (c). Law of multiple proportion (d). Law of
conservation of energy
Answer: D
64. Determinate error are classified into (a). 4 (b). 7 (c). 2 (d). 8
Answer: C
65. ________are error due to apparatus or reagent
(a). Instrumental error (b). Operative error (c). Personal error (d). Methodical error
Answer: A
66. Calculate the formula of a compound which has the following of magnesium of 9.8%, sulphur 13%, oxygen
26%, water of crystallization 51.2%
(a). Mg𝑆𝑂4 . 5𝐻2 𝑂 (b). MgS𝑂3 . 7𝐻2 𝑂 (𝐶). 𝑀𝑔𝑆𝑂4 . 7𝐻2 𝑂 (𝑑). 𝑀𝑔𝑆𝑂3 . 5𝐻2 𝑂
Answer: C
67. Round off to 3 significant figure 5.38 × 2,53 ÷ 3.23
(a). 4.41 (b). 5.30 (c). 7.310 (d). 4.21
Answer: D
68. Which of the following is an oxidising agent and reducing agent 𝐹𝑒2 𝑂3 + 3𝐶𝑂 → 2𝐹𝑒 + 3𝐶𝑂2
(a). 𝐹𝑒2 𝑂3 is a reducing agent and C𝑂2 is an oxidising agent (b). 𝐹𝑒2 𝑂3 is an oxidizing agent and 3CO is a
reducing agent (c). 𝐹𝑒2 𝐶𝑂3 is a reducing agent and 3CO is a oxidizing agent (d). 𝐹𝑒2 𝑂3 is a oxidizing agent and
C𝑂3 is reducing agent
Answer: B
69. How many numbers of moles of oxygen atoms are there in 0.3mole of 𝑆𝑂2
(a). 0.2mol (b). 0.4mol (c). 0.3mol (d). 0.6mol
Answer: D
70. R.A Millikan contributed in (a). Electron affinity (b).Neutron and Proton (c). Charge to mass ratio for the
electron (d) Nucleus
Answer: C
71. In the bombardment of the alpha particles, the positive ion are trapped in ________
(a). Magnetic field (b). Electric field (c). Ionization chamber (d). Vacuum pump
Answer: C
72. Millikan discovered? (a) Cathode ray (b). Proton ray (c). Charge on an element (d). Mass
Answer: C
73. Convert 5.36799 to 3 significant figure (a). 5.367 (b). 5.37 (c). 5.370 (d). 5.368
Answer: B
74. Given Zn/Z𝑛2+ //P𝑏 2+ /Pb where Z𝑛2+ /Zn = 0.76v and P𝑏 2+ /Pb = –0.13v. What is the EMF of the cell (a). 0.89v
(b).0.82v (c). 0.76v (d). 0.13v
Answer: A
75. Round off 5.83 + 0.069 – 2.29679 to 3 significant figure (a). 3.60 (b). 3.61 (c). 3.6 (d). 3.62
Answer: A
76. Which of the following is not one of the uses of electrolysis (a). Extraction of aluminium (b). Purification of
metals (c). Extraction of iron (d). Tin plating
Answer: C
77. Error is divided into (a). 3 (b). 4 (c).7 (d). 2
Answer: D
78. Atomic theory was supported by experimental evidences except (a). Law of conservation of mass (b). Law of
multiple proportion (c). Frose law (d). Avogadro’s law
Answer: C
79. _______is a chemical substance that dissociate in water to give proton (a). Acid (b). Base (c). Buffer solution
(d). Basic
Answer: A
80. Round up 6.7560 to 3 significant figure (a). 6.750 (b). 6.7560 (c). 6.76 (d). 6.756
Answer: C
81. Find the atom particle of mass 63g of copper (Cu = 63.5g/mol) (a). 5.0 × 1022 atoms (b). 5.96 ×
1023 atoms (𝑐). 4.96 × 1022 atoms (𝑑). 4.0 × 1023 atoms
Answer: B
82. Which of the following does not describe the gas theory
(a). Gravity does not attract gases because gases are so light that gravity does not acts on them (b). Gas
molecules moves in random motion (c). The kinetic energy function as its temperature increases (d). Gas
molecules contain of small molecules but large distance between them. (e). None of the options.
Answer: E
83. The method of coating the surface of a metal is ____ (a). Electroduction (b). Electroplating (c). Electrometal
(d). Electrolysis
Answer: B
84. In an electrochemical cell, the symbol / / represents _____ (a). Salt bridge (b). Electrolyte (c). Boundary (d).
Volt cell
Answer: A
[𝐻 + ]
85. If x = – 𝐿𝑜𝑔10 , [𝐻 + ] denotes (a). Equilibrium constant (b). Hydroxyl concentration (c). Degree of Hydrogen
concentration (d). Enthalpy change
Answer: C
86. Ionization energy decreases down the group due to (a). Increase in ionic radius (b). Increase in atomic radius
(c). Decrease in atomic radius (d). Decrease in ionic radius
Answer: B
87. The electronic configuration of isotope of an element is? (a). Different (b). Same (c). Similar (d). I don’t know
Answer: B
88. An error that varies from one measurement to another is called (a). Random error (b). Operative error (c).
Instrumental error (d). Systematic error
Answer: D
89. The difference between the experimental value and the true value is (a). Error (b). Mistake (c). Precision (d).
Accuracy
Answer: A
5.8 × 2.568
90. Calculate (a). 3.5581 (b). 3.56 (c). 3.55 (d). 3.6
4.186
Answer: D
91. Reducing agent ____ (a). Is reduced (b). Is oxidised (c). Gain electron (d). Decrease in the number of oxidation.
Answer: B
92. Oxidising agent ____ (a). Is reduced (b). Is oxidised (c). Loses electron (d). Increase in the number of oxidation
Answer: A
93. The shape of the D-orbital is (a). Spherical (b). Dumb bell (c). Spherical circular (d). Double dumb bell
Answer: D
94. Give the number of electrons in N𝑎+ and C𝑙 − (a). 11 and 17 (b). 10 and 17 (c). 10 and 18 (d). 12 and 18.
Answer: C
95. The screening effect is a factor that has more effect on the (a). Period (b). Group (c). Orbitals (d). Electron
shells
Answer: D
96. which of the following quantum numbers defines the main energy level the electrons occupies ____ (a).
Azimuthal (b). Magnetic (c). Spin (d). Principal
Answer: D
97. The nucleus of an atom consists of ____ and ____ (a). Proton and Neutron (b). Proton and electron (c).
Electron and Neutron (d).Mass no and Atomic no
Answer: A
98. Which of the scientists modified Dalton’s atomic theory (a). Chadwick (b). Niels Bohr (c). Millikan (d).
Rutherford
Answer: B
99. The mutual repulsion between electrons causing an increase in atomic radius is referred to as ____ (a).
Screening expulsion (b). Screening force (c). Screening effect (d). Inductive effect
Answer: C
100. In the arrangement of electrons in the orbital, electrons are arranged singly before pairing. Which law is
obeyed (a). Pauli’s (b). Dalton’s (c). Bohr’s (d). Hund’s
Answer: D
101. In a laboratory, a gaseous compound of carbon and hydrogen contain 80% carbon by mass. The molar mass of
the hydrocarbon is 30.2g. Calculate both the empirical and molecular formula of the hydrocarbon (C = 12, H =
1) (a). C𝐻3 and 𝐶2 𝐻6 (b). C𝐻4 and 𝐶2 𝐻6 (c). C𝐻3 and 𝐶3 𝐻6 (d). C𝐻4 and 𝐶3 𝐻6
Answer: A
102. Calculate the molarity of a solution which contain 6.00g of NaCl (Molar weight = 58.44) in 200c𝑚3 of the
solution. (a). 0.521 mold𝑚−3 (b). 0.413 mold𝑚−3 (c). 0.513 mold𝑚−3 (d). 0.214 mold𝑚−3
Answer: C
103. Calculate the amount of moles and in grams of KMn𝑂4 present in 3.00d𝑚3 of a 0.250M solution (MW =
158.0) (a). 0.75mol and 119g (b). 0.25mol and 158g (c). 0.75mol and 158g (d). 0.25mol and 119g
Answer: A
104. What mass of copper (II) sulphate could be obtained by starting with 10g of copper (II) oxide from the
following reaction
Cu𝑂(𝑠) + 𝐻2 𝑆𝑂4 (𝐿) CuS𝑂4 (𝑠) + 𝐻2 𝑂(𝐿)
1 : 1 1 : 1
(a). 20.02g (b). 20.1g (c). 20.09g (d). 20.45g
Answer: B
105. What is the number of copper atoms in one naira coin which weighs 7.39g (Assume the material from which
the coin was made contains 86% of Copper) (Cu = 63.5g/mol) (a). 6.20 × 1022 atoms (b). 6.20 × 1023 atoms
(c). 6.30 × 1023 atoms (d). 6.03 × 1023 atoms
Answer: A
106. 45.7c𝑚3 of 0.5mold𝑚−3 𝐻2 𝑆𝑂4 is required to react completely with 20c𝑚3 sample of sodium hydroxide
solution. What is the concentration of sodium hydroxide in mold𝑚−3 and gd𝑚−3 (a). 20.4mold𝑚−3 and 80.6
gd𝑚−3 (b). 2.29 mold𝑚 −3 and 80.6 gd𝑚−3 (c). 2.29mold𝑚−3 and 91.6 gd𝑚−3 (d). 4.29 mold𝑚−3 and 80.6
gd𝑚−3
Answer: C
107. A redox reaction is made up of ______ and _____ reaction (a). Oxidation and Reduct (b). Oxidation and
Oxidation (c). Oxidation and Reduction (d). Reduction and Reduction
Answer: C
108. What happen to the electrolyte in the electrolysis of copper (II) chloride solution using copper as the
electrodes? The electrolyte becomes (a). Unchnaged (b). Diluted (c). Acidic (d). Basic
Answer: A
109. Which of the following ions will migrate to the cathode during electrolysis? (a). C𝑙 − (b). Z𝑛2+ (c). 𝑆 2+ (d).
S𝑂42−
Answer: B
110. If 2S𝑂3(𝑔) ↔ 2S𝑂2(𝑔) + 𝑂2(𝑔) (∆𝐻 = −𝑣𝑒)
Which of the following factors will increase the yield of S𝑂2 ?
(a). Decrease in temperature (b). Increase in pressure (c). Increase in temperature (c). Addition of 𝑂2
Answer: A
111. The oxidation number of an uncombined atom of Lithium is (a). +1 (b). – 1 (c). I don’t know (d). 0
Answer: D
112. The name of the scientist that define the PH scale is
(a). Lauter Peter (b). Peter Sorenson (c). Peter Sorensen (d). Soren Sorenson
Answer: C
113. The solution that resists changes in PH when limited amount of acid or base is added to it is _____
(a). Acid (b). Base (c). Salt (d). Buffer
Answer: D
114. When an element loses an electron, it becomes (a). Positively charged (b). Negatively charged (c). Uncharged
(d). Neutral
Answer: A
115. When an element gain an electron, it becomes (a). Positively charged (b). Negatively charged (c). Uncharged
(d). Neutral
Answer: B
116. The substance that leads to a decrease in the oxidation number of a substance is called ____ (a). Oxidising
agent (b). Reducing agent (c). Redox (d). Reduxidation
Answer: B
117. The type of error caused by the tip of the pipette being broken can be classified as (a). Operative (b). Personal
(c). Indeterminate (d). Instrumental
Answer: D
118. A person claimed not to observe any colour change with using methyl orange indicator during acid-base
titration. This type of error is classified as ____ (a). Operative (b). Personal (c). Indeterminate (d). Instrumental
Answer: B
119. The electronic configuration of A𝑙 3+ is
(a). 1𝑠 2 2𝑠 2 2𝑝6 3𝑠 2 2𝑝4 (b). 1𝑠 2 2𝑠 2 2𝑝6 3𝑠 2 (c). 1𝑠 2 2𝑠 2 2𝑝6 (d). 1𝑠 2 2𝑠 2 2𝑝6 3𝑠 2 2𝑝1
Answer: C
120. Which of the following has the same electronic configuration as 18Ar (a). C𝑙 − (b). G𝑎+ (c). N𝑎 + (d). F𝑒 2+
Answer: A
121. Photolytic reaction take place in the presence of ____ (a). Heat (b). Catalyst (c). Light (d). Temperature
Answer: C
122. The balanced equation for the reaction
𝐶6 𝐻14 + 𝑂2 C𝑂2 + 𝐻2 O is
(a). 2𝐶6 𝐻14 + 19𝑂2 → 12C𝑂2 + 14𝐻2 O
(b). 𝐶6 𝐻14 + 7𝑂2 → 6C𝑂2 + 7𝐻2 O
(c). 2𝐶6 𝐻14 + 8𝑂2 → 6C𝑂2 + 7𝐻2 O
(d). 𝐶6 𝐻14 + 19𝑂2 → 12C𝑂2 + 14𝐻2 O
Answer: A
123. What mass of C𝐻3 C𝐻2 COOH would be dissolved in a mixture of 60g of 𝐻2 O and 55g of C𝐻3 C𝐻2 C𝐻2 OH. If
the mole fraction of propanoic acid is 0.054 (a). 17.89g (b). 17.48g (c). 17.91g (d). 17.08g
Answer: C
124. A combination of the two Faraday’s laws of electrolysis can be expressed mathematically as (a). m ∝ Q (b). m
∝ E (c). m ∝ It (d). m ∝ EIt
Answer: D
125. A Lewis base ____ (a). Donates protons (b). Accept protons (c). Donates lone pair of electrons (d). Accept a
lone pair of electrons
Answer: C
126. 𝐻2 𝑆(𝑔) + C𝑙2(𝑔) → 2HC𝑙(𝑔) + 𝑆(𝑔)
The Reducing agent in the above reaction is?
(a). 𝐻2 𝑆 (b). C𝑙2 (c). 2HC𝑙 (d). S
Answer: A
127. 2Mn𝑂4 + S𝑂32− + 𝐻 + → S𝑂42− + M𝑛2+ + 𝐻2 𝑂
Balance the above reaction in an acidic medium
(a). 2Mn𝑂4 − + 5S𝑂32− + 6𝐻 + → 2M𝑛2+ + 5S𝑂42− + 3𝐻2 O
(b). 4Mn𝑂4 − + 8S𝑂32− + 5𝐻 + → 2M𝑛2+ + 5S𝑂42− + 9𝐻2 O
(c). 2Mn𝑂4 − + 5S𝑂32− + 6𝐻 + → 8M𝑛2+ + 4S𝑂42− + 3𝐻2 O
(d). 4Mn𝑂4 − + 5S𝑂32− + 5𝐻 + → 2M𝑛2+ + 5S𝑂42− + 9𝐻2 O
Answer: A
128. In the reaction, 𝑁2 + 3𝐻2 → 2N𝐻3
The unit for 𝐾𝑐 for the reaction is
(a). mo𝑙 2 d𝑚−6 (b). mo𝑙 −2 d𝑚6 (c). mo𝑙 −2 d𝑚−6 (d). mo𝑙 2 d𝑚6
Answer: B
129. Consider the following equilibrium at 127℃. Calculate 𝐾𝑝 for the reaction, if 𝐾𝑐 = 2.6 × 10−5
2N𝐻3(𝑔) → 𝑁2(𝑔) + 3𝐻2(𝑔)
(a). 2.6 × 10−5 (b). 0.028 (c). 0.25 (d). 3.890
Answer: B
130. The element used as an electrode in car battery is?
(a). Potassium (b). Sodium (c). Magnesium (d). Lead
Answer: D
131. How many moles of hydrogen ion will be produced at the cathode during electrolysis of water with a current
of 4A for a period of 100s? (a). 2.07 × 10−3 mol (b). 4.14 × 10−3 mol (c). 2.07 × 10−2 mol (d). 4.14 ×
10−3 mol
Answer: A
132. The reaction of electrolysis takes place in a unit called? (a). Electrolyse (b). Electrote (c). Electrolyzer (d).
Electrode
Answer: C
133. The equilibrium constant of the reaction between 0.012mold𝑚−3 of propanol and 0.832mold𝑚−3 of butanoic
acid to give 0.174mold𝑚−3 propylbutanoate is (a). 4.03 (b). 3.03 (c). 5.03 (d). 6.03
Answer: B
146. Find the percentage by mass of nitrogen in Magnesium trioxonitrate v (a). 5.7% (b). 16.2% (c). 18.9% (d).
64%
Answer: C
147. What is the percentage by mass of carbon in limestone?
(a). 40% (b). 12% (c). 48% (d). 17%
Answer: B
148. An oxide of antimony is found to contain 24.73% oxygen. What is its empirical formula [Sb = 122, O = 16] (a).
S𝑏2 𝑂5 (b). S𝑏2 𝑂7 (c). S𝑏3 𝑂5 (d). S𝑏3 𝑂7
Answer: A
149. 8.00g of Iron when burned in air yielded 11.40g of it oxide. What is the empirical formula of this oxide? (a).
F𝑒𝑂3 (b). F𝑒2 𝑂5 (c). F𝑒3 𝑂3 (d). F𝑒2 𝑂3
Answer: D
150. The characteristics odour of pineapple is due to ethylbutyrate, a compound containing carbon, hydrogen and
oxygen. Combustion of 2.78mg of ethylbutyrate leads to formation of 6.32mg of C𝑂2 and 2.58mg of 𝐻2 𝑂.
Calculate the empirical formula (a). 𝐶6 𝐻10 𝑂2 (b). 𝐶6 𝐻12 𝑂2 (c). 𝐶6 𝐻12 𝑂 (d). 𝐶3 𝐻12 𝑂2
Answer: B
151. How many moles of ammonia gas are there in 500c𝑚3 of the gas (a). 0.032mol (b). 0.042mol (c). 0.022mol
(d). 0.052mol
Answer: C
152. What is the mass in grams of 1.45× 1023 molecules of sucrose 𝐶12 𝐻22 𝑂11 (a). 82.42g (b). 80.42g (c). 12.42g
(d). 81.42g
Answer: A
153. 45.7c𝑚3 of 0.5mold𝑚3 in 𝐻2 S𝑂4 is required to react completely with 20c𝑚3 sample of sodium hydroxide
solution. What is the concentration of sodium hydroxide in mold𝑚−3 and gd𝑚−3 .
(a). 4.29mold𝑚−3 and 91.6g/d𝑚3 (b). 2.29mold𝑚−3 and 80.6g/d𝑚3 (c). 4.29mold𝑚−3 and 80.6g/d𝑚3 (d).
2.29mold𝑚−3 and 91.6g/d
Answer: D
154. One mole of an ideal gas occupies 12L at 25℃. What is the pressure of the gas?
(a). 206kPa (b). 200kPa (c). 234kPa (d). 190kPa
Answer: A
155. If 12grams of 𝑁2 , 0.4grams of 𝐻2 and 9.0grams of 𝑂2 are put into a 1.00 litre container at 27℃. What is the
total pressure in the container? (a). 224atm (b). 22.4atm (c). 221atm (d). 21.2atm
Answer: B
156. For the dissociation of Sulphur (VI) oxide at 120℃, the value of 𝐾𝑝 with partial pressure is 1.78×10−6 atm.
Calculate the corresponding value of 𝐾𝑐 assuming ideal behaviour of gases. [R = 0.08205d𝑚3 atm
mo𝑙 −1 𝐾 −1 ]. (a). 7.52×10−8 mold𝑚−3 (b). 6.52×10−8 mold𝑚−3 (c). 5.52×10−8 mold𝑚−3 (d).
8.52×10−8 mold𝑚−3
Answer: C
157. In 1895, ______ discovered that uranium salts emitted certain rays which had penetrating properties.
(a). Newton (b). Charles (c). Henry (d). Becquerel
Answer: D
158. Arrange the following in order of increasing frequency (𝛼, 𝛽, 𝛾)
(a). 𝛼 < 𝛽 < 𝛾 (b). 𝛼 > 𝛽 > 𝛾 (c). 𝛾 < 𝛽 < 𝛼 (d). 𝛾 > 𝛽 > 𝛼
Answer: A
159. 110g of a material was found to be 55g in 6 minutes. What is its half-life? (a). 16mins (b). 6mins (c). 6secs
(d). 7mins
Answer: B
160. If 10g out of 20g of substance Y present initially decomposed in 10seconds. The half-life is?
(a). 10sec (b). 5sec (c). 15sec (d). 30sec
Answer: A
161. Iodine-131 has a half-life of 8days. If there are 200grams of this sample, how much of I-131 will remain after
32days? (a). 10.4g (b). 9.5g (c). 12.5g (d). 16.4g
Answer: C
CONTACT GEN DAVID FOR SECOND SEMESTER ON 07063776455, 08078959590. WE HAVE
TESTIMONIES FROM INCEPTION
NOTE: QUESTION NO 10 SHOULD BE TREATED AS
THE ERROR THAT ARE NOT SUSCEPTIBLE TO MATHEMATICAL TREATMENT ARE
DETERMINATE ERROR (THIS SHOULD BE CHANGED IN GEN DAVID MANUAL)