1 - Atomic Structure Exercise
1 - Atomic Structure Exercise
Dev…
ATOMIC STRUCTURE
SOLVED EXAMPLES
Ex.1 A particle after passing through a potential Ex.4 A hydrogen atom rises from its n = 1 state to the
difference of V volt collides with a nucleus. If n = 4 state by absorbing energy. If the potential
the atomic number of the nucleus is Z then the energy of the atom in the n = 1 state be –13.6
distance of closest approach of -particle to the eV, then potential energy in the n = 4 state will
nucleus will be- be -
Z Z (A) 3.4 eV (B) –1.54 eV
(A) 14.4 Å (B) 14.4 m (C) 0.85 eV (D) –0.85 eV
V V
Rch
Z Sol. En = –
(C) 14.4 cm (D) All of the above n2
V
k ( Ze)( 2e) Given E1 = –13.6 eV = –Rch
Sol. Ek = U, 2eV =
d Rch E1
E4 = Energy of 4th state = – = ,
2
k Ze Z 4 16
d= = 9 × 109 × 1.6 × 10–19 ,
V V 13.6
E4 = – = –0.85 eV
Z Z 16
d = 14.4 × 10–10 m = 14.4 Å
V
V
Ex.2 The radius of hydrogen atom in the ground state Ex.5 The wavelength of the first line of lymen series
is 5.3 × 10–11 m. If this atom collides with an for hydrogen is identical to that of the second
electron then its values becomes line of Balmer series for some hydrogen like ion
21.2 × 10–11 m. The value of principal quantum x. Energies of two levels of x will be : (Ground
number will be- state binding energy of hydrogen atom = 13.6
(A) 2 (B) 16 eV)
(C) 3 (D) 4 (A) –54.4 eV, –6.07 eV
2
r2 n n2 r (B) –13.6 eV, –3.4 eV
Sol. = 2 , n22 = 1 2
r1 r1 (C) –3.4 eV, –13.6 eV
n1
(D) –54.4 eV, –13.6 eV
r2 Sol. We know that
n2 = n1 n2 = 1
r1 1
1 1
= RZ2
21.2 10 11 n2 n2
1 2
5.3 10 11 For first line of Lyman series in hydrogen atom
n2 = 2 1 1 1 3R
=R 2 2=
Ex.3 An electron revolves round a nucleus of charge 1 1 2 4
Ze. In order to excite the electron from the state
n = 3 to n = 4, the energy required is 66.0 eV. Z For second line of Balmer series of hydrogen
will be - like ion x
(A) 25 (B) 10 (C) 4 (D) 5 1 1 1 3Z 2 R
Sol. Energy of hydrogen atom = Z2R 2 2 =
2 2 4 16
1 1 7
= 13.6 2
eV = 13.6 × eV = .66 Given that, 1 = 2
3 4 144
eV 3R 3Z 2 R
= Z=2
The ionisation potential of hydrogen 4 16
= 13.6 eV Energy of nth state of ion X is given by
En Z2
Ex = –
13.4
× Z2, (Ex)1 = –
13.4 4
66
Z2 = = 100, Z = 10 n2 1
0.66
= – 54.4 eV
SCO – 63, TOP FLOOR, SECTOR – 46C, CHANDIGARH M. – 9888207644 PAGE NO.- 1
Run By Er. Dev…
13.4 4 = –13.6 eV Sol. In sodium spectrum only two lines are obtained
(Ex)2 = –
4 whose wavelengths are 5890 Å and 5896 Å
respectively.
Ex.6 The wavelength of the first member of the The excitation energy between there energy
Balmer series in hydrogen spectrum is 6563 Å. levels will be-
Calculate the wavelength of first member of hc 1 1 hc 1 2
E = , E =
Lyman series in the same spectrum. e 1 2 1 2
(A) 1000 Å (B) 1215.37 Å
(C) 1512 .37 Å (D) None 6.62 10 34 3 108 6 10 10
E =
Sol. For the first member of the Balmer series 1.6 10 19 5896 5896 10 20
1 1 1 E = 2.1 eV,
= =R 2 2
1 2 3 Excitation potential V = 2.1 volt
5
= R .... (1) Ex.9 The radius of first orbit of hydrogen atom is
36
0.53 Å. The radius of its fourth orbit will be-
For the first member of Lyman series
(A) 0.193 Å (B) 4.24 Å
1 1 1 (C) 2.12 Å (D) 8.48 Å
= =R 2 2
2 1 2 Sol. 2
rn = 0.53 n , n = 4
3R r4 = 0.53 × 16
=
4 r4 = 8.48 Å
.... (2)
Dividing eq. (1) by eq.(2) , we get Ex.10 The wavelength of D1 and D2 lines of sodium
2 5 5 are 5890 Å and 5896 Å respectively, if their
= or 2 = mean wavelength is 6000 Å then the difference
1 27 27 1 of exicted energy states will be
5 6563 (A) 2 × 103 eV (B) 2 × 10–3 eV
2 = = 1215.37 Å 6
27 (C) 2 × 10 eV (D) 2 eV
hc hc
Sol. E= E = 2
Ex.7 The radius of first orbit of hydrogen atom is
0.53 Å and the electron is executing 6.62 10 34 3 108 6 10 10
6.54 × 1015 revolutions per second. The E =
6000 6000 10 20
magnetic moment of electron will be-
E = 3.31 × 10–22 J
(A) 9.3 × 10–24 Amp-m2
3.31 10 22
(B) 6.54 × 10–27 Amp-m2 E = 2 × 10–3 eV
16 10 19
(C) 6.54 × 10–24 Amp-m2
(D) 5.3 × 10–24 Amp - m2 Ex.11 An electron makes transition from n = 4 state to
Sol. = iA = efA = efr2 n = 1 state in hydrogen atom. The momentum of
recoil hydrogen atom in kg-m/s will be-
= 1.6 × 10–19 × 6.54 × 1015 × 3.14
(A) 12.75 × 10–19 (B) 13.6 × 10–19
× (0.53 × 10–10)2 (C) 6.8 × 10 –27 (D) zero
= 9.3 × 10–24 Amp-m2 Sol. According to law of conservation of
momentum of recoil atom
Ex.8 The wavelength of first and second lines of E 4 E1
= momentum of photon =
sodium are 5890 Å and 5896 Å respectively. Its C
first excitation potential will be- 19
12.75 1.6 10
(A) 4.1 V (B) 10.2 V P=
(C) 2.1 V (D) 3.7 V 3 108
= 6.8 × 10–27 kg-m/s
SCO – 63, TOP FLOOR, SECTOR – 46C, CHANDIGARH M. – 9888207644 PAGE NO.- 2
LEVEL # 1
Questions Q.5 In Rutherford’s -particle scattering experiment,
based on Scattering experiment
the ratio of number of -particles scattered
through an angle of 60º and 120º is -
Q.1 The path of the scattered -particles is - (A) 1 : 2 (B) 3 : 1
(A) circular (B) parabolic (C) 3 : 1 (D) 9 : 1
(C) elliptical (D) hyperbolic
Questions
based on Distance of closest approach
Q.2 Which of the following forces is responsible for
- particle scattering ?
Q.6 An -particle of energy 5 MeV is scattered
(A) Gravitational (B) Nuclear
through 180º by a stationary uranium nucleus.
(C) Coulomb (D) Magnetic
The distance of closest approach is of the order
of -
Q.3 A beam of -particle is incident on a gold foil. (A) 1Å (B) 10–10 cm
corresponding to the incident beams A, B and –12
(C) 10 cm (D) 10–15 cm
C, the emergent beams A, B and C. The
transmission and deflection of -particles through Questions Radius and velocity of electron
the foil take place such that - based on in circular orbit
C
Q.7 The radius of first orbit of hydrogen atom is
A 0.53Å. The radius of its fourth orbit will be -
C
A (A) 0.193 Å (B) 4.24 Å
B
B (C) 2.12 Å (D) 8.48 Å
(A) The number of -particle in A is maximum Q.8 The ratio of the radius of a hydrogen like atom
in the ground state & that of one in the second
and in B minimum
excited state is -
(B) The number of -particles in A is minimum
(A) 1 : 9 (B) 1 : 4
and in C maximum
(C) 1 : 3 (D) 1 : 2
(C) The number of -particles in A, B and in
C is the same. Q.9 If the radius of the first orbit of hydrogen atom
(D) The number of -particles in B is minimum is 5.29 × 10–11 meter, the radius of the second
and in C maximum orbit will be -
(A) 21.16 × 10–11 m (B) 15.87 × 10–11 m
Q.4 In Rutherford’s experiment, the number of (C) 10.58 × 10 m–11
(D) 2.64 × 10–11 m
alpha particles scattered through an angle of 60º
by a silver foil is 200 per minute. When the Q.10 The velocity of an electron in ground
silver foil is replaced by a copper foil of the state of H-atom is nearly
(A) 2 × 10 5 m/s (B) 2 × 10 6 m/s
same thickness, the number of -particles
(C) 2 × 10 7 m/s (D) 2 × 10 8 m/s
scattered through an angle of 60º per minute is -
2
Z Cu Z Q.11 The ratio of the radii of Bohr orbits in hydrogen
(A) 200 × (B) 200 Cu
Z Ag Z Ag atom in increasing order is -
(A) 2 : 4 : 8 : 16 (B) 2 : 3 : 4 : 5
2
Z Ag Z Ag (C) 1 : 3 : 6 : 9 (D) 1 : 4 : 9 : 16
(C) 200 × (D) 200 ×
Z Cu Z
Cu
Q.12 The radius of electron’s second stationary orbit Q.18 Which of the following parameters are the same
in Bohr’s atom is R. The radius of the third orbit for all hydrogen-like atoms and ions in their
will be- ground states ?
(A) 3R (B) 2.25 R (A) radius of the orbit
(C) 9 R (D) R/3 (B) speed of the electron
(C) energy of the atom
Q.13 The ratio of the area of orbit of first excited (D) orbital angular momentum of the electron
state of electron to the area of orbit of ground
level, for hydrogen atom, will be - Q.19 Choose the correct relation from the following
(A) 2 : 1 (B) 4 : 1 for hydrogen like atoms -
(C) 8 : 1 (D) 16 : 1 (A) rn = n2r1, En = E1/n2, vn = v1/n
(B) rn = r1/n2, En = n2E1, vn = v1/n
Q.14 The electron in a hydrogen atom jumps from
(C) rn = r2/n2, En = E1/n2 , vn = v1/n2
ground state to the higher energy state where its
velocity is reduced to one-third its initial value. (D) rn = n2r, En = n2E1, vn = n2v1.
If the radius of the orbit in the ground state is r,
the radius of new orbit will be - Q.20 The angular velocity of an electron moving in
(A) 3r (B) 9r the nth orbit of Bohr hydrogen atom is -
r r (A) directly proportional to n
(C) (D) (B) inversely proportional to n
3 9
(C) inversely proportional to n2
Q.15 The ratio of velocities of electron in H-atom in (D) inversely proportional to n3
its first, second & third orbit respectively will
be - Q.21 The ratio of frequency of revolution of electrons
(A) 6 : 3 : 1 (B) 3 : 2 : 1 in first and second Bohr’s orbit of He-atom is -
(C) 6 : 3 : 2 (D) 1 : 3 : 6 (A) 4 : 1 (B) 1 : 4
(C) 8 : 1 (D) 1 : 8
Q.16 From Bohr’s theory the product of the radius
and the velocity of the electron in different Q.22 The ratio of the energies of the hydrogen atom
orbits is - in its first to second excited state is -
(A) constant (A) 1/4 (B) 4/9
(B) proportional to the square root of radius (C) 9/4 (D) 4
(C) proportional to the radius
(D) proportional to the square of the radius Q.23 The angular momentum of electron in hydrogen
atom is proportional to -
Questions Energy of electron in Bohr's (A) r (B) 1/r (C) r2 (D) 1/r
based on circular orbit
Q.24 Which of the following products in a hydrogen
Q.17 Ionisation energy of a hydrogen like ion A is atom are independent of the principal quantum
greater than that of another hydrogen like ion B. number n ? The symbols have their usual
Let r,u, E and L represent the radius of the meanings ?
orbit, speed of the electron, energy of the atom (A) vn (B) Er (C) En (D) vr
and orbital angular momentum of the electron
respectively. In ground state - Q.25 The energy of an atom (or ion) in its ground
(A) rA > rB (B) uA > uB state is – 54.4 eV. It may be -
(C) EA > EB (D) LA > LB (A) hydrogen (B) deuterium
(C) He +
(D) Li++
Q.26 The kinetic energy of an electron in second Q.33 As per Bohr model, the minimum energy (in eV)
Bohr orbit of hydrogen atom will be - required to remove an electron from the ground
(A) 13.6 eV (B) 6.8 eV state of doubly ionized Li atom (Z = 3) -
(C) 3.4 eV (D) 1.7 eV (A) 1.51 (B) 13.6
(C) 40.8 (D) 122.4
Q.27 When a hydrogen atom is raised from the
ground state to an excited state - Q.34 An electron jumps from the 4th orbit to the 2nd
(A) the P.E. decreases and K.E. increases
orbit of hydrogen atom. Given : the Rydberg’s
(B) the P.E. increases and K.E. decreases
constant R = 105 cm–1. The frequency in Hz of
(C) both K.E. and P.E. increases
the emitted radiation will be -
(D) both K.E. and P.E. decrease
3 3
(A) 10 5 (B) 1015
Q.28 The first excitation potential of given atom is 16 6
10.2 volt. Then ionization potential must be - 9 3
(C) 1015 (D) 1016
(A) 20.4 volt (B) 13.6 volt 16 4
(C) 30.6 volt (D) 40.8 volt
Q.35 A hydrogen atom in ground state absorbs 10.2 eV
Q.29 If En and Jn are the magnitude of total energy of energy. The orbital angular momentum of the
and angular momentum of electron in the nth electron is increased by -
Bohr orbit respectively, then - (A) 1.05 × 10–34 J-s (B) 2.11 × 10–34 J-s
1 (C) 3.16 × 10–34 J-s (D) 4.22 × 10-34 J-s
(A) E Jn2 (B) En
J 2n
1 Q.36 The binding energy of H-atom in its ground
(C) E Jn (D) En state is 13.6 eV. The energies required to
Jn
remove an electron from the three lowest orbits
Q.30 The angular momentum of an electron in a of the H-atom are respectively(in eV) -
given orbit is J. Its kinetic energy will be - (A) 13.6 , 10.2 , 3.4 (B) 13.6 , 3.4 , 1.5
1 J2 Jv (C) 10.2, 1.9, 0.7 (D) 13.6, 6.8 , 1.5
(A) (B)
2 mr 2 r
Q.37 The energy of an electron in the first Bohr orbit
J2 J2
(C) (D) for hydrogen is –13.6 eV. Which one (s) of the
2m 2
following is (are) possible excited state (s) for
electrons in Bohr orbits of hydrogen –
Q.31 The minimum energy in electron volt required
(A) – 3.4 eV (B) – 6.8 eV
to skip a ten times ionised sodium atom (i.e. Z = 11)
(C) – 1.7 eV (D) 13.6 eV
of its last electron is -
13.6
(A) 13.6 eV (B) eV Q.38 The binding energy of the hydrogen atom in the
11
first excited state is –
(C) 13.6 × 11 eV (D) 13.6 × (11)2 eV
(A) 13.6 eV (B) 10.2 eV
Q.32 Total energy of electron in the first orbit of (C) 3.40 eV (D) 1.51 eV
hydrogen atom is equal to the -
(A) total energy of electron in 2nd orbit of He+ Q.39 How much energy is required to remove the
(B) total energy of electron in 3rd orbit of He+ electron from a He+ ion in its ground state ?
(C) total energy of electron in 2nd orbit of Li++ (A) 1.5 eV (B) 13.6 eV
(D) total energy of electron in 4th orbit to Li++ (C) 54.4 eV (D) 122.4 eV
Q.40 The potential energy (U) and the kinetic energy Q.47 The wavelength of radiation required to excite
(K) of an electron in the ground state of an electron from first to third Bohr orbit in a
hydrogen atom is - doubly ionised lithium atom will be -
(A) U = – 13.6 eV ; K = – 13.6 eV (A) 113.74 m (B) 113.74 cm
(B) U = – 27.2 eV ; K = – 13.6 eV (C) 113.74 Å (D) 113.74 mm
(C) U = – 27.2 eV ; K = + 13.6 eV
(D) U = – 6.8 eV ; K = – 6.8 eV Q.48 Any series of atomic hydrogen yet to be
discovered will probably be found in the
Questions following region of the spectrum -
based on Spectral lines
(A) X-ray (B) Ultraviolet
Q.41 A spectral line is emitted when an electron - (C) Visible (D) far infrared
(A) rotates in the circular orbit
Questions
(B) rotates in the elliptical orbit based on Reduced mass concept
(C) jumps from lower orbit to higher orbit
(D) jumps from higher orbit to lower orbit Q.49 The electron and positron form a positronium
atom (e–, e+ revolve round the centre of mass of
Q.42 Which of the following is true ? the system). Then, the ground state energy of
(A) Lyman series is a continuous spectrum this system is -
(B) Paschen series is a line spectrum in the (A) –13.6 eV (B) –27.2 eV
infrared (C) –6.8 eV (D) zero
(C) Balmer series is a line spectrum in the
ultraviolet Q.50 The radius of first orbit of muon-proton system
(D) The spectral series formula can be derived will be , if muon is 207 times heavier than
from the Rutherford model of the hydrogen electron -
atom 0.529 0.529
(A) 2 Å (B) Å
(186) (186)
Q.43 The minimum wavelength in Lyman series is -
(C) 0.529 × 186 Å (D) 0.529 × (186)2Å
1 1
(A) (B) R (C) (D) Rc
R RC
Q.51 The energy in the ground states of muon-proton
system will be -
Q.44 Out of the following transitions, the frequency
(A) –13.6 × 207 MeV (B) –13.6 × 186 eV
of emitted photon will be maximum for -
(C) 13.6 × 186 MeV (D) 13.6 × 207 eV
(A) n = 5 to n = 3 (B) n = 6 to n = 2
(C) n = 2 to n = 1 (D) n = 1 to n = 2
Questions
based on Recoiling of atom
Q.45 If an electron jumps from third orbit to second
orbit in hydrogen atom, then the wavelength of Q.52 An electron jumps from n = 4 to n = 1 state in
emitted photons, will be - H-atom. The recoil momentum of H-atom
36 5R (in eV/C) is -
(A) (B)
5R 36 (A) 12.75 (B) 6.75
4R 34 (C) 14.45 (D) 0.85
(C) (D)
34 4R Q.53 An excited hydrogen atom initially at rest in n = 3
state, emits a photon by making a transition to
Q.46 The wavelength of first line of Balmer series is
ground to state. Then the momentum of the
6563 Å. The wavelength of first line of Lyman
hydrogen atom will be (in N.s) -
series will be -
(A) 6.45 × 10–27 (B) 6.63 × 10–34
(A) 1215.4 Å (B) 2500 Å
(C) 2.15 × 10–27 (D) none of the above
(C) 7500 Å (D) 600 Å
LEVEL # 2
Q.1 In an electron transition inside a hydrogen atom, given below, the shortest wavelength is produced
orbital angular momentum may change by by -
(h = Plank constant) - (A) hydrogen atom
h (B) deuterium atom
(A) h (B) (C) singly ionized helium
(D) doubly ionized lithium
h h
(C) (D) Q.9 Bohr's atom model assumes -
6 4
(A) the nucleus is of infinite mass and is at rest
Q.2 When a hydrogen atom emits a photon of (B) electron in a quantized orbit will not radiate
energy 12.1 eV, its orbital angular momentum energy
changes by - (C) mass of the electron remains constant
(D) all of these
(A) 1.05 × 10–34 J s (B) 2.11 × 10–34 J s
(C) 3.16 × 10 J s
–34
(D) 4.22 × 10–34 J s
Q.10 Figure represents in simplified form some of the
energy levels of the hydrogen atom. The energy
Q.3 In Bohr model of the hydrogen atom, let R, V axis has a linear scale
and E represent the radius of the orbit, the speed E4
Increasing energy
of electron and the total energy of the electron E3
respectively. Which of the following quantities
is proportional to the quantum number n ? E2
(A) R/E (B) E/V
(C) RE (D) VR
E1
Q.4 If the radius of first orbit of hydrogen atom is If the transition of an electron from E4 to E2
0.5 Å and the velocity of electron in this orbit is were associated with the emission of blue light,
2 × 106 m/s, then the electric current due to which transition could be associated with the
electron motion will be nearly - absorption of red light ?
(A) 1 mA (B) 1 A (A) E4 to E1 (B) E3 to E2
(C) 1 A (D) None of these (C) E2 to E3 (D) E1 to E4
Q.5 The maximum Coulomb force that can act on Q.11 A mixture of ordinary hydrogen and tritium, is
the electron due to the nucleus in a hydrogen excited and its spectrum observed. Then, the
atom will be - ratio of the wavelengths of the H lines of the
(A) 0.82 × 10–8 N (B) 0.082 × 10–8 N two kinds of hydrogen would be nearly -
(C) 8.2 × 10 N
–8
(D) 820 × 10–8 N (A) 1 : 1
(B) 1 : 3
(C) 3 : 1
Q.6 The ionization potential of H-atom is
(D) nothing can be predicted
13.6 V. The H-atoms in ground state are excited
by mono chromatic radiations of photon energy Q.12 The second line of Balmer series has wavelength
12.09 eV. Then the number of spectral lines 4861 Å. The wavelength of the first line of
emitted by the excited atoms, will be - Balmer series is -
(A) 1 (B) 2 (A) 1216 Å (B) 6563 Å
(C) 3 (D) 4 (C) 4340 Å (D) 4101 Å
Q.7 Assume that there exist an atom, according to Q.13 The ionisation potential of H atoms is 13.6 V.
Bohr model, whose first ionization potential is The energy difference between n = 2 and
n = 3 levels is nearest to -
20 V, then the value of first excitation potential
(A) 1.9 eV (B) 2.3 eV
for this atom will be -
(C) 3.4 eV (D) 4.5 eV
(A) 5 V (B) 10 V Q.14 If the wavelength of photon emitted due to
(C) 15 V (D) 25 V transition of electron from third orbit to first
Q.8 Consider the spectral line resulting from the orbit in a hydrogen atom is , then the
transition n = 2 n = 1 in the atoms and ions
wavelength of photon emitted due to of electron transition from level B to A). Which of the
from fourth orbit to second orbit will be - following spectral lines will also occur in the
128 25 absorption spectrum ?
(A) (B) C
27 9
B
36 6
(C) (D) None of these
7 A
4 5
Q.15 If radiation of all wavelengths from ultraviolet x
1 2 3
to infrared is passed through hydrogen gas at
(A) 4, 5, 6 (B) 1, 2, 3, 4, 5, 6
room temperature absorption lines will be
(C) 1, 4, 6 (D) 1, 2, 3
observed in the -
(A) Lyman series (B) Balmer series Q.21 A sample of hydrogen is bombarded by
(C) both (A) and (B) (D) neither (A) or (B) electrons. Through what potential difference
should the electrons be accelerated so that
Q.16 Electrons accelerated from rest by a potential second line of Balmer series be emitted ?
difference of 12.75V, are bombarded on a (A) 2.55 V (B) 10.2 V
mono-atomic hydrogen gas. Possible emission (C) 12.09 V (D) 12.75 V
of spectral lines are -
(A) first three Lyman lines, first two Balmer Q.22 Let 1 be the frequency of the series limit of the
lines and first Paschen line
(B) first three Lyman lines only Lyman series, 2 be the frequency of the first
(C) First two Balmer lines only line of the Lyman series, and 3 be the
(D) none of the above frequency of the series limit of the Balmer
series -
Q.17 In hydrogen atom H-line arises due to (A) 1 – 2 = v3 (B) 2 – 1 = 3
transition n = 3 n = 2. In the spectrum of 1
singly ionised helium there is a line having the (C) 3 – (1 + 2) (D) 1 + 2 = 3
2
same wavelength as the H line. This is due to
the transition - Q.23 For a sodium light, the two yellow lines occur at
(A) n = 3 n = 2 (B) n = 2 n = 1 1 and 2 wavelengths. If the mean of the two is
(C) n = 5 n = 3 (D) n = 6 n = 4 takes as = 6000Å and |2 – 1| = 6Å. Then the
energy difference between the two levels
Q.18 Three photons coming from excited atomic- corresponding to 1 and 2 is -
hydrogen sample are picked up. Their energies
are 12.1 eV, 10.2 eV and 1.9 eV. These photons (A) 2 × 10–3 eV (B) 2 eV
must come from - (C) 2 × 103 eV (D) few meV
(A) a single atom
(B) two atoms Q.24 Energy levels A, B, C of a certain atom
(C) three atoms correspond to increasing values of energy, i.e.
(D) either two atoms or three atoms EA < EB < EC. If 1, 2, 3, are the wavelengths
of radiations for the transitions C B, B A
Q.19 Radiations of wavelength are incident on and C A respectively, which of the following
hydrogen in the ground state. A fraction of these statements is correct -
radiations absorbed by these atoms. There are 1 2
ten different wave in the emission spectrum of (A) 3 = 1 + 2 (B) 3 =
1 2
excited atoms. The will be -
(A) 1211Å (B) 912 Å (C) 1 + 2 +3 = 0 (D) 23 = 21 + 22
(C) 1211Å (D) 950.7 Å
Q.20 The figure indicates the energy level diagram of Q.25 An excited hydrogen atom emits a photon of
an atom and the origin of six spectral lines in wavelength in returning to the ground state. If
emission (e.g. line no. 5 arises from the
R is the Rydberg’s constant, then the quantum Q.32 A photon of energy 10.2 eV corresponds to light
number n of the excited state is - of wavelength 0. Due to an electron transition
(A) R (B) R 1 from n = 2 to n =1 in a hydrogen atom, light of
R wavelength is emitted. If we take into account
(C) (D) R (R 1) the recoil of the atom when the photon is
R 1
emitted -
(A) = 0
Q.26 For hydrogen atom the energy of electron is
(B) < 0
13.6 (C) > 0
En = – eV, where n = principal quantum
n2 (D) the data is not sufficient to reach a
number. The least energy which it can absorb in conclusion
its primitive stage is -
(A) 1.00 eV (B) 3.40 eV Q.33 If n >> 1, then the dependence of frequency of
(C) 6.80 eV (D) 10.2 eV a photon, emitted as a result of transition of
electron from nth orbit to (n – 1)th orbit, on n
Q.27 In which of the following transitions will the will be -
wavelength be minimum ? 1
(A) (B)
(A) n = 5 to n = 4 (B) n = 4 to n = 3 n
(C) n = 3 to n = 2 (D) n = 2 to n = 1 1
n2
Q.28 A hydrogen atom in the ground state is excited
1 1
by radiations of wavelength 975Å. Then how (C) (D)
3
many lines will be possible in the visible n v3
spectrum -
Q.34 Suppose that the potential energy of an
(A) 2 (B) 4 hypothetical atom consisting of a proton and an
(C) 6 (D) 3 electron is given by U = –ke2/3r3. Then if
Bohr’s postulates are applied to this atom, then
Q.29 The ratio of wavelength of first line of lyman the radius of the nth orbit will be proportional to -
series of doubly ionised lithium atom to that of (A) n2 (B) 1/n2 (C) n3 (D) 1/n3
the first line of Lyman series of deuterium ( 1H2)
Q.35 In a hypothetical atom like that of hydrogen, the
will be - mass of the electrons is doubled. Then the
(A) 4 : 1 (B) 1 : 4 energy E0 and radius r0 of the first Bohr orbit
(C) 9 : 1 (D) 1 : 9
will be (a0 = Bohr radius of hydrogen) -
Q.30 If the difference of energies of an electron in the (A) E0 = –27.2 eV ; r0 = a0/2
second and the fourth orbits of an atom is E, (B) E0 = –27.2 eV ; r0 = a0
then the ionisation energy of that atom will be - (C) E0 = –13.6 eV ; r0 = a0/2
36 16 (D) E0 = –13.6 eV ; r0 = a0
(A) E (B) E
15 3
15
(C) E (D)
36
3
E
16
Q.4 Find the ratio of magnetic dipole moment to (D) can't say anything
angular momentum in a hydrogen like atom -
e e e 2e Q.11 Ionisation potential for hydrogen atom in its
(A) (B) (C) (D)
m 2m 3m m ground state is -
3e (A) 13.6 eV (B) 13.6 volt
(E)
m (C) 10.2 eV (D) None
Q.5 If An is the area enclosed in the nth orbit in a
An Q.12 When electron jumps n = 2 to n = 1 in H atom
hydrogen atom then the graph log
A
1 then emitted energy is -
against log n - (A) exactly 10.2 eV
(A) will have slope 2 (straight line) (B) about 10.2 eV
(B) will have slope 4 (straight line)
(C) will be a monotonically increasing nonlinear (C) May be something less or more than
curve 10.2 eV
(D) will be a circle (D) None
Q.6 According to Bohr model, the diameter of first
orbit of hydrogen atom will be - Q.13 The electron in a hydrogen atom makes a
(A) 1 Å (B) 0.529 Å
(C) 2.25 Å (D) 0.725 Å transition from an excited state to the ground
state. Which of the following statements is
Q.7 For ionising an excited hydrogen atom the
energy required in eV will be - true -
(A) a little less than 13.6 (A) Its kinetic energy increases and its potential
(B) 13.6 and total energies decrease.
(C) more than 13.6
(D) 3.4 or less (B) Its kinetic energy decreases, potential
energy increases and its total energy
Q.8 In Humphery series electron jumps - remains the same.
(A) n2 = 6 to n1 = 5
(C) Its kinetic and total energies decrease and its
(B) n2 = 7, 8, 9 ....... to n1 = 6
(C) n2 = 5 to n1 = 4 potential energy increases
(D) None (D) Its kinetic, potential and total energies
decrease
Q.21 Statement I : Balmer series lies in the visible
Q.14 The difference of energies between first two region of electro magnetic spectrum.
Statement II : For Balmer series
energy level of hydrogen atom is 10.2 eV. The
same energy difference for an atom with charge 3648Ån 2
where n = 3, 4, 5,.... and
number 10 and mass number 20 will be - n2 – 4
(A) 2040 eV (B) 1020 eV wavelength of visible light-ranges from 3800 Å
to 7200Å.
(C) 510 eV (D) 102 eV.
Q.22 Statement I : Electron can emit 6 types of
Statement Type Questions : photons during transition from n = 4 to n = 1.
(A) If both Statement- I and Statement- II are Statement II : Number of photons emitted can
true, and Statement - II is the correct never be less than 5.
explanation of Statement– I.
(B) If both Statement - I and Statement - II are Q.23 Statement I : An electron jumps from 5 th to
true but Statement - II is not the correct 2nd shell, number of possible transition state = 3.
explanation of Statement – I. Statement II : Possible transition state
(C) If Statement - I is true but Statement - II is
= n = (5 – 2)
false.
(D) If Statement - I is false but Statement - II is
Q.24 Statement I : In outermost orbit energy of
true.
electron is most negative.
Q.15 Statement I : Distance of closest approach for Statement II : In such orbit electron is at
free target is more than that for fixed target. maximum distance from nucleus.
Statement II : Total energy is conserved for
free target but not for fixed target.
Passage Based Questions :
Q.16 Statement I : Fraunhoffer lines are found in Passage - I
solar spectrum. A mixture of hydrogen atom (in ground sate)
Statement II : Some wavelengths are absorbed and hydrogen like atom (z) (in their first excited
by chromo sphere of sun.
state) is being excited by electrons which have
Q.17 Statement I : Most part of atom is empty and been accelerated by same potential difference
atom is spherical and hollow. 'V', After excitation when they come in to
Statement II : Most -particles passed with ground state, the wavelength of emitted light are
large deflection through gold foil when it was found in the ratio 5 : 1.
bombarded with high speed -particles.
Q.18 Statement I : The angular momentum of Q.25 The final excited state of hydrogen like atom is-
electron in a closed shell is always continuously (A) 3 (B) 4
varying with speed of electron. (C) 5 (D) 6
Statement II : The angular momentum of
nh Q.26 The final excited state of hydrogen atom is -
electron is given by equation mvr = .
2 (A) 2 (B) 3
Q.19 Statement I : Lyman series involves higher (C) 4 (D) 5
energy transitions than Balmer series.
Statement II : Lyman series falls in UV Q.27 Identify the other ion -
region, whereas Balmer series falls in visible (A) He+ (B) Li+2
region. (C) Be +3
(D) None of these
ANSWER KEY
LEVEL # 1
Q.No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. D C A B D C D A A B D B D B C
Q.No. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans. B B D A D C C A A,B C C B B B A
Q.No. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
Ans. D A D C A B A C C C D B A C A
Q.No. 46 47 48 49 50 51 52 53
Ans. A C D C B B A A
LEVEL # 2
Q.No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. B B D A C C C D D C A B A A A
Q.No. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans. A D D D D D A A B C D D A D B
Q.No. 31 32 33 34 35
Ans. C C C B A
LEVEL # 3
Q.No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14
Ans. B A B B B A D B B C B B A B
Q.No. 15 16 17 18 19 20 21 22 23 24 25 26 27
Ans. C A C D A B A C D D B A A
LEVEL # 4
SECTION – A
Q.No. 1 2 3 4 5 6 7 8 9 10 11 12 13
Ans. C B A D A A C A D C C C B
SECTION – B
1 ke 2 ( 2) 2
1.[A] K.E. = + mv2 = E2 = 13.6 = 13.6 × 4 = 54.4
2 2r 12
1 ke 2 Enet = E1 + E2 = 54.4 + 24.6 = 79 eV
T.E. = – mv2 = –
2 2r
Ratio = –1
2.[A] E1 = 24.6 eV 3.[A] = mB
= mBsin
q only possible for n1 = 5, n2 = 4.
= .L B sin 10.[B] H atom and Li++ both are in 2nd excited state.
2m
H and Li are electronic angular momenta.
e nh EH and ELi are energies.
= . .Bsin90º
2m 2n nh nh
nehB LH = LLi =
= 2 2
8m
LH = L Li ....(1)
2
13.6 Z
and E = ELi < EH
n2
|ELi| > |EH|
13.6 Z 2
4.[D] E=
1
r
= 13.6 × 9 = 122.4 eV 11.[C] v = v0 ln
5.[A,D] T n3 r0
T1 n 13 8T n 13 r
= 3 = 3 ev = ev0 ln
T2 n2 T n2 r0
2n2 = n1 r
U = U0 ln
P.E. r0
6.[A] As T.E = – K.E. =
2 dU d r
F= = –U0 ln
kze 2
kze 2
dr dr r
and K.E = , T.E. = and 0
2r 2r U0 1
2 . U0
kze F = r r0 =
P.E. =
r r
r0
1 1 1
7.[C] = R ' 2 2 mv 2 U0
F = =
n1 n 2 r r
1 mv2 = U0
1
= 1 1 U0
µR 2 2 v=
n1 n 2 m
1 nh
L =
= 1 1 2
µR 2 2
n1 n 2 h U0
n = m. r
For n1 = 2, n2 = 3 2 m
1 rn
= 94 12.[B] 100
Fm257
µ R
9 4 Bohr radius for H-atom
1 r0 = 0.53 Å
18
= 5 = 0.53 n 2
2 R. 5R r=
36 Z
qL electronic configuration (2n2)
8.[C] M = 100 = 2,8,18,32,40
2m
n=5
M M 1
q, n2 (5) 2 r
L L m r = r0 . = r0 × = 0
9.[D] Infrared waves means maximum wavelength Z 100 4
E = minimum
1 5
r= .r0 =
4 27
13.[A] Energy of ionisation for H-atom = 13.6 eV 6561 5
= = 243 × 5
K.E. of ejected electron 27
=15 – 13.6 = 1.4 eV = 1215 Å
electron can produce a photon of 10.2 eV
1 1 1
14.[B] = R 2 2
n1 n 2
Paschan series infrared radiation
1 1 1
= R 2 2
3
9
= = 912 × 9 = 8208 Å 823 nm
R
15.[ AR,P ; B Q, S; C P ; D Q,R]
In hydrogen spectrum electron makes transition nh 3h
between two atomic energy level. In photo 20.[A,C] =
2 2
electric effect, photon energy converted into n=3
electrical energy. Mosley's law is related to
characteristic x-ray. In -decay emission of n2
a0 × = 4.5 a0
electron take place. Z
2 9
nh =2
1 2 L 2
n 2h 2 Z
16.[D] kref = I = = 2 =
2 2I 8 2 I Z=2
2I
1 1 1
17.[B] E =
1 2 n 2h
I = 1
= R × 221 2
2 8I 3
(2 2 12 ) h 2
1 1 1
= 4R 2 2
E = = h 2 2 3
8 2 I
3 h 2 3h 1 1 1
I= = = 4R 2
8.h. 32 10 22 3 1 2
= 1.87 × 10–46 kg m2
18.[C] I = mr = µ.r2
2 9 9 1
1 = , 2 = , 3 =
m1 m 2 2 32R 5R 3R
I= r
m1 m 2
I( m1 m 2 )
r= = 1.3 × 10–10 m.
m1 m 2
hc 1 1
19.[A] = 13.6 2 2
6561 2 3
hc 1 1
= 13.6 × 4 2 2
2 4
hc 5
= 13.6 ×
6561 36
hc 3
= 13.6 × 4 ×
16
hc 5 4
= ×
6561 36 3