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UHS MCAT 2014

Chemistry Portion
Answer Key: White
By: www.Edu.Apnafort.com
Q.45 A polymer of empirical formula CH3 has molar mass of 26000 gmole-1. Its molecular formula will be :
A) 100 times of its empirical formula
B) 200 times of its empirical formula
C) 500 times that of its empirical formula
D) 2000 times that of its empirical formula
Q.46 The number of molecules in 9.8g of ice (H2O):
A) 6.02×1023
B) 3.01×1023
C) 6.02×1023
D) 6.02×1022
E) 3.01×1022
Q.47 Ice is less dense than water at:
A) O degree C
B) 4 degree C
C) -4 degree C
D) 2 degree C
Q.48 At a given temperature and pressure, the one which shows marked deviation from ideal behavior is:
A) N2
B) H2
C) CO2
D) He
Q.49 According to the number of protons, neutrons and electrons given in the table, which one of the following
options is correct?

Q.50 If the e/m value of electron is 1.7586×1011 CoulombsKg-1, then what would be the mass of electron in grams ( charge
on electron is 1.6022×10-19 Coulombs)?
A) 9.1095×10-31g
B) 91.095×10-11g
C) 9.1095×1030g
D) 0.919095×10-31g
Q.51 The suitable representation of dot structure of chlorine molecule is:
A) :Cl: :Cl: ( dots above Cl on both sides)

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B) :Cl : Cl: (dots above and down on Cl both sides)

C) Cl :: Cl (Dots on above Cl on both sides)
D) Cl : Cl (Dots `` on only above of Cl at both sides)
Q.52 When the two partially filled atomic orbitals overlap in such a way that the probability of finding the electron is
maximum around the joining the two nucelei, the result is the formation of:
A) Sigma bond
B) Pi-Bond
C) Hydrogen bond
D) Metallic bond
Q.53 2H2 + O2 --------------------- 2H2O+285.5 KJmol-1
What will be the change in the above reaction?
A) 285.5 KJ/mol
B) Zero KJ/mol.
C) -285.5 KJ/mol.
D) 1 KJ/mol.
Q.54 Combustion of graphite to form CO2 can be done by two ways, reactions are given as follows:
C+O2 ---------CO2 DeltaH =-393.7 KJ/mol

What will be the enthalpy of formation of CO?

A) -676 KJ/mol
B) -110 KJ/mol
C) 110KJ/mol.
D) 676 KJ/mol

Q.55 One mole of glucose was dissolved in Kg of water, ethanol, ether and benzene separately and metal boiling point
of constant of each solution was found to be .52, 1.75, 2.16, 2.70 in the units of /C Kgmol -1 respectively. Which of the
following figure shows benzene as solvent in solution?

A) I
B) II
C) III
D) IV
Q.56 The vapour pressure lines for pure as well as solutions of different concentrations are shown below. Which line
repeats pure water?

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A) (I)
B) (II)
C) (III)
D) (IV)
Q.57 In SO4-2 the oxidation number of sulpphur of is:

A) -8

B) +8

C) -6

D) +6

Q.58 Coinage metals Cu, Ag and Au are the least reactive because they have:

A) Negative reduction potential

B) Positive reduction potential

C) Negative oxidation potential

D) Positive oxidation potential

Q.59 The value of equilibrium constant (Kc) for the reaction 2HF (s) <-- H2 (g) + F2(g) is 10-13 at

2000 oC. calculate the value of Kpfor the reaction:

A) 2×10-13

B) 10-13

C) 186×10-13

D) 3.48×10-9

Q.60 What will be pH of a solution of NaOH with concentration of 10-3M?

A) 3

B) 14

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C) 11

D) 7

Q.61 If the reactant or product of a chemical reaction can absorb ultraviolet, visible or

infra-red radiation then the rate of a chemical reaction can be best be measured by which one

of the following methods?

A) Chemical method

B) Spectrometry

C) Graphical method

D) Differential method

Q.62 For the reaction 2NO + O2 <------>2NO2 the rate equation for the forward reaction is:

A) Rate= K [NO] [02]

B) Rate= K [NO]-2 [O2]

C) Rate = K [NO2]2

D) Rate = K [NO2]

Q.63 The trends in melting points of the elements of the 3rd period are depicted in figure

below.

The sharp decrease observed from Sl to P is due to:

A) Decrease in atomic radius from Sl to P

B) Change in bonding and structure of two elemnts

C) Different densities of two elements

D) Increase in electron density from Sl to P

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Q.64 Arrange the following elements according to the trends of ionization energies:

A) Ne<N<C<B

B) B<N<C<Ne

C) B<C<N<Ne

D) Ne<B<C<N

Q.65 Radon is ______ emitter and being radioactive is use in ____treatment in radiotherapy:

A) Beta,cancer

B) Alpha, cancer

C) Alpha, kidney stone

D) Beta, kidney stone

Q.66 Which one of the following noble gases is used for providing an inert atmosphere for

welding?

A) Helium

B) Neon

C) Argon

D) Krypton

Q.67 Electronic configuration of Manganese(Mn) is:

Q.68 The percentage of carbon in different types of iron products is in the order of:

A) Cast iron > Wrought iron > Steel

B) Wrought iron > steel > Cast iron

C) Cast iron > steel > Wrought Iron

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D) Cast Iron > Steel=Wrought Iron

Q.69 Which one of the following is correct equation of 1st ionization of sulphuric acid?

A) H2SO4 +H2O 2H+ + SO4-3

B) H2SO4 +H2O H+ + HSO4-

C) H2SO4 +H2O  2 H+ + SO4-2

D) H2SO4 +H2OH2O+ + SO4-2

Q.70 Which one of the following is the correct chemical reaction for ammonia formation by

Haber process?

A) N2 + 3H  2NH3

B) 2N + 3H   NH3

C) 2N + 3H2  2NH3

D) N2 +3H2   2NH3

Q.71 The pH of acid rain is?

A) 7

B) Between 5 and 7

C) Below 5

D) Between 7 and 14

Q.72 Which one of the following products os obtained from Sulphur trioxide is concerned

sulphuric acid?

A) A

B) A

C) A

D) A

Q.73 Which one of the following pair of compounds is cis and trans isomers of each other?

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Q.74 Which one of the following compound is ktone?

A) CH2-O-CH2-CH3

B) CH3-CO-CH2-CH3

C) CH3COCOOH

D) CH3-CH2CHO

Q.75 Addition of unsymmetrical reagent to an unsymmetrical alkene is governed by:

A) Cannizaro`s Reaction

B) Krichoff Rule

C) Aldol condensation

D) Markownkov`s Rule

Q.76 Ethylene glycols are used as:

A) Anaesthetic

B) Knocking agent

C) Freezing agent

D) Anti-freezing agent

Q.77 The halothane used in hospitals as an anesthetic is chemically:

A) 2-bromo-2-chloro-1,1,1-trifluorethane

B) 2,2-dibromo-1,1,1-trifluoretahne

C) 2-fluoro-2-bromo-1,1,1-

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D) 2-chloro-2-fluoro-1,1,1-

Q.78 If halogenoalkanes are mixed with an excess of ethanolic ammonia and heated under

pressure amine are formed. Which amine is formed in the following reaction?

CH3CH2Br + NH3  Amine

A) CH3-CH2-NH-CH2-CH3

B) CH3-CH2-NH2

C) CH3-CH2-CH2-NH3

D) H2N-CH2-CH2-NH3

Q.79 The formula of 2,4,6-tribromophenol is:

Q.80 Primary, secondary and tertiary alcohols can be identified and distinguished by:

A) Lucas Test

B) Bakwas test

C) Baeyer`s test

D) Silver mirror test

Q.81 Which one of the following alcohol is indicated by formation of yellow crystals in

iodoform test?

A) Methanol

B) Ethanol

C) Butanol

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D) Propanol

Q.82 Which one of the following groups is indicated when HCl is formed by reaction ethanol

with phosphorus pentachloride?

A) Amino group

B) Hydroxyl group

C) Halide group

D) Hydride group

Q.83 A student mixed ethyl alcohol with small amount of sodium dichromate and added it to

the hot solution of dilute sulphuric acid. A vigorous reaction took place. He distilled the

product formed immediately. What was the product?

A) Acetone

B) Acetic acid

C) Dimethyl ether

D) Acetaldehyde

Q.84 The structural formula of the product of reaction of acetone with 2,4-dinitrophenyl

hydrazine is:

Q.85 For the reaction:

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A) C3H5COCH3

B) C3H3CH(CH2) OH

C) CH3COCH3

D) C3H5CH2CHO

Q.86 Ethyl butyrate and butyl butanoate are esters with the flavor of:

A) Pear

B) Banana

C) Pineapple

D) Apple

Q.87 Acetamide is formed by dehydration of:

A) Oxalic acid

B) Ethanoic acid

C) Butanoic acid

D) Propanoic acid

Q.88 Organic compounds X and Y both can react with Na-metal to evolve hydrogen gas. X

and Y if react with each other form an organic compound Z which gives fruity smell. What

types of compounds X , Y and Z are?

Q.89 The amino acid which are prepared in human body are called?

A) Essential amino acids

B) Non-essential amino acids

C) Alpha amino acids

D) Delta amino acids

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Q.90 Which one of the following is glutamic acid?

Q.91 Indicate the cyclic amino acid from the following:

A) Cysteine

B) Serine

C) Glutamine

D) Proline

Q.92 At low pH or in acidic condition amino acid acts as:

A) Anion

B) Cation

C) Zwittor ion

D) Neutral specie

Q.93 The structure shown below represents:

A) Proline

B) Histidine

C) Diyrine

D) Lysine

Q.94 Which one of the following reagent is used for identification of amino acids?

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A) Fehling`s solution

B) Benedicts solution

C) Ninhydrin

D) Copper sulphate

Q.95 Which one of the following is an example of condensation polymer?

A) Polyvinylchloride

B) Polystyrene

C) Polythene

D) Polyamide

Q.96 Among the most common diasaccharides, which one of the following is present in

milk?

A) Sucrose

B) Maltose

C) Fructose

D) Lactose

Q.97 Fats are types of lipid called glycerides. They are esters of long chain carboxylic acid

ands and:

A) Propene 1, 2 ,3 triol

B) Propane 1 ,2 ,3 triol

C) Propene 1,2,3-diol

D) Propane 1,2,3-diol

Q.98 Which one of the following base is not present in RNA?

A) Cytosine

B) Adenine

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C) Thymine

D) Guanine

Q.99 Collagen proteins are absent in _______ throughout the body.

A) Muscle

B) Red blood cells

C) Tendons

D) Blood plasma

Q.100 Polystyrene is an addition polymer. Which one of the following structures represents

---- the polysters?

Q.101 ______ is an aye irritant.

A) Peroxyacetyl nitrate

B) Peroxyacetyl nitrite

C) Plz check from book (Thanks)

D) 

Q.102 Which one of the following pollutants can cause of death of a person by binding with

haemoglobins in red blood cells?

A) Chlorofluerocarbons

B) Oxides of sulphur

C) Carbon monoxide

D) Oxides of nitrogen

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