Material Safety Data Sheet

Trade Name SHL SYNTHDRO 46AW

1. CHEMICAL PRODUCT & COMPANY IDENTIFICATION
Trade Name SHL SYNTHDRO 46AW
General Characteristics Petroleum Hydrocarbon & Additives
Hazard Classification Not applicable
Application Hydraulic Oil
Manufacturer's Name & Address
SHL ASEAN CO., LTD.
Address: My Xuan B1-Conac Industrial Zone, My Xuan Ward, Phu My Town, Ba Ria Vung Tau Province, Vietnam.
TEL: +84(0) 2543 876 287 - Fax: +84(0) 2543 876 288
Supplier's Name SHL ASEAN CO., LTD.
Department Technical Institute

2. HAZARD IDENTIFICATION
Hazard Classification in Korea Acute inhalation hazardous material Class 4
GHS Pictogram.

Signal Words Warning

Hazard statements When inhales, is harmful
Precautionary statement
Prevention
Wash your hands after handling
Before using secure the instruction book
Avoid the inhalation of the dust, hume, gas, mist & fume.
The outdoor or aeration handles well only the place which becomes.
The individual protection which is appropriate will roll and wear.
Do not discharge to the environment
Countermeasure
If is inconvenient feel and the medical institution (doctor) be examined.
If irritating the skin , receive medical treatment.
Wash the skin with soap and much water .
Take off the polluted clothes and shoes.
When inhales, moves with the place which has the fresh air breathes, keep the balance in easy attitude.
Storage
Seal up and store.
Disposal
Dispose in a legal self-disposal system or through waste disposal company.
Other hazard
Repeated contact may result in slightly irritation.
Liquid vapors may cause vomiting and dizziness.
Vapor inhalation under ambient conditions is normally not a problem.
○ NFPA Index
Hydrotreated Heavy Paraffinic Distillate : Public health :1, Fire : 1, Reaction : 0
Solvent Refined Hydrotreated Bottoms : Public health :1, Fire : 1, Reaction : 0
Anti-Wear Addtive : Public health :1, Fire : 1, Reaction : 0
Chronic Symptom No data
Carcinogenicity No carcinogenicity
Industrial Safety and Health Act(in Korea): Not classified
Occupational Safety & Health Administration (OSHA): No
National Toxicology Program (NTP): No
International Agency for Research on Cancer (IARC): No

3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical identity Synonyms CAS No. Concentration (%)
Hydrotreated heavy paraffinic distillate Mineral oil 64742-54-7 ≥ 95

Anti-wear addtive Secret Secret <5

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 Methyl methacrylate, polymerized Polymethyl methacrylate 9011-14-7 < 0.5
Estimated exposure limit for this product : 5mg/㎥ f or oil mist in air (ACGIH TLV, OSHA PEL)

4. FIRST AID MEASURES

Eye Contact
Open the eyelid and wash the eye with water over 15 minutes.
If the eye is bloodshot and the congestion maintains continuously, receive medical treatment immediately.
Move person to fresh air.
Skin Contact
Wash the skin with soap and much water
Take off the polluted clothes and shoes immediately.
If the irritation maintains on skin continuously, receive medical treatment.
Inhalation
Expose to fresh air. If not recovered, seek medical aid.
If breathing has stopped,apply artificial respiration and administer oxygen if necessary.
Ingestion
If swallowed much amount, receive medical treatment Immediately.
Advice to Physician
If necessary, gastrolavage should be considered.

5. FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA
Suitable Extinguishing Media: Dry chemical, carbon dioxide, water fog, normal foam
Unsuitable Extinguishing Media : Straight streams of water
HAZARDOUS SUBSTANCE CREATED DURING BURNING
Smoke, Fume, Incomplete combustion products, Oxides of carbon
Extinguishing Method and Extinguisher
Evacuate area.
Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply.
Shut off all sources of fuel if possible, and use water to cool fire-exposed materials.
Use water to cool fire-exposed tanks, containers, and structures.
Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing
Use water spray to cool fire exposed surfaces and to protect personnel.
Use foam if exposed to heat or flame.
FLAMMABILITY PROPERTIES
Flash Point [Method]: 242 °C (ASTM D-92)
Upper/Lower Flammable Limits (Approximate volume % in air): No data
Autoignition Temperature: No data

6. ACCIDENT RELEASE MEASURES

Human Body Protection Methods
Avoid inhalation and skin exposure.
Change pollutant clothes to new one.
Wear air respirator or ventilate the air in an airtight room.
Shut off source of exposure or remove source of fire if possible.
Environment Protection Methods
Prevent water pollution.
If polluted, use absorber to remove pollutant.
Clean Up Methods
Use sand or noninflammable absorber.
Use water to dilute gas.
Collect exposed materials in a proper container to dispose them.

7. HANDLING AND STORAGE

Handling
Prevent skin contact, vapor inhalation, and eye contact.
Empty containers may retain product residue including flammable vapors.
Storage
Store the substance according to the current rules and regulations.
Store the substance in a cool and well-ventilated area.

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 Seal the storage container up and do not impact on the container.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Occupational exposure limit
Chemical identity Exposure limit in KOREA ACGIH control acts Biological exposure limit
Hydrotreated heavy paraffinic distillate No data TWA: 5mg/m3. STEL: 10mg/m3 No data

Anti-wear addtive No data No data No data

Methyl methacrylate, polymerized No data No data No data
Appropriate engineering controls
Adequate ventilation in accordance with good engineering practice must be provided to keep any oil mist
concentration below the PEL.
Check if the exposure is proper within the exposure criteria.
Personal protection
Respiratory Protection
Not required under normal usage.
If product is handled in such a way as to create a vapor or mist, a KOSHA(Korea Occupational Safety
& Health Agency) approved respirator should be used to prevent overexposure.
Use either a full-face, atmospheresupplying respirator or an air-purifying respirator for organic vapors.
Eye Protection
Wear chemical goggles to prevent eye contact from scattering materials or harmful liquids. Install spray
washing system for eyes near the work field.
Hand Protection Wear chemical-resistant gloves, if needed.
Body Protection Wear chemical-resistant protective clothing.

9. PHYSICAL AND CHEMICAL INFORMATION

Appearance Transparent yellow liquid
Odor Unique hydrocarbon odor
pH N/A
Melting Point < - 35.0℃
Boiling point >399 F (>204 ℃)
Flash Point 246℃ (Cleveland open cup test)
Oxidation Stable
Flammability Inflammable at temperature above the flash point
Explosion Stable
Vapor Pressure < 0.1 mmHg @20 ℃
Solubility In Water Unsoluble in water
Vapor Density > 1 (Air=1)
Specific Gravity 0.85 (15/4℃)
Distribution Coefficient No data
Autoignition Temp. No data
Dissolution Temp. No data
Viscosity 45 cSt (40℃)
Molecular weight No data

10. STABILITY AND REACTIVITY

Stability
Stable in normal temperature and pressure, and for normal usage
Possibility of Hazardous Material Creation during Reaction
Will not occur.
Conditions & Materials to Avoid
All sources of ignition and excessive heat, and strong oxidants.
Material created during Degradation
Thermal decomposition product : Toxic carbon compounds may be included (e.g. CO).

11. TOXICOLOGICAL INFORMATION

URGENT RISK & HARMFULNESS INFORMATION
Inhalation
May be harmful if inhaled
Eye Contact

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 May cause slight irritation.
Skin Contact
May cause slight irritation. Repeated contact may result in skin troubles
Ingestion
Ingestion may result in irritation, vomiting, diarrhea, stomachache
TOXICOLOGICAL INFORMATION
Acute Oral Toxicity
Hydrotreated heavy paraffinic distillate : LD50 > 5000 ㎎/㎏ Rat
Other ingredients : No data
Acute Dermal Toxicity
Hydrotreated heavy paraffinic distillate : LD50 > 5000 ㎎/㎏ Rabbit
Other ingredients : No data
Acute Inhalation Toxicity
Hydrotreated heavy paraffinic distillate : LC50 2.18 ㎎/ℓ 4 hr Rat (oil mist)
Other ingredients : No data
Dermal Irritability Low irritation
Eye Irritability Low irritation
Subacute Toxicity No data
Repeated Dose Toxicity No data
Mutagenicity N/A
Effect on Next Generation N/A
Carcinogenicity N/A ( <3% (DMSO extract) )
ADDITIONAL ADVICE Repeated exposure may decrease the fat of skin and result in dermatitis.

12. ECOLOGICAL INFORMATION

AQUATIC TOXICITY AND ECOTOXICITY
Chronic and Aquatic Toxicity
It is expected that this substance is not toxic to fish within the solubility in water.
Fishes LC50 : > 5000mg/L 96hrs (Hydrotreated heavy paraffinic distillate)
Invertebrate EC50 : > 1000mg/L 48hrs Daphnia (Hydrotreated heavy paraffinic distillate)
Algae EC50 : > 1000mg/L 96hrs (Hydrotreated heavy paraffinic distillate)
MOBILITY IN SOIL
Lubricant mineral oils, immediately following a release into the environment, will remain largely
on the soil surface, on the water surface and in the water.
PERSISTENCE / DEGRADABILITY
6% degradable during 28 days. (Hydrotreated Heavy Paraffinic Distillate)
This product is expected to be resistant to biodegradation and to persist in the environment.
POSSIBILITY OF BIOACCUMULATION : No data

13. DISPOSAL CONSIDERATION

REGULATION OF WASTE MANAGEMENT ACT
Classified as specified wastes.
WASTE DISPOSAL METHODS
Dispose in a legal self-disposal system or through waste disposal company.
CAUTION FOR DISPOSAL
Follow the detailed criteria of Wastes Control Act.
EMPTY CONTAINER WARNING
Empty containers may contain residue and can be dangerous.
Do not attempt to refill or clean containers without proper instructions.
Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed.
Empty containers should be taken for recycling, recovery, or disposal through suitably qualified
or licensed contractor and in accordance with governmental regulations.
DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO
FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION.

14. TRANSPORT INFORMATION

Classification and Regulation According to Ship Transportation and Storage Rule of Hazardous Material
of Ship Safety Act
Not classified

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 Caution during Transport
No data
Classification and Regulation According to Rule of Foreign Transportation
Not Regulated for transport according to UN, IMDG, ADR/RID, IATA/ICAO codes

15. REGULATORY INFORMATION

Regulation According to the Substance Control Act of
Another Department such as Toxic Substance N/A
Control Act
Toxic Substance Control Act N/A
High-Pressure Gas Safety Control Act N/A
Act on Safety Management of Dangerous Goods
The fourth class of petroleum of the fourth class of hazardous substance
Regulation According to Foreign Laws
EC : EC Classification : N/A
EC Symbols : N/A
EC Risk and Safety Data : N/A
USA : CERCLA 103(40CFR302.4) : N/A
OSHA(29CFR1910.119) : N/A
SARA 302(40CFR355.30) :N/A
SARA 304(40CFR355.40) :N/A
SARA 313(40CFR372.65) : N/A
OSHA(29CFR1910.119) : N/A
TSCA : Listed

16. OTHER INFORMATION

Source
Material's data of our laboratories, Korea Occupational Safety & Health Agency and raw material supplier
Written Date 23-May-99
Revision Count. Final Revision Date Rev.13 23-Nov-16
Other References
The data and advice given apply when the product is sold for the stated application or applications.
The product is not sold as suitable for any other application. Use of the product for applications
other than as stated in this sheet may give rise to risks not mentioned in this sheet. You should not
use the product other than for the stated application or applications without seeking advice from us.
If you have purchased the product for supply to a third party for use at work, it is your duty to take
take all necessary steps to secure that any person handling or using the product is provided with the
information in this sheet.
If you are an employer, it is your duty to tell your employees and others who may be affected of any
hazards described in this sheet and of any precautions which should be taken.
Further copies of this Safety Data Sheet may be obtained from SAMHWA LUBE OIL CO,LTD

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