Atomic Structure
Atomic Structure
REVISION SERIES
ATOMIC STRUCTURE
Q-1 - 12225289
statement is correct ?
3d sub-energy level
electrons
electrons.
CORRECT ANSWER: C
SOLUTION:
( c) for n = 2,
2s 2p
1+ 3 = 4orbitals
2 +6 = 8electrons
Q-2 - 34964406
(A) s
(B) p
(C) d
(D) All
CORRECT ANSWER: A
SOLUTION:
Q-3 - 12225293
h
(A) √l(l + 1)
2π
h
(B) √l(l − 1)
2π
h
(C) √s(s + 1)
2π
h
(D) √s(s − 1)
2π
CORRECT ANSWER: A
SOLUTION:
h
(a) √l(l + 1) .
2π
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Q-4 - 69094858
SOLUTION:
The dxy orbital has lobes between x-axis and y-axis, i.e.,
Q-5 - 12225290
SOLUTION:
(a)
Cr24
2 2 6 2 2 4
− 1s 2s 2p 3s 4s 3d
(original configuration)
5
but − d − its's half-filled state and that is state most
state.
Cu
2 2 6 2 6 2 9
− 1s 2s 2p 3s 3p 4s 3d
but
2 2 6 2 6 1 10
1s 2s 2p 3s 3p 4s 3d
(full filled).
Q-6 - 12225287
true.
an electron
CORRECT ANSWER: B
SOLUTION:
(b) A plane on which there is maximum probability that
Q-7 - 14157447
impossible arrangement :-
n l m ms
(A) 3 2 − 2 12
1
(B) 4 0 0 2
1
(C) 3 2 − 3 2
1
(D) 5 3 0 2
CORRECT ANSWER: C
SOLUTION:
Hund's rule
(A) (2l + 1)
(B) 2(2l + 1)
CORRECT ANSWER: B
SOLUTION:
Q-9 - 23583453
The quantum number not obtained from the schrodinger's wave
equation is
(A) n
(B) l
(C) m
(D) s
CORRECT ANSWER: D
SOLUTION:
Q-10 - 12225281
If the electronic structure of oxygen atom is written as
1s2 , 2s2 it
would violate-
CORRECT ANSWER: A
SOLUTION:
occupied.
Q-11 - 46827304
The following quantum numbers are possible for how many orbitals
(A) 3
(B) 2
(C) 1
(D) 4
CORRECT ANSWER: C
The total energy of the electron in the hydrogen atom in the ground
(A) 13.6eV
(B) zero
(C) − 13.6eV
(D) 6.8eV
CORRECT ANSWER: A
SOLUTION:
(a)
1
∵ KE = mv2
2
Ze2
= , TE =
2r
Ze2
−
2r
.
Q-13 - 12225345
(A) + 3.4eV
(B) + 6.8eV
(C) − 13.6eV
(D) + 13.6eV
CORRECT ANSWER: A
SOLUTION:
Q-14 - 46827379
− 25
(B) 2 × 10
− 18
(C) 5 × 10
(D) 4 × 101
CORRECT ANSWER: D
SOLUTION:
8
c 3 × 10
λ= =
v 8 × 1015
= 3.75 × 10 − 8
= 3.75 × 10 − 8
× 109 nm = 4 × 101
nm.
Q-15 - 46826921
The frequency of radiation emitted when the electron falls from n=4
15 − 1
(A) 3.08 × 10 s
15 − 1
(B) 2.00 × 10 s
15 − 1
(D) 1.03 × 10 s
CORRECT ANSWER: A
SOLUTION:
EIonisation = E ∞ − En
2
13.6Zeff
= 2
eV
n
=[
13.6Z 2
n22
]
2
13.6Z
−
n21
2
13.6 × 1
E = hv = 2
(1)
2
(13.6 × 1)
− 2
, hv
(4)
= 13.6 − 0.85
− 34
∵ h = 6.625 × 10
13.6 − 0.85
v= − 34
6.625 × 10
− 19
× 1.6 × 10 = 3.08
15 − 1
× 10 s
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Q-16 - 12225126
(A) − 41kJmol − 1
−1
(B) − 1312kJmol
−1
(C) − 164kJmol
(D) − 82kJmol − 1
CORRECT ANSWER: D
SOLUTION:
(d)
2
E4 2 4
= 2 =
E2 4 16
1
= ,
4
E2 − 328
E4 = = =
4 4
− 82kJ / mol
.
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Q-17 - 74865140
6
(A) 5.79 � 10 ms( � 1)
8 �1
(C) 5.79 � 10 ms
5 �1
(D) 5.79 � 10 ms
CORRECT ANSWER: A
SOLUTION:
h
Δ × xΔv ≥
4πm
∴ Δx = 0.1
− 11
= 1 × 10 m
h
ΔV ≥
4πm × Δx
ΔV
− 34
6.626 × 10 J sec
≥
4 × 3.14 × 9.11
× 10 − 31 kg × 10 − 11 m
Δ ≥ 5.79
6 −1
× 10 m sec
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Q-18 - 30545666
CORRECT ANSWER: B
Q-19 - 12225354
9 × 10 − 28 g)
5 −1
(B) 1 × 10 cms
11 −1
(C) 1 × 10 cms
9
(D) 1.1 × 10 cms − 1
CORRECT ANSWER: D
SOLUTION:
(d)
Δx = Δp ∴ ΔxΔp
h
=
4π
or Δx = √
h
4π
h
Δx. Δu =
4πm
Δp = 1
− 18 −1
× 10 gcm sec
− 18
m × Δu = 1 × 10
1 × 10 − 18
∴ Δu = − 28
9 × 10
9 −1
= 1.1 × 10 cm sec
.
(A) 2n2
(B) 4l + 2
(C) 2l + 1
(D) 4l − 2
CORRECT ANSWER: B
SOLUTION:
= 2(2l + 1)
=4l + 2.
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Q-21 - 12973042
(i)
n = 1, l = 1, ml 0, ms =
+ 1/2
(ii)
n = 3, l = 1, m1 = − 2, ms
= − 1/2
(iii)
n = 1, l = 1, ml = 0, ms =
+ 1/2
(iv)
n = 2, l = 0, ml = 0, ms
=1
(A) (i), (ii), (iii), (iv)
CORRECT ANSWER: C
SOLUTION:
Q-22 - 69094897
The energy absorbed by each molecule (A 2 ) of a substance is
− 19
(A) 2.2 × 10 J
(B) 2.0 × 10 − 19 J
− 20
(C) 4.0 × 10 J
− 20
(D) 2.0 × 10 J
CORRECT ANSWER: D
SOLUTION:
− 19
(4.4 × 10 )
− 19
− (4.0 × 10 )
K.E. per atom = J
− 19
2
0.4 × 10
= J
2
− 20
= 2.0 × 10 J
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Q-23 - 12225358
(A) 6.6 × 10 − 32 m
− 34
(B) 6.6 × 10 m
− 35
(C) 1.0 × 10 m
− 32
(D) 1.0 × 10 m
CORRECT ANSWER: C
SOLUTION:
( c)
h
λ=
mv
− 34
6.6 × 10
= =1
0.66 × 100
− 35
× 10 m
.
Q-24 - 12225359
atom is.
(A) 4
(B) 8
(C) 16
(D) 32
CORRECT ANSWER: C
SOLUTION:
2
( c) Number of atomic orbitals = n
th
Number of atomic orbitals in 4 energy shell
2
= 4 = 16.
Q-25 - 69094787
λ1 and λ2 will be
1
(A) λ1 = λ2
2
(B) λ1 = λ2
(C) λ1 = 2λ2
(D) λ1 = 4λ2
CORRECT ANSWER: C
SOLUTION:
c E1
E = hv = h ∴
λ E2
λ2
=
λ1
i.e.,
λ1 E2 50eV
= =
λ2 E1 25eV
= 2 or λ1 = 2λ2
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Q-26 - 12225362
is.
(A) 10
(B) 12
(C) 14
(D) 16
CORRECT ANSWER: C
SOLUTION:
14.
Q-27 - 34964647
The correct set of four quantum numbers for the valence electrons
1
(A) 5, 0, 0, +
2
1
(B) 5, 1, 0, +
2
1
(C) 5, 1, 1, +
2
1
(D) 5, 0, 1, +
2
CORRECT ANSWER: 1
SOLUTION:
Z = 37
Rb is in fifth period.
Q-28 - 11034236
h
The orbital angular momentum of a p electron is equal to √2
2π
SOLUTION:
Q-29 - 69094789
(A) 10
(B) 25
(C) 50
(D) 75
CORRECT ANSWER: C
SOLUTION:
c c
v= or λ =
λ v
17
3 × 10 nms − 1
= 15 − 1
6 × 10 x
= 50nm
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Q-30 - 12225366
(A) 2
(B) 4
(C) 6
(D) 10
CORRECT ANSWER: A
SOLUTION:
Q-31 - 12225367
Based on equation
E = − 2.178
2
J( 2 )
− 18 Z
× 10
n
, certain conclusions are written. Which of them is not correct ?
(A) the larger the value of n. The larger is the orbit
radius.
CORRECT ANSWER: C
SOLUTION:
Q-32 - 69094800
the nucleus.
CORRECT ANSWER: D
SOLUTION:
loosely bound
Q-33 - 12225368
(B) 2
(C) 3
(D) 4
CORRECT ANSWER: A
SOLUTION:
(a) Given : n = 3, l = 1, m = 0
Hence orbital is 3p
one only.
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Q-34 - 12225369
45nm :
− 34
(Planck' constant h = 6.63 × 10 Js , speed of light
c = 3 × 108 ms − 1 )
11
(B) 6.67 × 10
− 15
(C) 4.42 × 10
− 18
(D) 4.42 × 10
CORRECT ANSWER: D
SOLUTION:
(d)
hc
λ
− 34
6.63 × 10 ×3
8
= × 10
−9
45 × 10
=4.42 × 10 − 18 J .
Q-35 - 69094806
(A) 2√3h
(B) 0h
(C) √6h
(D) √2h
CORRECT ANSWER: C
SOLUTION:
For d-orbital, l = 2
∴ Angular momentum
= √2(2 + 1)h
= √6h
Q-36 - 12225371
(A) Cr2 +
2+
(B) Co
2+
(C) Ni
3+
(D) T i
CORRECT ANSWER: C
SOLUTION:
Q-37 - 33031317
CORRECT ANSWER: B
SOLUTION:
2+ 6 0
(b) Electronic configuration of F e is [Ar] 3d 4s .
∴ Number of electrons = 6
2 2 6 2
Mg - 1s 2s 2p 3s (6s electrons)
Q-38 - 46826814
CORRECT ANSWER: C
SOLUTION:
This is because chargeless particles do not undergo any
electron.
Q-39 - 12225377
(A) Chadwick
(B) Thomson
(C) Goldstein
(D) Bohr
CORRECT ANSWER: C
SOLUTION:
( c) Proton is represented by p having charge + 1
Q-40 - 12225378
(A) Photon
(B) Neutron
(C) Positron
(D) Proton
CORRECT ANSWER: C
SOLUTION:
0
( c) Positron ( + 1e ) has the same mass as that of an
0
electron ( − 1e ).
Q-41 - 12225380
The most probable radius (in pm) for finding the electron in He +
is.
(A) 0.0
(B) 52.9
(C) 26.5
(D) 105.8
CORRECT ANSWER: C
SOLUTION:
Q-42 - 12225055
CORRECT ANSWER: C
SOLUTION:
( c) Mass no ≈ At. W t
Q-43 - 12225382
(A) Li
(B) He +
(C) He
(D) Be
CORRECT ANSWER: C
SOLUTION:
( c)
−= 2
H 1s and He
2
= 1s
.
Q-44 - 12225383
(A) 6
(B) 12
(C) 0
(D) 3
CORRECT ANSWER: C
SOLUTION:
( c) In the nucleus of an atom only proton and neutrons
are present.
Q-45 - 12225384
electrons is.
(A) + 1
(B) − 2
(C) − 1
(D) zero
CORRECT ANSWER: C
SOLUTION:
−
( c) Cl has 17 protons, 18 neutrons and 18 electrons.
Q-46 - 12225385
CORRECT ANSWER: C
SOLUTION:
( c) In Xe231
89 , number of protons and electrons is 89 and
no. of neutrons
= A − Z = 231 − 89
= 142
.
Q-47 - 12225053
small
electrons
SOLUTION:
Q-48 - 12225091
theory ?
frequency
CORRECT ANSWER: D
SOLUTION:
(d) E = nhv, n = 1, 2, 3
Q-49 - 12225388
(A) H
(B) Li +
(C) Na
+
(D) He
CORRECT ANSWER: B
SOLUTION:
+
(b) Both He and Li contain 2 electrons each.
Q-50 - 12225389
(A) Electron
(B) Photon
(C) Positron
(D) Proton
CORRECT ANSWER: B
SOLUTION:
(b) According to quantum theory of radiation, a hot body
Q-51 - 12225390
The ratio of area covered by second orbital to the first orbital is.
(A) 1 : 2
(B) 1 : 16
(C) 8 : 1
(D) 16 : 1
CORRECT ANSWER: D
SOLUTION:
2 4
(d) rn ∝ n : An ∝ n
A2 n42
2 4
= 4 = 4
A1 n1 1
16
= = 16: 1
1
.
Q-52 - 12225210
(A) c = v × λ
h
(B) λ =
p
(C) diffraction
SOLUTION:
h
(b) In the expression λ = , λ is a characteristic of
p
wave motion and momentum ' p' is a characteristic of
particle motion.
Q-53 - 12225393
(A) 6.63 × 10 − 33
− 34
(B) 6.63 × 10 m
− 35
(C) 6.63 × 10 m
− 35
(D) 6.65 × 10 m
CORRECT ANSWER: A
SOLUTION:
(a)
h
λ=
mv
− 34
6.63 × 10
= −3
10 × 100
= 6.63 × 10 − 33 m
.
Q-54 - 12225184
(A) 2 �
(B) 4 �
(C) 8 �
(D) 100 �
CORRECT ANSWER: B
SOLUTION:
=
− 27
6.62 × 10 × 6.023
23
× 10 cm
4
2 × 5 × 10
=4 × 10 − 8 cm = 4.
− 28
(A) 1.05 × 10 m
− 26
(B) 1.05 × 10 m
(C) 5.27 × 10 − 30 m
− 28
(D) 5.25 × 10 m
CORRECT ANSWER: C
SOLUTION:
h
( c) According to Δx × Δp =
4π
h
Δx =
Δp × 4π
− 34
6.62 × 10
= −5
1 × 10 × 4 × 3.14
=5.27 × 10 − 32 m.
Q-56 - 11033634
respetively related to
SOLUTION:
Principal quantum number gives size azimaller gives
Q-57 - 12225398
14 4 2
(A) [Rn]5f , 6d , 7s
14 1 2 3
(B) [Rn]5f , 6d , 7s 7p
CORRECT ANSWER: D
SOLUTION:
(d)
UnH106 = [Rn]5f 14 ,
6d 5 , 7s1
.
Q-58 - 12225258
having l = 3.
(A) 3
(B) 7
(C) 5
(D) 9
CORRECT ANSWER: B
SOLUTION:
(b)
2 2 6
n = 4 → 1s 2s 2p ,
3s2 3p6 , 3d 10 , 4s2 4p6 ,
4d 10 4f 14
orbitals.
Q-59 - 46827165
(A) 2
(B) 0
(C) 3
(D) 1
CORRECT ANSWER: C
SOLUTION:
Q-60 - 46827134
statements is correct
(B) The second principal energy level can have four sub-
energy levels and contains a maximum of eight electrons
electrons
CORRECT ANSWER: B
SOLUTION: