NEET

REVISION SERIES

ATOMIC STRUCTURE

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Q-1 - 12225289

For the energy level is an atom which one of the following

statement is correct ?

(A) The 4s sub-energy level is a higher energy than the

3d sub-energy level

(B) The M-energy level can have maximum of 32

electrons

(C) The second principal energy level can have four

orbitals and contain a maximum of 8 electrons

(D) The 5th main energy level can have maximum of 49

electrons.
 CORRECT ANSWER: C

SOLUTION:

( c) for n = 2,
2s 2p
1+ 3 = 4orbitals
2 +6 = 8electrons

It has 4 orbitals and contains 8 electrons.

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Q-2 - 34964406

Which orbital is non-directional

(A) s

(B) p

(C) d
 (D) All

CORRECT ANSWER: A

SOLUTION:

The lobes of dx2 − y2 orbital are alligned along X and Y

axis. Therefore the probability of finding the electron is

maximum along x and y-axis.

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Q-3 - 12225293

In centre-symmetrical system, the orbital angular momentum, a

measure of the momentum of a particle travelling around the

nucleus, is quantised. Its magnitude is

h
(A) √l(l + 1)
2π
h
(B) √l(l − 1)
2π
 h
(C) √s(s + 1)
2π
h
(D) √s(s − 1)
2π

CORRECT ANSWER: A

SOLUTION:

h
(a) √l(l + 1) .
2π
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Q-4 - 69094858

The maximum probability of finding electron in the dxy orbital is

(A) along the x-axis

(B) along the y-axis

(C) at an angle of 45 ∘ from the x-axis and y-axis

(D) at an angle of 90 ∘ from the x-axis and y-axis

 CORRECT ANSWER: C

SOLUTION:

The dxy orbital has lobes between x-axis and y-axis, i.e.,

at an angle of 45 from x-axis and y-axis.

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Q-5 - 12225290

The electronic configurations of Cr24 and Cu29 are abnormal -

(A) Due to extra stability of exactly half filled and exactly

fully filled sub shells

(B) Because they belong to d-block

(C) both (a) and (b)

(D) None of the above

CORRECT ANSWER: A

SOLUTION:

(a)
Cr24
2 2 6 2 2 4
− 1s 2s 2p 3s 4s 3d

(original configuration)
5
but − d − its's half-filled state and that is state most

stable than other state.

Cr24
2 2 6 6 1 5
− 1s 2s 2p 3s 4s 3d

As above full filled stata that is most stable than other

state.
Cu
2 2 6 2 6 2 9
− 1s 2s 2p 3s 3p 4s 3d

but
2 2 6 2 6 1 10
1s 2s 2p 3s 3p 4s 3d
 (full filled).

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Q-6 - 12225287

Which of the following statements about nodal planes is/are not

true.

(A) A plane on which there is zero probability of finding

an electron

(B) A plane on which there is maximum probability that

the electron will be found

(C) Ψ 2 is non zero at nodal plane

(D) None of these

CORRECT ANSWER: B

SOLUTION:
 (b) A plane on which there is maximum probability that

the electron wll be found.

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Q-7 - 14157447

Which of the following sets of quantum numbers represent an

impossible arrangement :-
n l m ms
(A) 3 2 − 2 12
1
(B) 4 0 0 2
1
(C) 3 2 − 3 2
1
(D) 5 3 0 2

CORRECT ANSWER: C

SOLUTION:

Hund's rule

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 Q-8 - 12225285

Maximum numbers of electrons in a subshell is given by-

(A) (2l + 1)

(B) 2(2l + 1)

(C) (2l + 1)2

(D) 2(2l + 1)2

CORRECT ANSWER: B

SOLUTION:

(b) 2(2l + 1).

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Q-9 - 23583453
The quantum number not obtained from the schrodinger's wave

equation is

(A) n

(B) l

(C) m

(D) s

CORRECT ANSWER: D

SOLUTION:

Spin quantum number is not obtained from

Schrodinger's wave equation.

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Q-10 - 12225281
If the electronic structure of oxygen atom is written as

1s2 , 2s2 it

would violate-

(A) Hund's rule

(B) Pauli's exclusion principle

(C) Both Hund's and Pauli's principles

(D) None of these

CORRECT ANSWER: A

SOLUTION:

(a) According to this rule pairing of electrons does not

 take place until all the orbitals of the sub-shell are singly

occupied.

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Q-11 - 46827304

The following quantum numbers are possible for how many orbitals

n=3, l=2, m=+2

(A) 3

(B) 2

(C) 1

(D) 4

CORRECT ANSWER: C

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 Q-12 - 12225344

The total energy of the electron in the hydrogen atom in the ground

state is −13.6eV . The KE of this electron is.

(A) 13.6eV

(B) zero

(C) − 13.6eV

(D) 6.8eV

CORRECT ANSWER: A

SOLUTION:

(a)
 1
∵ KE = mv2
2
Ze2
= , TE =
2r
Ze2
−
2r
.

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Q-13 - 12225345

In hydrogen atom, energy of first excited state is −3.4eV . Then,

KE of the same orbit of hydrogen atom is.

(A) + 3.4eV

(B) + 6.8eV

(C) − 13.6eV

(D) + 13.6eV

CORRECT ANSWER: A
 SOLUTION:

(a) ∵ Total energy (En ) = KE + P E

In the first excited state

2
1
= mv2 + [ − ]
Ze
2 r
1 Ze2 Ze2
=+ −
2 r r
1 Ze2
− 3.4eV = −
2 r
2
1 Ze
∴ KE = =
2 2
+ 3.4eV
.

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Q-14 - 46827379

The value of Planck's contant is 6.63 × 10 − 34 Js. The velocity of

8 −1
light is 3.0 × 10 ms . Which value is closest to the wavelength

in nanometers of a quantum of light with frequency of 8 × 1015 s − 1

 7
(A) 3 × 10

− 25
(B) 2 × 10

− 18
(C) 5 × 10

(D) 4 × 101

CORRECT ANSWER: D

SOLUTION:
8
c 3 × 10
λ= =
v 8 × 1015
= 3.75 × 10 − 8

= 3.75 × 10 − 8
× 109 nm = 4 × 101
nm.

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Q-15 - 46826921
The frequency of radiation emitted when the electron falls from n=4

to n=1 in a hydrogen atom will be (Given ionization energy of

− 18 −1 − 34
H = 2.18 × 10 J atom and h = 6.625 × 10 js)

15 − 1
(A) 3.08 × 10 s

15 − 1
(B) 2.00 × 10 s

(C) 1.54 × 1015 s − 1

15 − 1
(D) 1.03 × 10 s

CORRECT ANSWER: A

SOLUTION:

EIonisation = E ∞ − En
2
13.6Zeff
= 2
eV
n
 =[
13.6Z 2
n22

]
2
13.6Z
−
n21

2
13.6 × 1
E = hv = 2
(1)
2
(13.6 × 1)
− 2
, hv
(4)
= 13.6 − 0.85

− 34
∵ h = 6.625 × 10
13.6 − 0.85
v= − 34
6.625 × 10
− 19
× 1.6 × 10 = 3.08
15 − 1
× 10 s
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Q-16 - 12225126

The energy of second Bohr orbit of the hydrogen atom is

− 328kJmol − 1 , hence the energy of fourth Bohr orbit would be.

(A) − 41kJmol − 1

−1
(B) − 1312kJmol

−1
(C) − 164kJmol

(D) − 82kJmol − 1

CORRECT ANSWER: D

SOLUTION:

(d)
2
E4 2 4
= 2 =
E2 4 16
1
= ,
4

E2 − 328
E4 = = =
4 4
− 82kJ / mol
.
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Q-17 - 74865140

Given: The mass of electron is 9.111031 Kg Planck constant is

6.6261034 Js, the uncertainty involved in the measurement of

velocity within a distance of 0.1 is:-

6
(A) 5.79 � 10 ms( � 1)

(B) 5.79 � 107 ms9 � 1)

8 �1
(C) 5.79 � 10 ms

5 �1
(D) 5.79 � 10 ms

CORRECT ANSWER: A

SOLUTION:

h
Δ × xΔv ≥
4πm
∴ Δx = 0.1
− 11
= 1 × 10 m
 h
ΔV ≥
4πm × Δx
ΔV
− 34
6.626 × 10 J sec
≥
4 × 3.14 × 9.11
× 10 − 31 kg × 10 − 11 m
Δ ≥ 5.79
6 −1
× 10 m sec
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Q-18 - 30545666

Consider the following sets of quantum numbers:

n l m s
(A) 3 0 0 + 1 /2
(B) 2 2 1 + 1 /2
(C) 4 3 −2 − 1 /2
(D) 1 0 −1 − 1 /2
(E) 3 2 3 + 1 /2
Which of the following sets of quantum nubmers is not possible?

(A) A,B,C and D

(B) B,D and E

 (C) A and C

(D) B,C and D

CORRECT ANSWER: B

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Q-19 - 12225354

The measurement of the electron position is associated with an

uncertainty in momentum, which is equal to 1 × 10 − 18 gcms − 1 .

The uncertainty in electron velocity is (mass of an electron is

9 × 10 − 28 g)

(A) 1 × 106 cms − 1

5 −1
(B) 1 × 10 cms

11 −1
(C) 1 × 10 cms

9
(D) 1.1 × 10 cms − 1
CORRECT ANSWER: D

SOLUTION:

(d)
Δx = Δp ∴ ΔxΔp
h
=
4π

or Δx = √
h

4π
h
Δx. Δu =
4πm
Δp = 1
− 18 −1
× 10 gcm sec

− 18
m × Δu = 1 × 10
1 × 10 − 18
∴ Δu = − 28
9 × 10
9 −1
= 1.1 × 10 cm sec
.

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 Q-20 - 12225355

Maximum number of electrons in a sub-shell of an atom is

determined by the following.

(A) 2n2

(B) 4l + 2

(C) 2l + 1

(D) 4l − 2

CORRECT ANSWER: B

SOLUTION:

(b) Total number of subshells = (2l + 1)

∴ Maximum number of electrons in the subshells

= 2(2l + 1)

=4l + 2.
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Q-21 - 12973042

Which of the following sate of quantum numbers is not permissible

for an electron in an atom?

(i)
n = 1, l = 1, ml 0, ms =
+ 1/2

(ii)
n = 3, l = 1, m1 = − 2, ms
= − 1/2

(iii)
n = 1, l = 1, ml = 0, ms =
+ 1/2

(iv)
n = 2, l = 0, ml = 0, ms
=1
 (A) (i), (ii), (iii), (iv)

(B) (ii), (iii), (iv)

(C) (i), (ii), (iv)

(D) (i), (iii), (iv)

CORRECT ANSWER: C

SOLUTION:

(i) is not permissible because the l quantum number is

equal to n, it must be less than n. (ii) is not permissible

because the magnitude of the ml quantum number (that

is, the ml value, ignoring its sign) must not be greater

than l. (iv) is not permissible beacuse ms ,quantum

number can be only + 1 / 2 or − 1 / 2.

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Q-22 - 69094897
The energy absorbed by each molecule (A 2 ) of a substance is

4.4 × 10 − 19 J and bond energy per molecule is 4.0 × 10 − 19 J .

The kinetic energy of the molecule per atom will be

− 19
(A) 2.2 × 10 J

(B) 2.0 × 10 − 19 J

− 20
(C) 4.0 × 10 J

− 20
(D) 2.0 × 10 J

CORRECT ANSWER: D

SOLUTION:
− 19
(4.4 × 10 )
− 19
− (4.0 × 10 )
K.E. per atom = J
− 19
2
0.4 × 10
= J
2
− 20
= 2.0 × 10 J
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Q-23 - 12225358

A 0.66kg ball is moving wih a speed of 100m /s. The associated

wavelength will be.

(A) 6.6 × 10 − 32 m

− 34
(B) 6.6 × 10 m

− 35
(C) 1.0 × 10 m

− 32
(D) 1.0 × 10 m

CORRECT ANSWER: C

SOLUTION:

( c)
 h
λ=
mv
− 34
6.6 × 10
= =1
0.66 × 100
− 35
× 10 m
.

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Q-24 - 12225359

The total number of atomic orbitals in fourth energy level of an

atom is.

(A) 4

(B) 8

(C) 16

(D) 32

CORRECT ANSWER: C
 SOLUTION:

2
( c) Number of atomic orbitals = n
th
Number of atomic orbitals in 4 energy shell
2
= 4 = 16.

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Q-25 - 69094787

The energines E1 and E2 of two radiations are 25 eV and 50 eV

respectively. The relation between their wavelengths, i.e.,

λ1 and λ2 will be

1
(A) λ1 = λ2
2
(B) λ1 = λ2

(C) λ1 = 2λ2

(D) λ1 = 4λ2
 CORRECT ANSWER: C

SOLUTION:

c E1
E = hv = h ∴
λ E2
λ2
=
λ1

i.e.,
λ1 E2 50eV
= =
λ2 E1 25eV
= 2 or λ1 = 2λ2
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Q-26 - 12225362

Maximum number of electrons in a sub-shell with l = 3 and n = 4

is.

(A) 10
 (B) 12

(C) 14

(D) 16

CORRECT ANSWER: C

SOLUTION:

( c) If n = 4 and l = 3, it means it is a 4 f-orbital

Therefore, the total number od electrons in 4 f-orbital is

14.

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Q-27 - 34964647

The correct set of four quantum numbers for the valence electrons

of rubidium atim (Z = 37) is:

1
(A) 5, 0, 0, +
2
 1
(B) 5, 1, 0, +
2
1
(C) 5, 1, 1, +
2
1
(D) 5, 0, 1, +
2

CORRECT ANSWER: 1

SOLUTION:

Z = 37

Rb is in fifth period.

[Kr]5s1 is its configuration: " " So

n = 5, l = 0, m = 0, s
1
= +
2
1
or −
2
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Q-28 - 11034236
 h
The orbital angular momentum of a p electron is equal to √2
2π

SOLUTION:

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Q-29 - 69094789

The value of Planck's constant is 6.63 × 10 − 34 Js. The speed of

light is 3 × 1017 nms − 1 . Which value is closest to the wavelength

in nanometer of a quantum of light with frequency of 6 × 1015 s − 1

(A) 10

(B) 25

(C) 50
 (D) 75

CORRECT ANSWER: C

SOLUTION:
c c
v= or λ =
λ v
17
3 × 10 nms − 1
= 15 − 1
6 × 10 x
= 50nm
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Q-30 - 12225366

What is the maximum number of electrons that can be associated

with a following set of quantum numbers ?

(n = 3, l = 1 and m =
− 1)
.

(A) 2
 (B) 4

(C) 6

(D) 10

CORRECT ANSWER: A

SOLUTION:

(a) n = 3, l = 1 is 3p sub-shell and thus 2 electrons

can exists in one of the 3p-orbital (m = -1).

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Q-31 - 12225367

Based on equation
E = − 2.178
2
J( 2 )
− 18 Z
× 10
n
, certain conclusions are written. Which of them is not correct ?
(A) the larger the value of n. The larger is the orbit

radius.

(B) Equation can be used to calculate the change in

energy when the electron changes orbit.

(C) For n = 1, the electron has a more negative energy

than it does for n = 6 which means that the electron is

more loosely bound in the smallest allowed orbit

(D) The negative sign in equation simply means that the

energy of electron bound to the nucleus is lower than it

would be if the electrons were at the infinite distance

from the nucleus.

CORRECT ANSWER: C

SOLUTION:

( c) For n = 1, the electron has a more negative energy

 than it does for n = 6 which means that the electron is

more loosely bound in the smallest allowed orbit. This is

not correct. Electron is more tightly held in the 1st orbit.

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Q-32 - 69094800

Based on the equation

E = − 2.178
2
× 10 − 18 J( 2 )
Z
n
certain conclusions are written. Which of them is not correct ?

(A) The negative sign in equation simply means that the

energy of electron bound to the nucleus is lower than it

would be if the electrons were at infinite distance from

the nucleus.

(B) Lower the value of n, the larger is the orbit radius

 (C) Equation can be used to claculate the change in

energy when the electron changes orbit

(D) For n = 1, the electron has a more negative energy

that it does for n = 6 which means that the electron is

more lossely bound in the smallest allowed orbit.

CORRECT ANSWER: D

SOLUTION:

Statement (d) is not correct because in the smallest

allowed orbit, the electron is more tightly bound and not

loosely bound

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Q-33 - 12225368

What is the maximum number of orbitals that can be identified with

the following quantum numbers ? n = 3, l = 1, ml = 0.

(A) 1

(B) 2

(C) 3

(D) 4

CORRECT ANSWER: A

SOLUTION:

(a) Given : n = 3, l = 1, m = 0

Hence orbital is 3p

Hence the number of orbital identified by m = 0 can be

one only.
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Q-34 - 12225369

Calculate the energy in joule corresponding to light of wavelength

45nm :
− 34
(Planck' constant h = 6.63 × 10 Js , speed of light

c = 3 × 108 ms − 1 )

(A) 6.67 × 1015

11
(B) 6.67 × 10

− 15
(C) 4.42 × 10

− 18
(D) 4.42 × 10

CORRECT ANSWER: D

SOLUTION:

(d)
 hc
λ
− 34
6.63 × 10 ×3
8
= × 10
−9
45 × 10

=4.42 × 10 − 18 J .

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Q-35 - 69094806

The angular momentum of electron in 'd' orbital is equal to

(A) 2√3h

(B) 0h

(C) √6h

(D) √2h

CORRECT ANSWER: C
 SOLUTION:

Angular momentum = √l(l + 1)h

For d-orbital, l = 2

∴ Angular momentum
= √2(2 + 1)h

= √6h

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Q-36 - 12225371

Magnetic moments 2.84B. M is given by :

(At. nos. ni = 28, Ti = 22, Cr = 24, Co = 27).

(A) Cr2 +

2+
(B) Co

2+
(C) Ni
 3+
(D) T i

CORRECT ANSWER: C

SOLUTION:

( c) Magnetic momentum (m) = √n(n + 2)

2.84B. M corresponding to 2 unpaired electrons.

Cr2 + − 3d 4 , 3 unpaired electrons

2+ 7
Co − 3d , 3 unpaired electrons

Ni2 + − 3d 8 , 2 unpaired electrons

3+ 1
Ti − 3d , 1 unpaired electron.

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Q-37 - 33031317

The number of d-electrons in F e2 + (Z=26) is not equal to the

number of electrons in which one of the following ?

(A) s-electrons in Mg (Z=12)

(B) p-electrons in Cl (Z=17)

(C) d-electrons in Fe (Z=26)

(D) p-electrons in Ne (Z=10)

CORRECT ANSWER: B

SOLUTION:

2+ 6 0
(b) Electronic configuration of F e is [Ar] 3d 4s .

∴ Number of electrons = 6
2 2 6 2
Mg - 1s 2s 2p 3s (6s electrons)

It matches with the 6d electrons of F e2 +

2 2 6 2 5
Cl − 1s 2s 2p 3s 3p (11 p electrons)

It does not match with the 6d electrons of F e2 +

6 2
Fe - [Ar] 3d 4s (6d electrons)

It does not match with the 6d electrons of F e2 +

 2 2 6
Ne - 1s 2s 2p (6 p electrons)

It matches with the 6d electrons of F e2 + .

Hence, Cl had 11p electrons which does not matches in

number with 6d electrons of F e2 + .

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Q-38 - 46826814

The discovery of neutron becomes very late because

(A) Neutrons are present in nucleus

(B) Neutrons are highly unstable particles

(C) Neutrons are chargeless

(D) Neutrons do not move

CORRECT ANSWER: C

SOLUTION:
 This is because chargeless particles do not undergo any

deflection in electric or magnetic field unlike proton and

electron.

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Q-39 - 12225377

Proton was discovered by

(A) Chadwick

(B) Thomson

(C) Goldstein

(D) Bohr

CORRECT ANSWER: C

SOLUTION:
 ( c) Proton is represented by p having charge + 1

discovered in 1988 by Goldstein.

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Q-40 - 12225378

Which of the following has the same mass as that of an electron ?

(A) Photon

(B) Neutron

(C) Positron

(D) Proton

CORRECT ANSWER: C

SOLUTION:

0
( c) Positron ( + 1e ) has the same mass as that of an
 0
electron ( − 1e ).

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Q-41 - 12225380

The most probable radius (in pm) for finding the electron in He +

is.

(A) 0.0

(B) 52.9

(C) 26.5

(D) 105.8

CORRECT ANSWER: C

SOLUTION:

( c) Most probable radius = a0 / Z

 where a0 = 52.9 pm. For helium ion, Z = 2.
52.9
rmp = = 26.45 pm.
2
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Q-42 - 12225055

If the atomic weight of an element is 23 times that of the lightest

element and it has 11 protons, then it contains.

(A) 11 protons, 23 neutrons, 11 electrons

(B) 11 protons, 11 neutrons, 11 electrons

(C) 11 protons, 12neutrons, 11 electrons

(D) 11 protons, 11 neutrons, 23 electrons.

CORRECT ANSWER: C

SOLUTION:
 ( c) Mass no ≈ At. W t

Mass no. = no. of protons + no. of neutrons

At. No = no. of protons = no. of electrons.

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Q-43 - 12225382

The hydride ions (H − ) are isoelectronic with

(A) Li

(B) He +

(C) He

(D) Be

CORRECT ANSWER: C

SOLUTION:
 ( c)
−= 2
H 1s and He
2
= 1s
.

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Q-44 - 12225383

The number of electrons in the nucleus of C 12 is

(A) 6

(B) 12

(C) 0

(D) 3

CORRECT ANSWER: C

SOLUTION:
 ( c) In the nucleus of an atom only proton and neutrons

are present.

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Q-45 - 12225384

The charge on the atom containing 17 protons, 18 neutrons and 18

electrons is.

(A) + 1

(B) − 2

(C) − 1

(D) zero

CORRECT ANSWER: C

SOLUTION:
 −
( c) Cl has 17 protons, 18 neutrons and 18 electrons.

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Q-46 - 12225385

Number of protons, neutrons and electrons in the element .231

89 Y is.

(A) 89, 231, 89

(B) 89, 89, 242

(C) 89, 142, 89

(D) 89, 71, 89

CORRECT ANSWER: C

SOLUTION:

( c) In Xe231
89 , number of protons and electrons is 89 and

no. of neutrons
 = A − Z = 231 − 89
= 142
.

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Q-47 - 12225053

When atoms are bombarded with alpha particles, only a few in

millon suffer deflection, other pass out undeflected. This is because.

(A) The force of repulsion on the moving alpha particle is

small

(B) The force of attraction on the alpha particle to the

oppositely charged electrons is very small

(C) There is only one nucleus and large number of

electrons

(D) The nucleus occupies much smaller volume

compared to the volume of the atom.

 CORRECT ANSWER: D

SOLUTION:

(d) The nucleus occupies much smaller volume

compared to the volume of the atom.

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Q-48 - 12225091

Which of the following is not correct according to Planck's quantum

theory ?

(A) Energy is emitted or absorbed discontinuously

(B) Energy of a quatum is directly proportional to its

frequency

(C) A photon is also a quantum of light

(D) Energy less than a quantum can also be emitted or

 absorbed

CORRECT ANSWER: D

SOLUTION:

(d) E = nhv, n = 1, 2, 3

Only integer quantum can be emitted or absorbed.

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Q-49 - 12225388

The spectrum of He is expected to be similar to.

(A) H

(B) Li +

(C) Na

+
(D) He
 CORRECT ANSWER: B

SOLUTION:

+
(b) Both He and Li contain 2 electrons each.

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Q-50 - 12225389

What is the packet of enegry called ?

(A) Electron

(B) Photon

(C) Positron

(D) Proton

CORRECT ANSWER: B

SOLUTION:
 (b) According to quantum theory of radiation, a hot body

emits radiant enegry not continuously but

discontinuously in the form of small packets of energy

called quanta or photons.

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Q-51 - 12225390

The ratio of area covered by second orbital to the first orbital is.

(A) 1 : 2

(B) 1 : 16

(C) 8 : 1

(D) 16 : 1

CORRECT ANSWER: D

SOLUTION:
 2 4
(d) rn ∝ n : An ∝ n
A2 n42
2 4
= 4 = 4
A1 n1 1
16
= = 16: 1
1
.

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Q-52 - 12225210

Which of the following best explains light both as a stream of

particles and wave motion ?

(A) c = v × λ

h
(B) λ =
p
(C) diffraction

(D) photoelectric effect.

 CORRECT ANSWER: B

SOLUTION:

h
(b) In the expression λ = , λ is a characteristic of
p
wave motion and momentum ' p' is a characteristic of

particle motion.

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Q-53 - 12225393

The de-Broglie wavelength of a particle with mass 1g and velocity

100m/ sec is.

(A) 6.63 × 10 − 33

− 34
(B) 6.63 × 10 m

− 35
(C) 6.63 × 10 m

− 35
(D) 6.65 × 10 m
 CORRECT ANSWER: A

SOLUTION:

(a)
h
λ=
mv
− 34
6.63 × 10
= −3
10 × 100
= 6.63 × 10 − 33 m
.

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Q-54 - 12225184

If the velocity of hydrogen molecule is 5 × 104 cm sec − 1 , then its

de-Broglie wavelength is.

(A) 2 �

(B) 4 �
(C) 8 �

(D) 100 �

CORRECT ANSWER: B

SOLUTION:

(b) According to de-Broglie

h
λ=
mv
6.62 × 10 − 20 erg. sec
= 2 4
23 × 5 × 10 cm
6.023 × 10
/ sec

=
− 27
6.62 × 10 × 6.023
23
× 10 cm
4
2 × 5 × 10

=4 × 10 − 8 cm = 4.

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 Q-55 - 12225197

The uncertainty in momentum of an electron is

1 × 10 − 5 kg − m / s. The uncertainty in its position will be

(h = 6.62 × 10 − 34 kg = m2
/ s)
.

− 28
(A) 1.05 × 10 m

− 26
(B) 1.05 × 10 m

(C) 5.27 × 10 − 30 m

− 28
(D) 5.25 × 10 m

CORRECT ANSWER: C

SOLUTION:

h
( c) According to Δx × Δp =
4π
 h
Δx =
Δp × 4π
− 34
6.62 × 10
= −5
1 × 10 × 4 × 3.14

=5.27 × 10 − 32 m.

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Q-56 - 11033634

Principal azimuthal , and magnetic quantum numbers are

respetively related to

(A) Size,orbital,and shape

(B) size, shape, and orientation

(C) shape, size and oricutation

(D) None of these

SOLUTION:
 Principal quantum number gives size azimaller gives

shape red magnetic orientation

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Q-57 - 12225398

Elements up to atomic number 103 have been synthesized and

studied. If a newly discovered element is found to have an atomic

number 106, its electronic configuration will be

14 4 2
(A) [Rn]5f , 6d , 7s

14 1 2 3
(B) [Rn]5f , 6d , 7s 7p

(C) [Rn]5f 14 , 6d 6 , 7s0

(D) [Rn]5f 14 , 6d 5 , 7s1

CORRECT ANSWER: D

SOLUTION:
 (d)
UnH106 = [Rn]5f 14 ,
6d 5 , 7s1
.

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Q-58 - 12225258

For principle quantum number n = 4 the total number of orbitals

having l = 3.

(A) 3

(B) 7

(C) 5

(D) 9

CORRECT ANSWER: B
 SOLUTION:

(b)
2 2 6
n = 4 → 1s 2s 2p ,
3s2 3p6 , 3d 10 , 4s2 4p6 ,
4d 10 4f 14

So l = (n-1) = 4 -1 =3 is for f orbit which contains 7

orbitals.

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Q-59 - 46827165

Number of unpaired electrons in 1s2 2s2 2p3 is

(A) 2

(B) 0

(C) 3
 (D) 1

CORRECT ANSWER: C

SOLUTION:

In this type of electronic configuration the number of

unpaired electrons are 3.

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Q-60 - 46827134

For the energy levels in an atom, which one of the following

statements is correct

(A) There are seven principal electron energy levels

(B) The second principal energy level can have four sub-
energy levels and contains a maximum of eight electrons

(C) The M energy level can have maximum of 32

electrons

(D) The 4s sub-energy level is at a higher energy than

the 3d sub-energy level

CORRECT ANSWER: B

SOLUTION:

The second principal shell contains four orbitals viz 2s ,

2px , 2py and 2pz

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