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Problems On Fugacity

The document provides instructions and data for calculating the fugacity of various gases at different pressures and temperatures. It includes calculating fugacity for ammonia at 10 bar and 298 K, oxygen at 100 bar and 200 K, and CO at 50 bar and 400 bar based on specified equations of state, compressibility factors, and other thermodynamic property data provided.

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Akshat Rawat
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2K views

Problems On Fugacity

The document provides instructions and data for calculating the fugacity of various gases at different pressures and temperatures. It includes calculating fugacity for ammonia at 10 bar and 298 K, oxygen at 100 bar and 200 K, and CO at 50 bar and 400 bar based on specified equations of state, compressibility factors, and other thermodynamic property data provided.

Uploaded by

Akshat Rawat
Copyright
© © All Rights Reserved
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
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The density of gaseous NH3 at 473 K and 50 bar is 24.3 kg/m3. Estimate its fugacity.

Calculate the fugacity of liquid water at 303 K and 10 bar if the saturation pressure at 303K is 4.241
kPaand specific volume is 1.004 ×10-3 m3/kg
Calculate the fugacity of n-butane in liquid state at 350 K and 60 bar. The vapourpressure of n-butane is
9.35 bar at 350 K. Molar volume is 1.072 ×10-3m3/mol. Fugacity coefficient is 0.834
Find the fugacity coefficient at 1 bar, 5 bar and 10 bar for a gas that follows the equation of state PV =
RT(1-0.00513P)
Derive an expression for fugacity coefficient of a gas obeying the equation of state

P(V-b) = RT

Estimate the fugacity of ammonia at 10 bar and 298 K given that b = 3.707 ×10 -5m3/mol
At 200 K, the compressibility factor of oxygen varies with pressure as given below. Evaluate the fugacity
of oxygen at this temperature and 100 bar.

P, bar 1 4 7 10 40 70 100
Z 0.99701 0.98896 0.97880 0.96956 0.8734 0.7764 0.6871
Z-1
(Z-1)/P -2.99 x 10-3 -2.76 x 10-3 -3.02 x 10-3 -3.044 x 10-3 -3.16 x 10-3 -3.19 x 10-3 -3.12 x 10-3
50
From the PVT data for a gas it is found that ∫ α dP=−556.61 J /mol . Find the fugacity of the gas at 50
0
bar and 300 K.
Calculate the fugacity of CO at 50 bar and 400 bar, if the following data are applicable at 273 K.

P, bar 25 50 100 200 400 800 1000


Z 0.9890 0.9792 0.9741 1.01961 1.2482 1.8057 2.0819

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