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MSDS-PELLASTOL 94 S - English

This document provides a safety data sheet for PELLASTOL 94 S, identifying it as a leather treatment chemical. It causes mild skin irritation and serious eye irritation. It is harmful to aquatic life. Personal protective equipment should be worn when handling. In the event of accidental release, isolate the area and contain any spillage. Dispose of in accordance with local regulations.
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0% found this document useful (0 votes)
1K views13 pages

MSDS-PELLASTOL 94 S - English

This document provides a safety data sheet for PELLASTOL 94 S, identifying it as a leather treatment chemical. It causes mild skin irritation and serious eye irritation. It is harmful to aquatic life. Personal protective equipment should be worn when handling. In the event of accidental release, isolate the area and contain any spillage. Dispose of in accordance with local regulations.
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 13

SAFETY DATA SHEET

PELLASTOL 94 S

Section 1. Identification
Product identifier : PELLASTOL 94 S
Chemical name : Not available.
Product code : 12551000
Recommended use of the chemical and restrictions on use
Identified uses
Leather treatment chemical.
Formulation or re-packing
Manufacture

Supplier's details : Zschimmer & Schwarz GmbH & Co KG


Max-Schwarz-Str. 3-5
56112 Lahnstein / GERMANY
+49 (0)2621 12-0

Emergency telephone : +49 (0)2621 12-0 (24/7)


number

Section 2. Hazard identification


Classification of the : SKIN CORROSION/IRRITATION - Category 3
substance or mixture SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A

GHS label elements


Hazard pictograms :

Signal word : Warning


Hazard statements : H319 - Causes serious eye irritation.
H316 - Causes mild skin irritation.
H402 - Harmful to aquatic life.
Precautionary statements
Prevention : P280 - Wear eye or face protection.
P273 - Avoid release to the environment.
P264 - Wash hands thoroughly after handling.
Response : P332 + P313 - If skin irritation occurs: Get medical attention.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 - If eye irritation persists: Get medical attention.
Storage : Not applicable.
Disposal : P501 - Dispose of contents and container in accordance with all local, regional,
national and international regulations.

Other hazards which do not : None known.


result in classification

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PELLASTOL 94 S

Section 3. Composition/information on ingredients


Substance/mixture : Mixture

Ingredient name % CAS number


sodium oleate ≤10 143-19-1
2-(2-butoxyethoxy)ethanol ≤10 112-34-5
Butanedioic acid, sulfo-, C-C10-18-alkyl esters, disodium salts, ≤5 115535-37-0
ethoxylated
2-butoxyethanol ≤5 111-76-2
Benzenesulfonic acid, C10-13-alkyl derivs., sodium salts <3 68411-30-3
Fatty acids, tall-oil, C12-15-alkyl esters, sulfated, sodium salts ≤3 68424-50-0
Alcohols, C16-18, ethoxylated ≤3 68439-49-6
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures


Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
If not breathing, if breathing is irregular or if respiratory arrest occurs, provide
artificial respiration or oxygen by trained personnel. It may be dangerous to the
person providing aid to give mouth-to-mouth resuscitation. Get medical attention if
adverse health effects persist or are severe. If unconscious, place in recovery
position and get medical attention immediately. Maintain an open airway. Loosen
tight clothing such as a collar, tie, belt or waistband.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention if adverse
health effects persist or are severe. Wash clothing before reuse. Clean shoes
thoroughly before reuse.
Ingestion : Wash out mouth with water. Remove dentures if any. Remove victim to fresh air
and keep at rest in a position comfortable for breathing. If material has been
swallowed and the exposed person is conscious, give small quantities of water to
drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If vomiting occurs,
the head should be kept low so that vomit does not enter the lungs. Get medical
attention if adverse health effects persist or are severe. Never give anything by
mouth to an unconscious person. If unconscious, place in recovery position and get
medical attention immediately. Maintain an open airway. Loosen tight clothing such
as a collar, tie, belt or waistband.

Most important symptoms/effects, acute and delayed


Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : No known significant effects or critical hazards.
Skin contact : Causes mild skin irritation.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : No specific data.

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PELLASTOL 94 S

Section 4. First aid measures


Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : No specific data.

Indication of immediate medical attention and special treatment needed, if necessary


Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

See toxicological information (Section 11)

Section 5. Fire-fighting measures


Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

Specific hazards arising : In a fire or if heated, a pressure increase will occur and the container may burst.
from the chemical This material is harmful to aquatic life. Fire water contaminated with this material
must be contained and prevented from being discharged to any waterway, sewer or
drain.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
metal oxide/oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.

Section 6. Accidental release measures


Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or
mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers. Inform the relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air). Water polluting material.
May be harmful to the environment if released in large quantities.

Methods and materials for containment and cleaning up

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PELLASTOL 94 S

Section 6. Accidental release measures


Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop
up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry
material and place in an appropriate waste disposal container. Dispose of via a
licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas.
Wash spillages into an effluent treatment plant or proceed as follows. Contain and
collect spillage with non-combustible, absorbent material e.g. sand, earth,
vermiculite or diatomaceous earth and place in container for disposal according to
local regulations (see Section 13). Dispose of via a licensed waste disposal
contractor. Contaminated absorbent material may pose the same hazard as the
spilled product. Note: see Section 1 for emergency contact information and Section
13 for waste disposal.

Section 7. Handling and storage


Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not ingest.
Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Avoid
release to the environment. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed when not in use.
Empty containers retain product residue and can be hazardous. Do not reuse
container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected
including any from direct sunlight in a dry, cool and well-ventilated area, away from incompatible
incompatibilities materials (see Section 10) and food and drink. Keep container tightly closed and
sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination. See Section 10
for incompatible materials before handling or use.

Section 8. Exposure controls/personal protection


Control parameters
Occupational exposure limits
Ingredient name Exposure limits
2-(2-butoxyethoxy)ethanol ACGIH TLV (United States, 3/2017).
TWA: 10 ppm 8 hours. Form: Inhalable
fraction and vapor
2-butoxyethanol ACGIH TLV (United States, 3/2017).
TWA: 20 ppm 8 hours.

Appropriate engineering : Good general ventilation should be sufficient to control worker exposure to airborne
controls contaminants.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

Individual protection measures

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PELLASTOL 94 S

Section 8. Exposure controls/personal protection


Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: chemical splash
goggles.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary. Considering the parameters specified by the glove manufacturer,
check during use that the gloves are still retaining their protective properties. It
should be noted that the time to breakthrough for any glove material may be
different for different glove manufacturers. In the case of mixtures, consisting of
several substances, the protection time of the gloves cannot be accurately
estimated. > 8 hours (breakthrough time): nitrile rubber
Body protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.

Section 9. Physical and chemical properties and safety


characteristics
Appearance
Physical state : Liquid.
Color : Brown.
Odor : Characteristic.
Odor threshold : Not available.
pH : 8 [Conc. (% w/w): 10%]
Melting point/freezing point : <-5°C (<23°F)
Boiling point : 100°C (212°F)
Flash point : Closed cup: >100°C (>212°F)
Evaporation rate : Not available.
Flammability : Not available.
Lower and upper explosion : Not available.
limit/flammability limit
Vapor pressure : 2.3 kPa (17.25 mm Hg) [room temperature]
Relative vapor density : Not available.
Density : 0.98 g/cm³ [20°C]
Solubility : Easily soluble in the following materials: cold water.
Solubility in water : Not available.
Partition coefficient: n- : Not applicable.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.

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PELLASTOL 94 S

Section 9. Physical and chemical properties and safety


characteristics
Viscosity : Dynamic (room temperature): 150 mPa·s (150 cP)
Flow time (ISO 2431) : Not available.

Section 10. Stability and reactivity


Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : No specific data.

Incompatible materials : No specific data.

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products
products should not be produced.

Section 11. Toxicological information


Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
2-(2-butoxyethoxy)ethanol LC50 Inhalation Dusts and mists Rat >29 ppm 2 hours
LD50 Dermal Rabbit - Male 2764 mg/kg -
LD50 Oral Rat - Male 7291 mg/kg -
Butanedioic acid, sulfo-, C- LD50 Oral Rat >2000 mg/kg -
C10-18-alkyl esters,
disodium salts, ethoxylated
2-butoxyethanol LC50 Inhalation Vapor Rat - Male, 10 to 20 mg/l 4 hours
Female
LD50 Dermal Rat - Male, >2000 mg/kg -
Female
LD50 Oral Rat - Male, 1746 mg/kg -
Female
Benzenesulfonic acid, LD50 Dermal Rat - Male, >2000 mg/kg -
C10-13-alkyl derivs., sodium Female
salts
LD50 Oral Rat - Male, 1080 mg/kg -
Female
Fatty acids, tall-oil, LD50 Dermal Rat - Male >2000 mg/kg -
C12-15-alkyl esters,
sulfated, sodium salts
LD50 Oral Rat - Male, >2000 mg/kg -
Female
Alcohols, C16-18, LD50 Oral Rat >2000 mg/kg -
ethoxylated
Irritation/Corrosion

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PELLASTOL 94 S

Section 11. Toxicological information


Product/ingredient name Result Species Score Exposure Observation
2-(2-butoxyethoxy)ethanol Skin - Edema Rabbit 0.56 - -
Skin - Erythema/Eschar Rabbit 1.78 - -
Eyes - Irritant Rabbit - - -
Butanedioic acid, sulfo-, C- Eyes - Irritant Mammal - - - -
C10-18-alkyl esters, species
disodium salts, ethoxylated unspecified
2-butoxyethanol Skin - Irritant Rabbit - - -
Eyes - Irritant Rabbit - - -
Benzenesulfonic acid, Skin - Irritant Rabbit - - -
C10-13-alkyl derivs., sodium
salts
Eyes - Severe irritant Rabbit - - -
Fatty acids, tall-oil, Skin - Primary dermal Human 0 - -
C12-15-alkyl esters, irritation index (PDII)
sulfated, sodium salts
Eyes - Cornea opacity Rabbit 0 - -
Alcohols, C16-18, Skin - Erythema/Eschar Rabbit <1.5 - -
ethoxylated
Eyes - Irritant Rabbit - - -
Sensitization
Product/ingredient name Route of Species Result
exposure
2-(2-butoxyethoxy)ethanol skin Guinea pig Not sensitizing
2-butoxyethanol skin Guinea pig Not sensitizing
Benzenesulfonic acid, skin Guinea pig Not sensitizing
C10-13-alkyl derivs., sodium
salts
Fatty acids, tall-oil, skin Mouse Not sensitizing
C12-15-alkyl esters,
sulfated, sodium salts
Mutagenicity
Product/ingredient name Test Experiment Result
2-(2-butoxyethoxy)ethanol OECD 471 Bacterial Experiment: In vitro Negative
Reverse Mutation Test Subject: Bacteria
OECD Experiment: In vitro Negative
Subject: Mammalian-Animal
OECD 476 In vitro Experiment: In vitro Negative
Mammalian Cell Gene Subject: Mammalian-Animal
Mutation Test
OECD 475 Mammalian Experiment: In vivo Negative
Bone Marrow Subject: Mammalian-Animal
Chromosomal
Aberration Test
2-butoxyethanol OECD 471 Bacterial Experiment: In vitro Negative
Reverse Mutation Test Subject: Bacteria
OECD 473 In vitro Experiment: In vitro Negative
Mammalian Subject: Mammalian-Animal
Chromosomal
Aberration Test
OECD 476 In vitro Experiment: In vitro Negative
Mammalian Cell Gene Subject: Mammalian-Animal
Mutation Test
OECD 474 Mammalian Experiment: In vitro Negative
Erythrocyte Subject: Mammalian-Animal
Micronucleus Test
Benzenesulfonic acid, OECD 473 In vitro Experiment: In vitro Positive
C10-13-alkyl derivs., sodium Mammalian Subject: Mammalian-Animal
salts Chromosomal
Aberration Test
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PELLASTOL 94 S

Section 11. Toxicological information


OECD 471 Bacterial Experiment: In vitro Negative
Reverse Mutation Test Subject: Bacteria
OECD 476 In vitro Experiment: In vitro Negative
Mammalian Cell Gene Subject: Mammalian-Animal
Mutation Test
OECD 474 Mammalian Experiment: In vivo Negative
Erythrocyte Subject: Mammalian-Animal
Micronucleus Test
Fatty acids, tall-oil, OECD 471 Bacterial Experiment: In vitro Negative
C12-15-alkyl esters, Reverse Mutation Test Subject: Bacteria
sulfated, sodium salts
OECD 473 In vitro Experiment: In vitro Negative
Mammalian Subject: Mammalian-Animal
Chromosomal
Aberration Test
OECD 476 In vitro Experiment: In vitro Negative
Mammalian Cell Gene Subject: Mammalian-Animal
Mutation Test
Carcinogenicity
Not available.
Reproductive toxicity
Product/ingredient name Maternal Fertility Development Species Dose Exposure
toxicity toxin
2-(2-butoxyethoxy)ethanol - Negative - Rat - Male, Female Oral: -
1000 mg/
kg
Benzenesulfonic acid, Negative Negative Negative Rat - Male, Female Oral: 350 2 years; 7
C10-13-alkyl derivs., sodium mg/kg days per
salts week
Fatty acids, tall-oil, Negative Negative Negative Rat - Male, Female Oral: 47 days; 7
C12-15-alkyl esters, sulfated, 1000 mg/ days per
sodium salts kg week
Teratogenicity
Product/ingredient name Result Species Dose Exposure
2-(2-butoxyethoxy)ethanol Negative - Dermal Rabbit 1000 mg/kg -
2-butoxyethanol Positive - Oral Rat 200 mg/kg -
Benzenesulfonic acid, Negative - Oral Rat 300 mg/kg 10 days; 7 days
C10-13-alkyl derivs., sodium per week
salts
Specific target organ toxicity (single exposure)
Not available.
Specific target organ toxicity (repeated exposure)
Not available.
Aspiration hazard
Not available.

Information on the likely : Not available.


routes of exposure
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : No known significant effects or critical hazards.
Skin contact : Causes mild skin irritation.
Ingestion : No known significant effects or critical hazards.

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PELLASTOL 94 S

Section 11. Toxicological information


Symptoms related to the physical, chemical and toxicological characteristics
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : No specific data.

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Product/ingredient name Result Species Dose Exposure
2-(2-butoxyethoxy)ethanol Sub-chronic NOAEL Oral Rat - Male, 250 mg/kg 90 days; 7 days
Female per week
Sub-chronic NOAEL Dermal Rat - Male, >2000 mg/kg 90 days; 6 hours
Female per day
Sub-chronic NOAEL Rat - Male, 14 ppm 90 days; 6 hours
Inhalation Vapor Female per day
2-butoxyethanol Sub-chronic NOAEL Oral Rat - Male, <69 mg/kg -
Female
Sub-chronic NOAEL Dermal Rabbit - Male, >150 mg/kg -
Female
Benzenesulfonic acid, Sub-chronic NOAEL Oral Rat - Male, 85 mg/kg 9 months; 7
C10-13-alkyl derivs., sodium Female days per week
salts
Fatty acids, tall-oil, Sub-acute NOEL Oral Rat - Male, 1000 mg/kg 8 weeks; 7 days
C12-15-alkyl esters, Female per week
sulfated, sodium salts
General : No known significant effects or critical hazards.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity


Acute toxicity estimates
Route ATE value
Oral 26629.4 mg/kg
Dermal 20266.6 mg/kg
Inhalation (vapors) 366.7 mg/l

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Section 11. Toxicological information

Section 12. Ecological information


Toxicity
Product/ingredient name Result Species Exposure
sodium oleate Acute EC50 71 mg/l Algae 72 hours
Acute EC50 24 mg/l Daphnia 48 hours
Acute LC50 >100 mg/l Fish 96 hours
2-(2-butoxyethoxy)ethanol Acute EC10 >1995 mg/l Fresh water Micro-organism 30 minutes
Acute EC50 >100 mg/l Fresh water Algae - Desmodesmus 96 hours
subspicatus
Acute EC50 >100 mg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 1300 mg/l Fresh water Fish - Lepomis macrochirus 96 hours
Butanedioic acid, sulfo-, C- EC50 1 to 10 mg/l Daphnia 48 hours
C10-18-alkyl esters,
disodium salts, ethoxylated
LC50 10 to 100 mg/l Fish 96 hours
2-butoxyethanol Acute EC10 >700 mg/l Fresh water Micro-organism - Pseudomonas 16 hours
putida
Acute EC50 1840 mg/l Fresh water Algae - Pseudokirchneriella 72 hours
subcapitata
Acute EC50 1800 mg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 1474 mg/l Fresh water Fish - Oncorhynchus mykiss 96 hours
Chronic NOEC 100 mg/l Fresh water Daphnia - Daphnia magna 21 days
Chronic NOEC >100 mg/l Fresh water Fish - Danio rerio 21 days
Benzenesulfonic acid, Acute EC10 13.1 mg/l Fresh water Algae - Pseudokirchneriella 96 hours
C10-13-alkyl derivs., sodium subcapitata
salts
Acute EC50 235 mg/l Fresh water Algae - Pseudokirchneriella 72 hours
subcapitata
Acute EC50 2.9 mg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 2.88 mg/l Fresh water Fish - Pimephales promelas 96 hours
Chronic NOEC 1.18 mg/l Fresh water Daphnia - Daphnia magna 21 days
Chronic NOEC 0.23 mg/l Fresh water Fish - Oncorhynchus mykiss 72 days
Fatty acids, tall-oil, Acute EC50 140 mg/l Fresh water Algae - Desmodesmus 72 hours
C12-15-alkyl esters, sulfated, subspicatus
sodium salts
Acute EC50 32 mg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 269 mg/l Fresh water Fish - Danio rerio 96 hours
Acute NOEL 10 mg/l Fresh water Algae - Desmodesmus 72 hours
subspicatus
Acute NOEL >4900 mg/l Micro-organism - Pseudomonas 30 minutes
putida
Alcohols, C16-18, Acute EC50 1 to 10 mg/l Algae 72 hours
ethoxylated
Acute EC50 1 to 10 mg/l Daphnia 48 hours
Acute LC50 1 to 10 mg/l Fish 96 hours

Persistence and degradability


Product/ingredient name Test Result Dose Inoculum
sodium oleate - >60 % - 28 days - -
2-(2-butoxyethoxy)ethanol OECD 301C 85 % - 28 days - -
Ready
Biodegradability -
Modified MITI
Test (I)
2-butoxyethanol OECD 301B 90 % - 28 days - -
Ready
Biodegradability -
CO₂ Evolution
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Section 12. Ecological information


Test
Benzenesulfonic acid, OECD 301B 83 % - 28 days - -
C10-13-alkyl derivs., sodium Ready
salts Biodegradability -
CO₂ Evolution
Test
Fatty acids, tall-oil, OECD 301D 49 % - 28 days - -
C12-15-alkyl esters, sulfated, Ready
sodium salts Biodegradability -
Closed Bottle
Test
PELLASTOL 94 S OECD 302B 99 % - 7 days - -
Inherent
Biodegradability:
Zahn-Wellens/
EMPA Test

Product/ingredient name Aquatic half-life Photolysis Biodegradability


sodium oleate - - Readily
2-(2-butoxyethoxy)ethanol - 50%; < 28 day(s) Readily
Butanedioic acid, sulfo-, C- - - Readily
C10-18-alkyl esters,
disodium salts, ethoxylated
2-butoxyethanol - 50%; 0.27 day(s) Readily
Benzenesulfonic acid, - - Readily
C10-13-alkyl derivs., sodium
salts
Fatty acids, tall-oil, - - Inherent
C12-15-alkyl esters, sulfated,
sodium salts
Alcohols, C16-18, - - Readily
ethoxylated

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
2-(2-butoxyethoxy)ethanol 1 - low
2-butoxyethanol 0.81 - low
Benzenesulfonic acid, 1.4 87 low
C10-13-alkyl derivs., sodium
salts
Fatty acids, tall-oil, 11.6 1.1 to 70.8 low
C12-15-alkyl esters, sulfated,
sodium salts

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations


Disposal methods : The generation of waste should be avoided or minimized wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor. Waste should not be
disposed of untreated to the sewer unless fully compliant with the requirements of
all authorities with jurisdiction. Waste packaging should be recycled. Incineration or
landfill should only be considered when recycling is not feasible. This material and
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Section 13. Disposal considerations


its container must be disposed of in a safe way. Care should be taken when
handling emptied containers that have not been cleaned or rinsed out. Empty
containers or liners may retain some product residues. Avoid dispersal of spilled
material and runoff and contact with soil, waterways, drains and sewers.

Section 14. Transport information


UN IMDG IATA
UN number Not regulated. Not regulated. Not regulated.

UN proper - - -
shipping name
Transport hazard - - -
class(es)

Packing group - - -
Environmental No. No. No.
hazards

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.

Transport in bulk according : Not available.


to Annex II of MARPOL and
the IBC Code

Section 15. Regulatory information


International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
Montreal Protocol (Annexes A, B, C, E)
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.

Section 16. Other information


History
Date of printing : 8/7/2019
Date of issue/Date of : 8/7/2019
revision
Date of previous issue : 7/4/2019
Version : 1.08

Date of issue/Date of revision : 8/7/2019 Date of previous issue : 7/4/2019 Version : 1.08 12/13
PELLASTOL 94 S

Section 16. Other information


Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Procedure used to derive the classification
Classification Justification
SKIN CORROSION/IRRITATION - Category 3 Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method
AQUATIC HAZARD (ACUTE) - Category 3 Calculation method
References : Not available.
Indicates information that has changed from previously issued version.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-
named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or
completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described herein,
we cannot guarantee that these are the only hazards that exist.

Date of issue/Date of revision : 8/7/2019 Date of previous issue : 7/4/2019 Version : 1.08 13/13

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