TOLLEN’S REAGENT MSDS

CAS No: MSDS

MATERIAL SAFETY DATA SHEET (MSDS)

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product form : Mixture
:
Product code : 6337D

1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Use of the substance/mixture : Laboratory chemicals

1.2.2. Uses advised against

No additional information available

1.3. Details of the supplier of the safety data sheet

LOBA CHEMIE PVT.LTD.
107 Wode House Road, Jehangir Villa, Colaba
400005 Mumbai - INDIA
T +91 22 6663 6663 - F +91 22 6663 6699
[email protected] - www.lobachemie.com

1.4. Emergency telephone number

Emergency number : + 91 22 6663 6663 (9:00am - 6:00 pm)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture/Substance: SDS EU 2015: According to Annex II
of Regulation (EC) No. 453/2010 (REACH Annex II)
Corrosive to metals, H290
Category 1
Acute toxicity (oral), H302
Category 4
Skin corrosion/irritation, H315
Category 2
Serious eye damage/eye H319
irritation, Category 2

Full text of classification categories and H statements : see section 16

Adverse physicochemical, human health and environmental effects

No additional information available

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2.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display
Hazard pictograms (CLP) :

GHS05 GHS07
Signal word (CLP) : Warning
Hazard statements (CLP) : H290 - May be corrosive to metals
H302 - Harmful if swallowed
H315 - Causes skin irritation
H319 - Causes serious eye irritation
Precautionary statements (CLP) : P264 - Wash ... thoroughly after handling
P302+P352 - IF ON SKIN: Wash with plenty of soap and water
P332+P313 - If skin irritation occurs: Get medical advice/attention
P337+P313 - If eye irritation persists: Get medical advice/attention

2.3. Other hazards

No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Not applicable

3.2. Mixture

Name Product identifier % Classification according

to Regulation (EC) No.
1272/2008 [CLP]
Water (CAS No) 7732-18-5 96.75 - Not classified
(EC no) 231-791-2 101.89
Sodium hydroxide (CAS No) 1310-73-2 0.9 - 1.65 Skin Corr. 1A, H314
(EC no) 215-185-5
silver nitrate (CAS No) 7761-88-8 0.1 - 0.12 Aquatic Acute 1, H400
(EC no) 231-853-9
(EC index no) 047-001-00-2

Full text of H-phrases: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Give oxygen or
artificial respiration if necessary. If you feel unwell, seek medical advice.

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First-aid measures after skin contact : Take off contaminated clothing. Gently wash with plenty of soap and water. If skin
irritation occurs: Get medical advice/attention.
First-aid measures after eye contact : Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously
with water for several minutes. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do not induce vomiting. If you feel unwell, seek medical advice.

4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries after skin contact : Causes skin irritation.
Symptoms/injuries after eye contact : Causes serious eye irritation.
Symptoms/injuries after ingestion : Harmful if swallowed.

4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : Water spray. Foam. Dry powder. Carbon dioxide.

5.2. Special hazards arising from the substance or mixture

No additional information available

5.3. Advice for firefighters

Protection during firefighting : Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.

6.1.2. For emergency responders

Protective equipment : Use personal protective equipment as required.
Emergency procedures : Stop release. Ventilate area.

6.2. Environmental precautions

Avoid release to the environment.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up : Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills
with inert solids, such as clay or diatomaceous earth as soon as possible.

6.4. Reference to other sections

No additional information available
SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling : Avoid contact with skin, eyes and clothing.
Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating,
drinking or smoking and when leaving work.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions : Store in original container. Keep cool. Protect from sunlight. Store in a dry place.
Store in a closed container.
Incompatible products : Oxidizing agent. Strong bases. Strong acids.

7.3. Specific end use(s)

No additional information available

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SECTION 8: Exposure controls/personal protection

8.1. Control parameters

No additional information available

8.2. Exposure controls

Hand protection : protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear appropriate mask

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Liquid

Colour : Clear colrless.

Odour : characteristic.

Odour threshold : No data available

pH : 14

Relative evaporation rate (butylacetate=1) : No data available

Melting point : No data available

Freezing point : -10 - -12 °C

Boiling point : 105 - 140 °C

Flash point : No data available

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Flammability (solid, gas) : No data available

Vapour pressure : No data available

Relative vapour density at 20 °C : No data available

Relative density : No data available

Solubility : No data available

Log Pow : No data available

Viscosity, kinematic : No data available

Viscosity, dynamic : No data available

Explosive properties : No data available

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Oxidising properties : No data available

Explosive limits : No data available

9.2. Other information

No additional information available
SECTION 10: Stability and reactivity

10.1. Reactivity
No additional information available

10.2. Chemical stability

Stable under normal conditions of use.

10.3. Possibility of hazardous reactions

No additional information available

10.4. Conditions to avoid

Finely divided metals.

10.5. Incompatible materials

No additional information available

10.6. Hazardous decomposition products

No additional information available

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Oral: Harmful if swallowed.

ATE CLP (oral) 500 mg/kg bodyweight

Skin corrosion/irritation : Causes skin irritation.

pH: 14
Serious eye damage/irritation : Causes serious eye irritation.
pH: 14
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified

Reproductive toxicity : Not classified

Specific target organ toxicity (single : Not classified
exposure)

Specific target organ toxicity (repeated : Not classified

exposure)

Aspiration hazard : Not classified

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SECTION 12: Ecological information

12.1. Toxicity
No additional information available

12.2. Persistence and degradability

No additional information available

12.3. Bioaccumulative potential

No additional information available

12.4. Mobility in soil

No additional information available

12.5. Results of PBT and vPvB assessment

No additional information available

12.6. Other adverse effects

No additional information available
SECTION 13: Disposal considerations

13.1. Waste treatment methods

No additional information available
SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN

14.1. UN number
UN-No. (ADR) : 1760
UN-No. (IMDG) : 1760
UN-No.(IATA) : 1760
UN-No.(ADN) : Not regulated
UN-No. (RID) : Not regulated

14.2. UN proper shipping name

Proper Shipping Name (ADR) : CORROSIVE LIQUID, N.O.S.
Proper Shipping Name (IMDG) : CORROSIVE LIQUID, N.O.S.
Proper Shipping Name (IATA) : CORROSIVE LIQUID, N.O.S.
Proper Shipping Name (ADN) : Not regulated
Proper Shipping Name (RID) : Not regulated
Transport document description (ADR) : UN 1760 CORROSIVE LIQUID, N.O.S., 8, II, (E)
Transport document description (IMDG) : UN 1760 CORROSIVE LIQUID, N.O.S., 8, II
Transport document description (IATA) : UN 1760 CORROSIVE LIQUID, N.O.S., 8, II

14.3. Transport hazard class(es)

ADR
Transport hazard class(es) (ADR) : 8

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Danger labels (ADR) : 8

IMDG
Transport hazard class(es) (IMDG) : 8
Danger labels (IMDG) : 8

IATA
Transport hazard class(es) (IATA) : 8
Hazard labels (IATA) : 8

ADN
Transport hazard class(es) (ADN) : Not regulated

RID
Transport hazard class(es) (RID) : Not regulated

14.4. Packing group

Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : Not regulated
Packing group (RID) : Not regulated

14.5. Environmental hazards

Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available

14.6. Special precautions for user

- Overland transport
Classification code (ADR) : C9
Special provision (ADR) : 274
Limited quantities (ADR) : 1L
Excepted quantities (ADR) : E2
Packing instructions (ADR) : P001, IBC02
Mixed packing provisions (ADR) : MP15

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Portable tank and bulk container : T11
instructions (ADR)
Portable tank and bulk container special : TP2, TP27
provisions (ADR)
Tank code (ADR) : L4BN
Vehicle for tank carriage : AT
Transport category (ADR) : 2
Hazard identification number (Kemler No.) : 80
Orange plates :

Tunnel restriction code (ADR) : E

EAC code : 2X
APP code : B

- Transport by sea
Special provision (IMDG) : 274
Limited quantities (IMDG) : 1L
Excepted quantities (IMDG) : E2
Packing instructions (IMDG) : P001
IBC packing instructions (IMDG) : IBC02
Tank instructions (IMDG) : T11
Tank special provisions (IMDG) : TP2, TP27
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-B
Stowage category (IMDG) : B
Stowage and handling (IMDG) : SW2

- Air transport
PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y840
PCA limited quantity max net quantity : 0.5L
(IATA)
PCA packing instructions (IATA) : 851
PCA max net quantity (IATA) : 1L
CAO packing instructions (IATA) : 855
CAO max net quantity (IATA) : 30L
Special provision (IATA) : A3
ERG code (IATA) : 8L

- Inland waterway transport

Not regulated

- Rail transport
Not regulated

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations

Contains no substances with Annex XVII restrictions

Contains no REACH candidate substance

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Contains no REACH Annex XIV substances.

15.1.2. National regulations

Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 3, strongly hazardous to water (Classification according
to AwSV, Annex 1)
12th Ordinance Implementing the Federal : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Immission Control Act - 12.BImSchV

Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product

15.2. Chemical safety assessment

No additional information available

SECTION 16: Other information

Full text of H- and EUH-phrases:

Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1
Eye Irrit. 2 Serious eye damage/eye irritation, Category 2
Met. Corr. 1 Corrosive to metals, Category 1
Skin Corr. 1A Skin corrosion/irritation, Category 1A
Skin Irrit. 2 Skin corrosion/irritation, Category 2
H290 May be corrosive to metals
H302 Harmful if swallowed
H314 Causes severe skin burns and eye damage
H315 Causes skin irritation
H319 Causes serious eye irritation
H400 Very toxic to aquatic life

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and
environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product

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