Energy Band Gap
Energy Band Gap
Theory: A semiconductor doped or undoped always possesses an energy gap between its
conduction and valence bands. For conduction of electricity a certain amount of energy is to
be given to the electron, so that it goes from the valence band to the conduction band. This
energy so needed is the measure of the energy gap Eg between the two bands.
P N
- +
When a p-n junction is reverse biased as shown in Figure 1, the current through the
junction is due to minority carriers i.e., due to electrons in P section and holes in N section.
The concentration of these carriers is dependent upon the energy gap Eg. The reverse
saturation current IS is a function of the junction diode temperature, and varies according to
the following relation
eEg
IS =
[ ( )]
I S( max ) exp −
2 kT
where
Thermome
PN junction
Procedure:
1. Plug the mains lead to the nearest mains socket carrying 230V ± 10% at 50 Hz A.C.
2. Insert the thermometer and the diode in the holes of the oven (The holes near the meter is
for diode OA-79 ).
3. Plug the two leads to the diode in the socket, red plug in red socket and black plug in
black socket.
4. No other connections are necessary as rest of the wiring is built in.
5. Now put the power ON/OFF Switch to ‘ON’ position and see that the jewel light is
glowing.
6. Put the ‘OVEN’ switch to ‘ON’ position and allow the oven temperature to increase up to
850C.
Note: As soon as the temperature reaches 85 0C switch off the oven enabling the
temperature to rise further and then become stable around 900C.
7. When the temperature becomes stable at around 900C, start taking readings of current and
temperature. The current reading should be noted for every 50C drop in temperature. The
readings should be taken till the thermometer reading drops to 400 C.
2
8. Tabulate your readings in the form shown in Table 1.
1. 90 = IS (maximum I)
2. 85
3. 80
4. 75
5. 70
6. 65
7. 60
8. 55
9. 50
10. 45
11. 40
9. Plot a graph between the readings of 103 /T on positive x–axis and ln (IS/IS(max)) on
negative y–axis.
10. After determining the slope of the line calculate the band gap as follows:-
y 2− y1
E g =−
Slope of the line
=−
( x 2−x 1 )
. = . .. . .. eV
5. 797 5 .797
Model Graph
0.5 x1 x2
1.0 y1
1.5
2.0 y2
2.5
ln(IS/IS(max))
3
Precautions :
2) Bulb of the thermometer and the diode should be inserted well in the oven.
3) Silicon diodes should not be used with the set up as in that case the temperature
needed is 1250 C, and the oven thermometer provided will not stand to this
temperature.
Result
The band gap of the semiconductor is _____________________.