ABC-4 & Structure Identification

ONLY ONE OPTION CORRECT TYPE

dsoy ,d lgh fodYi çdkj (ONLY ONE OPTION CORRECT TYPE)
PART-A (CARBOXYLIC ACID) ¼dkckZsfDlfyd vEy½
1. MgBr 1. CO2,Et2O Product is –
2. H3O

MgBr 1. CO2,Et2O mRikn gS %

2. H3O

COOH
COOH
(A) (B) (C*) COOH (D)
COOH

1. CO2, Et2O COOH

2. A A is gS&
2. H3O

MgBr
(A) (B*) MgBr (C) (D)
MgBr MgBr

K2Cr2O7/H+
3. Ph–CH2–OH Product is - mRikn gS&
O
(A) Ph–CH2–COOH (B) Ph–CH–CH3 (C*) Ph–COOH (D) Ph–CH2–O–C–CH3
COOH

CH2–OH

K2Cr2O7/H+
4. Find product is – vafre mRikn gS&

COOH COOH
(A) COOH (B) (C) (D*)
COOH

OH

+
CrO3/H
5. Product is - mRikn gS&

CH3
OH
COOH
COOH

(A*) (B) (C) (D)

CH3 CH3 COOH COOH

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ABC–4 & SI - 1
 ABC-4 & Structure Identification

O
+
H2O/H
6. C2H5–C–OCH3 Product is - mRikn gS&

(A) CH3COOH, C2H5OH (B) CH3COOH,C2H5–COOH

(C*) C2H5–COOH, CH3OH (D) CH3OH, C2H5–OH

O
H2O/H+
7. CH3–C–NH–Ph A+B

A rFkk B gS&
A & B are -
O O
(A) Ph–NH–C–H + CH3 –COOH (B) CH3–C–NH2 + Ph–OH
O O
+
(C) CH3–C–NH2 + Ph–COOH (D*) CH3–C–OH + Ph–NH3

O O
H2O/H+
8. C2H5–C–O–C–Ph A+B
Ratio of A and B is –
A rFkk B dk vuqikr gS&
(A) 1 : 2 (B) 2 : 1 (C*) 1 : 1 (D) 2 : 3

9. CN H2O/H Product is - mRikn gS&

COOH

(A) (B)
COOH
COOH

(C*) COOH (D)

Chemical reaction of Carboxylic acid

dkcksZfDlfyd vEy dh jklk;fud vfHkfØ;k,sa%
Red P Br2
10. CH3CH2CH2COOH   CH –CH –CH–COOH
3 2

Br
This reaction is called -
(A) cannizzaro reaction (B) Aldol reaction
(C*) HVZ reaction (D) Reimer Tiemann reaction
Red P Br2
CH3CH2CH2COOH   CH –CH –CH–COOH
3 2

Br
;g vfHkfØ;k dgykrh gS&
(A) dSfutkjks vfHkfØ;k (B) ,YMkWy vfHkfØ;k
(C*) HVZ vfHkfØ;k (D) jkbej fVeku vfHkfØ;k

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ABC–4 & SI - 2
 ABC-4 & Structure Identification

COOH SOCl2
11. Product is - mRikn gS&

O
O
C
(A) (B*) C (C) COOH
H (D)
Cl Cl
Cl Cl

COOH 
12. + NH3 Product is- mRikn gS&
O O
(A) (B*)
C–O–NH2 C–NH2

COOH
NH2
(C) (D)
COOH
NH2

(i) Ag2O
13. Ph–CH–CH–COOH (ii) Br2, 
Product is- mRikn gS&
CH3 CH3
Br
(A) Ph–CH–CH–CH2–Br (B) Ph–CCH–CH3
CH3 CH3 CH3 CH3
(C*) Ph–CH–CH–Br (D) Ph–CH–CH2
CH3 CH3 CH3 CH2–Br

COOH (i) Ag2O

14. Product is- mRikn gS&
(ii) Br2, 
Br
Br
COOH
(A) (B) COOH

Br
(C*) (D) C–Br
O

COOH NaOH + CaO

15.  Product is- mRikn gS&
COOH

(A) (B*) (C) (D)

Lab test of carboxylic acid:

dkcksZfDlfyd vEy dk izk;ksfxd ijh{k.k

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ABC–4 & SI - 3
 ABC-4 & Structure Identification

16. CH3–CH–CH2–SO3H + NaHCO3 Product is - mRikn gS&

CH3
(A) CH3–CH–SO3Na (B*) CH3–CH–CH2–SO3Na + CO2
CH3 CH3
SO3Na

(C) CH3–CH–SO3Na (D) CH3–C–CH3

CH2–CH3 CH3

PART-B (CARBONYL COMPOUND) ¼dkcksZfuy ;kSfxd½

17. Product of given reaction is
CH3 –CH2–C–Cl  
H2 / Pd (BaSO 4 )

O
(A) CH3–CH2 –CH2–OH (B*) CH3 –CH2–C–H
O

(C) (D) None of these

nh x;h vfHkfØ;k dk mRikn gS &

CH3 –CH2–C–Cl  
H2 / Pd (BaSO 4 )

O
(A) CH3–CH2 –CH2–OH (B*) CH3 –CH2–C–H
O

(C) (D) buesa ls dksbZ ugha

18. Predict the reactant

Reactant   Ph–CH=O
H2 / Pd (BaSO 4 )

fØ;kdkjd dks igpkfu,

fØ;kdkjd   Ph–CH=O
H2 / Pd (BaSO 4 )

(A) Ph–CH2OH (B*) Ph–COCl (C) Ph–COOCH3 (D) Ph–COCH3

19. X   Y
H2
Pd (BaSO 4 )

X is :

X    Y
H2
Pd (BaSO 4 )
VkWysu
vfHkdeZd
X gS :
(A) (B)

(C*) (D)

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ABC–4 & SI - 4
 ABC-4 & Structure Identification

CH3–CH–CH2–OH  X
PCC
20.
CH3
O
(A) CH3–CH–COOH (B) CH3–C
CH3 CH2–CH3
(C*) CH3–CH–CHO (D) CH3–C=O
CH3 CH3

21. Which of the following is product of given reaction

HO OH
PCC
(Pyridinium
Chlorochromate)

CH2OH
nh x;h vfHkfØ;k dk mRikn gS &
HO OH

PCC
¼fijhMhuh;e Dyksjks ØksesV½

CH2OH

O O O O
(A*) (B)

CHO COOH
O O
HO
(C) OH (D) None of these buesa ls dksbZ ugha

COOH

22.

X is :

VkWysu
vfHkdeZd
X gS :

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ABC–4 & SI - 5
 ABC-4 & Structure Identification

(A) (B) (C*) (D)

23. CH3–CN    X + NH4Cl

(i ) SnCl 2 / HCl
(ii) H2O

Identify ‘X’ : ‘X’ igpkfu,

(A*) CH3–CH=O (B) CH3–CH2–CH=O (C) CH3CH2OH (D) CH3CH(OH)CH3

O
C–H
24. R    
(i ) SnCl 2 / HCl
(ii) H2O

Identify ‘R’ : ‘R’ igpkfu,

CN CH2–OH NH2 CH3

(A*) (B) (C) (D)

O
Ph–C–O
Ca   Product
Dry distillati on
25.
Ph–C–O
O
O
Ph–C–O ' kq" d vklou
Ca 
 mRikn
Ph–C–O
O
O O O OH
(A) Ph–C–H (B*) Ph–C–Ph (C) Ph–C–C–Ph (D) Ph–C–C–Ph
O O H

O
Ph–C–O
Ca   Product
Dry distillati on
26.
H–C–O
O
O
Ph–C–O ' kq" d vklou
Ca 
 mRikn
H–C–O
O
O O
(A*) Ph–C–H (B) Ph–C–Ph (C) H–C–H (D) Ph–C–C–H
O O O

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ABC–4 & SI - 6
 ABC-4 & Structure Identification


27. Ca-Salt of Carboxylic acid 

X and Y
(A*) (H–COO)2Ca + (CH3–COO)2 Ca (B) (HCOO)2Ca + (CH3–CH2–COO)2Ca
(C) (CH3COO)2Ca + (CH3CH2–COO)2Ca (D) None of these


dkcksZfDlfyd vEy ds dSfY'k;e yo.k 

X rFkk Y gS &
(A*) (H–COO)2Ca + (CH3–COO)2 Ca (B) (HCOO)2Ca + (CH3–CH2–COO)2Ca
(C) (CH3COO)2Ca + (CH3CH2–COO)2Ca (D) buesa ls dksbZ ugha

Chemical properties
jklk;fud xq.k
28. Benzaldehyde, when heated with conc. KOH solution, gives
(A) C6H5CH2OH only (B) C6H5COOH only
(C) C6H5COOK only (D*) a mixture of C6H5COOK and C6H5CH2OH
cSUtfYMgkbM dks lkUnz KOH foy;u ds lkFk xeZ djus ij curk gS &
(A) dsoy C6H5CH2OH (B) dsoy C6H5COOH
(C) dsoy C6H5COOK (D*) C6H5COOK rFkk C6H5CH2OH dk feJ.k
29. The Cannizzaro’s reaction is not given by :
dSuhtkjks vfHkfØ;k ugh nsrk gS &
(A) C6H5CHO (B) HCHO (C*) CH3CHO (D) (CH3)3C–CHO

(CH3)3CCHO + HCHO   A + B

NaOH
30. In the reaction,
heat
the products (A) and (B) are respectively :
(A*) (CH3)3CCH2OH and HCOO– Na+. (B) (CH3)3CCOONa and CH3OH.
(C) (CH3)3CCH2OH and CH3OH. (D) (CH3)3COONa and HCOO– Na+.
(CH3)3CCHO + HCHO  NaOH
 A+B
xeZ
vfHkfØ;k esa mRikn (A) rFkk (B) Øe'k% gS &
(A*) (CH3)3CCH2OH ,oa HCOO– Na+. (B) (CH3)3CCOONa ,oa CH3OH.
(C) (CH3)3CCH2OH ,oa CH3OH. (D) (CH3)3COONa ,oa HCOO– Na+

31. ( X)   
SnCl 2
HCl
 C6H5COO  C6H5CH2 – OH
HO

(A) (B) (C) (D*) C6H5–CN

32. Which of the products is formed when acetone is reacted with dil. NaOH solution after heating?
tc ,lhVksu dks ruq NaOH foy;u ds lkFk xeZ fd;k tkrk gS rks cuus okyk mRikn gksxk \
O CH3 O
||
(A*) CH3–C–CH=C–CH3 (B) CH3 – C – CH – CH – CH3
| |
CH3 OH
O OH OH
| |
(C) CH3–C–CH2–C=CH2 (D) CH3 – C — C – CH3
| |
CH3 CH3 CH3
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ABC–4 & SI - 7
 ABC-4 & Structure Identification

33. Product is : mRikn gSA

(A) (B*) (C) (D)

34. Reactant    CH3–CH=CH–C–H

(i ) dil. NaOH
(ii) 
O
Reactant is :
fØ;kdkjd    CH3–CH=CH–C–H
(i ) dil. NaOH
(ii) 
O
fØ;kdkjd gSA

O O O O
(A) CH3–CH3 (B) H–C–C–H (C) CH3–C–CH3 (D*) CH3–C–H


35.

(A) H–CN (B*) CH3–CN (C) CH3–CH2–CN (D) CH3–COCl

36. The structure of the compound when acetaldehyde reacts with NH2–OH is
,lhVSfYMgkbM dh NH2–OH ds lkFk vfHkfØ;k djkus ij izkIr mRikn gksxk &
(A) CH3CH = NCONHNH2 (B) CH3CH = NNHCONH2
(C*) CH3CH = NOH (D) CH3CH = NNH2


CH3 OH
37. (X) + (Y)  H
C=N
–H2O

idenitfy (X) and (Y)

(X) rFkk (Y) igpkfu, &
CH3 CH3
(A) X  C=O ; y = NH2CONHNH2 (B) X  C=O ; y = NH2–NH2
H H
CH CH
(C*) X  3 C=O ; y = NH2–OH (D) X  3 C=O ; y = NH2–NH–Ph
H H

38. BaSO4
H2
Identify (X) and (Y).
(X) rFkk (Y) igpkfu, &

(A*) (B)

(C) (D)

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ABC–4 & SI - 8
 ABC-4 & Structure Identification

39. Benzaldehyde and acetone can be distinguished by

(A) Mulliken Baker test (B) Fehling solution
(C*) Iodoform test (D) Ninhydrin test
csUtsfYMgkbM rFkk ,flVksu dks foHksfnr dj ldrs gSA
(A) eqfydu csdj ijh{k.k }kjk (B) Qsgfyax foy;u
(C*) vk;ksMksQkeZ ijh{k.k }kjk (D) uhugkbfMªu ijh{k.k }kjk
40. Acetaldehyde and benzaldehyde can be distinguished by
(A) Tollen's test (B*) Fehling solution
(C) FeCl3 test (D) NaHCO3 test
,flVsfYMgkbM rFkk csUtsfYMgkbM dks foHksfnr dj ldrs gSA
(A) VkWysu ijh{k.k }kjk (B*) Qsgfyax foy;u
(C) FeCl3 ijh{k.k }kjk (D) NaHCO3 ijh{k.k }kjk

41. Propanal and propanone can not be distinguished by

(A) Iodoform test (B) Fehling solution
(C) Tollen's test (D*) 2,4- DNP test
izksisusy rFkk izksisukWu dks foHksfnr ugha dj ldrs gSA
(A) vk;ksMksQkeZ ijh{k.k }kjk (B) Qsgfyax foy;u
(C) VkWysu ijh{k.k }kjk (D) 2,4- DNP ijh{k.k }kjk

42. Which of the following compound will not react with I2/OH–.
fuEu esa ls dkSulk ;kSfxd I2/OH– ds lkFk vfHkfØ;k ugh djrk gSaA

(A) (B) (C*) (D) CH3 – CHO

Sol. group gives positive iodoform test.

gy % lewg /kukRed vkW;ksMksQkWeZ ijh{k.k nsrk gSA

43. 2-Pentanone can be distinguished from 3- Pentanone by which reagent ?

(A) 2, 4- Dinitrophenyl hydrazine (B) Tollen's reagent
(C*) I2 and dilute NaOH (D) Fehling solution
2-isUVsukWu vkSj 3- isUVsukWu dks fuEu esa ls fdl vfHkdeZd }kjk foHksfnr fd;k tk ldrk gSA
(A) 2, 4-MkbukbVªks QSfuy gkbMªsthu (B) VkWysu vfHkdeZd
(C*) I2 vkSj ruq NaOH (D) Qsgfyax foy;u
Sol. Iodoform test. (vk;ksMksQkeZ ijh{k.k)

44. Tollen’s reagent (AgNO3 + NH4OH) can be used to distinguish between.

(A) and (B) and

(C*) and (D) and

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ABC–4 & SI - 9
 ABC-4 & Structure Identification

VkW y s u vfHkdeZ d (AgNO3 + NH4OH) ls fuEu es a foHks n dj ldrs gS A

(A) rFkk (B) rFkk

(C*) rFkk (D) rFkk

Sol. Aldehydes gives black or silver mirror ppt. with tollen's reagent.
gy % ,fYMgkbM VkWysu vfHkdeZd ds lkFk dkyk ;k jtr niZ.k vo{ksi nsrk gSA

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ABC–4 & SI - 10