Module 1 5 PHYSCI PDF
Module 1 5 PHYSCI PDF
Chemical
BONDING
Topic: The VSEPR Model
Objective: To use the VSEPR Model in predicting the electron and molecular geometry of certain
molecules.
Valence-shell electron-pair repulsion (VSEPR) model accounts for the geometric arrangements of
shared and unshared electron pairs around a central atom in terms of the repulsions between electron pairs.
For a molecule to be stable, each atom connected to the central atom must attain the maximum angle of
separation from its neighboring atoms.
To determine the shape and geometry of a molecule, you will have to:
1. Draw the Lewis structure of the molecule or ion. (Note: Wrong Lewis Structure of an atom will give you
incorrect information in determining the geometry of the molecule)
2. Determine the electron-domain geometry by counting the number of electron domain or the total number of
bond pairs and lone/non-bonding pairs in a molecule.
➢
Each lone/non-bonding pair and single/multiple bond CONNECTED TO THE CENTRAL ATOM
counts as one electron domain
3. Determine the molecular geometry by counting the number of bond pairs and lone/non-bonding pairs in an
atom.
➢
Electron Domain = Number of bond pairs + number of lone/non-bonding pairs
Refer to the handout about the corresponding VSEPR model per every number of bond pairs, lone pairs, and
electron domain for each molecule.
Example 1 H2O
The water molecule consists of two bonding pairs (blue circle) and two lone/non-bonding pairs
(red circle), having an electron domain of 4. Thus, its electron domain geometry is tetrahedral, and its
molecular geometry is bent.
A CO2 molecule consists of 2 bonding pairs (blue color) and 0 lone/non- bonding pairs, having an electron
domain of 2. Thus, its electron domain geometry and molecular geometry is linear.
Example 3 SF4
omplete the table below by filling up the missing information. Refer to the handout of VSEPR model for the
orresponding geometry.
Molecule Lewis # of # of Electron Electron Molecular
Structure Bonding lone/non- Domain geometry Geometry
Pair bonding (bonding
pair + lone)
CS2
PCl3
BrF5
CCl4
XeF4
CH4
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-= PHYSCI MODULE 2 =-
Chemical
BONDING
Topic: Intermolecular Forces of Attraction
Objectives:
1. Differentiate intermolecular and intramolecular forces of attraction; and
2. Discuss the intermolecular forces of attraction and its effect on the physical properties of matter.
Intermolecular forces are much weaker than the intramolecular forces of attraction but are important because the
determine the physical properties of molecules like their boiling point, melting point, density, and enthalpies of fusion an
vaporization. Intramolecular forces are the forces that hold atoms together within a molecule. Intermolecular forces a
forces that exist between molecules.
Nonpolar
1. Elements with same kind of atom in a molecule; diatomic (e.g. H2, N2, Cl2)
2. Noble gases
3. Elements containing only carbon and hydrogen (e.g. CH4, C6H6)
4. If a molecule has symmetry (e.g. CF4, SBr6, CO2, BH3, PCl5)
5. Different elements but belongs to the same group (e.g. IBr, BrCl)
Polar
1. If H is directly connected to N, O, and F (H2O, NH3, HF, CH3OH)
2. Shape of molecule can affect polarity (e.g. SO2 is bent)
1. Dipole-dipole interactions:
✓ These forces occur when the partially positively charged (+) part of
molecule interacts with the partially negatively charged (- ) part of th
neighboring molecule.
✓ Among polar molecules
Example: HCl molecules
2. Hydrogen bonding:
✓ a special type of intermolecular attraction between the hydrogen
atom in a polar bond (particularly H-F, H-O, and H-N) and lone
pair on a nearby atom usually F, O, or N
✓ Strongest intermolecular force between polar molecules
Example: H2O
References:
Chang, R. & Goldsby, K. (2016). Chemistry. New York, NY: McGraw Hill, Inc.
Unday, J.E., Makalintal, N., and Dinglasan, M.G. (2017). Physical Science for Senior High School. Malabon City: Mutya
Publishing House
Additional Learning Reference: https://www.youtube.com/watch?v=08kGgrqaZXA&t=78s
-= PHYSCI MODULE 3 =-
CHEMICAL
REACTIONS
Topic: Chemical Reactions and Equations
Objectives:
• Explain what a chemical reaction is;
• Discuss and examine a chemical equation; and
• Describe the different types of chemical reaction and examine the factors affecting reaction rate
A chemical reaction is a process through which one or more substances are changed into different
substances. The original substances are called reactants, and the resulting substances are referred to as
products.
Chemical reactions are represented by chemical equations. Consisting of symbols and formulas,
chemical equations show what happens during chemical reactions. (See Table 1 for symbols in chemical
equations).
Reactant Product
Compounds at the left- hand side (blue color) are the reactants needed for the reaction to take place.
Those at the right- hand side (red color) are the products formed in the reaction.
coefficient 2 H2 subscript
You may notice that there are two types of numbers in our example- the big number (green color)
written before the chemical formula and the small (dark-red color) one written after some elements in the
formula.
Big numbers are called coefficients , which gives the idea of the number of molecules or formula units.
The small numbers are termed as subscripts, which tell how many atoms are present in specific compound.
(Note: the absence of coefficients or subscripts means the number is equal to “1”).
Word Equations
Chemical reactions may also be written through word equations. A word equation presents reactants
and products of a chemical reaction using words. It only identifies the reactants and products involved, but not
their quantities.
A word equation can be converted into chemical equation by replacing the names of the reactants
and products with their corresponding symbols or formulas. (Note: physical state of matter (e.g solid, liquid,
gas, aqueous) are indicated using italicized letters in parenthesis after each chemical element [(s), (l), (g), (aq) ]
Example 1.
Solid sodium (Na) is combined with water (H2O) to form aqueous sodium hydroxide (NaOH) and
hydrogen gas (H2).
Solution:
First, identify your reactants (left side) and products (right side) with their physical state.
In our example, the reactants and products are as follows:
To know the symbols for the physical state of the reactant and/or product, you can check
Table 1.
Answer:
Solution:
First, identify your reactants (left side) and products (right side) with their physical state.
Reactants:
aqueous calcium hydroxide [ Ca(OH)2]
carbon dioxide (CO2) gas
Products:
calcium carbonate (CaCO3) solid precipitate
liquid water (H2O)
Answer:
Ca(OH)2(aq) + CO2(g) CaCO3(s)+ H2O(l)
1. Combination Reaction
In a combination reaction or synthesis reaction, 2 or more substances combine to form new
compound. It takes the general representation as follows:
General: A + B AB
Example: 2Na(s) + Cl2(g) 2NaCl(s)
A B A B
2. Decomposition Reaction
Involves breaking down of a single compound to produce 2 or more simpler substances. It is the
opposite of combination reaction and represented by this general representation:
General: AB A+B
Example: 2H2O(l) 2H2(g) + O2(g)
AB A B
General: AX + BY AY+ BX
Example: AgNO3(aq) + NaCl(aq) AgCl(s) + NaNO3(aq)
AX BY AY B X
Reference:
Chang, R. & Goldsby, K. (2016). Chemistry. New York, NY: McGraw Hill, Inc.
Written Work
A. Convert each word equations into chemical equations. Do not forget to write the symbols for the physical
states of the reactants and products.
1. Solid potassium (K) metal combine with chlorine (Cl 2) gas to form potassium chloride (KCl) solid
powder.
Chemical equation:__________________________________________________________________
2. Aqueous potassium hydroxide (KOH) is combined with aqueous sulfuric acid (H2SO4) to form
liquid water (H2O) and aqueous potassium sulfate (K2SO4).
Chemical equation:__________________________________________________________________
3. Sulfur (S) burns in oxygen gas (O2) to form gaseous sulfur dioxide (SO2).
Chemical equation:__________________________________________________________________
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-= PHYSCI MODULE 4 =-
CHEMICAL
REACTIONS
Topic: Balancing Chemical Equations
Objectives:
• Discuss and examine a chemical equation; and
• Describe the different types of chemical reaction and examine the factors affecting reaction rate;
To complete the process of writing a correct chemical equation, the Law of Conservation of Mass
must be considered. This law states that, in a chemical reaction, the total amount of products must be equal
to the amount of the reactants. The process of adjusting the relative amounts of both reactants and products
in a chemical reaction so that numbers of each type of atom are the same at both sides of the equation is
called balancing an equation.
Example 1
Ammonia, a colorless, pungent gas, is widely used in pharmaceutical and agricultural industries. It is
also used as an ingredient in commercial cleaning products. Ammonia (NH3) gas is industrially produced
from hydrogen (H2) gas and nitrogen (N2) gas through the Haber process.
Solution:
a. Considering the gaseous states of all reactants and products, the reaction is represented by:
Notice that the number of H and N atoms (counting the subscripts) are not equal for both the
reactant and product. This means that the chemical equation is UNBALANCED.
To balance the equation, we should add certain coefficients so that the number of atoms will be
equal.
First let us take nitrogen, adding a coefficient 2 (big number in blue color) for NH3 will make the number of
N atoms at both sides of the equation to be equal. Note: Coefficients can be placed only at the front of a
chemical formula and NEVER in the middle of a formula. You cannot change, add, erase the subscript of the
element.
Now, as you can see at the table above, H atoms at the reactant side lacks 4 H atoms to match those
at the product side. Since there are 6 H atoms at the product side divide it by the 2 H atoms at the reactant
side to get the coefficient needed for the H atoms.
Since the number of each atom is equal on the reactant and the product side, the equation now is
balanced.
Example 2
Balance this chemical reaction:
CH4 + O2 → CO2 + H2O
Solution:
a. Based from this unbalanced equation, count the number of atoms (subscripts in red color) for
each element at the reactant and product side.
Reactant Side Product Side
C atoms 1 1
H atoms 4 2
O atoms 2 2 + 1 =3
As you can see, O appears to the two chemical formulas on the product side. To count the total
number of the O atoms, you just need to add the subscripts of O for each chemical formula on the product
side together.
b. To balance the equation, we need to add certain coefficients (big numbers in blue color) at the
front of a chemical formula. Looking at the number of atoms, it looks like the H and O atoms are
unequal. So, let us look at the H atom first.
For the H atoms to be equal, we need to add 2 more H atoms at the product side. With this, we can get a
coefficient (blue color) of 2 to be add at the front of H2O.
c. Now, as you can see at the table above, O atoms at the reactant side lacks 2 O atoms to match those at the
product side. Since there are 4 O atoms at the product side divide it by the 2 O atoms at the reactant side to
get the coefficient (blue color) needed for the O atoms.
Rate of Reaction
- Chemical reaction is governed by the Collision Theory, which states that reactant particles require
enough kinetic energy to initiate successful collisions that will lead to formation of products.
- The speed by which reactants are converted to products is referred to as the rate of reaction.
- A reaction that takes too long to complete is described to have a low reaction rate.
-
Factors affecting the Reaction Rate
1. Temperature
Reaction rate increases as temperature also increases because at a higher temperature,
particles have more energy. Thus, they move faster and are more likely to collide with other particles
2. Pressure
As the pressure increases, the space in which the gas particles are moving becomes smaller.
3. Catalyst
Catalyst is a substance that increases the rate of a chemical reaction without being used up by
lowering the activation energy.
4. Surface Area
If the solid is split into several pieces, the surface area increases. This means that there is an
increased area for the reactant particles to collide with.
5. Concentration
If there are more particles in the same amount of space, the particles are more likely to collide.
Reference:
Chang, R. & Goldsby, K. (2016). Chemistry. New York, NY: McGraw Hill, Inc.
Exercise
Balance the following equations by adjusting the coefficients.
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your work
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-= PHYSCI MODULE 5 =-
CHEMICAL
REACTIONS
Topic: Reaction Rates and Stoichiometric Calculations
Objectives:
• Calculate the amount of substances used or produced in a chemical reaction and percent yield of reaction;
and
• Calculate the amount of product formed considering its limiting reactant.
Stoichiometry refers to the quantitative relationships between the substances that are used up and
produces in chemical reactions.
Avogadro’s Number
- Avogadro’s number is a constant used to quantify the number of particles of an element or compound.
- 6.02214076 x 1023 particles
Mole Concept
Molar Mass
- Numerically equal to the:
o Atomic mass of the element
o Molecular mass of the compound
- Expressed in grams/mole (g/mol)
- Molar mass is obtained as the sum of the product of the atomic masses and the number of atoms of
every element that comprise the compound.
For example, the molar mass of Fe2O3 is calculated as follows:
2 atoms Fe x 55.85 g/mol Fe = 111.7 g/mol Fe
3 atoms O x 16.00 g/mol O = 48.00 g/mol O
Molar mass of Fe2O3 = 159.7 g/mol Fe2O3
The molar mass of the compound Fe2O3 is obtained by sum of the product of the number of atoms
(subscript in blue color) of an element and the atomic masses (red color) of the element. Note: You can get
the atomic mass of an element at the periodic table .
How to solve stoichiometry problems?
Use this chart:
Mass of Mole of Mole of Mass of
Use molar mass Use molar mass
reactant reactant Use molar ratio product of product product
of reactant
Example
Solution:
a. Conversion from grams to moles of a substance
Use the molar mass of the Fe2O3 to convert the expression from grams to moles of the sample using
dimensional analysis. A slash (/) symbol is included to emphasize the cancellation of the units.
To review, the molar mass of Fe2O3 is calculated as follows:
2 atoms Fe x 55.85 g/mol Fe = 111.7 g/mol Fe
3 atoms O x 16.00 g/mol O = 48.00 g/mol O
Molar mass of Fe2O3 = 159.7 g/mol Fe2O3
The molar mass of the compound Fe2O3 is obtained by sum of the product of the number of atoms
(subscript in blue color) of an element and the atomic masses (red color) of the element. Note: You can get
the atomic mass of an element at the periodic table .
We are given a 5.00 g Fe2O3 and we obtained a 159.7 g/mol as the molar mass of Fe2O3. Hence,
1 𝑚𝑜𝑙 𝐹𝑒2 𝑂3
5.00 𝑔 𝐹𝑒2 𝑂3 × = 𝟎. 𝟎𝟑𝟏𝟑 𝐦𝐨𝐥 𝑭𝒆𝟐 𝑶𝟑
159. 7 𝑔 𝐹𝑒2 𝑂3
As you can see, we have cancelled the unit 𝑔 𝐹𝑒2 𝑂3 and have performed the needed operation.
- The substance that is completely used up first in a reaction is called the limiting reactant.
- The substance that is not used up completely in a reaction is the excess reactant.
Sample Analogy:
Suppose you were asked by your mother to prepare as many burgers as possible for you and your
siblings. What you found in the refrigerator are 3 patties, 4 burger buns, 6 sliced cheese, and 7 sliced
tomatoes. How many burgers with complete component (patties, cheese, 2 tomatoes, buns) will you be able
prepare?
The answer is 3 because after making 3 burgers you will be out of patties. The buns, 1 tomato, and 3 sliced
cheese are said to be “excess”. Hence, they are called “excess reactants” and the patties are the “limiting
reactant”.
Reference:
Chang, R. & Goldsby, K. (2016). Chemistry. New York, NY: McGraw Hill, Inc.
Additional Learning Videos:
Stoichiometry https://www.youtube.com/watch?v=b2raanVWU6c
Exercise:
Write your solution and answer on a clean sheet of paper.
c. Moles of carbon
d. Ions of carbon
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