No t (menit) T(

℃ ) Flowrate (L/h)

F D B F D B
1 0 35.6 34.2 47.6 75 50 25
2 10 36.3 31 50.1 75 50 25
3 20 38.2 37.6 58.3 75 50 25
4 30 30.5 40.7 60.8 75 50 25
5 50 35.5 45.2 63.1 75 50 25
6 65 38.6 38.4 74.7 75 50 25
7 80 36.6 34.2 62.8 75 50 25
8 95 36.4 44 70 65 50 25
9 110 38.6 46 84.8 65 50 25
10 125 40 35.7 76 65 50 25
11 140 35.7 40.4 70 65 50 25
rata-rata flowrate 75 35.9 37.32857 59.62857 75 50 25
rata-rata flowrate 65 37.675 41.525 75.2 65 50 25

Diketahui : Densitas etanol 0.7807 kg/L Plate actual 12

Densitas air 0.9957 kg/L feed plate 4
BM etanol 46 g/mol waktu sampling 10
BM air 18 g/mol laju alir steam 100

Data Kesetimbangan Etanol-Air (Fraksi Massa)

T (°C) XA YA
100 0 0 Kurva Boiling Po
98.1 0.02 0.192 105
95.2 0.05 0.377
91.8 0.1 0.527 100
f(x) = 103.04301 x⁴ − 255.41767 x³ + 230.90
87.3 0.2 0.656 95 R² = 0.999797776521521
84.7 0.3 0.713
T (°C)

83.2 0.4 0.746 90

82 0.5 0.771
85
81 0.6 0.794
80.1 0.7 0.822 80
79.1 0.8 0.858
75
78.3 0.9 0.912 0 0.2 0.4 0.6 0.8 1 1.2
78.2 0.94 0.942 XA,YA
78.1 0.96 0.959
78.2 0.98 0.978
78.3 1 1

XF = 0.131
TB,F = 90.18 °C
363.33 K
TF = suhu fluida yang keluar dari preheater
TF 85 °C 358.15 K
T average = (Tb,f + Tf) / 2
T avg 87.59 °C 360.74 K

1. Mencari Cp pada Tavg = 87,59 °C di buku Geankoplis ed 5 hal 1673 (figure A.3-5)
Cp etanol 87,59 °C 0.81 cal/g°C 3.38904 kJ/kg K
Cp air 87,59 °C 0.9 cal/g°C 3.7656 kJ/kg K
Cp campuran = (fraksi massa etanol * Cp etanol) + (fraksi massa air * Cp air)
Cp campuran 3.716171 kJ/kg K

2. Mencari λ pada TB,F = 90.18 °C dengan interpolasi di buku Geankoplis ed 3 hal 887 (append
Enthalpy Liquid Enthalpy Vapor
T,C HL (kj/kg) T,C HV (kj/kg)
84.7 314 84.7 2193
90.18 358.56 90.18 2443.23
91.8 371.7 91.8 2517

λ = HV - HL
λ = 2084.66 kJ/kg

3. Mencari q line
q = 1 + (CpL * (TB - TF) ) / λ
q = 1.00924

Mencari persamaan garis q line

1.00924 0.131
y = x -
0.00924 0.00924
y = 109.23 x - 14.206

Data q line Garis XD

x y x y
0.131 0.131 0.44 0
0.14 0.976 0.44 0.44 Garis XF
x
Data operating line Garis XB 0.13
x y x y 0.13
0 0 0.02 0
1 1 0.022 0.022

Reflux ratio(R)= L/D

 R 1.5
XD 0.441

𝑦_(𝑛+1) =Enriching
(𝑅/(𝑅+1)) 𝑋_𝑛
Operating line+ 𝑿_𝑫/((𝑹+𝟏))

y= 0.6 Xn + 0.1764

Data Enriching
x y
0 0.176
0.1 0.236
0.2 0.296
0.3 0.356
0.4 0.416
0.441 0.441
 %etanol (v/v) Reflux Ratio Fraksi Massa Fraksi Mol

F D B L D F D B F D
15% 47% 3% 30 20 0.122 0.410 0.024 0.051 0.214
21% 50% 0% 30 20 0.172 0.439 0.000 0.075 0.235
15% 52% 0% 30 20 0.122 0.459 0.000 0.051 0.249
12% 51% 0% 30 20 0.097 0.449 0.000 0.040 0.242
17% 50% 5% 30 20 0.138 0.439 0.040 0.059 0.235
17% 50% 3% 30 20 0.138 0.439 0.024 0.059 0.235
16% 51% 8% 30 20 0.130 0.449 0.064 0.055 0.242
19% 58% 0% 30 20 0.155 0.520 0.000 0.067 0.298
19% 60% 0% 30 20 0.155 0.540 0.000 0.067 0.315
25% 60% 0% 30 20 0.207 0.540 0.000 0.093 0.315
23% 65% 3% 30 20 0.190 0.593 0.024 0.084 0.363
16.14% 50.14% 2.71% rata-rata flowrate 75 0.131 0.441 0.022 0.056 0.236
21.50% 60.75% 0.75% rata-rata flowrate 65 0.177 0.548 0.006 0.078 0.323

Luas penampang masing-masing HE

Cooler(W3) 1 m2
menit Reboiler(W2) 1 m2
L/jam Preheater(W5) 0.5 m2
Kondensor(W1) 5.3 m2

Kurva Boiling Point

01 x⁴ − 255.41767 x³ + 230.90844 x² − 100.09126 x + 99.890193

776521521
T Vs XA
Polynomial (T Vs XA)
T Vs YA

4 0.6 0.8 1 1.2

XA,YA
73 (figure A.3-5)

koplis ed 3 hal 887 (appendix A.3-23)

1
f(x) = − 42.591639 x⁶ + 148.06766x x⁵
f(x) = 109.225770781983 − 201.54819 x⁴ + 136.75753 x³ − 48.614325 x² + 8.9040625 x + 0.0179098
− 14.2061184760197
0.9
R² = 0.998540909123525
R² = 1

0.8
q line Kesetimbangan
Polynomial (Kesetimbangan)
0.7
Operating line
q line
0.6
Linear (q line)
XF
0.5 XB
XD
0.4 f(x) = 0.6 x + 0.176377187096598 enriching
R² = 1
Linear (enriching)
0.3 stripping
Linear (stripping)
f(x) = 2.11334148385216 x − 0.02398627196034
0.2 stage
R² = 1
0.1
XB XF XD
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

y ∑ tray + 1 reboiler = 2
0 ∑ tray teoritis = 1
0.13 ∑ tray actual = 12
% efisiensi tray = (∑ tray teoritis / ∑ tray actual) x 100%
%efisiensi tray 8%
Stripping Operation line Mencari jumlah stage
Mencari titik potong antara garis q line dan garis enricing dengan cara goal seek x
x = 0.132398 0.441
persamaan y1 garis q line sama dengan y2 garis enriching : 0.069
y1 = y2 0.069
0 = y2-y1 0.026
0 = 8.171E-14 0.026

y = 0.255816

garis stripping
x y
0.022 0.022
0.132398 0.255816
Fraksi Mol

B
0.009
0.000
0.000
0.000
0.016
0.009
0.026
0.000
0.000
0.000
0.009
0.009
0.002

XF = 0.177
TB,F = 88.10 °C
361.25 K
 TF = suhu fluida yang keluar dari preheater
TF 85 °C 358.15 K
T average = (Tb,f + Tf) / 2
T avg 86.55 °C 359.70 K

1. Mencari Cp pada Tavg = 86,55 °C di buku Geankoplis ed 5 hal 1673 (figure A.3-5)
Cp etanol 86,55 °C 0.808 cal/g°C 3.380672 kJ/kg K
Cp air 86,55 °C 0.9 cal/g°C 3.7656 kJ/kg K
Cp campuran = (fraksi massa etanol * Cp etanol) + (fraksi massa air * Cp air)
Cp campuran 3.697501 kJ/kg K

2. Mencari λ pada TB,F = 88.10 °C dengan interpolasi di buku Geankoplis ed 3 hal 8

Enthalpy Liquid Enthalpy Vapor
T,C HL (kj/kg) T,C HV (kj/kg)
84.7 314 84.7 2193
88.10 341.60 88.10 2347.99
91.8 371.7 91.8 2517

λ = HV - HL
25 x + 0.0179098 λ = 2006.39 kJ/kg

3. Mencari q line
timbangan q = 1 + (CpL * (TB - TF) ) / λ
omial (Kesetimbangan) q = 1.005706
ating line

r (q line) Mencari persamaan garis q line

hing
r (enriching)
ping 1.005706 0.177
r (stripping) y = x -
0.005706 0.005706
y = 176.24 x - 31.003

Data q line Garis XD

x y x y
0.177 0.177 0.548 0
0.181 0.897 0.548 0.548

Data operating line Garis XB

x y x y
0 0 0.01 0
1 1 0.006 0.006

Reflux ratio(R)= L/D

 R 1.5
XD 0.548

Mencari jumlah stage 𝑦_(𝑛+1) = (𝑅/(𝑅+1)) 𝑋_𝑛 +line

Enriching Operating 𝑿_𝑫/((𝑹+𝟏))
y
0.441
0.441 y= 0.6 Xn + 0.2194
0.218
0.218 Data Enriching
0.031 x y
0 0.219
0.1 0.279
0.2 0.339
0.3 0.399
0.4 0.459
0.548 0.548
lis ed 5 hal 1673 (figure A.3-5)

aksi massa air * Cp air)

di buku Geankoplis ed 3 hal 887 (appendix A.3-23)

1
f(x) = − 42.591639 x⁶ + 148.06766 x⁵ − 201.54819 x⁴ + 136.75753 x³ − 48.614325 x² + 8.9040625 x + 0.0179098
0.9
R² = 0.998540909123525
f(x) = 176.243957049698 x − 31.0031796357575
R² = 1
0.8
q line Kesetimbangan
Polynomial (Kesetimbangan
0.7
Operating line
q line
0.6
Linear (q line)
f(x) = 0.6 x + 0.219365266370239 XF
0.5 XB
R² = 1
XD
0.4 enriching
Linear (enriching)
0.3 f(x) = 1.86275455698358 x − 0.005106538913094 stripping
R² = 1 Linear (stripping)
0.2 stage

0.1

XB XF XD
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Garis XF
x y ∑ tray + 1 reboiler = 3
0.177 0 ∑ tray teoritis = 2
0.177 0.177 ∑ tray actual = 12
% efisiensi tray = (∑ tray teoritis / ∑ tray actual) x 100%
%efisiensi tray 17%
Stripping Operation line
Mencari titik potong antara garis q line dan garis enricing dengan cara goal seek
x = 0.177764
persamaan y1 garis q line sama dengan y2 garis enriching :
y1 = y2
0 = y2-y1
0 = -4.41E-13

y = 0.326023

garis stripping
x y
0.006 0.006
0.177764 0.326023
² + 8.9040625 x + 0.0179098

Kesetimbangan
Polynomial (Kesetimbangan)
Operating line
q line
Linear (q line)
XF
XB
XD
enriching
Linear (enriching)
stripping
Linear (stripping)
stage
Mencari jumlah stage
x y
0.548 0.548
0.120 0.584
0.120 0.291
0.038 0.291
0.038 0.065
0.005 0.065
0.005 0.005
No T (menit) T hot (⁰C) T cold (⁰C) Flowrate (L/h)
in out in out hot
1 0 79 30.6 26.8 29 25
2 10 63.2 35.3 27.7 34.2 25
3 20 58 30.9 27.8 30.1 25
4 30 57 31.2 28.8 34.2 25
5 40 72 32.8 29.5 31.8 25
6 50 60.7 31.6 30 32 25
7 65 58.2 38.4 30.3 32 25
8 80 62.9 33.4 29.8 31.8 25
9 95 58.9 33.4 30.8 32.4 25
10 110 65 34 30.6 32.7 25
11 125 67.5 33.5 29.6 34.8 25
12 140 74.4 30 30 31.7 25
Flowrate (L/h)
cold
600
600
600
600
600
600
600
600
600
600
600
600
NO t (menit) T hot (⁰C) T cold (⁰C) Flowrate (L/h)
in out in out hot cold
1 0 120.1 93 54 88.2 100 22
2 10 121.1 95 56 90 100 22
3 20 120.4 92 58 88.2 100 22
4 30 122 95 56.7 90.4 100 22
5 40 120.6 92 59 89.9 100 22
6 50 119.6 94 66.8 90.3 110 22
7 65 119.1 92 84 88.6 95 22
8 80 119.5 95 85.5 89.6 98 22
9 95 128.8 94 86.9 90.8 110 22
10 110 118.7 95 88.6 91.2 130 20
11 125 118.7 92 56.5 91.3 100 20
12 140 118.1 92 83.3 87.1 100 22
NO t (menit) T Hot (⁰C) T Cold (⁰C) Flowrate (L/h)
in out in out hot cold
1 0 80.9 51.3 25.2 33.4 25.2 2
2 10 82 56.6 26.6 37.6 25.2 2
3 20 84.6 47.9 26.4 36.1 25.2 2
4 30 83.3 55.4 29.6 37.7 25.2 2
5 40 81.9 46.1 28.3 36.1 25.2 2
6 50 82.3 52.7 28.7 38.8 25.2 2
7 65 79.6 42.2 29.3 35.3 25.2 2
8 80 78.5 44.3 29.5 35.6 25.2 2
9 95 80.5 53.2 29.1 39.2 25.2 2
10 110 82.4 53.2 29.5 41 25.2 2
11 125 77.8 48 29.6 36.6 25.2 2
12 140 70.4 48 29.7 35.7 25.2 2

rata-rata 80.35 49.90833 28.45833 36.925 25.2 2

 Flowrate
1. Fluida Dingin (air pendingin/cold water) 2. Fluida Panas
T in 28.45833 °C T in 80.35
T out 36.925 °C T out 49.90833
∆T 8.466667 °C ∆T 30.44167
Tav 32.69167 °C Tav 65.12917
Flowrate 2 L/h XD 0.440943
m 1.989514 kg/h %etanol (v/v) di D

Densitas air pada Tav = 32.04 °C (geankoplis ed 5 hal 1643 table A.2-3) Mencari Cp air dan etanol (Geankoplis e
30 995.68 kg/m3 Cp etanol 0.935
40 992.25 kg/m3 interpolasi Cp air 0.998
32.69167 994.7568 kg/m3 Cp campuran
0.994757 kg/L Flowrate 25.2
m 19.65791
Cp air pada Tav = 32.04 °C (geankoplis ed 5 hal 1673 figure A.3-5)
Cp air 0.996 cal/g Densitas etanol pada Tav = 340.08 K (pe
4.167264 kJ/kg 159.05 19.413
513.92 5.965
q = m * Cp * ∆T (panas sensible) 338.1292 12.62669
q 70.19568 kJ 0.580828

Densitas air pada Tav = 67.08 °C (geank

60 983.24
70 977.83
65.12917 980.4651
0.980465
densitas campuran

λ 2084.66
q = (m * Cp * ∆T) + (m * λ)
q 43409.35

qav = (q panas + q dingin) / 2

qav 21739.77

Flowrate
1. Fluida Dingin (air pendingin/cold water) 2. Fluida Panas
T in 28.45833 °C T in 80.35
T out 36.925 °C T out 49.90833
∆T 8.466667 °C ∆T 30.44167
Tav 32.69167 °C Tav 65.12917
Flowrate 2 L/h XD 0.548413
m 1.989514 kg/h %etanol (v/v) di D
Densitas air pada Tav = 32.04 °C (geankoplis ed 5 hal 1643 table A.2-3) Mencari Cp air dan etanol (Geankoplis e
30 995.68 kg/m3 Cp etanol 0.935
40 992.25 kg/m3 interpolasi Cp air 0.998
32.69167 994.7568 kg/m3 Cp campuran
0.994757 kg/L Flowrate 25.2
m 18.58967
Cp air pada Tav = 32.04 °C (geankoplis ed 5 hal 1673 figure A.3-5)
Cp air 0.996 cal/g Densitas etanol pada Tav = 340.08 K (pe
4.167264 kJ/kg 159.05 19.413
513.92 5.965
q = m * Cp * ∆T (panas sensible) 338.1292 12.62669
q 70.19568 kJ 0.580828

Densitas air pada Tav = 67.08 °C (geank

60 983.24
70 977.83
65.12917 980.4651
0.980465
densitas campuran

λ 2084.66
q = (m * Cp * ∆T) + (m * λ)
q 41034.41

qav = (q panas + q dingin) / 2

qav 20552.3
 Flowrate 75
(distilat) 3. Nilai U
°C qav 21739.77 kJ
°C A 6.3 m2
°C ∆T1 43.425 °C ∆T1 = T hot in - T cold out
°C 338.1292 K ∆T2 21.45 °C ∆T2 = T hot out - T cold in
∆T LMTD 31.15648 (Counter Current)
50%
Q = U × A × ∆T LMTD
Cp air dan etanol (Geankoplis ed 5 hal 1673 figure A.3-5) U = Q / (A × ∆T LMTD)
cal/g°C 3.91204 kJ/kg K U 110.7557 kJ/m2
pada suhu 67.08 °C
cal/g°C 4.175632 kJ/kg K
4.059403 kJ/kg K
L/h
kg/h

etanol pada Tav = 340.08 K (perry hal 135 table 2-30)

kmol/m3
kmol/m3 interpolasi
kmol/m3
kg/L

air pada Tav = 67.08 °C (geankoplis ed 5 hal 1643 table A.2-3)

kg/m3
kg/m3 interpolasi
kg/m3
kg/L
0.780076 kg/L

kJ/kg
p * ∆T) + (m * λ)
kJ

anas + q dingin) / 2
kJ

Flowrate 65
(distilat) 3. Nilai U
°C qav 20552.3 kJ
°C A 6.3 m2
°C ∆T1 43.425 °C ∆T1 = T hot in - T cold out
°C 338.1292 K ∆T2 21.45 °C ∆T2 = T hot out - T cold in
∆T LMTD 31.15648 (Counter Current)
61%
Q = U × A × ∆T LMTD
Cp air dan etanol (Geankoplis ed 5 hal 1673 figure A.3-5) U = Q / (A × ∆T LMTD)
cal/g°C 3.91204 kJ/kg K U 104.706 kJ/m2
pada suhu 67.08 °C
cal/g°C 4.175632 kJ/kg K
4.031075 kJ/kg K
L/h
kg/h

etanol pada Tav = 340.08 K (perry hal 135 table 2-30)

kmol/m3
kmol/m3 interpolasi
kmol/m3
kg/L

air pada Tav = 67.08 °C (geankoplis ed 5 hal 1643 table A.2-3)

kg/m3
kg/m3 interpolasi
kg/m3
kg/L
0.737686 kg/L

kJ/kg
p * ∆T) + (m * λ)
kJ

anas + q dingin) / 2
kJ
∆T1 = T hot in - T cold out
∆T2 = T hot out - T cold in

∆T1 = T hot in - T cold out

∆T2 = T hot out - T cold in
 T hot (⁰C) T cold (⁰C) Flowrate (L/h)
No t (menit) hot
In out in out cold
(mL/s)
1 0 100 72.6 46.2 85 23.6 75
2 10 100 77.3 43.5 85.3 12.4 75
3 20 100 71.7 50.9 87 24 75
4 30 100 53 36.6 82.4 19.8 75
5 40 100 76 45 85.3 23 75
6 50 100 78 37.3 86.7 20.2 75
7 65 100 68 37.1 89.3 16 75
8 80 100 79 39.9 89.1 16.2 75
9 95 100 76 44.8 77.1 25.8 65
10 110 100 80 38.5 86.2 27.8 65
11 125 100 77 42.5 72.5 22 65
12 140 100 68.8 48.8 74.4 10 65
100 71.95 42.0625 86.2625 19.4 75
average
100 75.45 43.65 77.55 21.4 65

flowrate 75
fluida dingin densitas etanol 337.26K
Tin 42.0625 C Perry 210 pdf 83
T out 86.2625 C 159.05 19.413
ΔT 44.2 C 513.92 5.965
T avrg 64.1625 C 337.3125 12.65764
337.3125 K 0.582252
flowrate fluida dingin 75 L/h
fraksi volume feed etanol 16.14% Densitas air 73.04 oC
fraksi massa feed etanol 0.021544 Geankoplis A.3-23
densitas etanol T avrg 0.582252 kg/L 70 0.977781
densitas air T avrg 0.975304 kg/L 80 0.97183
densitas campuran 0.911854 kg/L 64.1625 0.975304
Cp etanol T avrg 3.88535 kJ/Kg.K
Cp air T avrg 4.17424 kJ/Kg.K
Cp campuran 4.168016 kJ/Kg.K
m fluida dingin 68.38905 kg/H
lamda 2084.66 kJ/kg.K

fluida panas
Tin 100 C Densitas air 730.4oC
Tout 71.95 C Geankoplis A.3-23
ΔT 28.05 C 80 0.97183
T avrg 85.975 C 90 0.96534
flowrate fluida panas 1.164 L/h 85.975 0.967952
fraksi volume feed etanol 16.14%
fraksi massa feed etanol 0.021544 Densitas etanol
densitas etanol T avrg 0.967952 kg/L 159.05 19.413
densitas air T avrg 0.546085 kg/L 513.92 5.965
densitas campuran 0.899851 kg/L 358.06 11.8714
Cp etanol T avrg 3.88535 kJ/Kg.K 0.546085
Cp air T avrg 4.17424 kJ/Kg.K
Cp campuran 4.168016 kJ/Kg.K
m fluida panas 1.126696 kg/H
lamda 2084.66 kJ/kg

q fluida dingin 155167.2 ΔT1 13.7375

q fluida panas 2480.705 ΔT2 29.8875
q average 78823.97 LMTD 20.77675

A 0.5
U 7587.708
lowrate (L/h)
hot
(L/s)
1.416
0.744
1.44
1.188
1.38
1.212
0.96
0.972
1.548
1.668
1.32
0.6
1.164
1.284

flowrate 65
etanol 337.26K fluida dingin densitas etanol 337.26K
Tin 43.65 C Perry 210 pdf 83
kmol/m3 T out 77.55 C 159.05 19.413
kmol/m3 ΔT 33.9 C 513.92 5.965
kmol/m3 T avrg 60.6 C 333.75 12.79264
g/mL 333.75 K 0.588462
flowrate fluida dingin 65 L/h
air 73.04 oC fraksi volume feed etanol 21.50% Densitas air 73.04 oC
fraksi massa feed etanol 0.005919 Geankoplis A.3-23
g/mL densitas etanol T avrg 0.588462 kg/L 70 0.977781
g/mL densitas air T avrg 0.977424 kg/L 80 0.97183
g/mL densitas campuran 0.893797 kg/L 60.6 0.977424
Cp etanol T avrg 3.88535 kJ/Kg.K
Cp air T avrg 4.17424 kJ/Kg.K
Cp campuran 4.17253 kJ/Kg.K
m fluida dingin 58.09681 kg/H
lamda 2006.39 kJ/kg.K

fluida panas
Tin 100 C Densitas air 730.4oC
Tout 75.45 C Geankoplis A.3-23
g/mL ΔT 24.55 C 80 0.97183
g/mL T avrg 87.725 C 90 0.96534
g/mL flowrate fluida panas 1.284 L/h 87.725 0.966816
fraksi volume feed etanol 21.50%
fraksi massa feed etanol 0.005919 Densitas etanol
 densitas etanol T avrg 0.966816 kg/L 159.05 19.413
densitas air T avrg 0.546085 kg/L 513.92 5.965
densitas campuran 0.876359 kg/L 358.06 11.8714
g/ml Cp etanol T avrg 3.88535 kJ/Kg.K 0.546085
Cp air T avrg 4.17424 kJ/Kg.K
Cp campuran 4.17253 kJ/Kg.K
m fluida panas 1.241392 kg/H
lamda 2006.39 kJ/kg

q fluida dingin 124782.6 ΔT1 22.45

q fluida panas 2617.933 ΔT2 31.8
q average 63700.28 LMTD 26.85426

m2 A 0.5
kJ/m2 U 4744.147
etanol 337.26K

kmol/m3
kmol/m3
kmol/m3
g/mL

air 73.04 oC

g/mL
g/mL
g/mL

g/mL
g/mL
g/mL
g/ml

m2
kJ/m2