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Thermochemistry Worksheet 1

1. The document is a chemistry worksheet on thermochemistry. It contains questions about enthalpy changes, standard enthalpy of formation, drawing enthalpy profile diagrams, calculating heat of reaction from calorimetry data, using standard enthalpies of formation to calculate enthalpy changes, and determining enthalpy changes from bond energies. 2. The questions require students to copy and complete sentences about enthalpy using provided terms, identify the standard enthalpy of formation equation for hydrogen iodide, draw an enthalpy profile diagram for a reaction, perform calorimetry calculations to determine heat of reaction and enthalpy change, use standard enthalpies of formation in enthalpy

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Bennett Bong
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313 views7 pages

Thermochemistry Worksheet 1

1. The document is a chemistry worksheet on thermochemistry. It contains questions about enthalpy changes, standard enthalpy of formation, drawing enthalpy profile diagrams, calculating heat of reaction from calorimetry data, using standard enthalpies of formation to calculate enthalpy changes, and determining enthalpy changes from bond energies. 2. The questions require students to copy and complete sentences about enthalpy using provided terms, identify the standard enthalpy of formation equation for hydrogen iodide, draw an enthalpy profile diagram for a reaction, perform calorimetry calculations to determine heat of reaction and enthalpy change, use standard enthalpies of formation in enthalpy

Uploaded by

Bennett Bong
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOCX, PDF, TXT or read online on Scribd
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Name: __________________________ Class: XIC/D Date: ______________________

Thermochemistry
Worksheet

1. Copy and complete these sentences about enthalpy changes using words from the list below.
[10]

chemical exothermic ΔH kelvin atm


physical products surroundings heat absorbed

An enthalpy change is the exchange of _______heat______ energy between a


_________chemical____________ reaction mixture and its ______ surroundings
______________at constant pressure. The symbol for enthalpy change is _____ ΔH
_____________. If heat is _______ absorbed _______________from the surroundings
the reaction is endothermic. If heat is released to the surroundings the reaction is _____
exothermic ___________. In comparing enthalpy change we use standard conditions. These area
pressure of 1 _______ atm__________, a temperature of 298 ________ kelvin __________ with
the reactans and ____ products ______________ in their normal ______ physical ___________
state under these conditions.

2. Which of the following equations represents the standard enthalpy change of formation of
hydrogen iodide? [1]
A. H2(g) + I2(g)  2HI(g)
B. H2(g) + I2(s)  2HI(g)
1 1
C. H2(g) + I2(g)  HI(g)
2 2
1 1
D. H2(g) + I2(s)  HI(g)
2 2

3. Given an equation to shows the reaction of calcium with iron (III) oxide.
3Ca(s) + Fe2O3(s)  2Fe(s) + 3CaO(s)

The enthalphy cange of the reaction is -1081.1 kJ per 2 moles of iron formed. Draw an
enthalpy profile diagram (Shows Ea) for the reaction. [4]

Chemistry grade-11 Smart, Wise, & Accountable


Name: __________________________ Class: XIC/D Date: ______________________

4. Two solutions, 25 mL of 2.5 M HNO3 solution and 25 mL of 2.5 M Mg(OH)2 solution, both
initially at 25°C, are added to a styrofoam cup calorimeter and allowed to react. The
temperature rises to 37.8°C.
2HNO3(aq) + Mg(OH)2(aq)  Mg(NO3)2(aq) + 2H2O(l)

a. Is the reaction endothermic or exothermic? [1] Exothermic


b. Calculate the heat of the reaction. Specific heat capacity of water is 4.18 J°C-1g-1. [2]

Chemistry grade-11 Smart, Wise, & Accountable


Name: __________________________ Class: XIC/D Date: ______________________

c. Calculate the enthalpy change for 2 moles of water produced. [1]

5. In an experiment to measure the enthalpy change of combustion of ethanol, a student heated a


copper calorimeter containing 100 cm3 of water with a spirit burner and collected the following
data.
Initial temperature of water : 22℃

Chemistry grade-11 Smart, Wise, & Accountable


Name: __________________________ Class: XIC/D Date: ______________________

Final temperature of water : 60℃


Mass of ethanol burned : 2.2 g
Density of water : 1 g.cm-3

a) Use the data to calculate the heat evolved when the ethanol was combusted. [2]
b) Calculate the enthalpy change of combustion per mole of ethanol. [2]
c) Write the thermochemical equation for combustion reaction of 1 mol ethanol. [1]
d) Suggest a reason why the result is not the same as the value in the Data Booklet? [1]
Because the energy loss in the form of heat.

6. Iron (II) oxide can be reduced by carbon monoxide:


Fe2O3(s) + 3CO(g)  2Fe(s) + 3CO2(g)

a. Complete the enthalpy cycle for this diagram. [1]

b. Calculate the enthalpy change, ΔH °r , given: [2]


ΔH °f of Fe2O3(s) = -824.2 kJ mol-1
ΔH °f of CO(g) = -110.5 kJ mol-1
ΔH °f of CO2(g) = -393.5 kJ mol-1

Chemistry grade-11 Smart, Wise, & Accountable


Name: __________________________ Class: XIC/D Date: ______________________

7. Given the following data. [2]

N2(g) + O2(g)  2NO(g) ΔH = -180.5 kJ/mol


N2(g) + 3H2(g)  2NH3(g) ΔH = -91.8 kJ/mol
2H2(g) + O2(g)  2H2O (g) ΔH = -483.6 kJ/mol

Calculate the enthalpy change for the reaction:


4NH3(g) + 5O2(g)  4NO(g) + 6H2O (g)

Chemistry grade-11 Smart, Wise, & Accountable


Name: __________________________ Class: XIC/D Date: ______________________

8. Hydrazine is a valuable rocket fuel. The equation for the reaction between hydrazine and
oxygen is given below.
N2H4(g) + O2(g)  N2(g) + 2H2O(g)

Use the bond enthalpy values given to determine the enthalpy change for this reaction. [2]

Bond energy Bond energy


kJ/mol kJ/mol
N–H +391 N≡N +941 N–N +160
O–H +467 O═O +495

Chemistry grade-11 Smart, Wise, & Accountable


Name: __________________________ Class: XIC/D Date: ______________________

Total: 32

Chemistry grade-11 Smart, Wise, & Accountable

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