Plate Out in PVC Extrusion - A Never Ending Story?
Plate Out in PVC Extrusion - A Never Ending Story?
Dr. M. Schiller, Dr. B. Pelzl, R. Haberleitner (Chemson Group), Dr. Y. Salamonov (Elnova) Profiles 2006, Moscow
Influence of filler, Influence of
Titanium dioxide lubricants and
and modifier soaps
The mechanisms
Dr. M. Schiller, Dr. B. Pelzl, R. Haberleitner (Chemson Group), Dr. Y. Salamonov (Elnova) Profiles 2006, Moscow
Bohemian Rhapsody
Dr.Mercury,
F. M. Schiller,
R. Taylor,
Dr. B. Pelzl,
J. Deacon,
R. Haberleitner
B. May (Queen)
(Chemson Group), Dr. Y. Salamonov (Elnova) Profiles 2006, Moscow
Plate out in the Die
Extrusion direction
Dr. M. Schiller, Dr. B. Pelzl, R. Haberleitner (Chemson Group), Dr. Y. Salamonov (Elnova) Profiles 2006, Moscow
Plate out in the Die
Analytical results
Titanium 12 15 22 11 5 10 7 10 16
Lead 21 23 31 34 36 31 - - -
Calcium 15 11 5 8 13 12 17 19 12
Zinc - - - - - - 4 1 2
Organica 17 20 14 22 16 16 29 22 35
Chloride pos. pos. 8 pos. 0,3 0,4 pos. pos. pos.
Dr. M. Schiller, Dr. B. Pelzl, R. Haberleitner (Chemson Group), Dr. Y. Salamonov (Elnova) Profiles 2006, Moscow
Plate out in the Calibrator
Exceed of solubility
Deposites
Dr. M. Schiller, Dr. B. Pelzl, R. Haberleitner (Chemson Group), Dr. Y. Salamonov (Elnova) Profiles 2006, Moscow
Plate out analysis
Dr. M. Schiller, Dr. B. Pelzl, R. Haberleitner (Chemson Group), Dr. Y. Salamonov (Elnova) Profiles 2006, Moscow
Chemson’s method
Breaker Plate
#1
(Die)
#3
#4
Adaptor
#2
Dr. M. Schiller, Dr. B. Pelzl, R. Haberleitner (Chemson Group), Dr. Y. Salamonov (Elnova) Profiles 2006, Moscow
Reliability of the Method
20
Derivative plot
C u m u la tiv e fr e q u e n c y
3
15
10 2
5 1
Average = 8.03
Std. deviation = 0.60 0 0
Standard error = 0.14
6,75 7,25 7,75 8,25 8,75 9,25
Plate out
Dr. M. Schiller, Dr. B. Pelzl, R. Haberleitner (Chemson Group), Dr. Y. Salamonov (Elnova) Profiles 2006, Moscow
Influence of Water
13
12
Plate out rating
11
10
9
8
7
0 0,1 0,2 0,3
phr water
Dr. M. Schiller, Dr. B. Pelzl, R. Haberleitner (Chemson Group), Dr. Y. Salamonov (Elnova) Profiles 2006, Moscow
Dependency on phr PE wax
16 out
Plate 16 out
Plate
PE 1
14 14
12 12
10 10
8 8
6 6
4 4
0,1 0,2 0,3 0,4 phr PE0,5
1 0,1 0,2 0,3 0,4 phr CaSt
0,5
16 out
Plate 16 out
Plate
PE 1
14 14
12 12
10 10
8 8
6 6 PE 1
4 4
0,1 0,2 0,3 0,4 phr PbSt
0,5 190 191 192 193 194 195 MT/°C
196
Dr. M. Schiller, Dr. B. Pelzl, R. Haberleitner (Chemson Group), Dr. Y. Salamonov (Elnova) Profiles 2006, Moscow
Dependency on phr PE wax
16 out
Plate 16 out
Plate
14 14
12 12
10 10
8 8
6 6
4 4
0,1 0,2 0,3 0,4 phr PE0,5
1 0,1 0,2 0,3 0,4 phr PE0,5
2
16 out
Plate 16 out
Plate
14 14
12 12
10 10
8 8
6 6
4 4
0,1 0,2 0,3 0,4 phr PE0,5
3 0,1 0,2 0,3 0,4 phr PE0,5
4
Dr. M. Schiller, Dr. B. Pelzl, R. Haberleitner (Chemson Group), Dr. Y. Salamonov (Elnova) Profiles 2006, Moscow
The test formulation
Dr. M. Schiller, Dr. B. Pelzl, R. Haberleitner (Chemson Group), Dr. Y. Salamonov (Elnova) Profiles 2006, Moscow
Influence of filler
10
8
Plate out value
0
0,00 2,75 5,50 8,25 11,00 13,75
phr filler
Dr. M. Schiller, Dr. B. Pelzl, R. Haberleitner (Chemson Group), Dr. Y. Salamonov (Elnova) Profiles 2006, Moscow
Influence of Titanium dioxide
20
15
plate out
10
7,0 phr 5
3,5 phr
0
Supplier A Supplier B Supplier C
Dr. M. Schiller, Dr. B. Pelzl, R. Haberleitner (Chemson Group), Dr. Y. Salamonov (Elnova) Profiles 2006, Moscow
Influence of acrylic modifier
18
16
14
12
Plate out
10
8
6
4
2
0
ng
ng
ng
ng
al
al
al
al
rm
rm
rm
rm
i
i
tch
tch
tch
tch
no
no
no
no
ba
ba
ba
ba
le
le
le
le
ub
ub
ub
ub
do
do
do
do
Dr. M. Schiller, Dr. B. Pelzl, R. Haberleitner (Chemson Group), Dr. Y. Salamonov (Elnova) Profiles 2006, Moscow
Summary
Dr. M. Schiller, Dr. B. Pelzl, R. Haberleitner (Chemson Group), Dr. Y. Salamonov (Elnova) Profiles 2006, Moscow
Thank you for your
kind attention
Dr. M. Schiller, Dr. B. Pelzl, R. Haberleitner (Chemson Group), Dr. Y. Salamonov (Elnova) Profiles 2006, Moscow
DoE
Dr. M. Schiller, Dr. B. Pelzl, R. Haberleitner (Chemson Group), Dr. Y. Salamonov (Elnova) Profiles 2006, Moscow
DoE
0.6
- internal 0.1 ... 0.6 phr
Paraffin
6
Mixture 1 2 3 4 5 6 7 8
0.
al
rn
te
in
soap 0.3 0.6 0.3 0.6 0.3 0.6 0.3 0.6
0 Metal soap 0.7
Wax B 0.2 0.2 0.7 0.7 0.2 0.2 0.7 0.7
Wax C 0.1 0.1 0.1 0.1 0.6 0.6 0.6 0.6
Dr. M. Schiller, Dr. B. Pelzl, R. Haberleitner (Chemson Group), Dr. Y. Salamonov (Elnova) Profiles 2006, Moscow
DoE
Fitted values
extrusion-torque
*
100 * *
180
* *
90 * *
***
*
150 *
80
* *
*
*
*
70 12
70 80 90 100 110 0 120 150 180 210
Observations Observations
Dr. M. Schiller, Dr. B. Pelzl, R. Haberleitner (Chemson Group), Dr. Y. Salamonov (Elnova) Profiles 2006, Moscow
DoE
20 *
Fitted values Plate-out
15
*
*
** *
*
10 *
*
5
5 10 15 20
Observations
Dr. M. Schiller, Dr. B. Pelzl, R. Haberleitner (Chemson Group), Dr. Y. Salamonov (Elnova) Profiles 2006, Moscow