CLI

P ATOMI
C STRUCTURE FI
ITJEE-CRR
Q.
1 Thewav el
engthofacert
ainl
i
neinthe Q.
9I nahydr
ogenatom,i
ntr
ansi
ti
onofelectrona
Paschenseri
esin1094.
4nm ofH-
atom.Fi
nd phot
onofenergy2.
55eVisemit
ted,then
val
ueofnhighf
orthi
sli
ne. cal
cul
atechangei
nwavel
engt
hoft heelect
ron.

Q.
2Wav el
engt
hoft heBal
merHαl
ineis6565Å. Q.
10Amet alwasirradi
atedbyl i
ghtoff
requency
Calcul
atet
hewav el
engt
hofHβli
neofsame 25×1015Hz
3. .Thephot oel
ectr
onproduced
hydrogenl
ikeat
om. haditsKEtwot imest heKEofphotoelect
ron
whichwaspr oducedwhent hesamemet alwas
Q.
3Aphot onhavingλ=800Åcausest he i
rradi
atedwithal i
ghtoff equency2×1015Hz.
r
i
onizat
ionofanit
rogenat
om.Givet heI
Eper Whatiswor kfuncti
on?[ Giv NA=6×1023]
en:
moleofnit
rogeni
nKJ. [ Giv
en: E=hc=
1240eV-nm,1eV=96.43kJ/
mol ] Q.
11Apot .dif
fer
enceof20KVisappl
i
edacross
anX-r
aytube.Fi
ndthemini
mum wavel
engthof
Q.
4H-atom i
sexposedtoelectromagneti
c X-
raygenerat
ed.
r
adi
ati
onof1028Åandgi vesoutinduced
r
adi
ati
ons(r
adiati
onsemittedwhene–r etur
ns Q.
12 TheK. E.ofanel
ectr
onemittedf
rom
t
ogroundst
ate).Cal
cul
ateλofi nduced t
ungstansur
facei
s3.06eV.Whatvolt
agei
s
r
adi
ati
ons. r
equi
redtomakeelectr
onrest
?

Q.5 1. 8ghy dr ogenat omsar eex cit

edt or adi ations. Q.13 Fi ndt henumberofphot onsofr adiationof
13 –1
The frequency5×10 s t hatmustbeabsor bedin
st udyofspect raindi catest hat27%oft he ordert omel tonegm i cewhent hel atentheat
atoms off usi onofi cei s331. 5J/ g.
ar ei n3r dener gyl evel and15%ofat omsi n
2nd Q.14 Suppose10-17Jofl i
ghtener gyisneededby
ener gyl ev el andther esti ngr oundst at e.IfI .
P. thei nter ioroft hehumaney etoseeanobj ect.
of Howmanyphot onsofgr eenlight( λ=550nm)
Hi s21. 7×10-12er g, calculate areneededt ogener at et hismi nimum amount
(i)No.ofat omspr esenti nIII&I Iener gylev el. ofener gy?
(ii
)Tot alener gyev olvedi fal ltheatomsr etur nto
groundst at e. Q.15Thr oughwhatpot ent ial diff
erencemustan
el
ectron
Q. 6 Theener gyofanex cit
edH- atom i s–3. 4eV. passt ohav eawav elengt hof500Å?
Cal cul ateangul armoment um ofe– i nt hegi ven
orbi t. Q.16 Apr ot oni saccel erat edt oone-t enthoft he
veloci tyofl ight .Ifitsv elocit
ycanbe
Q.7 Asi ngl eel ectronor bitsar oundast ationar y measur ed
nucleus withapr ecision1%.Whatmustbei ts
ofchar ge+Zewher eZi sat omi cnumberand‘ e’ uncertainty
i
s inposi ti
on?
themagni tudeoft heel ectricchar ge.The
hy drogen Q.17 Towhatef fectivepot ent ialapr otonbeam be
l
ikespeci esr equi
red47. 2eVt oex citet he subj ect edt ogi v eitspr otonsawav elengt hof
–10
electr on 1x10 m ?
from t hesecondBohror bittot het hirdBohr
orbit. Q.18 Cal cul atet hewav elengt hoft her adiationt hat
Find woul dcausephot odi ssoci ati
onofchl orine
(i
)t hev al ueofZandgi vet hehy drogenl i
ke mol ecul ei ftheCl -Cl bondener gyi s241
speci es KJ/mol .
for med.
(ii
)t heki net icener gyandpot enti
al energyoft he Q. 19 X- ray semi t tedf rom acoppert argetanda
electr ont hef i
rstBohror bit. mol y bdenum t argetar ef oundt ocont ainal i
ne
ofwav elengt h22. 85nm at tri
butedt otheKαl i
ne
Q.8Ast at i
onar yHe+ i onemi ttedaphot on ofani mpur i
tyel ement .TheKαl inesofcopper
cor respondi ngt oaf irstlineoft heLy man (Z=29)andmol y bdenum ( Z=42)hav e
ser ies.Thephot onl i
ber atedaphot oelect ron wav el engt h15. 42nm and7. 12nm r espect ivel
y.
1/2
f rom ast ationaryHat om i ngr oundst ate.What UsingMosel ey ’
sl aw,v =a( Z–b), cal culate
ist hev eloci tyofphot oelectron? theat omi cnumberoft hei mpur i
tyel ement .
nd
FI
ITJEEPat
naCent
re,
2 f
loor
,SadayBhawan,
Mar
war
iAwasCompl
ex,
FraserRoad,
Pat
na,
Ph.:
0612-
3299798/99,
2205551/52
 (
ii
i)n=4,
l=2,
m =–1,
s=0
Q.
20 Anel ect
ronhasaspeedof40m/ s,accur
ate
upto Q.
30 Fi
ndt
heelect
roni
cconf
igur
atonofFe2+and
i
99.99%.Whatistheuncer
tai
ntyi
nlocati
ngit
s\ 3+ andt
Cr hei
rmagneti
cmoments.
posit
ion?
Q.
31 Howmanymax i
ma’sarefoundi
nradial
Q.
21 Anener gyof68eVi sr equir
edt oex ci
tea
pr
obabi
l
itydi
str
ibut
ioncur
veof7por bit
al?
hydrogenl ikeat om from i tssecondBohror bi
t
tothet hi
rd.Thenucl earchar gei sZe.Findt he
Q.
32 Ni
ckel
atom canl
oset
woel
ect
ronst
ofor
m
valueofZ, t hekineti
cener gyoft heelectr
oni n 2+
Ni
thef i
rstBohror bitandt hewav elengthoft he
i
on.From whi
chor
bit
alwi
l
lni
ckel
loset
wo
radiati
onrequi redtoej ectt heelectronsfrom
el
ectr
ons?
thef i
rstBohror bittoi nfinity.
Q.
33 Fi
ndthesetofdegener at
eorbit
alsamong:
Q.
22 Electr
onpr esentinsi ngleelectronspecie 3dxy, 4dxy , 3dz2,3dyz, 4dyz, 4dz2
jumpsf r
om ener gylev el3to1.Emi t
tedphotons
whenpassedt hroughasampl econt ai
ning Q.34 Aparti
cul
arl
evel
inahydr
ogenatom has
exciedHe+ i
t oncausesf urt
herex cit
ati
onto energy
equalt
o–RH/4.Whati
sthedegener
acyof
somehi gherener gylev el
.Find(i)Atomicno.of thi
s
singl
eelectronspecie. (i
i)pri
ncipalquantum l
evel
?
numberofi niti
alexcitedl ev
el&hi gherenergy
levelofHe+. Q.
35 1gofMgat oms( at
omicmass=24)i nthe
vapour
Q.23 Ani onwit
hmassnumber37possesses1 phaseabsor b50KJofener gy.Fi
ndthe
unitof composi ti
on oft he mixt
ure aft
erthe said
(–)v
echarge.I
ftheioncont
ains11.1%mor
e energyis
neut
ronsthanelectr
ons,
wri
teelect
roni
c absor bed.The f i
rstand second i
onisat
ion
confi
gurat
ionofion. energy
–1 –1
ofMgi s740KJmol and1450KJmol
Q.
24 Howmanyel
ect
ronsi
nanat
om canhav
e respecti
vely
.
n+l=6?
ANSWERS
Q.
25Findt hetotalnumberofspecieshavi
ng 1.( 6) 2.( 4863Å) 3.( 1494.66KJ/ mol)
magnet
ic 4.( 6563Å; 1216Å; 1028Å)
21 21
momentv alueof2.
84B.M.f r
om f ol
l
owi ng 5.i .( 292. 68×10 at oms,162.60×10 at oms),
species. ii
.(832. 50KJ)
Fe2+,Cr, Cr3+ 2+
,Ti , Mn2+, V3+ 6.( h/ π) 7.ii.(340eV, –680eV)
8.(3.09×108cm/ sec) 9.(6.64Å)
Q.
26 Whatisthemaximum numberofel
ect
rons 10.( 298. 35KJ/ mol ) 11.(0.62Å)12.( 3.06V)
22 –4
possi
blei
nNi
+
havi
ngsamespi n? 13.( 10 ) 14.( 28) 15.( 6.03×10 V)
16.(1. 05×10–13m)
Q.
27 TheIEvaluesof 17.( 0. 0826v olt
s) 18.( 4.96×10–7m) 19.
Al
(g)→ Al
+
+e is577. 5kJmol
–1 (24) 20.( 0.0144m) 21.( 6;489.6eV,
and∆Hf or 25.28Å)
Al(
g)→ Al
3+
+3ei s5140kJmol
–1
. 22.(1;f rom 2t o6) 24.( 18) 25.( 2) 26.
I
fsecondandt hirdIEv
al uesar
einther
ati
o (15) 27.( IE2=1825kJ/ mol, I
E3=2737. 5
2:3.Cal
culateIE2andIE3. kJ/mol )
28.( 18)31.( 6) 32.4s 34.(4)
Q.
28Or
bit
alangul
armoment
um ofan 35.( 68. 3% Mg+, 31. 7% Mg+2)
h
elect
roninaparti
cularsubshel
lis 5 ,
π
thenfindthemaximum numberof
elect
ronswhichmaybepr esentinthi
s
subshell
.

Q.
29 Whythegivensetofquant
um number
sar
e
notv
ali
d?
(i
)n=2, l=2,m =2,s=+1/2
(i
i)n=2,l=0,m =1, s=–1/2
nd
FI
ITJEEPat
naCent
re,
2 f
loor
,SadayBhawan,
Mar
war
iAwasCompl
ex,
FraserRoad,
Pat
na,
Ph.:
0612-
3299798/99,
2205551/52