SUBJECT: CHEMISTRY SOLUTION

NAME .. ENROLL NO . BATCH

SECTION-I (ONLY ONE CORRECT)

1. Solute A is a ternary strong electrolyte and solute B is non-electrolyte. If 0.1 M solution of solute B
produces an osmotic pressure of 2P, then 0.05 M solution of A at the same temperature will
produce an osmotic pressure equal to
(A) P (B) 1.5 P
(C) 2 P (D) 3 P
2. Assuming the formation of an ideal
solution, the boiling point of a mixture
containing 1560 g benzene (molar
mass = 78) and 1125 g Chlorobenzene
(molar mass = 112.5) using the given
vapour pressure vs. Temperature
diagram against an external pressure of
1000 torr, is
(A) 90°
(B) 100°C
(C) 110°C
(D) 120°C
3. The coagulation of 200 ml of a positive colloid took place when 0.73 g HCl was added to it without
changing the volume significantly. The flocculation value of HCl for the colloid is
(A) 150 (B) 100
(C) 36.5 (D) 10.0

4. Consider two liquids A and B having pure

vapour pressure PA° and PB° forming an ideal
1 1 1
solution. The plot of v/s (where XA and
XA YA XA
YA are mole fraction of liquid A in liquid and
vapour phase respectively) is linear with slope
and intercepts respectively.
1
YA
PA° P ° − P° PA° P ° − P°
(A) °
and A ° B (B) °
and B ° A
PB PB PB PB
PB° PA° − PB° PB° PB° − PA°
(C) and (D) and
PA° PB° PA° PB°
5. 1.3245 g of a monobasic acid when dissolved in 100 g of water lowers the freezing point by
N
0.2046°C. 0.2 g of the same acid when dissolved and titrated required 15.1 ml of alkall.
10
(Assuming molarity = molality), the pH of acid solution is: ( K f of water 1.86 K kg mol–1)
(A) 1 (B) 2
(C) 3 (D) 4
6. Select the correct statement
(A) The concentration of a dissolved gas depends on the total pressure of gaseous mixture.
(B) The value of Henry’s law constant depends on the solute, the solvent and the temperature
(C) Unit of Henry’s law constant is always at m litre mole
(D) Solubility of a gas in a liquid increases with the increase of temperature

7. 1.0 g of a monobasic acid HB (having pK a = 5 ) in 100 g water lowers the freezing point by 0.155
K. If 0.45 g of same acid required 15 ml M/5 NaOH solution for complete neutralization
 (K f H2O = 1.88k kg mol−1, deensity of H2O is 1g ml−1 ) then which of the following option is
incorrect regarding above question
(A) degree of ionization acid is 25%
(B) the pH of the resultant solution at the end point of neutralization is greater than 7
(C) normal molecular mass of acid is 150
(D) 1.0 g of acid HB is hypotonic with 0.625 g urea at the same temperature and same volume of
H2O

8. For the following equilibrium van’t hoff factor is 0.8

2A ( g ) A 2 ( g)
Hence, volume % of A 2 ( g ) in the total mixture is
(A) 25% (B) 50%
(C) 80% (D) 40%
9. pH of a 0.1 M weak monobasic acid is found to be 2. Hence it’s osmotic pressure at the given
temperature TK is (where S is solution constant)
(A) 1.1 ST (B) 0.1 ST
(C) 0.11 ST (D) 0.01 ST

10. For an ideal solution, osmotic pressure ( π ) is helpful to determine the molecular mass of solute.
Which of the following is correct representation osmotic pressure. Where C is concentration, T is
temperature
(A) (B)

(C) (D)

11. Solute A is a ternary strong electrolyte and solute B is non-electrolyte. If 0.1 M solution of solute B
produces an osmotic pressure of 2P, then 0.05 M solution of A at the same temperature will
produce an osmotic pressure equal to
(A) P (B) 1.5 P
(C) 2 P (D) 3 P

12. Which of the following statements is correct

(A) Composition of an zoetrope and that of the vapour at the boiling point are same.
(B) An azeotrope has both the boiling point and composition quite independent of external
pressure
(C) An azeotrope has a constant boiling point at a given external pressure, so it must be a
compound
(D) An azeotrope has stoichiometric composition
13. A solution of 120 g acetic acid (molar mass = 60 g mol–1) in 2 kg water has the depression of
( )
freezing point to be ∆Tf K. Molal depression constant of water is K f KKgmol−1 . . Ionization
−
constant of CH3 COO ion at 273 K is (Assume molarity to be equal to molality)
 ( ∆Tf − K f )
2

(A) ( ∆Tf − K f ) K f (B)

K12
K w K 2f K 2f
(C) (D)
( ∆Tf − K f ) K w ( ∆Tf − K f )
2 2

14. From the pair of chlorides, select the pair in which both the chlorides are soluble in conc. HCl.
(A) BiOCl, Hg2 Cl2 (B) BiOCl,HgCl2
(C) AgCl,BiOCl (D) FeCl3 ,CuCl2
15. The graph was observed for the solubility of Argon
in 1L water for 1 atmospheric pressure. Find the
ratio of mass of dissolved gas at 27°C to mass to
dissolved gas at 37°C [log2 = 0.3010]
(A) 0.4 (B) 0.8
(C) 0.2 (D) 1.2

16. Select the correct statement

(A) The concentration of a dissolved gas depends on the total pressure of gaseous mixture.
(B) The value of Henry’s law constant depends on the solute, the solvent and the temperature
(C) Unit of Henry’s law constant is always at m litre mole
(D) Solubility of a gas in a liquid increases with the increase of temperature

17. The van’t Hoff factor for 0.1 M Ba(NO3)2 solution is 2.74. The percentage of ionization is?
(A) 91.3% (B) 87%
(C) 100% (D) 74%

18. If 1 molal solution of benzoic acid in benzene has a freezing point depression of 2.4°C,
( ) ( )
K f = 5.12°Cmol−1 kg and boiling point elevation of 2.53°C K b = 2.53º Cmol−1 kg , then select
the correct statement(s);
Statement I: There is dimer formation when undergoes freezing
Statement II: There is no change when undergoes boiling
Statement III: There is no change either during boiling or freezing
Statement IV: Dimer formation in freezing and boiling state both.
(A) I, II (B) II, III
(C) I, III (D) only I
19. 30 ml of 0.1 M Kl (aq) and 10 ml of 0.2 M AgNO3 are mixed. The solution is then filtered out.
Assuming that no change in total volume, the resulting solution will be freezing at
K f for H2 O = 1.86K kg mole −1,assumemolarity = molality 
(A) −0.22º C (B) −0.28º C
(C) −0.149º C (D) −0.074º C

20. During osmosis, flow of water through a semi-permeable membrane is

(A) From both sides of semi-permeable membrane with unequal flow rate
(B) From solution having low concentration only
(C) From solution having high concentration only
(D) From both sides of semi-permeable membrane with equal flow rate.
21. An aqueous solution of glucose ( C6H12 O6 ) contains 1 mole glucose in 1.8 litre solution. Thus,
which is/are true statement(s)?
(A) It is 10% (W/V) solution
(B) Its density is 0.1 gm/cc.
(C) Solution contains 3.33×1018 glucose molecules per ml.
(D) Solution contains 24 gm atoms (as molecule) in 1.8 litre.

22. 20 gm of non-electrolyte, non-volatile solution ( CxH2x Ox ) when dissolved in 100 gm water at

th
 1 
100°C, lowers the vapour pressure of solution by   of the vapour pressure of pure water.
 100 
What is formula of the compound?
(A) C6H12 O6 (B) C12H24 O12
 (C) C44H88 O44 (D) C3H6 O3
23. 250 ml, 0.175 M NaOH is mixed with the equal volume of 0.2 M NiCl2 solution. What is the
freezing point of solution? (Assuming molarity of the solution is same as molality).
(given K sp of Ni ( OH)2 = 1.6 × 10 −14 ; molar mass of Ni is 58.6 and K f of water is 1.86 kg/mol)
(A) –0.76ºC (approx) (B) –0.651ºC (approx)
(C) –0.96ºC (approx) (D) –0.591ºC (approx)

24. The composition of the vapour over a binary ideal solution is determined by the composition of the
liquids. If X1 and Y1 are the mole fractions of one of the component (liq.) of the solution, in liquid
and vapour, respectively. What is the value of X1 , in term of P1º & P2º for which ( Y1 − X1 ) has a
maximum value ( P1º & P2º are the vapour pressure of both the liquids individually).
2P1º 2P2º
(A) X1 = (B) X1 =
P2º − P1º (Pº
2 − P1º )
(C) X1 =
(P 1
º
−P 2)
º 12
−P
º
2
(D) X1 =
P2 ( P1 − 1)
P −P
1
º º
2 (P1 − P2 )
25. Which one of the following statement is false?
(A) Raoult’s law states that vapour pressure of a component over a solution is proportional to its
mole fraction in solution.
(B) The correct order of osmotic pressure for 0.01M aqueous solution of each component is
CaCl2 > NaCl > CH3 COOH > glucos e
(C) The osmotic pressure ( π ) of a solution is given by the relation π = CRT where C is
molarity of solution.
(D) Two glucose solutions of same molality prepared in different solvents will have the same
freezing point depression
26. The amount of oxygen (at 0.2 atm) dissolved in 1dm3 of water at 293 K will be? Henry’s constant
for oxygen is 4.58 × 104 atm at 293 K.
(A) 7.71× 10 −3 g (B) 2.43 × 10 −6 g
(C) 1.24 × 10 −3 g (D) 6.6 × 10 −2 g
27. Which of the following is an example of Raoult’s law
(A) Trees transport water from their roots to their leaves.
(B) Champangne bubbles when opened to the atmosphere
(C) Light reflect off a mirror (metallic surface) to provide a nearly perfect reflection
(D) Salt lakes evaporate more slowly than fresh water lakes.
28. ( )
20 g of naphthoic acid ( C11H8 O2 ) dissolved in 50 g of benzene K f = 1.72 K kg mol−1 shows a
depression in freezing point of 2K. The van’t Hoff factor is
(A) 0.5 (B) 0.1
(C) 2 (D) 3
29. pH of a 0.1 M monobasic acid is measured to be 2. Its osmotic pressure at a given temperature
TK is
(A) 0.1 RT (B) 0.11 RT
(C) 1.1 RT (D) 0.01 RT

30. Which statement(s) is/are correct:

P ∆Hvap [ T2 − T1 ]
(A) 2.303log 2 = is Clausius Calpeyron equation
P1 R T1T2
∆Hvap
(B) = 88 is called Trouton’s rule
Boilingpoint
(C) Entropy is measure of unavoidable energy i.e. unavoidable energy = entropy ×
temperature
(D) All of the above

SECTION-II (ONE OR MORE THAN ONE)

1. Addition of 10 gram of a substance in 100 gram CCl4 (mol wt. = 154) increases the boiling point of
CCl4 by 0.6°C. If K b and K f of CCl4 are 5 K kg mol−1 and 32 K kg mol–1 respectively, then
select the correct statement of the following
 (A) mol. Wt. of substance = 833.33 g mol–1
(B) depression in freezing point of the solution is 3.84°C
(C) osmotic pressure of the solution at 300 K is 2.95 atm is molarity is assumed to be equal to
molality
(D) relative lowering of V.P. is approximately equal to 0.018

2. For the depression of freezing point experiment with non-volatile solute, the correct statement(s)
is/are
(A) vapour pressure of pure solvent is more than that of solution
(B) vapour pressure of pure solvent is less than that of solution
(C) only solute molecules solidify at the freezing point
(D) only solvent molecules solidify at the freezing point

3. 0.1 M each of aqueous solution of KCNS and FeCl3 are separated by means of a semipermeable
membrane. Which of the following statements pertaining to the system are correct
(A) No osmosis occurs in either direction.
(B) Osmosis occurs from KCNS solution towards FeCl3 side.
(C) Red colouration will develope on FeCl3 side.
(D) Vapour pressure on KCNS side is greater than that on FeCl3 side.

4. Select the correct statement among the following

(A) Sugar containing solution freezes at a lower temperature than pure water
(B) Boiling point of impure AcOH is always greater than that of the pure AcOH
( ) ( )
(C) If the total vapour pressure of mixture of 1 mol X Px° = 150 torr and 2 mol Y PY° = 300 torr is
240 torr than it will from minimum boiling point azeotrope.
(D) When HgSO4 is added to the aqueous solution of KI then freezing point is raised.

5. Addition of 10 gram of a substance in 100 gram CCl4 (mol wt. = 154) increases the boiling point of
CCl4 by 0.6°C. If K b and K f of CCl4 are 5 K kg mol−1 and 32 K kg mol–1 respectively, then
select the correct statement of the following
(A) mol. Wt. of substance = 833.33 g mol–1
(B) depression in freezing point of the solution is 3.84°C
(C) osmotic pressure of the solution at 300 K is 2.95 atm is molarity is assumed to be equal to
molality
(D) relative lowering of V.P. is approximately equal to 0.018

SECTION-III (ASSERTION & REASONING)

1. STATEMENT-1: Azeotropic mixtures are formed only by non-ideal solution
and
STATEMENT-2: Bolling point of an Azeotrope is either higher than both the components or lower
than both are component.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for
Statement-1
(B) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for
Statement-1.
(C) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True

SECTION-IV (PARAGRAPH-I)

A solution containing 1 mole of solute ‘X’ in 1 kg of a solvent (molal depression constant Kf) gives the
depression of freezing point ∆Tf . The solute undergoes association as follows:
3X X3
The degree of association ' α ' of solute is given by the following expression
1− i
α=
1
1−
n
Where ‘i’ the vant’ Hoff factor and ‘n’ is the number of molecules of solute giving rise to 1 molecules of the
association product.
Answer the following question

1. The degree of association can be given by

2 (K f − ∆Tf ) ∆Tf
(A) α = (B) α =
Kf 3K f
K f − ∆Tf 3 (K f − ∆Tf )
(C) α = (D)
3 ∆Tf 2K f
2. van’t Hoff factor for solute in the given solvent is
(A) i = 1 − 3α (B) i = 1 + 3α
2 3
(C) i = 1 − α (D) i = 1 − α
3 2

PARAGRAPH-II
In 1180 Van’t introduce a factor I, known as the Van’t Hoff factor, to account for the extent of dissociation
or association. This factor is defined as
Normalmolar mass
I=
Abnormalmolar mass
observedcolligativeproperty
=
Calculatedcolligativeproperty
Totalnumber of molesparticlesafter association / dissocation
=
Number of moles of particlesbefore association / dissociation
Here abnormal molar mass is the experimentally determined molar mass and calculated colligative
properties are obtained by assuming that the non-volatile solute is neither associated nor dissociated. In
case of association, value of i is less than unity while for dissociation it is greater than unity.

4. The ratio of the value of any colligative property for KCl solution to that of sugar solution is nearly
(A) 1 (B) 0.5
(C) 2 (D) 2.5
5. The Van’t Hoff factor for 0.1 M Ba (NO3 )2 solution is 2.74. The degree of dissociation is
(A) 91.3% (B) 74%
(C) 87% (D) 100%
6. The percentage dissociation of a 0.011 m aqueous solution of K 3 Fe ( CN)5  which freezes at
0.063°C is (Kf for water = 1.86)
(A) 75% (B) 67%
(C) 33% (D) 50%

PARAGRAPH-III
The vapour pressure of pure benzene and toluene are 0.12 bar and 0.04 bar, respectively at 300 K. A
liquid mixture composed of 1 mole, each of benzene and toluene.
7. If the pressure over the mixture at 300 K is reduced, at what pressure does the first vapour form
(A) 0.16 bar (B) 0.08 bar
(C) 0.10 bar (D) 0.09 bar

8. What is mole fraction of benzene in first trace of vapour formed

(A) 0.50 (B) 0.67
(C) 0.75 (D) 0.89

9. What is mole fraction of benzene in last trace of liquid

(A) 0.50 (B) 0.67
(C) 0.75 (D) 0.25
9. D

PARAGRAPH-IV
A non-volatile hydrocarbon has 5.6% hydrogen. When 3.0 gm of hydrocarbon is dissolved in 100 gm of
benzene the relative lowering in vapour pressure of benzene is 1.306 × 10–2 Nm–2
10. What is the molar mass of hydrocarbon?
(A) 156.71 (B) 176.83
(C) 125.28 (D) 135.5
11. Molecular formula of hydrocarbon is
(A) C7H5 (B) C3H2
(C) C14H10 (D) C15H10
PARAGRAPH-V
When a solution inside the bulb is separated from pure solvent in a beaker by a semipermeable
membrane. Net passage of solvent from the beaker through membrane occurs and the liquid in the tube
rises until an equilibrium is reached. At equilibrium, pressure exerted by the column of liquid in the tube is
sufficient to prevent further net passage of solvent. The pressure called osmotic pressure. It depends on
the concentration of solute particles in the solution. Thus, it is a colligative property. The osmotic pressure
is given as
π = i.C.S.T
Where π is osmotic pressure, C is molar concentration, S is equal to R (gas constant), T is absolute
temperature, ‘i’ is van’t Hoff factor.

12. At what pressure, the red blood cell when placed in water will burst. The concentration of
dissolved particles in red blood cells is 0.3 M at 298K.
(A) 3.65 atm (B) 4.87 atm
(C) 10.95 atm (D) 7.3 atm
13. Sea water has the composition 0.47 M NaCl and 0.068 M MgCl2 and both are completely
dissociated what is the osmotic pressure of sea water at 25°C?
(A) 13.16 atm (B) 26.3 atm
(C) 28 atm (D) 24.66 atm
14. If the reverse osmotic equipment can exert a maximum pressure of 100 atm at 25°C, what is the
maximum volume of fresh water than can be obtained from 1 L of sea water?
(A) 0.74 L (B) 0.87 L
(C) 0.26 L (D) 0.13 L
SECTION-V (MATRIX MATCH)
1. Match Column I with Column II
Column-I Column-II

Vapour pressure of binary solution of

two miscible and volatile liquids PAº − P
(A) (containing 1 mole of each) when half of (p) = χB
the liquid solution goes into vapour PAo
phase
Vapour pressure of two binary miscible
(B) (q) PAº + PBº
and volatile liquids

(C)
Vapour pressure of binary solution of
two immiscible and volatile liquids
(r) (P º
A )
− PBº χ A − PBº

Vapour pressure of binary solution

(D) (s) PAº PBº
having non-volatile solute
(t) Solution is ideal

SECTION-VI (INTEGER)
1. 1.2 kg of ethylene glycol was added to 9 litre water contained in a vessel. The solution is just
prevented from freezing at –4°C. Due to a sudden drop in temperature to –6°C, what will be the
mass of ice separated out in kilograms. K f H2 O = 1.86K Kg mol−1. (Assume the density of water
does not change)

Integer Answer Type

2. 1.2 kg of ethylene glycol was added to 9 litre water contained in a vessel. The solution is just
prevented from freezing at –4°C. Due to a sudden drop in temperature to –6°C, what will be the
mass of ice separated out in kilograms. K f H2 O = 1.86K Kg mol−1. (Assume the density of water
does not change)
3. (
When 20 g of naphthenic acid ( C11H8 O2 ) is dissolved in 50 g of benzene K f = 1.72kg mol−1 , )
°
van’t Hoff factor (i) is 0.5. What is the depression in freezing point in K .

4. To 250 ml of water, x g of acetic acid is added. If 11.5% of acetic acid is dissociated, the
depression in freezing point comes out 0.416. What will be the value of x if K f (water) = 1.86K
kg−1 mol−1 and density of water is 0.977 g ml−1.

5. A mixture of two immiscible liquids nitrobenzene and water boiling at 99°C has a partial vapour
pressure of water 733 and that of nitrobenzene 27 min. What is the ratio of the mass of
nitrobenzene to the water in distillate nearly?
6. A 0.4 molal aq. Solution of Na x A has freezing point of –3.27ºC. If Kf of water is 1.86 K. Kg mol–1.
The value of x is. (Assume complete ionization salt NaxA).

ANSWER

SINGLE CORRECT
1. D 7. D 13. C 19. B 25. D
2. B 8. A 14. C 20. A 26.
3. B 9. C 15. B 21. A 27. D
4. B 10. A 16. B 22. B 28. A
5. B 11. D 17. B 23. B 29. B
6. B 12. A 18. A 24. C 30. D

ONE OR MORE TAN ONE

1. A,B,C,D
2. A,D
3. B,D
4. AD
5. A,B,C,D
ASSERTION REASON
1 B
PARAGRAPH
1. D 9. D
2. C 10. B
4. C 11. C
5. C 12. D
6. B 13. C
7. B 14. A
8. C
MATRIX MATCH
1. A→s,t; B→r,t; C→q; D→p,t
INTEGER
1 3 2 3 3. 2 4. 3 5. 4 6. 4

SOLUTIONS

SINGLE CORRECT
1. D
For ternary electrolyte
P1 = CST = 0.05 × 3 × S × T;
For B; 2P = 0.1× S × T;
∴ P1 = 3P
2. B
1560 78 2 1
χbenzene = = , χchlorobenzene =
1560 78 + 1125 112.5 3 3
At boiling point, vapour pressure of solution should be 1000 torr.
At 100°C, from the graph
1
pchlorobenzene = 250 × torr
3
2
Also, pbenzene = × 1300
3
250 2600
∴ Total vapour of solution at 100°C = + = 950 torr, (closest to 1000 torr)
3 3
3. B
200 ml of the sol require = 0.73 g HCl
0.73
= mol = 200millimole
36.5
20
So 100 ml of sol will required = × 1000 = 100mmole
200
4. B
XA PA°
YA =
(
XA PA° − PB° + PB°)
° °
1 P −P P° 1
⇒ = °
+ B° ⋅
A B

YA PA PA XA
1 P° − P° P° 1
⇒ = B ° A + A° ⋅
XA PB PB YA
5. B
Meq. of alkali = Meq. of acid
1 0.2
⇒ 15.1× = × 1000
10 M
On, solving M = 132.45 g mol–1
 1.3245 × 1000
Now, molality of acid solution (m) = = 0.1
132.45 × 100
∴ ∆Tf = 1× K f × m
0.2048 = 1× 1.66 × 0.1
I = 1.1 = 1 + α
∴ α = 0.1
HA H+ + A−
Now,C 0 0
C − Cα C − Cα Cα
H+  = Cα = 0.1× 0.1 = 10 −2
∴ pH = 2
6. B
(i) According to Henry’s law at constant temperature, concentration of dissolved gas depends on
the partial pressure of gas.
(ii) Solubility of gas in a liquid decreases with the increase of temperature
7. D
∆Tf = K f M
(Macid )observed = 120
Meq of acid = Meq of base
(Macid )normal = 150
150
i= = 1.25
120
i = 1+ α
α = 25%
pH > 7 as the solution contains salt or strong base and weak acid.
Osmotic pressure is same by calculation.
8. A
2A ( g ) A 2 ( g)
1− α α 2
α
1− α +
i= 2 = 1− α
1 2
α
0.8 = 1 − ; α = 0.4
2
2A ( g ) A 2 ( g)
1 − 0.4 0.4 2
0.2
% Volume of A 2 = × 100% = 25%
0.2 + 0.6
9. C
10 −2
Cα = 10 −2 , α = = 0.1
0.1
i = 1 + α = 1.1
π = iCST
= 1.1× 0.1× ST = 0.11ST
10. A
n
π =   RT
V
11. D
For ternary electrolyte
P1 = CST = 0.05 × 3 × S × T;
For B; 2P = 0.1× S × T;
∴ P1 = 3P
12. A
13. C
CH3 COOH + H2O CH3 COO− + H3 O+
1−α α α

If degree of ionisation of CH3 COOH is α near the freezing point of water, then
Van’t Hoff factor of acid = 1 – α + 2α
i=1+α
120
Molality of acid = = 1mol kg−1
60 × 2
Effective molality = i.m = (1 + α ) × 1
∆Tf = K f × i m = (1 + α ) K f
∆Tf − K f
⇒α=
Kf
Cα 2
Ionisation constant of CH3 COOHK a = ≈ α 2 ( as c = 1mol / L )
1− α
2
 ∆T − K f 
Ka =  f 
 Kf 
Ionisation constant of conjugate base ( CH3 COO− ) of the acid
Kw K w K 2f
Kb = =
K a ( ∆Tf − K f )2
14. C
[ AgCl2 ]
−
AgCl + Cl−
Soluble Complex

BiOCl + 2HCl BiCl3 + H2O

Solub le

15. B
From the Henry’s law, solubility ∝ pressure
∴x ∝ P
x = kP
Since pressure is constant
at T1,
at T2
x1 k 1
∴ =
x2 k2
If mass of dissolved gas is m.
m1 x1 k1
∴ = =
m2 x 2 k 2
Solubility constant k varies with temperature as
∆H
lnk = cons tan t −
RT
−∆H
Slope = = −1.804 × 103
R
∆H
∴ = 1.804 × 103
R
at T1 & T2 ( T1 = 300, T2 = 310 )
k2 ∆H  1 1 
log =  − 
k1 2.303  T1 T2 
k 1.804 × 103  1 1 
log 2 = − = 0.0842
k1 2.303  300 301
k2 m
=10 0.0842 ⇒ 2 =10 0.0842 ≈ 0.8
k1 m1
16. B
 (i) According to Henry’s law at constant temperature, concentration of dissolved gas depends on
the partial pressure of gas.
(ii) Solubility of gas in a liquid decreases with the increase of temperature
17. B
i = 1 + ( n − 1) α
2.74 = 1 + ( 3 − 1) α
∴ α = 0.87
18. A
During freezing, i ≈ 0.5; follows demonization
During boiling, i = 1; follows no change
19. B
KI + AgNO3  → KNO3 + Agl ↓
Initial : 3mmoles 2mmoles 0 0
Final : 1 0 2 2
1
Kl in solution = M
40
2
KNO3 in solution = M
40
∆Tf = ∆Tf ( by Kl ) + ∆Tf ( by KNO3 )
1 2
= 1.86 × × ( 2 ) + 1.86 × ×2
40 40
≈ 0.28
20. A
Osmosis is a bilateral process involving moment of solvent particles through SPM and only net
flow (more from dilute solution to conc. solution) is notice.
21. A
w weight of soluteingm
% = × 100
v volume of solutioninml
180
= × 100 = 10%
1.8 × 1000
weight of solution
Density =
volume of solution
1.8 litre solution has 1 mole of glucose as well as some moles of water
22. B
P0 − p 1 n
0
= = s
P 100 nw
20
= M
100
18
1 18
⇒ =
100 5M
18
⇒M = × 100 = 360
5
CxH2x O x = ( CH2 X ) x
30 x
30x = 360
x = 12
∴ C12H24 O12
23. B
no.of moles(initially) 0.0438 0.05 − −
after reaction 0 0.0281 0.0219 0.0438
 [OH] & Ni2+  obtained from Ni ( OH)2 are negligible as K sp of Ni ( OH)2 is very less. Hence total
ion concentration = [Cl] + Na +  + Ni2+  ≈ 0.35M.
Hence ∆Tf = 1.86 × 0.35
= 0.651
Freezing point of aqueous solution n= – 0.651°C
24. C
PT = P1º X1 + P2º + P2º X 2
Aslo P1 = P1º X2 = Y2PT
P2 = P2º X2 = Y2PT
PTº P2º X2
i.e Y1 = .X1; Y2 =
PT PT
P1º X1
So, PT =
Y1
25. D
26.
27. D
Due to elevation in boiling point on addition of non-volatile solute in a volatile solven
28. A
20 1000 400
∆Tf = iK f m, m = × =
172 50 172
∆Tf 2
i= =
Kf × m 400
1.72 ×
172
i = 0.5

29. B
HA H+ + A−
t=0 C 0 0
t eq C (1 − α ) Cα Cα
+ + − pH
H  = Cα H  = 10
∴ Cα = 10 −2
a = 0.1
i −1 i −1
α= , 0,1 =
n −1 2 −1
i = 1.1
π = iCRT = 1.1× 0.1RT = 0.11RT
30. D

ONE OR MORE TAN ONE

1. A,B,C,D
∆Tb = ixm xK b
0.60
∴ ixm = = 0.12mol kg
5
10 × 1000
(A) 0.12 = ∴ mB = 833.33 g mol−1
mB × 100
(B) ∆Tf = i × m × K f = 0.12 × 32 = 3.84°C
(C) π = ICRT
= lmRT
= 0.12 × 0.0821×300 = 2.95 atm
2. A,D
3. B,D
4. AD
(C) there is devation from Raoult’s law. If ideal: Ptotal would beb 275
 (D) KI + Hg22 + → Hg ↓ +HgI2 ↓
5. A,B,C,D
∆Tb = ixm xK b
0.60
∴ ixm = = 0.12mol kg
5
10 × 1000
(A) 0.12 = ∴ mB = 833.33 g mol−1
mB × 100
(B) ∆Tf = i × m × K f = 0.12 × 32 = 3.84°C
(C) π = ICRT
= lmRT
= 0.12 × 0.0821×300 = 2.95 atm

PARAGRAPH
1. D
Molality m = 1; n = 3
 2 
∆Tf = K f 1 − α  × 1
 3 
3 (K f − ∆Tf )
⇒α=
2K f
2. C
4. C
For KCl, i = 2
KCl → K + + Cl−
While for sugar which is non-electrolyte, i = 1. Ratio of any colligative property for KCl and
sugar solution depends upon the value of i, hence it will be.
5. C
l −1
Degree of dissociation, α =
n −1
‘n’ is the number of ions produced from one molecule
2.74 − 1 1.74
α= = = 0.87
3 −1 2
∴ Degree of dissociation = 87%
6. B
∆Tf = m × K f = 0.011× 1.86 = 0.021
∆Tf ( Calculated ) = 0.021°C
∆Tf ( observed ) = 0.063°C ( given )
observed ∆Tf 0.063
i= = =3
calculated ∆Tf 0.021
i −1
Degree of dissociation, α =
n −1
3−
K 3 Fe ( CN)6  3K + + Fe ( CN)6 
Thus, n = 4
3 −1
α= = 0.87
4 −1
7. B
8. C
7-9. Benzene and toluene form a ideal binary mixture which follow Rauoult’s law.
°
PBenzene = 0.12
°
PToluene = 0.04
PT = X A PA° + XBPB°
= 0.5 × 0.12 + 0.5 × 0.04
0.08 + 0.02
PT = 0.08
8 & 9 The ratio of mole fraction in initial vapours will be in ratio of their partial pressures as their mole
fraction are equal initially
10. B
11. C
Pº −Ps wm
=
Pº ( w m ) + ( w M)
m = molar mass of solvent
M = Molar mass of solvent
3m
1.306 × 10 −2 =
100
(3 m) +
78
∴ m = 176.83
For empirical formula

Element % Molar Mass %M Simple ration

C 94.5 12 7.88 1.40 7
H 5.6 1 5.60 1 ×5=
5
∴ m = 176.83
molar mass 176.83
n= = =2
empirical formula 89
∴ molecular formula = C14H10
12. D
π = C.S.T. = 0.3 × 0.0821× 298 = 7.34 atm
13. C
π = ( 0.47 × 2 + 0.068 × 3 ) × 0.0821× 298 = 28atm
14. A
Since volume of water is 1L, moles of NaCl is 0.47 and MgCl2 is 0.068 and let V is the volume of
sea water present at a pressure of 100 atm.
( 0.47 × 2 + 0.068 × 3 ) × 0.0821× 298
∴ 100 = = 0.26L
V
∴ Volume of fresh water = 1 –0.26 = 0.74 L

INTEGER
1 3
At –6°C, calculate the amount of water present. The difference in mass of water initially and finally
is the mass of ice separated out.
1.2 × 1000
∆Tf = K f .m ⇒ 6 = 1.86 ×
62 × WH2 O
⇒ WH2O = 6kg
∴ Mass of ice separated out = 9 –6 = 3 kg
2 3
At –6°C, calculate the amount of water present. The difference in mass of water initially and finally
is the mass of ice separated out.
1.2 × 1000
∆Tf = K f .m ⇒ 6 = 1.86 ×
62 × WH2 O
⇒ WH2O = 6kg
∴ Mass of ice separated out = 9 –6 = 3 kg
3. 2
4. 3
i −1
α = 0.115 α=
n +1
So, I = 1.115
∆Tf = i × m × K f
x × 1000 × 1.86
0.416 = 1.115 ×
60 × 249.25
 0.416 × 60 × 249.25
x= = 3g
1.115 × 1000 × 1.86
5. 4
Partial P = PT × X A in gaseous state.
w 2 123
27 = 760.
w1 w 2
+
18 123
w 1 18
733 = 760.
w1 w 2
+
18 123
w
∴ 1 =4
w2
6. 4