SOLUTIONS & ANSWERS FOR AIEEE-2011 [11-05-2011]

VERSION – A
PART A − CHEMISTRY 10. Ans: 2–Methyl–2–pentene

1. Ans: Ozone absorbs infrared radiation CH3 C CH CH2 CH3

Sol:
Sol: Ozone does not absorb I.R radiation CH3
ozonolysis
1
2. Ans: (PA / PB ) (MB / MA ) 2 O

CH3 + CH3 CH2 CHO

1 CH3 C
Sol: rA α PA
MA 11. Ans: –219 kJ
rA PA MB
= Sol: ∆rH = –111 –2 × 54 kJ
rB PB MA = –219 kJ

1 × 10
–10
3. Ans: RS( − ) is less basic but more nucleophilic 12. Ans:

than RO( − ) Sol: [H ] = Cα

+

α = 10
–5

Sol: Since RSH is more acidic than ROH, Ka = Cα = 10

2 –10

RS( − ) will be less basic than RO( − ) .

Since the negative charge on sulphur is 13. Ans: Cl > F > Br > I
more polarisable, RS( − ) is more
Sol: The electron gain enthalpies of I, Br, F &
nucleophilic than RO( − )
–1
Cl are –295, –325, –328 & –349 kJ mol

4. Ans: mutarotation 14. Ans: n = 2 to n = 1

Sol: It is the definition of mutarotation Sol: At. no. of H = 1 and He = 2

+
For He n = 4 to n = 2
5.55 × 10
–4
5. Ans: m 4 2
For H n= to n =
2 2
0.01
= 5.55 × 10 m
–4
Sol: m=
60 × 0.3 15. Ans: 68.4

6. Ans: directly proportional to square root of 5 1

Sol: =
temperature 342 w
w = 68.4
T
Sol: Vα 16. Ans: For lead +2, for tin +4
M
+2 +4
Sol: Pb is more stable than Pb , since
7. Ans: D>C>A>B ∆r G° is negative.
+4 +2
Sol: p–nitrophenol is the most acidic among Sn is more stable than Sn , since
the given phenols. ∆r G° is positive.

8. Ans: –1364.0 kJ
17. Ans: 4 1.6 × 10−30 / 27
Sol: ∆H = ∆U + ∆nRT
4
–1366.5 = ∆H – 8.314 × 10 × 300
–3
Sol: Ksp = 27S
∆H = –1364 kJ K sp
S= 4
9. Ans: HCHO 27

Sol: The monomers of bakelite are phenol and 18. Ans: Li2O + NO2 + O2
formaldehyde.
Sol: 4LiNO3 → 2Li2O + 4NO2 + O2
 6.25 × 10
–4 2 –1
19. Ans: S m mol 27. Ans: Oxide ion accepts sharing in a pair of
electrons
l
Sol: K=C× Sol:
2– –
O becomes OH by sharing a pair of
a
2 electrons between hydrogen & oxygen.
l
= 1.3 × 50 S m
–1
a 28. Ans: XeF2
−3
l 10
∧=C× × Sol: Compound Lone pairs
a M XeF4 2
1 10 −3 XeF6 1
= × 1.3 × 50 × XeF2 3
260 0. 4
XeO3 1
= 6.25 × 10 S m mol
–4 2 –1

– 29. Ans: Benzene diazonium chloride and

20. Ans: NH3 < en < CN < CO
benzonitrile
Sol: The correct increasing order of field
strength for the ligands is + −
– Sol: A : C6H5 N2 Cl
NH3 < en < CN < CO
B : C6H5 – CN
21. Ans: Acetylene 3+
30. Ans: [Co(NH3)2(en)2]
Sol: Acetylene is not formed by treating 3+
Sol: [Co(NH3)2(en)2] exists in cis & trans
ethanol with con.H2SO4.
isomers.

22. Ans: PART B − PHYSICS

1
31. Ans:
Sol: Cyclopentadiene is not aromatic. t

23. Ans: One sigma, two pi Sol: u = 0 at t = 0

1
mv 2 = kt
− − 2
C ≡ C
2+
Sol: Ca
2kt
⇒ v2 = , k = +ve constant
Ea1 m
24. Ans: k1 = A k 2 − e RT 2kt
⇒ v=
m
Sol: k1 = A1e −Ea1 / RT a=
dv
=
B
⇒ F = ma ∝
1
dt
k2 = A 2e −Ea 2 / RT
E t

Ea2 − Ea1 32. Ans: 2:1

k1 A
= 1 −e RT
k2 A2 Sol: ΙP = 4 Ι
Ea1 ΙQ = Ι + Ι + 2Ι cos90°
k1 = A k 2 − e RT = 2Ι
Ι 4Ι
∴ P = =2:1
25. Ans: 128 pm ΙQ 2Ι
λ
Sol: 2 a = 4r (Path difference
4
2 × 361 π
r= = 128 pm = phase difference rad)
4 2

26. Ans: 22.05 g

GM
33. Ans:
4R
Cr2O72− + 6Fe → Cr
2+ 3+ 3+
Sol: + Fe
3
75 750 cm
mv 2 Gm2
m.mols 0.6 M Sol: =
Wt. of potassium dichromate = 75 × 0.294 R 4 R2
= 22.05 g
 32 T 3
dT (kJ)
GM 100
v= w.r.t centre of circle, which also = − ×
4R 1000 (400 )3
is centre of mass of system. 1 32
Centre of mass of system is at rest. = − × T3 dT
10 64 × 106
1
= −
3
34. Ans: 3 T dT (kJ)
2 × 10 7

Sol: It is assumed that F1 and F2 are applied 4K 4 20

− T3dT T4
parallel to the plane.
F1 = mg sinθ + µmg cosθ
∴Q= dQ = ∫
2 × 10 7 ∫
kJ = 7

8 × 10  4
20 K 20
F2 = mg sinθ − µmg cosθ
F1 tan θ + µ 2µ + µ 3
= = = =
[20 4
− 44 ] kJ = 19968 × 10
kJ −7

F2 tan θ − µ 2µ − µ 1 8 × 10 7

= 0.0019968 kJ
35. Ans: 20% Q T2 Q(T1 − T2 )
COP = = ⇒W=
W (T1 − T2 ) T2
0.0019968 × (300 − 4 )
Sol: R = 4 R1
∆R ∆R1 W max =
=4 4
R R1
= 0.148 kJ
= 4 × 5 = 20%
0.0019968 × (300 − 20 )
W min =
36. Ans: 11q 20
= 0.028 kJ
Sol: F = qE + q v × B ( )
= (3q î + q ĵ + 2qk̂ ) 40. Ans: 2π
λd

+ q(3 î + 4 ĵ + k̂ )(î + ĵ − 3k̂ )

ρg

[F = qĵ + (9qĵ + qĵ)] = 11qĵ

y Sol: m=λ d
3

∆F = −λ ρgx
2

∆F −ρgx
37. Ans: 0.1 V m−
1 ∴a= =
m λd
ρg
ρλ ⇒ω =
2
Sol: R= ; V = iR λd
A
iρλ V iρ 2π λd
V= ⇒ = T= = 2π
A λ A ω ρg
V 0.2 × 4 × 10 −7
∴ =
λ 8 × 10 −7 41. Ans:
P
,T
= 0.1 V m− 2
1

3 mv 3 Sol: There is no heat loss and no work is done

38. Ans: ⇒ U is same ⇒ T is same.
16 g
P
V ⇒ 2 V, so P ⇒ for T to be same
2
3v
Sol: vH = v cos30° = (Θ PV = constant for T to be constant)
2
P
∴ , T is the final state.
3 2
p = mvH = mv
2
v 2 sin2 30° v 2 42. Ans: 2
Hmax = =
2g 8g
Sol: Ι1 = 4Ι, for coherent light
3 mv 3 Ι2 = Ι + Ι = 2Ι for incoherent light
∴ LH = p Hmax =
16 g Ι 4Ι
∴ 1 = =2
Ι 2 2Ι
39. Ans: between 0.148 kJ and 0.028 kJ

Sol: dQ = −mS dT
43. Ans: NOR gate  1  1 
=  1 − h1 +  1 − h2

Sol: Becomes combination of OR gate and  µ1   µ2 
NOT gate
⇒ NOR gate 47. Ans: Y∝t

1 2qQ  1  Sol: Thermal stress = Y ∝ t

44. Ans: 1 − 
4 πε0 a  5
48. Ans: A standing wave having nodes at
 1 λ
Sol: x =  n +  , (n = 0, 1, 2, …..)
2a  2 2
−q −q

Sol: y1 = A sin (ωt − kx)

2a •B
y2 = A sin (ωt + kx)
y = y1 + y2
+q • +q
A = A [2 sinωt cos(−kx)]
= 2 A cos kx sinωt ⇒ standing wave;
2q 2q 2q  1  2π
VA = − = 1 −  k= Nodes are at
4πε0a 4 πε0 5 a 4πε0a  5 λ
2qQ  1   1 λ
∴ U1 = x =  n +  , (n = 0, 1, 2, …..)
1 −  ; VB = 0 ⇒ U2 = 0  2 2
4πε0  5
2qQ  1 
∴ KE2 = ∆U = U1 = 1 −  πR 4
4πε0a  5 49. Ans: σω
4

45. Ans: 2.5 second Sol: dq = (2πrdr)σ for an elemental ring of

radius r and width dr.
Sol:
di = (dq)f =
(dq)ω = ωrσdr
2π
dM = πr di = πωσr dr
2 3

R
πωσR 4
∴M= ∫ dM = 4
0

τP = RC’ = 2 RC 50. Ans: 28.9 cc

t
−
τP Sol: ∆V = V0γ∆θ
V = V0e
10 = V0 [3 ∝ ∆θ]
−
1 π
= D3 [3 ∝ ∆θ]
τP
⇒ =e
2 6
−10 π
⇒ −λn 2 = = × 203 [3 × 23 × 10− × 100]
6
τP 6
−10 10 = 28.9 cm
3
⇒ τP = = = 2 RC
− λn2 λn2
2 πr T
8/3 2
RC 2 RC 5 51. Ans:
τS = RC’’ = = =
2 4 2λn2
1/3
−
t Sol: R=2 r
1 τS t × 2λn2 2
⇒ =e ⇒ −λn2 = − E = 4πR T
2 5 2 2/3 2
= 2 .π.2 .r T
5 = 2 πr T
8/3 2
⇒t= = 2.5 s ⇒ t = 2.5 second
2
6.25 × 10− cm s−
4 1
52. Ans:
 1  1 
46. Ans:  1 − h1 +  1 − 
 µ   µ h2
 1  2 2r 2g(ρ − σ )
Sol: v=
9η
Sol: S = S1 + S2
 v 2 η1 (7.8 − 1.2 ) 59. Ans: Statement – 1 is true, statement – 2 is
=
v1 η2 (7.8 − 1.0 ) true, statement – 2 is the correct
explanation of statement – 1.
η1 6.6
⇒ v2 = v1 ×
η2 6.8 Sol: Statement – 1 is true, statement – 2 is true
−4 and explain 1.
10 × 8.5 × 10 6 .6
× = 6.25 × 10− cm s−
4 1
=
13.2 6 .8 60. Ans: Statement – 1 is true, statement – 2 is
true, statement – 2 is not the correct
53. Ans: 3 mV explanation of statement – 1.

Sol: λ = 20 m Sol: Statement – 1 is correct. Statement 2 is

v = 5 m s−
1
correct but doest not explain 1.
Bh = 0.3 × 10− Wb m−
4 2

E = Bh vλ PART C − MATHEMATICS
= 0.3 × 10− × 5 × 20 = 0.3 × 10− V
4 2

= 3 mV 61. Ans: Statement-1 is true, Statement-2 is true;

statement-2 is a correct explanation for
54. Ans: λ statement-1.

f(x) = f− (x), this point lies on f(x) = x

1
Sol: Considering the nucleus to be at rest Sol:
initially, total linear momentum = zero for ⇔ f(x) = x
(x − 1) + 1 = x ⇒ x − 3x + 2 = 0
2 2
system
⇒ x = 1, 2
⇒ p of m1 and p of 5 m, are equal in
Statement-1 is true
magnitude but opposite in direction.
f(x) is a bijection and f− (x) = 1 + x −1
1
h
λ = = same for both
p Statement 2 is true
and Statement-1 follows from Statement-2
55. Ans: To reduce the time lag between
transmission and reception of the
information signal. f(x)

5
56. Ans: k
2

1 1
Sol: k∝ ∝
N λ 62. Ans: H
⇒ kλ = constant
kA λA = kλ ω 0 
kλ 5λ 5k Sol: H=   = ωI
⇒ kA = =k =  0 ω
λA 2λ 2
∴ H = ω I = ωI = H
70 70

57. Ans: Statement – 1 is correct, statement – 2 is 3

63. Ans:
correct and statement – 2 is not the correct 4
explanation of statement-1.
Sol:
Sol: Statement – 1 is correct as energy of
∫ [ ]
1.5 1 2 1.5
antineutrino is negligible.
Statement – 2 is also correct but does not
∫
x x 2 dx = x × 0 dx + ∫ x dx + ∫ 2x + dx
0 0 1 2
explain-1. 2 1.5
x 2
= 1 + x2
2 2
58. Ans: Increase
1
= + 2.25 − 2
Sol: 2
δr 3
δv =
4
fv fr

fr > fv
64. Ans: y=
6 ⇒ λ = − 10
4 ∴ p(− 9, −15, − 1)
∴ distance = 10 3
Sol:
B ρ
69. Ans: 0

Sol: (a + 3b) + 6c = (k1 + 6) c = (1 + 3k2)a

P(x1, y1)
C & a are non − collinear
∴ coefficients are zero
a + 3b + 6c = 0
A
70. Ans: 2x + 3y =1
Let m be the slope of taught at P(x1, y1)
∴ Equation of AB is Sol: Let (x, y) be coordinates of centroid
y − y1 = m(x − x1) 2 − 2 + x3 −3 + 1 + y 3
x= y=
− y1 3 3
∴ A is (0 y1 − mx1) and B is (x1 , 8)
m x3 2 − y3
= =
∴ and point of AB (x1, y1) 3 3
y dx dy x3 = 3x y3 = 3Y + 2
⇒ 2x1 = x1 − 1 ⇒ + =0
m x y 2x3 + 3y3 = 9 ⇒ 6x + 9y + 6 = 9
2x + 3y = 1
⇒ xy = k it passes in (2, 3)
6 N ≤ 100
xy = 6 ⇒ y = 71. Ans:
4
Sol: Maximum number of triangles are possible if
65. Ans: 32, 2 rest of the points are non-collinear.
Then Nmax = C3 − C3 = 100
10 6

Sol: Mean = 30 + 2 = 32 ∴ N ≤ 100

Standard deviation remains same = 2
72. Ans: Statement-1 is true, statement-2 is false
66. Ans: [1, ∞)
1
Sol: x + y |x|, ax − y = 1 Sol: lim sin does not exist
x→0 x
a +1 a +1 ∴ f2(x) is not continuous at x = 0
x= , y= a −
a +1 a +1 Statement-2 is false
a a −1
= 73. Ans: Statement-1 is true, Statement-2 is true;
a +1 statement-2 is a correct explanation for
If x > 0 ⇒ a + 1 > 0 ⇒ a > − 1 statement-1.
y > 0 ⇒ a |a| − 1 > 0 ⇒ a |a| > 1
If − 1 < a < 0 − a > 1 no soln
2 Sol: Statement-2
By induction p(1) is true
If a ≥ 0 Let p(m) be true
a ≥ 1 ⇒ |a| ≥ 1
2
Then (m + 1) : (m + 1) − (m + 1)
7

∴ a ∈ [1, ∞) = m + 7 C1 , m + ….. + 7m + 1 − m − 1
7 6

= (m − m) + 7k divisible by 7
7
67. Ans: −2
∴ p(n) is true
Statement-2 is true
p 1 1 ∴ (n + 1 − (n + 1) divisible by 7
7

Sol: 1 q 1 = 0 ⇒ pqr − (p + q + r) = − 2 Also, n − n divisibly by 7

7

Subtracting, (n + 1) − n − 1 divisible by 7
7 7
1 1 r
Statement-1 is true and follows from
Statement-2
68. Ans: 10 3
74. Ans: x + y − x − y = 0
2 2

Sol: Equation of the lime through (1, − 5, 9)

parallel to x = y = 12 is Sol: (x − 1) x + y (y − 1) = 0
x +y −x−y=0
2 2
x −1 y + 5 z − 9
= = =λ
1 1 1 75. Ans: 3x − y = 3
2 2

p(λ + 1, λ − 5, λ + 9)
(λ + 1) − (λ − 5) + (λ + 9) = 5 Sol: e = 2
 ae = 2 ⇒ a =1 1 1 1
∴x= +1− − e y
b2 2 y e
e= 1+ ⇒b =3
a2 1
1 e y
2
y x=1+ −
∴ required equation is x −
2 y e
=1
3
3x − y = 3
2 2
80. Ans: 3

76. Ans: R − {2, −3}

Sol: lim
(f ( x ))2 − 9 = 0
1 −k 1 x →5 1x − 51
Sol: k 3 − k ≠0
lim
(f ( x ))2 − 9 = 0
3 1 −1 x →5 x−5
2k + 2k − 12 ≠ 0 lim (f ( x ))2 − 9 = 0
2
x →5
k +k−6≠0
2

k ≠ − 3, 2 lim f ( x ) = 3
x →5

77. Ans: 6, 1
81. Ans: Statement-1 is true and Statement-2 is
Sol: Sum of roots = 4 + 3 = 7 false.
product = 3 × 2 = 6
Sol: Statement-1 is true
∴ correct equation is x − 7x + 6 = 0
2
In Statement-2
Roots are 6, 1 T
Det (A ) = det(A) But
Det(−A) = − Det (A) only for
α −β
78. Ans: odd order so it is not true.
100
2π π 4 π π 3 π 8 π
100 82. Ans: , , , , ,
∑ (a2r − a2r −1)
9 4 9 2 4 9
Sol: α−β=
1
Sol: sin θ + sin 4θ + sin 7θ = 0
100
α −β ⇒ sin 4θ + 2 sin 4θ cos 3θ = 0
= ∑ d = 100 d ⇒d =
100 ⇒ sin 4θ (1 + 2 cos 3θ) = 0
1
1 2π
⇒ sin 4θ = 0 cos 3θ = − = cos
1 2 3
1 e y 2π
79. Ans: 1 + − ⇒ 4θ = n π 3θ = 2nπ ±
y e 3
nπ 2nπ 2π
⇒θ= ,θ = ±
1 4 3 9
Sol: y dx + xdy − dy = 0
2
y π π 3 π 8 π 4 π 2π
, , , , ,
dx 1 1 2 4 4 9 9 9
⇒ + n. 2 = 3
dy y y
16
−1 83. Ans:
y 3
I. F = e
−1 1 −1 1
∫ y3
y y 2
∴ xe = e dy z= Sol: y = 9 ax
y 2
x = 9by
−z −1 16 1
∫ z.e − dy dz =
y2
dy A=
3
ab =
3

[
− ze− z + e − zdz ∫ ] dy = y dz
2 ∴ Required Area =
16
3
−1
y
= ze− + e− + C
z z
xe 84. Ans: Statement-1 is true, Statement-2 is true;
−1 statement-2 is a correct explanation for
y
x = z + 1 + ce statement-1.
1
1
x= + 1 + ce y Sol: Statement- 2 is true
y
Clearly f(x) has minimum at x = 0 at
y = 1 ⇒ x = 1 ⇒ 1 = 2 + ce minimum point f’(x) = 0
⇒c= −
1 ∴ follows from 1
e
85. Ans: [A ∧ (A → B)] → B 88. Ans: 53
Sol: Using following truth table we can see that
Sol: General point on line Q (2λ, 3λ + 2, 4λ + 3)
only
⇒2(2λ − 3) + 3 (3λ + 3) + 4 (4λ − 8) = 0
A ∧ (A → B) → B is tautology
⇒λ=1
∴ point Q (2, 5, 7) given point P (3, −1, 11)
A B A →B A ∩ (A →B) (A∩(A→ B))→B
1 2 3 1∩3=4 4→2 ∴ length PQ = 53
T T T T T
T F F T T 89. Ans: Statement-1 is true, Statement-2 is true;
F T T F T statement-2 is a correct explanation for
F F T F T statement-1.

86. Ans: P(A ) − P(B)

C Sol: R is an equivalence relation since
reflexivity, symmetry, transitivity are
(
Sol: P A C ∩ BC C ) satisfied. ∴ Statement-1 is true
Statement-2 is always true
P(C) − P(B ∩ C) − P( A ∩ C) And it is correct explanation of Statement-1
=
P(C)
90. Ans: 2af(a) − a f’(a)
2
= 1 − P(B) − P(A)
= 1 − P(A) − P(B)
= P(A ) − P(B)
C
x 2 f (a ) − a2 f ( x ) 0
Sol: lim  
x →a x−a 0
87. Ans: 18
lim f (a )2 x − a2 f ' ( x )
x →a
Sol: P(x) = f(x) − g(x) = A x + Bx + C
2
⇒2af(a) − a f’(a)
2
Since P−1) = 0 is the only one root
∴ P(x) = k(x + 1)
2

Given P(−2) = 2 ⇒ k = 2
∴ P(2) = 18