Periodic Properties of Elements - JEE Notes
Periodic Properties of Elements - JEE Notes
whjch ae Peatod
Propen ies,
alte aimd inteival a
Known as pehiodiC pro?eh hies
Effechve_ Nuchat Chatge CEetf
Rpuks'm
Attraction
e-
Snq la e sustemu Rapulbion
ASO attrachia ame AttTachon
by nucous
+In a mul
eSustem th Sin
ho inngu Shal
acEs as a Shai dd
CUntor for nucl and the
diftenentiating
wi ngt
e du&td which e
Cape ienca full nuelia
ohaige
Ac tua nucloat dhage
by
by tha e in Com expeienc@d
ton)i8
Knou Qs etfechve nudha chage,
S 9iven y
12 no et poBon
H 0 S l a J n Constant, taksB
account oF 80Lning
efect
innyi e behwe0n
xKopulsion ogtel
known O caon in9 Shaild n
niahng.e
nuclau8 and ditf dntiaing e i s is
erfect
* tet dono tes tha no of profons
achualatractio
*tet giving haiy to
wnich Q
tha (e)S.
t PTO ton Swhich 0g Lsed
*0 no
to ove1 Coma C-e ODULsion
S ovbital issphicolSummuttric
t Cove nucau& ful hus i E
CQ.ate maumum SCH0ing
ttectf -orbi tal, i8 hi9hy
ditfuyed du to which i i s
vely pao 8hiLdo
1Shuisding
Poudet
S>p>d>t
*
*
Vahia hion ot ~eyt
Aong peviod: Zet in cuaca8
Alon 9roup : Ramain8 Sama or
docwacO8
2Atomic Radi:
Cpn cop huall atomic Radius is
dina du distance
uclaus aned e ot out mo8
beto ean
Sho but it is not b
to det eming iES Possihl
exolct yalug
ATDm iS Small
Atom ,cdloes not
bound ax haye we datinad
ave natu0 ot e
But apmiç Nadii canlbe
in bondad Stoui
calalatad
Ty peb ot AtomicKadiub
)Coyolsnt Radius
Halt ot he dist a n a
oetuw eon tuoo CtomS
Covalont
bonclid by O
bond is known_ a
Covolmt Tadius
1 Covalont Radius d
CCR 2
Radius: (Sama atom)
) Homo atmic
Bonc Len
T (CRA daa9onc 2
A
1
(VR) daa VR)a -daa A
,
2matailic Ivanddnuoadl
Yovodsnt
Peniodichy in Atumic Kadiu
ALan Peniod CLR)
to mght in any
On moving iJott
nowaS plup td which
PeioddshoC"e's A90 uWlad tpwad
Ou
Nucdlous Cnd n& Sie olacuacs
Pevi od 2:
ARC Ne>Li>Be>B >C>N>0 >E)
y
Nog nnt gase aL, tho Sahgest
EacmhonS
d-bloclk
3 ie Sc Ti V CT Mn Fe
Co Ni
a 22 2 24 25 26 2t Cu Zn
EC 28 29
et , Si ze Zett, ee" su? High Rep.
111112|1 Juga >e-e JuPuls ion fs ma
Dl1 111
e-e uPulsion indu aCA
Si ze
1Sc>Ti Zn> V
7Cr=Mn Fe:Cu)> Co>Ni
us atorm ic
fo d-lock elomgntS,Sam ains
tadiys figt dpcLaca, hon
Cons tant and finally incLaçA
Ogaur his phnomtna, i8 aNSO Tansiti0n m t raLtion':
dtenad to as
1
Boron Family CG-13)
B 2-s Orden: B<Ga<A & InsTL
Not bgdtf
Sizedf
A Z13
Gha z - 3 1
is almet bame dua to
n 2 -497 Size con taaction
T Z -81 kantha noid
COmpaad to A is
omalll Size ot aa ComtoLtian
ndl
transi tim Olosenveç
dua t Comtiaction
dhlock
iso hsevel
t a inoa et iatomic
eoments with. piohom g0es
nto
uumbeN,
egctya Nuu
N uuaa
u
wnidn
nucduuS u fo0
Change inotgaas out eoctja e
intot8ub shll which
has Vy PoOT shgiLding, and
du to nuaa
Chage, Jss Shudc ing., utet Shall
O tightu purlid by
huclus Size Cont,gucrs
and nis phonomana i8 Known aS
hath Onoi'd Cont Tachi n
Sc C21) TC22)
Y CB9) TC4o)
La (s+) HFC42)
TiZr Hf
fsc 2Y2Laj cue
Lanthanoicl
ContraCtion
ecopt 9t 4d
Qnd O10 a met Sam
duL to hantho noicl Contacfion
Ionic Radiu The distane Detweln
Nuplus and e Ot eutSI Mest
Sha in. Cany i n is knaun s
CniCHaciis
cloud
F c ron Can t Anion is koeelu
hald be easiuu Polanisec
So t
au deUTm ed
Size st ion inlaQS On moVing
down tho qoup
k9 iZ Nat<K <R<Cs
Be M Ca2 S* Ba
0 S1 2 Se Tez
E Na T Mot2
A 13 N
lo IO
1Si ze N-3 7
2
F>Na >MgT>A
T2 13
fk>Lt >>Mg A
Cnma\ChOvqlsze) 4 aono KalotionShi
Kao
4,5 H C
H
Erphon 42H
20 2H
-2
H+ e H
1P,e CiP,2e3
Whan H S fomg from H
H,
hosuis Nange dacaaL in
tho
Lef becauSe t LOO incwa
in no 0f e whic indu0 CLS
e e 9PuliOn du to hich
Size HInOLaay tumendousy
LoniSahian En194
Fo k - kZe
Me M AH E
I soted
Gase.oud Ctom
Unit ot IE evlatdm
lev 6x 1o"T
AHhaat ot eochon
4H>O AH<o
Heat absosbed Heat Rolocsecl
tndothmic Exothohmic
uCCoSire IE
N e i r t a a
A M e IEL
Cahon M
M +e
MM 3) M
to ama elomant LIE> IE>IE1
gt Cahon, it is diffhicul t
atte fosmati on of incased
tomove ebecause
SuccosSive E a a hiqht
Kef, So
FactasAfechingLE
ha
SmovE e rom
LF high:
,
S Ko 4 K<Na< Li
Ba< Su Co <Mq<Be
ao
nd PakTE,1E2
Nitro9n
of Ozygen aIE,IE., IE, et an elomant aq
so, tO0, lboO kT Imo uSpec hyell
in eS
Cal.culatè no ot valonco
N2 2p Aalt flad ThO elament
IE CC> Mn) ,
LO 'y 4Sc
L
Au ErgPhon
A
Highest IE Helium A LAu
Lowest IE Ceasium noid ContotaChion
d u a to antmais
SiteoF Sma Au
NoTE Qame, elamants TE does Ezpected 5>AQ Gia > In 7TLX
dupend an net
ondy Chai9 e eleroniq COmi9
iS ConSicdaa d
IE
O O
IF O 4040)
ioouS? ecive st Confi9: AQ
E
)NoTE Fp? caiomS, highS is th
ChaiGe_ moO wi loe Ondon TB >TL > aa >AL In
ha I
Smallaat otall
A(IE)at Change an iaony B
AQ TianSition Contrachion (Sizel,IET)
3) NOTE F o r anignS , ighoi is
Chanqe Cmaqnifdol) h
smaWlhh In
TO
TO
Loanthanoid Cont Csize, IET)
w iU N ' H d a ) smalb
he
Casnbon Famiy
IE anion Si Cae S Po
Chan9 e an in C
Si ae> Ph>Sn
Eraphan8 ot TE Onde
C >
hanthano iol
bonon Famil ihis is, bec awse
Contyachon optateS on
B AL In Chang n9 Ord
TL Lead,
3d-Blak AS1an9e tefoALocoinq 0idos
OidA GTauduic
in, iiUUOSin
natusa'-
G Sd 4
4d 43d
G iaO, CO, N,0,Beo, B,03
4,5,6, 1O Bd <4d< Sol
G ki,0< Be0 <B.0,< C<N,O
+8,9,u,12 4d <3d < Sdl Thus Non Metallic Oaides- Audic
IoniSation Enthalpies Metulc Oidas
Applic ai on ot IE: CEA)
EJact ron Affinity:- elechon
O Babic, Nansa allso tfewd to
as
Metalic fouwe Inveubely prop It is
Oid Sing Yous en
7 to IE -
9aun enthan y CAHege)
EAo AHegeO
R,Metallic CaT And it EALO AHeeO
Metals Noose e easi whan
s e d whgn
aloased
I t is ena19y
+hoO d d e Y
Babic chooctoT et Oido- e is addedt
iS to ,Outen most
iSoa n d _ g a s e o u S
Ojbit o t aV
1 Basic
Otom, S knoUn
Stungth IE as. Echon Afhinity
Qnd thQ EnthalPy
Basic as
Change iS knouwN
E, Basic EGE
Na,O is Joss oosic than K A+e A A Cgaeous)
Succasw e Elacrron Affinity AH 140
O te AH +h O
Acg
Acg)+e Ag) EA,:e AH=600
gencial Net O+2e
outA+e A
AH7O aduways Thuus to fp7m 0id iqn
to upPJ bookT Imol
wehave
th net FA
A +2e A Factoss Affecting Eluchon Athinity
AHO Atom: EA
EAe iS nomay
couwe fo Peitive (4H<o)
O Size ot Si2e
to an, AniOn
we have
hom
Cie EAZ) Eltective Nudoa Change-
th Oye Com
orEA2
-e apuwion thu
CAH70) we EA Eet
have to Conigunatiom ot
Ln ths formahon
Supply enigy ENec topnic
ESornant:-
qt Poly valnt or piy
a hat, fllad,
ass
aso7o7 ebed yis tile
Emantsshols
havir
havin wi be jalue tantw
e thy would
uP e t o a
EA fo tako Contraton,
Gtgaeous,
isi4OkTIm o Oy Gen otom Aecse a
tohis
Stabg
thoiEA vclute ? is vey
ue ou, O i n iS,- DKTmol du oT
Oo itCan be znd
Cal culot e194, Tped At timS
+o 1
qabepuuso
d
tomo ian) fTom
E x c
P E
T I O N
Tu G Gl6
dcu _rcup valu
umimse 2n di Gf - Gi
EA 5 6,,and emLnt
wich
:
it
ta
irnan
S
Cr
A B ENCA > B)
T s 9 e sto 3 3?d
S ho which
hol
A
STEe, S o So ENCA4B)
ea e easidy accomodated
Mar 1 aluOt
* Valug FN. dopends upgn yalot
Min EA, IE Th elomaht, h e
E A, I E mo
EA - C
Maz i tho
EN
Ondh t EA for G Diffeonco inEA, EN-
1EACCO>F>Br I ) EJactron Afhniiy
EDechro Negahivify
) Ondn ot EA for GGl6 Proenty Gtisodaad ro?enty, c o N n t
o n d d y C o v a l n t
Elactro Negotviy
EN ot Atbm
Affechng
Tendoncy Oany Gtom to a ttract
Shaod
Factoa8
Pay ot,e D ads
itelf it a
COval nty, bondod DTEN Size ct atbm
mooculis known 0 Ectoo
Negatvi ty.
ffec hve Nucia Chatge Can cOmdud
it
Thut q
inLOWS, the mos w l
s hetr
e# xEN beitS
1Gu S
th Chatqe Cn Cahn, ie1EN CS?> SP* >sp
e+ nc , Thw E N ncwaces
Oadu ot EN SO S Chnectr
SChaudI
S ChaLCTUT
T <Mnt4 <Mntt
Cno Tg
ducuaAs t
Cn Anion Pnicd R tet
onga peicd ENT
2) aTup
Hu budisanon Gt Atom te Sam, Size
As () tet FN
SueShanudS,
S muh
we dowh a 9Toup
Mulli kun deale
EN GH Mukn
EN
EN iS ths avehaqe
EN: Elechon Afhinity
Ion Enngy
Apaicatian otEN
FoN CO >I:S-C> P H Nomaynclatuw
ovalont bond S
frmsd
Ound cant
EN SCais non matas, and Com?
oy
oy
2 n o n mitas A
khau s
Campound. and in pinaTy
S au bingu Nm Meta han
deteminL,
nc
thod
u wye
n using the tdcnng COm_ N iS &tTFen wiH
ComOund
mQw ide, and n a m ct Jass
tta
Suti witten hiut
Can S
EN Gtom
aun Scaie odine Chioico doido
Linus Pauing dyode?ede Poros TideCn da
,
imiG
Chanc tor
2) Covalnt bond
Ne t h any bon iS I00 1on i
MeraC ,Non MetaC Chotuctor-
Or00 Cavalunt each bun d Lou EN Metalic Chabic)
Of High EN>Nan Metac
we
Covalnt chahuc07
Os
Natu t
C Aidic)
AOH type ot moda.cules-
inic =16x|AXl+ 3S
2
Char AOH A + OH
Hamay
Hamoy Smith En Base
AX>diffesunCa in EN
Callculai, 7 9t ion iC ChooctaS1 in AOH AO + H*
HE bond Acidic
Moa is tha
dffeun ca in A 14,
ENbetyeon a to m S, moL A-0+ H
iS ha 8tabili ty A O-H ma. +CAcid)
mosL ioni¢|Poar
Gmo Bae) AO +
Eg Stalbilshy (HE> HCA> HBa> HI) AT+OH CBase)
Natuse of Onude-
Acdic Ocude Oide which
actS wih o ase and thiS
On dusSo inq in waten
tormS Ox aids
RL Oxido + H0 Oy Aid
Oy Acid
03 Nan Metal, O, H
E-HS04 CH bondid to O)
Hydota
E Acid
H c o NM,H
NMH
SOa HO HSO4
Non Rdo
Nore Acid Be RanctionsOuanol
HudolySis KxmS nol
RTdo
basic Oxides Oido, which Juacts
wit ocid onand dussoWving in
wal it formS HudiooLidog
a) AStnangethtolo unn9
9 nin
in Oteln
ÜIIng
aci duc nat L:
Nag0, COj, N,0, CuO, hi20
NO 0 CuO CO
N O
SblockK Non Metols
moda motalfc)
H
H F F
dOaNC
dorital
Paiy due
CA
id
tD
a a c a n t yacant
which
N hason
Back Bonod
C
NO
L
CA C CL CI
C
Dus to his tho stuc tus becomas
S2) mangularPana U oi th
BAC130), Mus8
NCA NH NF
Solubity Ondon Tsnds
o ALkali /ANKi East Metal Hydoo aidus
Hydhahom Enpgy /Soyation encigy
moa foxsmay1, ions uE
Qathco e19 dopend on tha2
ectennt OFOSOL, oenwen hlnn,
iS Proponnal to (292
tuus a ' w e move2 e
S , Hyd
dwnAnCU Lathicó
welweW a enong 4dc
but E doops Tapid uy
tuus
Eneqy Ralaased Huc -Lathce
i n a c o Kolaseod