Material Safety Data Sheet.

01. Product Identifier

Trade Name : Unik Spray Solutions.
Article No. : PA/02
Uses : Priming and Anti-corrosion additive.
Manufacturer : Unik Spray Solutions.
Phone. : +91 8919779219 , +966 557453712
Email : [email protected]
Emergency Ph No. : +91 8919779219 ,+966 557453712.

02. Classification of the mixture.

Classification according to Directive 67/548/EEC or Directive 1999/45/EC
R12 : F+;Extremely Flammable.
N : Dangerous for the environment.
R50/53 : Very toxic to aquatic organism.
R67 : Vapours may cause drowsiness and dizziness

Information concerning particular hazards for human and environment.

Contact with skin and inhalation of aerosols / vapours of the preparation should be avoided.
The product has to be labeled due to the calculation procedure of the “General Classification guideline for
preparation of the EU.“
Warning ! Pressurized container.
Has a narcotizing effect.

Label elements:
Labeling according to IS and EU guide ness.
Code letter and hazard designation of product.
F+ Extremely Flammable.
N Dangerous for the environment.

Risk Phrases :
12 Extremely Flammable
50/53 Very toxic to aquatic organisms.
67 Vapours may cause drowsiness and dizziness.

Safety Phrases :
2 keep out of the reach of children.
16 Keep away from source of ignition, No smoking.
23 Do not breathe spray.
24/25 Avoid contact with skin and eyes.
 29/56 Do not empty into drains, dispose of this material and its container at hazardous or special waste
collection point.
46 If swallowed seek medical advice immediately.
51 Use only in well ventilated areas.
Special labeling of certain preparation:
Pressurized container; protect from sunlight and do not expose to temperature exceeding 50 degrees
centigrade (e.g. in the car). Do not pierce or burn even after use.
Do not spray on a naked flame or any incandescent material.
Buildup of explosive mixtures possible without sufficient ventilation.
Classification in accordance with Directive 75/324/EEC: Extremely Flammable Other Hazards:
PBT : Not applicable.
vPvB : Not applicable.

03. Composition / Information on Ingredients.

Chemical characterization.
CAS: 7400-66-6 Zinc powder / dust / flake(stabilized) 25≤50%
EINECS: 231-175-3 N R50/53
Aquaticacute1, H400; AquaticChronic1,H410.
CAS: 67-64-1 Ketones 12.5≤20
EINECS: 200- XiR36;FR11,R66-67 %
662-2 Flame Liq.2, H225;Eye irrit2;H319;StotSE3;H336.
CAS:1330-20-7 Xylene, Mix of isomers 10≤12.5
EINECS: 215- Xn R 20/21;XiR 38; %
535-7 R10.
Flame Liq.3, H226; Acutetox4;H312SkinIrrit2.
CAS: 74-98-6 Propane 5≤10%
EINECS: 200-827-9 F+R12
Flam. Gas1, H220; Press. Gas, H280
CAS: 106-97-8 Butane 5≤10%
EINECS: 203-448-7 F+R12
CAS: 75-28-5 Isobutene ≤2.5%
EINECS: 200-857-2 F+R12
Flam. Gas1, H220; Press. Gas, H280
CAS: 1314-13-2 Zinc Oxide ≤2.5%
EINECS: 215-222-5 NR50/53
Aquatic Acute1, H400; AquaticChronic1, H410.

04. First Aid Measures.

General Information: Take affected persons out into the fresh air.
After Inhalation: Supply fresh air; consult doctor in case of complaint.
After skin contact: Generally, the product does not irritate the skin.
After eye contact: Rinse opened eye for several minutes under running water.
After swallowing: Drink plenty of water and provide fresh air. Call doctor.
05. Fire Fighting Measures.
Suitable extinguishing agents.: CO2, powder or water spray. Fight larger fires with water or alcohol resistant
foam.
For safety reasons unsuitable extinguishing agents.: Water with full jet.
Advice for fire fighters: Wear self-contained respiratory protective device. Do not inhale Explosion gases or
combustion gases.

06. Accidental Release Measures.

Keep away from ignition sources.
Ensure adequate ventilation.
Wear protective equipment. Keep unprotected persons away.
Inform respective authorities in case of seepage into water / sewage systems.
Do not allow to enter sewers / surface or ground water.
Do not allow product to reach sewage system or any water course.
Do not flush with water or aqueous cleaning agents.
Ensure adequate ventilation.

07. Handling and Storage.

Keep away from heat and direct sunlight.
Ensure good interior ventilation, especially at floor level.
Ensure good ventilation / exhaustion at the workplace.
Open and handle receptacle with care.
Fumes can combine with air to form an explosive mixture.
Keep ignition sources away; do not smoke.
Protect against electrostatic charges.
Store in a cool location.
Observe official regulation on storing packaging with pressurized containers.
Do not seal receptacle gas tight.
Store in cool, dry conditions in well-sealed receptacles.
Protect from heat and direct sunlight.
Storage class: 2B

08. Exposure Controls / Personal Protections.

Control Parameters.

Ingredients with limit values that require monitoring at the workplace.

67-64-1.Ketones, Acetone
WEL Short-term value: 3620mg/m 3,1500 ppm.
Long-term value: 1210mg/m 3, 500 ppm.
1300-20-7.Xylene, mixture of isomers.
WEL Short-term value:441mg/m 3,100 ppm.
Long-term value:220mg/m3,50 ppm.
106-97-8.Butane.
 WEL Short-term value: 1810mg/m3,750 ppm.
Long-term value:1450mg/m3,600 ppm.
Ingredients with biological limits values.
1330-20-7. xylene, mixture of isomers.
BMGV 650mmol/mol creatinine.
Medium: urine
Sampling time: post shift.
Parameters: methyl hippuric acid.
78-93-3. butanone
BMGV 70µmol/L Medium: urine
Sampling time: post shift.
Parameter: butan-2-one
Exposure controls.
Do not eat, drink, smoke, or sniff while working.
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
Respiratory protection: Not necessary if room is well ventilated. Otherwise, filter class A/P2 or self-
contained.
Use solvent resistant gloves.
In case of contact with spray dust protective gloves made of butyl should be used.
The glove material has to be impermeable and resistant to the product / preparation.
Material of gloves: Natural rubber, NR; Butyl rubber, BR.
Penetration time of glove material.
Butyl rubber gloves with a thickness of 0.4mm are resistant to:
Acetone:480min; Butylacetate:60min; Xylene:42 min.
Eye protection: Safety glasses.
Body protection: Light weight protective clothing.

09. Physical and Chemical Properties.

Appearance: Form-Aerosol Colour- Grey
Odor :Characteristic
Odor there should: Not determined.
pH value: Not determined.
Melting point: Undetermined.
Boiling point: Not applicable, as aerosol.
Flash point: Not applicable, as aerosol.
Flammability: Extremely flammable as aerosol.
Decomposition temperature: Not determined.
Self igniting: Product is not self-igniting
Danger of explosion : In use, may form flammable vapour -air mixture.
Explosion limits: Lower-1.1 Vol%;Upper-18.6Vol%
Vapourpressure@200C: 5200 hPa
Density at200C: 1.55 g/cm3
Relative density : Not determined.
Vapour density Not determined.
Evaporation rate: Not applicable.
 Solubility : Not miscible in water, miscible insolvents.
VOC-(EU):630.0g/l

10. Stability and Reactivity.

No decomposition if used according to specifications.
No dangerous reactions known.
No dangerous decomposition products known.

11. Toxicological Information.

LD/LC50 values relevant for classification:
67-64-1 acetone
Oral LD50 5800mg/kg(rat)
Dermal LD50 20000mg/kg(rabbit)
1330-20-7xylene,mixture of isomers
Oral LD50 4300mg/kg(rat)
Dermal LD50 500mg/kg(rabbit)
64742-95-6 solvent naphtha
Oral LD50 ≥6800mg/kg(rat)
Dermal LD50 ≥3400mg/kg(rab)
Inhalative LC50/4 ≥10.2mg/l(rat)
1314-13-2 Zinc oxide
Oral LD50 7950mg/kg(mouse)
Primary irritant effect:
On the skin: No irritant effect.
On the eye: No irritating effect.
Sensitization: No sensitizing effects known.
Additional toxicological information Vapours have narcotic effect.

12. Ecological Information.

Aquatic Toxicity : No further relevant information available.
Persistence and degradability : No further relevant information available.
Bio accumulated potential: No further relevant information available.
Ecotoxical effects -
Very toxic for fish.
Water hazard class 2, hazardous for water.
Do not allow product to reach ground water or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water biddies.
Very toxic for aquatic organisms.
PBT : Not applicable.
vPvB : Not applicable.
13. Disposal Considerations.
Must not be disposed together with house hold garbage.
Do not allow the product to reach sewage system.

14. Transport Information.

UN Number
ADR, IMDG,IATA UN1950.

UN Proper shipping name 1950 Aerosols, Environmentally hazardous

ADR, IMDG,IATA Aerosols, Marine Pollutant, flammable.

Transport hazard classes

ADR Class 2 5FGases
Label 2.1.
IMDG Class 2.1
Label 2.1
IATA Class 2.1
Label 2.1
Packing group
ADR, IMDG,IATA Void

Enviro, Marine pollutant Yes, symbol (fish and tree )

Special marking ADR Symbol (fish and tree )

Special precaution for user Warning: gases

EMS Number F-D,S-U.

15. Regulatory Information.

15.1 Safety, health and environmental regulations / legislation specific for mixture.
Information about limitation of use: Employment restrictions concerning juveniles must be
observed.
Water hazard class : Water hazard class2(self–assessment ):hazardous for water.
15.2 Chemical safety assessment : A chemical safety assessment has not been carried out.

16. Other Information.

This information is based on our present knowledge. However, this shall not constitute a guarantee for
any specific product features and shall not establish a legally valid contractual relationship.
Relevant Phrases.
H220 Extremely flammable gas.
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H280 Contains gas under pressure: may explode if heated.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effect.
R10 Flammable.
R11 Highly flammable.
R12 Extremely flammable.
R20 Harmful by in halation.
R20/21 Harmful by inhalation and in contact with skin.
R36 Irritating to eyes.
R36/37/38 Irritating to eyes, respiratory system and skin.
R37 Irritating to respiratory system.
R38 Irritating to skin.
R50/53 Very toxic to aquatic organisms may cause long term effects.
R51/53 Toxic to aquatic organisms, may cause long term adverse effects.
R65 Harmful; may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.
R67 vapours may cause drowsiness and dizziness.
RID: Regulations concerning the international Transport of Dangerous goods by rail.
IATA-DGR: Dangerous goods regulations by the “International Air Transport Association”
ICAO : International Civil Aviation Organization.
IMDG : International Marine code for Dangerous Goods.
IATA : International Air Transport Association.
LC50 : Lethalconcentration,50 percent.
LD50 : Lethal dose, 50 percent.