Methacrylic Acid

Safety Data Sheet

according to Regulation (E C ) N o. 1907/2006 (RE A C H ) w ith its amendment Regulation (E U ) 2015/830
Date of issue: 11/24/2011 Rev ision date: 3/22/2018 V ersion: 3.5

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Product form : Substance
Trade name : Methacrylic Acid
EC Index-No. : 607-088-00-5
EC-No. : 201-204-4
CAS-No. : 79-41-4
REACH registration No : 01-2119463884-26-XXXX
KH product code : 100371
Type of product : Pure substance,Stabilized product
Formula : C4H6O2
Synonyms : 2-methacrylic acid / 2-methyl acrylic acid / 2-methyl-2-propenoic acid / 2-methylene propionic
acid / 2-methylpropenoic acid / 2-propenoic acid, 2-methyl- / acide 2-méthylpropénoique / AI3-
15724 / alpha-methacrylic acid / alpha-methyl acrylic acid / alpha-methyl propenoic acid /
methacrylic acid / Methacrylinsäure / methyl acrylic acid
BIG no : 10294

1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Main use category : Industrial use
Industrial/Professional use spec : Intermediate
Use of the substance/mixture : Chemical intermediate

1.2.2. Uses advised against

No additional information available
1.3. Details of the supplier of the safety data sheet
KH Chemicals B.V.
Scheepmakerij 260
3331MB Zwijndrecht - The Netherlands
T +31 85 6255255
[email protected] - www.khchemicals.com

1.4. Emergency telephone number

Emergency number : +31 85 6255222 (+ Please see section 16)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixtures/Substances: SDS EU 2015: According to Regulation
(EU) 2015/830 (REACH Annex II)
Acute toxicity (dermal), Category 3 H311
Acute toxicity (oral), Category 4 H302
Skin corrosion/irritation, Category 1A H314

Full text of hazard classes and H-statements : see section 16

Specific concentration limits:
(C >= 1) STOT SE 3, H335

Adverse physicochemical, human health and environmental effects

No additional information available

2.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display
Hazard pictograms (CLP) :

GHS06 GHS05

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 Methacrylic Acid
Safety Data Sheet
according to Regulation (E C ) N o. 1907/2006 (RE A C H ) w ith its amendment Regulation (E U ) 2015/830
Date of issue: 11/24/2011 Rev ision date: 3/22/2018 V ersion: 3.5

CLP Signal word : Danger

Hazard statements (CLP) : H311 - Toxic in contact with skin.
H302 - Harmful if swallowed.
H314 - Causes severe skin burns and eye damage.
H332 - Harmful if inhaled.
H318 - Causes serious eye damage.
H335 - May cause respiratory irritation.
Precautionary statements (CLP) : P280 - Wear protective clothing, protective gloves.
P264 - Wash hands thoroughly after handling.
P310 - Immediately call a POISON CENTER/doctor
P321 - Specific treatment (see information on this label)
P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water/shower.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P301+P330+P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

2.3. Other hazards

This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

SECTION 3: Composition/infor mation on ingredients

3.1. Substances
Substance type : Mono-constituent

Name Product identifier % Classification according to

Regulation (EC) No.
1272/2008 [CLP]
methacrylic acid, stabilized (CAS-No.) 79-41-4 100 Acute Tox. 3 (Dermal), H311
(EC-No.) 201-204-4 Acute Tox. 4 (Oral), H302
(EC Index-No.) 607-088-00-5 Skin Corr. 1A, H314
(REACH-no) 01-2119463884-26-XXXX
Specific concentration limits:
Name Product identifier Specific concentration limits
methacrylic acid, stabilized (CAS-No.) 79-41-4 (C >= 1) STOT SE 3, H335
(EC-No.) 201-204-4

(EC Index-No.) 607-088-00-5

(REACH-no) 01-2119463884-26-XXXX

Full text of H-statements: see section 16

3.2. Mixtures
Not applicable

SECTION 4: First aid measures

4.1. Description of first aid measures
First-aid measures general : Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory
arrest: artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Victim conscious
with laboured breathing: half-seated. Victim in shock: on his back with legs slightly raised.
Vomiting: prevent asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no
warming up). Keep watching the victim. Give psychological aid. Keep the victim calm, avoid
physical strain. Depending on the victim's condition: doctor/hospital.
First-aid measures after inhalation : Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service.
Doctor: administration of corticoid spray.
First-aid measures after skin contact : Wash immediately with lots of water (15 minutes)/shower. Do not apply (chemical) neutralizing
agents. Remove clothing while washing. Do not remove clothing if it sticks to the skin. Cover
wounds with sterile bandage. Consult a doctor/medical service. If burned surface > 10%: take
victim to hospital.

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 Methacrylic Acid
Safety Data Sheet
according to Regulation (E C ) N o. 1907/2006 (RE A C H ) w ith its amendment Regulation (E U ) 2015/830
Date of issue: 11/24/2011 Rev ision date: 3/22/2018 V ersion: 3.5

First-aid measures after eye contact : Rinse immediately with plenty of water for 15 minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. Do not apply neutralizing agents. Take victim to an
ophthalmologist.
First-aid measures after ingestion : Rinse mouth with water. Immediately after ingestion: give lots of water to drink. Do not induce
vomiting. Do not give activated charcoal. Do not give chemical antidote. Immediately consult a
doctor/medical service. Call Poison Information Centre (www.big.be/antigif.htm). Ingestion of
large quantities: immediately to hospital. Take the container/vomit to the doctor/hospital.
Doctor: gastric lavage.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects after inhalation : EXPOSURE TO HIGH CONCENTRATIONS: Coughing. Dry/sore throat. Irritation of the
respiratory tract. Irritation of the nasal mucous membranes. FOLLOWING SYMPTOMS MAY
APPEAR LATER: Risk of lung oedema. Respiratory difficulties.
Symptoms/effects after skin contact : Caustic burns/corrosion of the skin.
Symptoms/effects after eye contact : Corrosion of the eye tissue. Blindness.
Symptoms/effects after ingestion : Nausea. Burns to the gastric/intestinal mucosa. Blood in vomit. Blood in stool.
Chronic symptoms : No effects known.

4.3. Indication of any immediate medical attention and special treatment needed
No additional information available

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media : Quick-acting ABC powder extinguisher. Quick-acting BC powder extinguisher. Quick-acting class
B foam extinguisher. Quick-acting CO2 extinguisher. Class B foam (not alcohol-resistant).
Unsuitable extinguishing media : Water (quick-acting extinguisher, reel); risk of puddle expansion. Water; risk of puddle
expansion.
5.2. Special hazards arising from the substance or mixture
Fire hazard : DIRECT FIRE HAZARD: Material presenting a fire hazard. In finely divided state: increased fire
hazard. INDIRECT FIRE HAZARD: Temperature above flashpoint: higher fire/explosion hazard.
Substance contains stabilizer against polymerization. Heat destroys stabilizer against
polymerization. Reactions involving a fire hazard: see "Reactivity Hazard".
Explosion hazard : INDIRECT EXPLOSION HAZARD: Heat may cause pressure rise in tanks/drums: explosion risk.
Reactions with explosion hazards: see "Reactivity Hazard".
Hazardous decomposition products in case of : Upon combustion: CO and CO2 are formed.
fire

5.3. Advice for firefighters

Precautionary measures fire : Exposure to fire/heat: keep upwind. Exposure to fire/heat: consider evacuation. Exposure to
fire/heat: seal off low-lying areas. Exposure to fire/heat: have neighbourhood close doors and
windows.
Firefighting instructions : Cool tanks/drums with water spray/remove them into safety. Physical explosion risk:
extinguish/cool from behind cover. Do not move the load if exposed to heat. After cooling:
persistant risk of physical explosion. Take account of toxic fire-fighting water. Use water
moderately and if possible collect or contain it.
Protection during firefighting : Heat/fire exposure: compressed air/oxygen apparatus.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Face-shield. Corrosion-proof suit. Large spills/in enclosed spaces: compressed air
apparatus. Large spills/in enclosed spaces: gas-tight suit.
Emergency procedures : Mark the danger area. No naked flames. Wash contaminated clothes. In case of hazardous
reactions: keep upwind. In case of reactivity hazard: consider evacuation. Large spills/in
confined spaces: consider evacuation.

6.1.2. For emergency responders

No additional information available

6.2. Environmental precautions

Prevent soil and water pollution. Prevent spreading in sewers.

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 Methacrylic Acid
Safety Data Sheet
according to Regulation (E C ) N o. 1907/2006 (RE A C H ) w ith its amendment Regulation (E U ) 2015/830
Date of issue: 11/24/2011 Rev ision date: 3/22/2018 V ersion: 3.5

6.3. Methods and material for containment and cleaning up

For containment : Contain released product, pump into suitable containers. Plug the leak, cut off the supply. Dam
up the liquid spill. Hazardous reaction: measure explosive gas-air mixture. Reaction: dilute
combustible gas/vapour with water curtain. Heat exposure: dilute toxic gas/vapour with water
spray. Take account of toxic/corrosive precipitation water.
Methods for cleaning up : Take up liquid spill into a non combustible material e.g.: kieselguhr or sand, earth, vermiculite.
Scoop absorbed substance into closing containers. Carefully collect the spill/leftovers.
Damaged/cooled tanks must be emptied. Clean contaminated surfaces with an excess of water.
Take collected spill to manufacturer/competent authority. Wash clothing and equipment after
handling.

6.4. Reference to other sections

No additional information available

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Precautions for safe handling : Keep away from naked flames/heat. At temperature > flashpoint: use spark-/explosionproof
appliances. In finely divided state: use spark-/explosionproof appliances. Finely divided: keep
away from ignition sources/sparks. Measure the concentration in the air regularly. Carry
operations in the open/under local exhaust/ventilation or with respiratory protection. Exhaust
gas must be neutralised. Comply with the legal requirements. Remove contaminated clothing
immediately. Clean contaminated clothing. Use corrosionproof equipment. Thoroughly
clean/dry the installation before use. Do not discharge the waste into the drain.
Hygiene measures : Observe very strict hygiene - avoid contact. Keep container tightly closed.
7.2. Conditions for safe storage, including any incompatibilities
Storage temperature : 18 - 25 °C
Heat and ignition sources : KEEP SUBSTANCE AWAY FROM: heat sources.
Information on mixed storage : KEEP SUBSTANCE AWAY FROM: oxidizing agents. (strong) acids. (strong) bases. highly
flammable materials. metals. water/moisture.
Storage area : Store in a cool area. Store in a dry area. Store in a dark area. Ventilation at floor level. Keep
locked up. Provide for a tub to collect spills. Unauthorized persons are not admitted. Store only
in a stabilized state. Meet the legal requirements.
Special rules on packaging : SPECIAL REQUIREMENTS: closing. clean. opaque. correctly labelled. meet the legal
requirements. Secure fragile packagings in solid containers.
Packaging materials : SUITABLE MATERIAL: glass. MATERIAL TO AVOID: metal.

7.3. Specific end use(s)

No additional information available

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Methacrylic Acid (79-41-4)

DNEL/DMEL (Workers)
Long-term - systemic effects, dermal 4.25 mg/kg bw/day
Long-term - systemic effects, inhalation 29.6 mg/m³
Long-term - local effects, inhalation 88 mg/m³
DNEL/DMEL (General population)
Long-term - systemic effects, inhalation 6.3 mg/m³
Long-term - systemic effects, dermal 2.55 mg/kg bw/day
Long-term - local effects, inhalation 6.55 mg/m³
PNEC (Water)
PNEC aqua (freshwater) 0.82 mg/l
PNEC aqua (marine water) 0.82 mg/l
PNEC (Soil)
PNEC soil 1.2 mg/kg dwt
PNEC (STP)
PNEC sewage treatment plant 10 mg/l

8.2. Exposure controls

Materials for protective clothing:

GIVE GOOD RESISTANCE: butyl rubber. viton. GIVE POOR RESISTANCE: PVA. neoprene. PVC. nitrile rubber. natural rubber

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 Methacrylic Acid
Safety Data Sheet
according to Regulation (E C ) N o. 1907/2006 (RE A C H ) w ith its amendment Regulation (E U ) 2015/830
Date of issue: 11/24/2011 Rev ision date: 3/22/2018 V ersion: 3.5

Hand protection:
Gloves

Eye protection:
Face shield

Skin and body protection:

Corrosion-proof clothing

Respiratory protection:
Full face mask with filter type A at conc. in air > exposure limit

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Liquid.
Molecular mass : 86.09 g/mol
Colour : Colourless.
Odour : Repulsive odour. Irritating/pungent odour.
Odour threshold : No data available
pH : 3 (9 %)
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 15 °C
Freezing point : No data available
Boiling point : 161 °C
Flash point : 67 °C
Auto-ignition temperature : 400 °C (1013 hPa)
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : 0.97 hPa (20 °C)
Vapour pressure at 50 °C : 6.7 hPa
Relative vapour density at 20 °C : 3
Relative density : 1
Relative density of saturated gas/air mixture : 1
Density : 1015 kg/m³
Solubility : Moderately soluble in water. Soluble in ethanol. Soluble in ether. Soluble in chloroform. Soluble
in other organic solvents.
Water: 9.8 g/100ml (20 °C)
Ethanol: complete
Ether: complete
Log Pow : 0.93 (Experimental value, 22 °C)
Viscosity, kinematic : No data available
Viscosity, dynamic : 1.38 mPa.s (25 °C)
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : 1.6 - 8.8 vol %
Lower explosive limit (LEL) : 1.6 vol %
Upper explosive limit (UEL) : 8.8 vol %
9.2. Other information
Saturation concentration : 3 g/m³
VOC content : 100 %
Other properties : Gas/vapour heavier than air at 20°C. Slightly volatile. Substance has acid reaction.

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 Methacrylic Acid
Safety Data Sheet
according to Regulation (E C ) N o. 1907/2006 (RE A C H ) w ith its amendment Regulation (E U ) 2015/830
Date of issue: 11/24/2011 Rev ision date: 3/22/2018 V ersion: 3.5

SECTION 10: Stability and reactivity

10.1. Reactivity
Reacts violently with many compounds e.g. (strong) oxidizers and (some) acids/bases. Unstabilized product polymerizes on exposure to light and
on exposure to some compounds. Violent polymerisation on exposure to temperature rise: pressure rise and possible bursting of container.

10.2. Chemical stability

Unstable on exposure to heat.

10.3. Possibility of hazardous reactions

No additional information available
10.4. Conditions to avoid
No additional information available

10.5. Incompatible materials

No additional information available

10.6. Hazardous decomposition products

Reacts with (some) metals: release of highly flammable gases/vapours (hydrogen).

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Acute toxicity (oral) : Oral: Harmful if swallowed.
Acute toxicity (dermal) : Dermal: Toxic in contact with skin.
Acute toxicity (inhalation) : Not classified
Methacrylic Acid (79-41-4)
LD50 oral rat 1320 mg/kg bodyweight (Equivalent or similar to OECD 401, Rat, Male, Experimental value)
LD50 dermal rabbit 500 - 1000 mg/kg bodyweight (Other, Rabbit, Experimental value)
LC50 inhalation rat (mg/l) 7.1 mg/l air (Equivalent or similar to OECD 403, 4 h, Rat, Male/female, Experimental value)
Skin corrosion/irritation : Causes severe skin burns and eye damage.
pH: 3 (9 %)
Serious eye damage/irritation : Serious eye damage, category 1, implicit
pH: 3 (9 %)
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified

Reproductive toxicity : Not classified

STOT-single exposure : Not classified

STOT-repeated exposure : Not classified

Aspiration hazard : Not classified

Methacrylic Acid (79-41-4)
Viscosity, kinematic 1.35960591 mm²/s
Potential adverse human health effects and : Harmful if swallowed. Toxic in contact with skin. Causes severe skin burns. Causes serious eye
symptoms damage.

SECTION 12: Ecological information

12.1. Toxicity
Ecology - general : Not classified as dangerous for the environment according to the criteria of Directive
67/548/EEC. Not classified as dangerous for the environment according to the criteria of
Regulation (EC) No 1272/2008.
Ecology - air : Not included in the list of fluorinated greenhouse gases (Regulation (EU) No 517/2014).
Photodegradation in the air. Not classified as dangerous for the ozone layer (Regulation (EC)
No 1005/2009).
Ecology - water : Slightly harmful to crustacea. Harmful to fishes. Inhibition of activated sludge. Harmful to
algae. pH shift.
Acute aquatic toxicity : Not classified
Chronic aquatic toxicity : Not classified

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 Methacrylic Acid
Safety Data Sheet
according to Regulation (E C ) N o. 1907/2006 (RE A C H ) w ith its amendment Regulation (E U ) 2015/830
Date of issue: 11/24/2011 Rev ision date: 3/22/2018 V ersion: 3.5

Methacrylic Acid (79-41-4)

LC50 fish 1 85 mg/l (EPA OTS 797.1400, 96 h, Salmo gairdneri, Flow-through system, Fresh water,
Experimental value)
EC50 Daphnia 1 > 130 mg/l (EPA OTS 797.1300, 48 h, Daphnia magna, Flow-through system, Fresh water,
Experimental value)
EC50 72h algae (1) 45 mg/l (OECD 201: Alga, Growth Inhibition Test, Selenastrum capricornutum, Static system,
Fresh water, Experimental value)

12.2. Persistence and degradability

Methacrylic Acid (79-41-4)
Persistence and degradability Readily biodegradable in water.
Biochemical oxygen demand (BOD) 0.89 g O₂/g substance
ThOD 1.67 g O₂/g substance
BOD (% of ThOD) 0.5329 (Calculated value)

12.3. Bioaccumulative potential

Methacrylic Acid (79-41-4)
BCF other aquatic organisms 1 3 (Calculated value)
Log Pow 0.93 (Experimental value, 22 °C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).

12.4. Mobility in soil

Methacrylic Acid (79-41-4)
Surface tension 0.0659 N/m (20 °C, 1.01 g/l)
Ecology - soil Low potential for adsorption in soil.
12.5. Results of PBT and vPvB assessment
Methacrylic Acid (79-41-4)
This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

12.6. Other adverse effects

No additional information available

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Regional legislation (waste) : LWCA (the Netherlands): KGA category 06.
Product/Packaging disposal recommendations : Remove waste in accordance with local and/or national regulations. Hazardous waste shall not
be mixed together with other waste. Different types of hazardous waste shall not be mixed
together if this may entail a risk of pollution or create problems for the further management of
the waste. Hazardous waste shall be managed responsibly. All entities that store, transport or
handle hazardous waste shall take the necessary measures to prevent risks of pollution or
damage to people or animals. Remove to an authorized incinerator equipped with an
afterburner and a flue gas scrubber with energy recovery.
Additional information : Hazardous waste according to Directive 2008/98/EC, as amended by Regulation (EU) No
1357/2014 and Regulation (EU) No 2017/997.
European List of Waste (LoW) code : 15 01 10* - packaging containing residues of or contaminated by dangerous substances
16 05 08* - discarded organic chemicals consisting of or containing dangerous substances

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN

14.1. UN number
UN-No. (ADR) : 2531
UN-No. (IMDG) : 2531
UN-No. (IATA) : 2531
UN-No. (ADN) : 2531
UN-No. (RID) : 2531
14.2. UN proper shipping name
Proper Shipping Name (ADR) : Methacrylic Acid
Proper Shipping Name (IMDG) : Methacrylic acid, stabilized
Proper Shipping Name (IATA) : Methacrylic acid, stabilized
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 Methacrylic Acid
Safety Data Sheet
according to Regulation (E C ) N o. 1907/2006 (RE A C H ) w ith its amendment Regulation (E U ) 2015/830
Date of issue: 11/24/2011 Rev ision date: 3/22/2018 V ersion: 3.5

Proper Shipping Name (ADN) : Methacrylic acid, stabilized

Proper Shipping Name (RID) : Methacrylic acid, stabilized
Transport document description (ADR) : UN 2531 Methacrylic Acid, 8, II, (E)
Transport document description (IMDG) : UN 2531 Methacrylic acid, stabilized, 8, II
Transport document description (IATA) : UN 2531 Methacrylic acid, stabilized, 8, II
Transport document description (ADN) : UN 2531 Methacrylic acid, stabilized, 8, II
Transport document description (RID) : UN 2531 Methacrylic acid, stabilized, 8, II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) (ADR) : 8
Danger labels (ADR) : 8

IMDG
Transport hazard class(es) (IMDG) : 8
Danger labels (IMDG) : 8

IATA
Transport hazard class(es) (IATA) : 8
Hazard labels (IATA) : 8

ADN
Transport hazard class(es) (ADN) : 8
Danger labels (ADN) : 8

RID
Transport hazard class(es) (RID) : 8
Danger labels (RID) : 8

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 Methacrylic Acid
Safety Data Sheet
according to Regulation (E C ) N o. 1907/2006 (RE A C H ) w ith its amendment Regulation (E U ) 2015/830
Date of issue: 11/24/2011 Rev ision date: 3/22/2018 V ersion: 3.5

14.4. Packing group

Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : II
Packing group (RID) : II
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available

14.6. Special precautions for user

- Overland transport
Transport regulations (ADR) : Subject
Classification code (ADR) : C3
Hazard identification number (Kemler No.) : 89
Orange plates :

Tunnel restriction code (ADR) : E

- Transport by sea
Transport regulations (IMDG) : Subject
IBC packing instructions (IMDG) : IBC02
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-B

- Air transport
Transport regulations (IATA) : Subject to the provisions

- Inland waterway transport

Classification code (ADN) : C3
Carriage permitted (ADN) : T

- Rail transport
Transport regulations (RID) : Subject
Classification code (RID) : C3

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations

No REACH Annex XVII restrictions

Methacrylic Acid is not on the REACH Candidate List
Methacrylic Acid is not on the REACH Annex XIV List

VOC content : 100 %

15.1.2. National regulations

No additional information available

15.2. Chemical safety assessment

No additional information available
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 Methacrylic Acid
Safety Data Sheet
according to Regulation (E C ) N o. 1907/2006 (RE A C H ) w ith its amendment Regulation (E U ) 2015/830
Date of issue: 11/24/2011 Rev ision date: 3/22/2018 V ersion: 3.5

SECTION 16: Other information

Full text of H- and EUH-statem ents:

Acute Tox. 3 (Dermal) Acute toxicity (dermal), Category 3
Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
Skin Corr. 1A Skin corrosion/irritation, Category 1A
H302 Harmful if sw allowed.
H311 Toxic in contact w ith skin.
H314 Causes severe skin burns and eye damage.

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be
construed as guaranteeing any specific property of the product
Emergency Numbers
AUSTRIA +43 1 40 400 2222 LATVIA +371 704 2468
BELGIUM/LUXEMBOURG +32 70 245 245 LITHUANIA +370 2 36 20 52 or +370 2 36 20 92
BULGARIA +359 2 9154 409 MALTA (+356) 21 247 860 or (+356) 21 241 251
CZECH REPUBLIC +42 2 2491 9293 or +42 2 2491 5402 NORWAY 22 59 13 00
DENMARK +45 82 12 12 12 NETHERLANDS +31 30 274 88 88
ESTONIA 16662 (24/5 9h00 monday till 9h00 Saturday) POLAND +48 22 619 66 54 or +48 22 619 08 97
FINLAND +358 9 471 977 PORTUGAL 808 250 143 or +351 21 330 3284
FRANCE +33 1 40 05 48 48 ROMANIA +40 21 230 8000
GERMANY +49 30 450 653565 SLOVAKIA +421 2 54 77 4 166
GREECE +30 10 779 3777 SLOVENIA +386 41 650 500
HUNGARY +36 80 20 11 99 SPAIN +34 937 192 561 (08:00-13:00 y 15:00-17:00)
ITALY +39 06 305 4343 SWEDEN +46 8 33 12 31
IRELAND +353 1 8379964 UNITED KINGDOM +44 (0)20 7771 5310

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