CHAPTER 1

NATURAL GAS
FUNDAMENTAL

1.1 INTRODUCTION

Natural gas is used primarily as a fuel and as a raw material in manu-

facturing. It is used in home furnaces, water heaters, and cooking stoves.
As an industrial fuel, it is used in brick, cement, and ceramic-tile kilns; in
glass making; for generating steam in water boilers; and as a clean heat
source for sterilizing instruments and processing foods. As a raw material
in petrochemical manufacturing, natural gas is used to produce hydrogen,
sulfur, carbon black, and ammonia. The ammonia is used in a range of
fertilizers and as a secondary feedstock for manufacturing other chemi-
cals, including nitric acid and urea. Ethylene, an important petrochemical,
is also produced from natural gas.
Natural gas is considered as an environmentally friendly clean fuel,
offering important environmental benefits when compared to other fossil
fuels. The superior environmental qualities over coal or crude oil are that
emissions of sulfur dioxide are negligible or that the levels of nitrous oxide
and carbon dioxide emissions are lower. This helps to reduce problems
of acid rain, ozone layer, or greenhouse gases. Natural gas is also a very
safe source of energy when transported, stored, and used.
This chapter covers, the essential technical points of natural gas. The
objectives of the chapter are to give the reader an introduction to natural
gas by describing the origin and composition of natural gas, gas sources,
phase behavior and properties, and transportation methods.
2 Handbook of Natural Gas Transmission and Processing

1.2 NATURAL GAS HISTORY

The discovery of natural gas dates from ancient times in the Middle East.
Thousands of years ago, it was noticed that natural gas seeps ignited by
lightning created burning springs. In Persia, Greece, or India, people built
temples around these eternal flames for their religious practices. However,
the energy value of natural gas was not recognized until approximately
900 BC in China, and the Chinese drilled the first known natural gas well
in 211 BC. In Europe, natural gas was unknown until it was discovered
in Great Britain in 1659, although it was not commercialized until about
1790. In 1821 in Fredonia, United States, residents observed gas bubbles
rising to the surface from a creek. William Hart, considered as America's
father of natural gas, dug the first natural gas well in North America
(Speight, 1993).
Historically, natural gas was discovered as a consequence of prospect-
ing for crude oil. Natural gas was often an unwelcome by-product, as
natural gas reservoirs were tapped in the drilling process and workers
were forced to stop drilling to let the gas vent freely into the air. Now,
and particularly after the crude oil shortages of the seventies, natural gas
has become an important source of energy in the world. Throughout the
19th century, natural gas was used almost exclusively as a source of light
and its use remained localized because of lack of transport structures,
making it difficult to transport large quantities of natural gas long dis-
tances. There was an important change in 1890 with the invention of
leak-proof pipeline couplings, but transportation of natural gas to long-
distance customers did not become practical until the 1920s as a result of
technological advances in pipelines. Moreover, it was only after World
War II that the use of natural gas grew rapidly because of the development
of pipeline networks and storage systems.

1.3 NATURAL GAS ORIGIN AND COMPOSITION

Natural gas exists in nature under pressure in rock reservoirs in the Earth's
crust, either in conjunction with and dissolved in heavier hydrocarbons
and water or by itself. It is produced from the reservoir similarly to or in
conjunction with crude oil. Natural gas has been formed by the degrada-
tion of organic matter accumulated in the past millions of years. Two main
mechanisms (biogenic and thermogenic) are responsible for this degrada-
tion (Rojey et aL, 1997). Biogenic gas is formed at shallow depths and
 Natural Gas Fundamental 3

low temperatures by the anaerobic bacterial decomposition of sedimentary

organic matter. In contrast, thermogenic gas is formed at deeper depths
by (1) thermal cracking of sedimentary organic matter into hydrocarbon
liquids and gas (this gas is cogenetic with oil and is called "primary"
thermogenic gas) and (2) thermal cracking of oil at high temperatures
into gas ("secondary" thermogenic gas) and pyrobitumen. Biogenic gas
consists almost entirely of methane. In contrast, thermogenic gas can also
contain significant concentrations of ethane, propane, butanes, and heav-
ier hydrocarbons. Knowing whether a natural gas show is biogenic gas or
thermogenic gas can have critical implications for the presence of liquid
hydrocarbons in a basin. Gas geochemistry readily reveals whether a gas
is biogenic or thermogenic.
The principal constituent of natural gas is methane. Other constituents
are paraffinic hydrocarbons such as ethane, propane, and the butanes.
Many natural gases contain nitrogen as well as carbon dioxide and hydro-
gen sulfide. Trace quantities of argon, hydrogen, and helium may also be
present. The composition of natural gas can vary widely. Table 1-1 out-
lines the typical makeup of natural gas before it is refined. Natural gas
can also contain a small proportion of C^" hydrocarbons. When separated,
this fraction is a light gasoline. Some aromatics such as benzene, toluene,
and xylenes can also be present, raising safety issues due to their toxi-
city. Natural gas can contain other contaminants too. Acid contaminants
such as mercaptans—R-SH, carbonyl sulfide (COS), and carbon disulfide
(CS2)—may be present in small quantities. Mercury can also be present
either as a metal in vapor phase or as an organometallic compound in

Table 1-1
Typical Composition of Natural Gas

Name Formula Volume (%)

Methane CH4 >85

Ethane C2H6 3-8
Propane C3H8 1-2
Butane C4H10 <1
Pentane C5H12 <1
Carbon dioxide CO2 1-2
Hydrogen sulfide H2S <1
Nitrogen N2 1-5
HeUum He <0.5
4 Handbook of Natural Gas Transmission and Processing

liquid fractions. Concentration levels are generally very small, but even
at very small concentration levels, mercury can be detrimental due its
toxicity and its corrosive properties (reaction with aluminium alloys).
Natural gas is considered "dry" when it is almost pure methane, having
had most of the other commonly associated hydrocarbons removed. When
other hydrocarbons are present, the natural gas is "wet".
The composition of natural gas varies depending on the field, forma-
tion, or reservoir from which it is extracted. Since the composition of
natural gas is never constant, there are standard test methods by which
the composition of natural gas can be determined and thus prepared for
use. However, it is not the intent to cover the test methods in any great
detail as they are available elsewhere (Speight, 2002).

1.4 GAS SOURCES

Natural gas produced from geological formations comes in a wide array

of compositions. The varieties of gas compositions can be broadly cat-
egorized into three distinct groups: (1) nonassociated gas that occurs in
conventional gas fields, (2) associated gas that occurs in conventional
oil fields, and (3) continuous (or unconventional) gas. Some types of
unconventional gas resources include "tight gas" or "tight sands gas,"
which is found in low-permeability rock; "coalbed methane (CBM),"
which is natural gas that has been formed along with the geological
processes that formed coal; "natural gas from geopressurized aquifers,"
which refers to gas dissolved under high pressure and at high temperatures
in brines located deep beneath the Earth's surface; "gas hydrates," which
are ice-like structures of water and gas located under the permafrost; and
"deep gas," which is found at levels much deeper than conventional gas.
Although there is no scientific consensus, some believe deep gas origi-
nated from inorganic sources and that it exists everywhere as a result of
the geological processes that formed the earth. Of the unconventional gas
sources, the one most important to the gas transportation industry is coal
bed methane.

1.4.1 Non-associated Gas

Nonassociated gas (sometimes called "gas well gas") is produced from

geological formations that typically do not contain much, if any, higher
boiling hydrocarbons (gas liquids) than methane. Nonassociated gas can
 Natural Gas Fundamental 5

contain nonhydrocarbon gases such as carbon dioxide and hydrogen sul-

fide. Nonassociated gas is directly controllable by the producer; one just
turns the valves. The gas flows up the well under its own energy, through
the wellhead control valves, and along the flow line to the treatment plant.
Treatment requires the temperature of the gas to be reduced to a point
dependent upon the pressure in the pipeline so that all liquids that would
exist at pipeline temperature and pressure condense and are removed.

1.4.2 Associated Gas

Associated gas is produced during crude oil production and is the gas
that is associated with crude oil. Crude oil cannot be produced without
producing some of its associated gas, which comes out of solution as the
pressure is reduced on the way to and on the surface. Properly designed
crude oil well completions and good reservoir management are used to
minimize the production of associated gas so as to retain the maximum
energy in the reservoir and thus increase ultimate crude oil recovery.
Crude oil in the reservoir with minimal or no dissolved associated gas is
rare and as dead crude oil is often difficult to produce as there is little
energy to drive it.
After the production fluids are brought to the surface, they are separated
at a tank battery at or near the production lease into a hydrocarbon liquid
stream (crude oil or gas condensate), a produced water stream (brine or
salty water), and a gaseous stream. The gaseous stream is traditionally
very rich (rich gas) in natural gas liquids (NGLs). Natural gas liquids
include ethane, propane, butanes, and pentanes and higher molecular
weight hydrocarbons (C^). The higher molecular weight hydrocarbons
product is commonly referred to as natural gasoline.
When referring to natural gas liquids in the natural gas stream, the term
gallons per thousand cubic feet of gas is used as a measure of hydro-
carbon richness. Depending on its content of heavy components, natural
gas can be considered as rich (5 or 6 gallons or more of recoverable
hydrocarbons per cubic feet) or lean (less than 1 gallon of recoverable
hydrocarbons per cubic feet). However, the terms rich gas and lean gas, as
used in the gas-processing industry, are not precise indicators of gas qual-
ity but only indicate the relative amount of natural gas liquids in the gas
stream.
In the case of associated gas, crude oil may be assisted up the well bore
by gas Uft (Speight, 1993). Thus, gas is compressed into the annulus of
6 Handbook of Natural Gas Transmission and Processing

the well and then injected by means of a gas lift valve near the bottom
of the well into the crude oil column in the tubing. At the top of the well
the crude oil and gas mixture passes into a separation plant that drops
the pressure down to nearly atmospheric in two stages. The crude oil
and water exit the bottom of the lower pressure separator, from where
it is pumped to tanks for separation of the crude oil and water. The gas
produced in the separators and the gas that comes out of solution with the
produced crude oil (surplus gas) are then treated to separate out the NGLs
that are treated in a gas plant to provide propane and butane or a mixture
of the two [liquefied petroleum gas^ LPG]. The higher boiling residue,
after the propane and butane are removed, is condensate, which is mixed
with the crude oil or exported as a separate product. The gas itself is then
dry and, after compression, is suitable to be injected into the natural gas
system where it substitutes for natural gas from the nonassociated gas
reservoir. Pretreated associated gas from other fields enters the system at
this stage (Manning and Thompson, 1991). Another use for the gas is as
fuel for the gas turbines on site. This gas is treated in a fuel gas plant to
ensure that it is clean and at the correct pressure. The start-up fuel gas
supply will be from the main gas system, but facilities exist to collect and
treat low-pressure gas from the various other plants as a more economical
fuel source.
Worldwide, governments are mandating that producers stop flaring
associated gas, as their citizens perceive that it is a waste of a valuable
nonrenewable resource. There are often regulatory restrictions on when
produced gas can be reinjected, or flared, with an understanding that any
reinjected gas must eventually be produced. When such restrictions occur,
oil production must be stopped until this associated gas can somehow be
exported or reinjected.

1.4.3 Coal Bed Methane

Coal bed methane is the generic term given to methane gas held in coal
and released or produced when the water pressure within the buried coal

^LPG is a hydrocarbon mixture containing propane and n-butane. To a lesser extent,

iso-butan& may also be present. The most common commercial products are propane,
butane, or some mixture of the two and are generally extracted from natural gas or crude
petroleum.
 Natural Gas Fundamental 7

is reduced by pumping from either vertical or inclined to horizontal sur-

face holes. The methane is predominantly formed during the coalification
process whereby organic matter is slowly transformed into coal by increas-
ing temperature and pressure as the organic matter is buried deeper and
deeper by additional deposits of organic and inorganic matter over long
periods of geological time. This is referred to as thermogenic coal bed
methane. Alternatively, and more often (but not limited to) in lower rank
and thermally immature coals, recent bacterial processes (involving natu-
rally occurring bacteria associated with meteoric water recharge at outcrop
or subcrop) can dominate the generation of CBM. This is referred to as
late-stage biogenic coal bed methane.
During the coalification process, a range of chemical reactions takes
place that produce substantial quantities of gas. While much of this gas
escapes into the overlying or underlying rock, a large amount is retained
within the forming coal seams. However, unlike conventional natural
gas reservoirs, where gas is trapped in the pore or void spaces of a
rock, such as sandstone, methane formed and trapped in coal is actu-
ally adsorbed onto the coal grain surfaces or micropores and held in place
by reservoir (water) pressure. Therefore, because the micropore surface
area is very large, coal can potentially hold significantly more methane
per unit volume than most sandstone reservoirs.
The amount of methane stored in coal is closely related to the rank and
depth of the coal; the higher the coal rank and the deeper the coal seam
is presently buried (causing pressure on coal) the greater its capacity to
produce and retain methane gas. Because coal has a very large internal
surface area of over 1 billion square feet per ton of coal, it can hold
on average three times as much gas in place as the same volume of a
conventional sandstone reservoir at equal depth and pressure. In order to
allow the "absorbed" gas to be released from the coal it is often necessary
to lower the pressure on the coal. This generally involves removing the
water contained in the coal bed. After the gas is released from the internal
surfaces of the coal it moves through the internal matrix of the coal until
it reaches natural fracture networks in the coal known as cleats. The gas
then flows through these cleats or fractures until it reaches the well bore.
Gas derived from coal is generally pure and requires little or no
processing because it is solely methane and not mixed with heavier hydro-
carbons, such as ethane, which is often present in conventional natural gas.
Coal bed methane has a slightly higher energy value than some natural
gases.
8 Handbook of Natural Gas Transmission and Processing

1.5 NATURAL GAS PHASE BEHAVIOR

The natural gas phase behavior is a plot of pressure vs temperature that

determines whether the natural gas stream at a given pressure and tempera-
ture consists of a single gas phase or two phases: gas and liquid. The phase
behavior for natural gas with a given composition is typically displayed
on a phase diagram, an example of which is shown in Figure 1-1. The
left-hand side of the curve is the bubble point line and divides the single-
phase liquid region from the two-phase gas-liquid region. The right-hand
side of the curve is the dew point line and divides the two-phase gas-
liquid region and the single-phase gas region. The bubble point and dew
point lines intersect at the critical point, where the distinction between
gas and liquid properties disappears. Note that dew point temperatures
are possible at a given pressure, and two dew point pressures are possible
at a given temperature. This phenomenon is known as retrograde con-
densation. The maximum pressure at which liquids can form (Pmax) is
called the cricondenbar, and the maximum temperature at which liquids
can form (Tmax) is called the cricondentherm.
The natural gas phase behavior is a function of the composition of the
gas mixture and is strongly influenced by the concentration of the heav-
ier hydrocarbons, especially C^. The presence of heavier hydrocarbons
will increase the phase envelope and failure to include them in a phase
calculation will underpredict the phase envelope.

Bubble point line

p
"[|2U» Critical point

Dew point line

Figure 1 - 1 . Pressure-temperature diagram for a typical natural gas mixture.

 Natural Gas Fundamental 9

1.6 NATURAL GAS PROPERTIES

1.6.1 Chemical and Physical Properties

Natural gas is colorless, odorless, tasteless, shapeless, and lighter than air
(see Table 1-2). The natural gas after appropriate treatment for acid gas
reduction, odorization, and hydrocarbon and moisture dew point adjust-
ment would then be sold within prescribed limits of pressure, calorific
value, and possibly Wobbe index (often referred to as the Wobbe number).
The Wobbe index (calorific value divided by the specific gravity) gives
a measure of the heat input to an appliance through a given aperture at
a given gas pressure. Using this as a vertical coordinate and the flame
speed factor as the horizontal coordinate, a combustion diagram can be
constructed for an appliance, or a whole range of appliances, with the
aid of appropriate test gases. This diagram shows the area within which

Table 1-2
Properties of Natural Gas

Properties Vailue

Relative molar mass 17-20

Carbon content, weight % 73.3
Hydrogen content, weight % 23.9
Oxygen content, weight % 0.4
Hydrogen/carbon atomic ratio 3.0^.0
Relative density, 15°C 0.72-0.81
Boiling point, °C -162
Autoignition temperature, °C 540-560
Octane number 120-130
Methane number 69-99
Stoichiometric air/fuel ratio, weight 17.2
Vapour flammabiUty limits, volume % 5-15
Flammabihty limits 0.7-2.1
Lower heating/calorific value, MJ/kg 38-50
Stoichiometric lower heating value, MJ/kg 2.75
Methane concentration, volume % 80-99
Ethane concentration, volume % 2.1-A.6
Nitrogen concentration, volume % 0.1-15
Carbon dioxide concentration, volume % 1-5
Sulfur concentration, weight % ppm <5
Specific CO2 formation, g/MJ 38-50
10 Handbook of Natural Gas Transmission and Processing

variations in the Wobbe index and flame speed factor of gases may occur
for the given range of appHances without resulting in incomplete com-
bustion, flame lift, or the lighting back of preaerated flames. This method
of prediction of combustion characteristics is not sufficiently accurate to
eliminate entirely the need for the practical testing of new gases.
Since natural gas as delivered to pipelines has practically no odor, the
addition of an odorant is required by most regulations in order that the
presence of the gas can be detected readily in case of accidents and leaks.
This odorization is provided by the addition of trace amounts of some
organic sulfur compounds to the gas before it reaches the consumer. The
sulfur compound, a chemical odorant (a mercaptan also called a thiol
with the general formula R-SH and the odor of rotten eggs), is added to
natural gas so that it can be smelled if there is a gas leak. The standard
requirement is that a user will be able to detect the presence of the gas
by odor when the concentration reaches 1% of gas in air. Since the lower
limit of flanmiability of natural gas is approximately 5%, this requirement
is equivalent to one-fifth the lower limit of flammability. The combustion
of these trace amounts of odorant does not create any serious problems
of sulfur content or toxicity.
The following section discusses important gas properties, including spe-
cific gravity, compressibility factor, formation volume factor, density,
isothermal compressibility, and viscosity.

1.6.2 Gas-Specific Gravity

Specific gravity of gas is defined as

where Mair is the molecular weight of air, which is equal to 29. Once
we can calculate the value of the molecular weight of the mixture, we can
calculate the specific gravity of the mixture. For a gas mixture, we can
calculate the molecular weight as

M = Y.y,^i (1-2)
i=\
 Natural Gas Fundamental 11

where Mi is the molecular weight of component /, ji is the mole fraction

of component /, and n is the total number of components.
Various gas properties, including the molecular weights for pure
components, are given in Table 1-3.

1.6.3 Ideal and Real Gas Laws

The volume of a real gas is usually less than what the volume of an ideal
gas would be, and hence a real gas is said to be supercompressible. The
ratio of the real volume to the ideal volume, which is a measure of the
amount the gas deviates from perfect behavior, is called the supercom-
pressibility factor, sometimes shortened to the compressibility factor. It is
also called the gas deviation factor and is given the symbol Z. The gas
deviation factor is, by definition, the ratio of the volume actually occu-
pied by a gas at a given pressure and temperature to the volume it would
occupy if it behaved ideally.
The real gas equation of state is then written as

PV = ZnRT (1-3)

where P is the pressure, V is the volume, T is the absolute temperature,

Z is the compressibility, n is the number of kilomoles of the gas, and R is
the gas constant.
The gas deviation factor, Z, is close to 1 at low pressures and high
temperatures, which means the gas behaves as an ideal gas at these con-
ditions. At standard or atmospheric conditions the gas Z factor is always
approximately 1.
The theory of corresponding states dictates that the Z factor can
be uniquely defined as a function of reduced pressure and reduced
temperature. The reduced pressure and reduced temperature are defined as

P T
Pr = - and T, = - (1-4)

where P^ and T^ are reduced pressure and reduced temperature, respec-

tively, and Pc and Tc are critical pressure and critical temperature of the
gas, respectively. The values of critical pressure and critical tempera-
ture can be estimated from the following equations if the composition
 N"
-S>i ^ ^ 00o ONr-H 1-H (N
^-H
CO 1—1
(N
^ C^ <N
O
cn cn
J. 88
O^ O o
8 8 8O^
d^ d^ O^
»n rt ON" vo"
ON ?O
^ »n O
VO en o
O o ^ en vn »n
o O o o
d d d d d d
c
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I—^ 0 0 ^o" r--
00 00 cN cs r^ ''^^ '^. en
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vq oT ''^ FT vo" oo" CTT ^.
asaswSodoNd^r^o ns ^H (N ^' 00 Tt en d vo 5^
o r- en (N S
u cn^ c2 ^ ^ L£J
oo'r^cn'r^'^oo'oo • ^ ' ^ vq" ^ iTf en ^
ONiriuS'^uSod'^cn^^ r^ ^ 00 ^ in t^ cN in r^ vo
^vovocn^(N ^Cr; o r-H o ^ in ^ r- r- <N ^
invot>r-oooo ON^ •^ »> in ^ in in vo r- <N ^"
I , in
^ ^ 0\ r-'Ooas'-HaNCMvovoiz-i
^ C
1D
O 00 ^ O ^'^^ooa^^eno-
r-^ viD en en ^^ o^ i>
VO 00 c^ en en en en en en ri
o- S; rS <^ ^ <^ oo o o\ ON
i> -^^
ri
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-
ON
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<N
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•|/>
Q. ;^ 21 2: d cK 00 d -• 0\
•• -• -• -• oj ^'^ -• -" ^ 00
•5 o
OO 00
v
^ in CS 00 O N
I ^ o tr^ - ^
^inm^^^Ti-enen 3 <r^ 0\ <D ^
en
u
\o o
D5 I
r-TtTt^^r-Hooin(N T-H 0 0 O vo ON en i n
I
^
O N C S C N i n i n i n i ^ O_ e n O O i n 00 en ^ r- i n ^ T-i
e
S
S r^cNenenoOOO o o o o
TtOOOO(N<NCNVOO'^00<NOO(NVO'^^'^0000
D T t i n i n c ^ r - t ^ o o O ' - H C N i ^ ( N r i - c ^ ^ e n v o < N ^
c
0 o
u
Q.
O <N O
O =^ X
c
D
o , 8 S § '^ ^
P (D
£ g PQ -§ PH & o -e -s s
uo -s
w^ < U X r^
 Natural Gas Fundamental 13

of the gas and the critical properties of the individual components are
known:

Pc = J2 ^ci>^i and To = ^ reiji (1-5)

where Pel and Td are the critical pressure and critical temperature of
component /, respectively; and yi is the mole fraction of component /.
Once critical properties of the mixture are calculated as stated in
Eq. (1-5), we can use Eq. (1-4) to calculate the reduced properties of
the mixture.
The values of critical pressure and critical temperature can be estimated
from its specific gravity if the composition of the gas and the critical
properties of the individual components are not known. The method uses
a correlation to estimate pseudocritical temperature and pseudocritical
pressure values from the specific gravity. There are several different corre-
lations available. The most common is the one proposed by Sutton (1985),
which is based on the basis of 264 different gas samples. Sutton (1985)
used regression analysis on raw data to obtain the following second-order
fits for the pseudocritical properties:

Pp, = 756.8 - 131.07Yg - 3.6Yg (1-6)

Tpc = 169.2 + 349.5Yg - 74.0Y5 (1-7)

These equations are valid over the range of specific gas gravities with
which Sutton (1985) worked 0.57 < Yg < 1-68.
The most commonly used method to estimate the Z factor is the chart
provided by Standing and Katz (1942). The Z factor chart is shown in
Figure 1-2. The chart covers the range of reduced pressure from 0 to 15,
and the range of reduced temperature from 1.05 to 3.
The Z factor chart of Standing and Katz (1942) is only valid for mixtures
of hydrocarbon gases. Wichert and Aziz (1972) developed a correlation
to account for inaccuracies in the Standing and Katz chart when the gas
contains significant fractions of acid gases, specifically carbon dioxide
(CO2) and hydrocarbon sulfide (H2S). The Wichert and Aziz (1972) cor-
relation modifies the values of the pseudocritical temperature and pressure
of the gas. Once the modified pseudocritical properties are obtained, they
14 Handbook of Natural Gas Transmission and Processing

PSEUDO REDUCED PRESSURE

2 3 4 5 6
1.1 M-O
%m^^Mm^

N N
DC DC

99 go
CO CO
CO
111 m
DC
DC
CL
Q_

o O
o o

7 8 9 10 11 12 13 14 15
PSEUDO REDUCED PRESSURE P^

Figure 1 - 2 . Compressibility of natural gases as a function of reduced pressure and

temperature (Standing and Katz, 1942).

are used to calculate pseudo-reduced properties and the Z factor is deter-

mined from Figure 1-2. The Wichert and Aziz (1972) correlation first
calculates a deviation parameter e:

8 = 120(A^-^ - A^-^) + 15(S^-^ - 5^) (1-8)

 Natural Gas Fundamental 15

where A is the sum of the mole fractions of CO2 and H2S in the gas
mixture and B is the mole fraction of H2S in the gas mixture.
Then, 8 is used to determine the modified pseudocritical properties as
follows:

7^0 = 7pc - e (1-9)

P T'
P' = lEilPS (1-10)

The correlation is applicable to concentrations of CO2 < 54.4 mol% and

H2S < 73.8 mol%. Wichert and Aziz found their correlation to have
an average absolute error of 0.97% over the following ranges of data:
154 psia < P < 7026 psia and 40°F <T< 300°F.

1.6.4 Gas Formation Volume Factor

The formation volume factor for gas is defined as the ratio of volume
of 1 mol of gas at a given pressure and temperature to the volume of
1 mole of gas at standard conditions (Ps and Tg). Using the real gas law
and assuming that the Z factor at standard conditions is 1, the equation
for formation volume factor (Bg) can be written as

VR nZRT Ps PsZT
B^ = — = — = —— (1-11)
^ Vs P nZsRTs TsP
when Ps is 1 atmosphere (14.6959 psia or 101.325 kPa) and T^ is 60°F
(519.67°R or 288.71°K), this equation can be written in three well-known
standard forms:

ZT
Bg = 0.0283— (1-11-1)

where Bg is in ft^/SCF, P is in psia, and T is in °R. Alternately,

ZT
5g = 0.3507— (1-11-2)

where Bo is in m^/Sm^, P is in KPa, and T is in °K.

16 Handbook of Natural Gas Transmission and Processing

In some cases, it is more convenient to define the value of 5g in bbl/SCF.

The equation can be written as

5g = 0.005— (1-11-3)

where T is in °R and P is in psia.

1.6.5 Gas Density

Gas density is defined as mass per unit volume and so can also be derived
and calculated from the real gas law:

m PM
Pg = - = (1-12)

Knowing that the molecular weight of gas is the product of specific gravity
and molecular weight of air and that the value of/? is 10.73 in field units
[8.314 in SI units], we can write the equation for density as

Pg = 2 . 7 ^ (1-12-1)

where pg is in Ibm/ft^, P is in psia, and Tis in °R. Alternately,

Pg = 3 . 4 9 ^ (1-12-2)

where pg is in kg/m^, P is in kPa, and T is in °K.

The density can also be written as

Pg = 0 . 0 7 6 4 ^ (1-12-3)
^g

where pg is in Ibm/ft^ and Bg is in ft^/SCF. Alternately,

Pg = 1.224^ (1-12-4)
^g

where pg is in kg/m-', and Bg is in m^/Sm^.

 Natural Gas Fundamental 17

1.6.6 Isothermal Compressibility of Gases

The isothermal gas compressibiUty, which is given the symbol Cg, is a

useful concept is used extensively in determining the compressible prop-
erties of the reservoir. The isothermal compressibility is also called the
bulk modulus of elasticity. Gas usually is the most compressible medium
in the reservoir. However, care should be taken so that it is not con-
fused with the gas deviation factor, Z, which is sometimes called the
supercompressibility factor:

' T-; (1-13)

where Vand P are volume and pressure, respectively, and Tis the absolute
temperature. For ideal gas, we can define the compressibiUty as

1
(1-13-1)

whereas, for nonideal gas, compressibility is defined as

1 1 /az\
'«= P - z [JPI •'•'"'
If the relationship between the Z factor and the pressure at a given tem-
perature is known, we can calculate the compressibility of gas. Since
we already know the relationship between Z and P, we can numerically
calculate the derivative and, hence, the value of the compressibility.

1.6.7 Gas Viscosity

Just as the compressibility of natural gas is much higher than that of oil,
water, or rock, the viscosity of natural gas is usually several orders of
magnitude lower than oil or water. This makes gas much more mobile
in the reservoir than either oil or water. Reliable correlation charts are
available to estimate gas viscosity, and the viscosity of gas mixtures at
one atmosphere and reservoir temperature can be determined from the gas
18 Handbook of Natural Gas Transmission and Processing

mixture composition:

H^ = '-^ (1-14)

i=l

where |Xga is the viscosity of the gas mixture at the desired temperature
and atmospheric pressure, yi is the mole fraction of the /th component,
|Xga is the viscosity of the /th component of the gas mixture at the desired
temperature and atmospheric pressure, Mgi is the molecular weight of the
/th component of the gas mixture, and A^ is the number of components in
the gas mixture. This viscosity is then multiplied by the viscosity ratio to
obtain the viscosity at reservoir temperature and pressure.

1.7 QUALITY

The amount of energy that is obtained from the burning of a volume of

natural gas is measured in British thermal units (Btu). The value of nat-
ural gas is calculated by its Btu content. The energy content of natural
gas is variable and depends on its accumulations, which are influenced
by the amount and types of energy gases they contain: the more noncom-
bustible gases in a natural gas, the lower the Btu value. In addition, the
volume mass of energy gases that are present in a natural gas accumula-
tion also influences the Btu value of natural gas. The more carbon atoms
in a hydrocarbon gas, the higher its Btu value. Btu analyses of natural gas
are done at each stage of the supply chain. Gas chromatographic process
analyzers are used in order to conduct fractional analysis of the natural gas
streams, separating natural gas into identifiable components. The compo-
nents and their concentrations are converted into a gross heating value in
Btu-cubic foot.
Normally, natural gas as it is when extracted is not suitable for pipehne
transportation or commercial use before being processed. Pipelines set
their specifications for the quality of natural gas. In any case, natural gas
must be processed in order to remove unwanted water vapor, solids, or
other contaminants and to get those hydrocarbons that have a higher value
as separate products.
 Natural Gas Fundamental 19

1.8 TRANSPORTATION

Gas, as a result of the storage difficulties, needs to be transported imme-

diately to its destination after production from a reservoir (Cranmore and
Stanton, 2000a). There are a number of options for transporting natural
gas energy from oil and gas fields to market (Rojey et ai, 1997; Thomas
and Dawe, 2003). These include pipelines, liquefied natural gas (LNG),
compressed natural gas (CNG), gas to solids (GTS), i.e., hydrates, gas
to power (GTP), i.e., electricity, and gas to liquids (GTL), with a wide
range of possible products, including clean fuels, plastic precursors, or
methanol and gas to commodity (GTC), such as aluminum, glass, cement,
or iron. The following section examines some of these technical methods
by which natural gas energy can be transported and covers many of the
essential points needed to enter the discussion.

1.8.1 Pipelines

Pipelines are a very convenient method of transport but are not flexible as
the gas will leave the source and arrive at its (one) destination (Cranmore
and Stanton, 2000b). If the pipeline has to be shut down, the produc-
tion and receiving facilities and refinery often also have to be shut down
because gas cannot be readily stored, except perhaps by increasing the
pipeline pressure by some percentage.
In the last decade, on average, over 12,000 miles per year of new gas
pipelines have been completed;most are transnational. If political sta-
bility can be guaranteed, pipelines may be able to provide a long-term
solution for transportation. An example of this approach is a proposed
deep water pipeline from Oman to India (EIA, 2002). However, the cost
of building such a pipeline remains unclear. Subsea lines over 2000 miles
have, until recently, been regarded as uneconomic because of the subsea
terrain making pipeline installation and maintenance expensive and any
recompression along the route difficult, but changes are in the air! If tech-
nical and economic hurdles can be overcome, these pipelines can become
effective.

1.8.2 Liquefied Natural Gas

Liquefied natural gas technology has been proven to be effective since

the mid-1970s. LNG is the liquid form of natural gas. Gas cooled to
20 Handbook of Natural Gas Transmission and Processing

approximately — 162°C liquefies and has a volume approximately 1/600

that of gas at room temperature. However, facilities for liquefying natural
gas require complex machinery with moving parts and special refriger-
ated ships for transporting the liquefied natural gas to market (Cranmore
and Stanton, 2000b). The costs of building a liquefied natural gas plant
have lowered since the mid-1980s because of greatly improved thermo-
dynamic efficiencies, making liquefied natural gas a major gas export
method worldwide, and many plants are being extended or new ones are
being built in the world.
Large cryogenic tanks are needed to store the liquefied natural gas;
typically these may be 70 m in diameter, 45 m high, and hold over
100,000 m^ of liquefied natural gas. At the consumer end, an infrastruc-
ture for handling the reprocessing of vast quantities of natural gas from
LNG is required, which is also expensive and vulnerable to sabotage.
The current largest specially built refrigerated tankers can carry
135,000 m^ of liquefied natural gas, equivalent to 2.86 billion scf of
gas, but are very expensive. This makes it difficult for liquefied natural
gas to use smaller isolated (offshore) reserves and to serve small markets
commercially because it is this large capacity and continuous running
that keep thermodynamic efficiency high and costs to a minimum. Thus
small volumes of intermittent gas are not economically attractive to the
major gas sellers for liquefied natural gas facilities. However, a small
well-insulated liquefied natural gas container trade is being investigated,
and, if successful, small quantities of liquefied natural gas may be able
to be delivered from liquefied natural gas storage, just like the gasoline
tankers of today. Even so, liquefied natural gas must be stored for periods
of time (months) without significant boil-off losses, which is difficult.
LNG will likely play an increasing role in the development of giant
gas fields, as most countries, especially net oil importers, are keen on
developing their gas reserves, however stranded, for greater energy inde-
pendence and extending domestic oil reserves where applicable, as well
as for environmental reasons.

1.8.3 Compressed Natural Gas

Gas can be transported in containers at high pressures, typically 1800 psig

for a rich gas (significant amounts of ethane, propane, etc.) to roughly
3600 psig for a lean gas (mainly methane). Gas at these pressures is
termed compressed natural gas. Compressed natural gas is used in some
 Natural Gas Fundamental 21

countries for vehicular transport as an alternative to conventional fuels

(gasoline or diesel). The filling stations can be supplied by pipeline gas,
but the compressors needed to get the gas to 3000 psig can be expensive
to purchase, maintain, and operate.
An alternative approach has dedicated transport ships carrying straight
long, large-diameter pipes in an insulated cold storage cargo package.
The gas has to be dried, compressed, and chilled for storage onboard.
By careful control of temperature, more gas should be transported in any
ship of a given payload capacity, subject to volume limitation and amount
and weight of material of the pipe (pressure and safety considerations).
Suitable compressors and chillers are needed, but would be much less
expensive than a natural gas liquefier and would be standard so that costs
could be further minimized. According to the proponents, the terminal
facilities would also be simple and hence less expensive. Two new types
of CNG transport are being promoted by their respective companies and
are discussed next (Fischer, 2001):
"VOTRANS" is a new type of CNG marine-transport technology from
EnerSea Transport, L.L.C. Its engineering studies indicate that it can move
up to 2 Bcf per ship over distances up to 4000 miles at significantly
lower total costs than LNG. The technology comprises large-diameter pipe
structures manifolded together in tiers, essentially a sea-going pipeline.
To maintain temperature, the pipe structures are contained within a
nitrogen-filled, insulated chamber. It can store CNG more efficiently at
significantly lower compression (~40% compared to LNG), increase ves-
sel capacities, reduce costs, and transport both lean and rich gas. Finally,
VOTRANS minimizes gas losses during processing and transport to less
than 7% compared to as much as 20% for LNG.
"Coselle" CNG technology is from Cran & Stenning Technology Inc.
The system uses conventional, 10.6-mile-long, 6-in diameter, 1/4-in wall
thickness line pipe in large coils (coselles). Such a CNG carrier may
have 108 coselles with a 330-MMcfg capacity. Stored gas temperature is
50°F at 3000 psi. American Bureau of Shipping and Det Norske Veritas
have concluded that a Coselle CNG carrier is "at least as safe as other
gas carriers." These ships can be loaded at relatively simple marine
facilities, including offshore buoy moorings, through flexible hoses con-
nected to onshore or on-platform compressor stations (Stenning, and
Cran, 2000).
"Coselle" and "VOTRANS" are two would-be commercial, high-
pressure gas storage and transport technologies for CNG. Technical and
22 Handbook of Natural Gas Transmission and Processing

economic analyses of these two technologies were done by Economides

et aL (2005).
Compressed natural gas technology provides an effective way for
shorter-distance transport of gas. The technology is aimed at monetizing
offshore reserves, which cannot be produced because of the unavailabil-
ity of a pipeUne or because the LNG option is very costly. Technically,
CNG is easy to deploy with lower requirements for facilities and infras-
tructure. Results show that for distances up to 2500 miles, natural gas
can be transported as CNG at prices ranging from $0.93 to $2.23 per
MMBTU compared to LNG, which can cost anywhere from $1.5 to
$2.5 per MMBTU depending on the actual distance. At distances above
2500 miles the cost of delivering gas as CNG becomes higher than the
cost for LNG because of the disparity in the volumes of gas transported
with the two technologies (Economides et aL, 2005).

1.8.4 Gas to Solid

Gas can be transported as a solid, with the solid being gas

hydrate (B0rrehaug and Gudmundsson, 1996; Gudmundsson, 1996;
Gudmundsson and B0rrehaug, 1996; Gudmundsson et aL, 1995, 1997).
Natural gas hydrate is the product of mixing natural gas with liquid water
to form a stable water crystalline ice-like substance. NGH transport, which
is still in the experimental stage, is believed to be a viable alternative to
liquefied natural gas or pipelines for the transportation of natural gas from
source to demand.
Gas to solids involves three stages: production, transportation, and
regasification. Natural gas hydrates are created when certain small
molecules, particularly methane, ethane, and propane, stabilize the hydro-
gen bonds within water to form a three-dimensional, cage-hke structure
with the gas molecule trapped within the cages. A cage is made up of
several water molecules held together by hydrogen bonds. Hydrates are
formed from natural gas in the presence of liquid water, provided the
pressure is above and the temperature is below the equilibrium line of
the phase diagram of the gas and liquid water. The solid has a snow-like
appearance.
In the oil/gas industry, natural hydrates are a pipeUne nuisance and
safety hazard. Considerable care must be taken by the operators to ensure
that these hydrates do not form, as they can block pipelines if precautions,
such as methanol injection, are not taken. However, vast quantities of gas
 Natural Gas Fundamental 23

hydrate have been found in permafrost and at the seabed in depths below
500 m (1500 ft) and, if exploited properly, could become the major energy
source in the next 30 years.
For gas transport, natural gas hydrates can be formed deliberately by
mixing natural gas and water at 80 to 100 bar and 2 to 10°C. If the slurry is
refrigerated to around — 15°C, it decomposes very slowly at atmospheric
pressure so that the hydrate can be transported by ship to market in sim-
ple containers insulated to near-adiabatic conditions. At the market, the
slurry is melted back to gas and water by controlled warming for use
after appropriate drying in electricity power generation stations or other
requirements. The hydrate mixture yields up to 160 m^ of natural gas
per ton of hydrate, depending on the manufacture process. The manu-
facture of the hydrate could be carried out using mobile equipment for
onshore and ship for offshore using a floating production, storage, and
off-loading vessel with minimal gas processing (cleaning, etc.) prior to
hydrate formation, which is attractive commercially.
Conceptually, hydrate slurry production is simply mixing chilled water
and gas. In practice, processed gas is fed to a hydrate production plant,
where a series of reactors convert it into hydrate slurry. Each reactor
further concentrates the hydrate slurry. It is then stored and eventually
offloaded onto a transport vessel. At the receiving terminal, the hydrate
is dissociated and the gas can be used as desired. The water can be used
at the destination if there is a water shortage or returned as ballast to the
hydrate generator; because it is saturated with gas, will not take more gas
into solution.
The hydrate mixture can be stored at normal temperatures (0 to — 10°C)
and pressures (10 to 1 atmosphere) where 1 m^ of hydrate should contain
about 160 m^ gas per m^ of water. This concentration of gas is attractive,
as it is easier to produce, safer, and less expensive to store compared to
the 200-m^ per 1 m^ of compressed gas (high pressure ca. 3000 psig)
or the 637-m^ gas per 1 m^ of liquefied natural gas (low temperatures
of-162°C).
Gas storage in hydrate form becomes especially efficient at relatively
low pressures where substantially more gas per unit volume is contained
in the hydrate than in the free state or in the compressed state when the
pressure has dropped. When compared to the transportation of natural gas
by pipeline or as liquefied natural gas, the hydrate concept has lower cap-
ital and operating costs for the movement of quantities of natural gas over
adverse conditions. Thus, gas hydrate is very effective for gas storage and
24 Handbook of Natural Gas Transmission and Processing

transport as it eliminates low temperatures and the necessity of compress-

ing the gas to high pressures. Dry hydrate pellets yield about 160 m-^ of
gas at standard conditions from 1 m^ of hydrate compared to the 637-m^
per 1 m-^ of Uquefied natural gas. This is a considerable volume penalty
(and hence transport cost) if considered in isolation; with less expensive
ships for hydrate transport, the process could be economic.

1.8.5 Gas to Power

Currently, much of the transported gas destination is fuel for electric-

ity generation. Electricity generation at or near the reservoir source and
transportation by cable to the destination(s) (GTP) is possible. Thus, for
instance, offshore or isolated gas could be used to fuel an offshore power
plant (may be sited in less hostile waters), which would generate electric-
ity for sale onshore or to other offshore customers. Unfortunately, because
installing high-power lines to reach the shoreline appears to be almost as
expensive as pipelines, that gas to power could be viewed as defeating
the purpose of an alternative less expensive solution for transporting gas.
There is significant energy loss from the cables along the long-distance
transmission lines, more so if the power is AC rather than DC; addition-
ally, losses also occur when the power is converted to DC from AC and
when it is converted from the high voltages used in transmission to the
lower values needed by the consumers.
Some consider having the energy as gas at the consumers' end gives
greater flexibility and better thermal efficiencies because the waste heat
can be used for local heating and desalination. This view is strengthened
by economics, as power generation uses approximately 1 million scf/day
of gas for every 10 MW of power generated so that even large gener-
ation capacity would not consume much of the gas from larger fields
and thus not generate large revenues for the gas producers. Neverthe-
less, gas to power has been an option much considered in the United
States for getting energy from the Alaskan gas and oil fields to populated
areas.
There are other practical considerations to note such as if the gas is
associated gas, then if there is a generator shutdown and no other gas
outlet, the whole oil production facility might also have to be shut down
or the gas released to flare. Also, if there are operational problems within
the generation plant the generators must be able to shut down quickly
(in around 60 s) to keep a small incident from escalating. Additionally, the
 Natural Gas Fundamental 25

shutdown system itself must be safe so that any plant that has complicated
processes that require a purge cycle or a cool-down cycle before it can
shut down is clearly unsuitable (Ballard, 1965). Finally, if the plant cannot
shut down easily and/or be able to start up again quickly (perhaps in an
hour), operators will be hesitant to ever shut down the process for fear of
financial retribution from the power distributors.

1.8.6 Gas to Liquids

In GTL transport processes, the natural gas is converted to a liquid, such

as syncrude methanol and ammonia, and is transported as such (Knott,
1997; Skrebowski, 1998; Thomas, 1998; Gaffney Cline and Associates,
2001). The technology of converting natural gas to liquids is not new.
In the first step, methane is mixed with steam and converted to syngas
or synthetic gas (mixtures of carbon monoxide and hydrogen) by one
of a number of routes using suitable new catalyst technology (Cranmore
and Stanton, 2000a). The syngas is then converted into a liquid using a
Fischer-Tropsch process (in the presence of a catalyst) or an oxygenation
method (mixing syngas with oxygen in the presence of a suitable catalyst).
The produced liquid can be a fuel, usually a clean-burning motor fuel
(syncrude) or lubricant, or ammonia or methanol or some precursor for
plastics manufacture (e.g., urea, dimethyl ether, which is also used as a
transportation fuel, LPG substitute, or power generation fuel, as well as
a chemical feedstock). Hundreds of modifications and patents have been
applied to this complex, energy-intensive process, and further develop-
ments continue to the present day. Most recent modifications generally
involve lowering capital expenditures and the overall energy required for
processing, especially through the use of proprietary catalysts and the
manner in which oxygen is added to the system.
Methanol is a gas-to-liquids option that has been in conmiission since
the mid-1940s. While methanol produced from gas was originally a rela-
tively inefficient conversion process, optimized technology has improved
the efficiency. Methanol can be used in internal combustion engines
as a fuel, but the current market for methanol as a fuel is limited,
although the development of fuel cells for motor vehicles may change this.
Methanol is best used as a basic chemical feedstock for the manufacture of
plastics.
Other GTL processes are being developed to produce clean fuels, e.g.,
syncrude, diesel, or many other products, including lubricants and waxes.
26 Handbook of Natural Gas Transmission and Processing

from gas but require a complex (expensive) chemical plant with novel
catalyst technology.

1.8.7 Gas to Commodity

Commodities such as aluminium, glass, bricks, cement, and iron bars all
require large quantities of energy in their making. In the gas-to-commodity
concept, the gas is converted to thermal or electrical power, which is
then used in the production of the conmiodity, which is then sold on the
open market. It is the energy from the gas, heat via electricity or direct
combustion, and not the components of the gas-to-liquids concept that is
used. The gas energy is, in essence, transported via the commodity, but
there are many market risks, which should be fully assessed. The cost of a
GTC plant is very high and raw materials for conversion to commodities,
e.g., bauxite, silica sand, and limestone, may be difficult to import to sites
with reliability. Therefore, much thought has to be given before embarking
on the project(s) and monetizing the gas by this route (Thomas and Dawe,
2003).
As discussed earlier, there are a number of options of exporting natural
gas energy from oil and gas fields to market. Any gas energy export route
requires a huge investment in infrastructure and long-term "fail-proof"
contracts, covering perhaps 20 years or more. But which is the best way
to monetize the gas? Gas-rich countries are currently in this challenging
debate. There could be options for handling niche markets for gas reserves
that are stranded (no market) and for associated gas (on- or offshore) that
cannot be flared or reinjected or for small reservoirs that cannot otherwise
be exploited economically. Transportation of natural gas as a hydrate or
CNG is believed feasible at costs less than for LNG and where pipelines
are not possible. The competitive advantage of GTS or CNG over the
other nonpipeline transport processes is that they are intrinsically simple,
making them much easier to implement at lower capital costs, provided
economically attractive market opportunities can be negotiated to the gas
seller. The transport options preferred by governments and companies
must not only take the economic risks into account, but must also consider
the negative effects of possible terrorist activity, political changes, and
trade embargos over long periods of time. Thomas and Dawe (2003)
cover many of the essential technical points and broad economic pointers
needed to enter the discussion of gas-rich states that do not need the gas
for domestic use, but wish to monetize their reserves by export.
 Natural Gas Fundamental 27

REFERENCES

Ballard, D., How to operate quick-cycle plants, Hydrocarbon Proc. 44(4),

131 (1965).
B0rrehaug, A., and Gudmundsson, J.S., Gas transportation in hydrate
form, "In Proceeding of EUROGAS 96," pp. 35-41, Trondheim
(June 3-5, 1996).
Cranmore, R.G, and Stanton, E., Natural gas. In Modem Petroleum Tech-
nology, (R.A. Dawe, ed.). Chapter 9. Wiley, Hoboken, NJ (2000a).
Cranmore, R.G, and Stanton, E., Transport, In Modem Petroleum
Technology, (R.A. Dawe, ed.,) Chapter 10. Wiley, Hoboken,
NJ (2000b).
Economides, M.J., Sun, K., and Subero, G, "Compressed Natural Gas
(CNG): An Altemative to Liquid Natural Gas (LNG)," SPE 92047,
Paper presented at the Asia Pacific Oil and Gas Conference and
Exhibition, Jakarta, Indonesia (April 5-7, 2005).
EIA, "Natural Gas Monthly" (August 1997), downloaded from Energy
Information Administration (EIA) web site: http://www.eia.gov
(2002).
Fischer, P.A., How operators will bring worthless gas to market. Natural
Gas, Part 8, Monetizing Stranded Gas, World Oil 222, 11 (2001).
Gaffney Cline and Associates, "GTL Discussion," Paper prepared for
the Gas to Liquids Taskforce, Australian Department of Industry,
Science & Resources, Commonwealth of Australia (June 2001).
Gudmundsson, J.S., "Method for Production of Gas Hydrate for Trans-
portation and Storage," U.S. Patent No. 5, 536, 893 (1996).
Gudmundsson, J.S., Hveding, R, and B0rrehaug, A., Transport of natural
gas as frozen hydrate, "In Proceeding of the 5th Intemational Off-
shore and Polar Engineering Conference," Vol. I, pp. 282-288, The
Hague, The Netherlands (June 11-16, 1995).
Gudmundsson, J.S., and B0rrehaug, A., Frozen hydrate for transport
of natural gas, "In Proceeding of the 2nd Intemational Confer-
ence on Natural Gas Hydrates," pp. 415^22, Toulouse (June 2-6,
1996).
Gudmundsson, J.S., Andersson, V., and Levik, O.I., "Gas Storage
and Transport Using Hydrates," paper presented at the Offshore
Mediterranean Conference, Ravenna (March 19-21, 1997).
Knott, D., Gas-to-liquids projects gaining momentum as process list
grows. Oil Gas /, 16-21 (June 23, 1997).
28 Handbook of Natural Gas Transmission and Processing

Manning, F.S., and Thompson, R.E., "Oil Field Processing of Petroleum,"

Vol. 1. Pennwell Publishing Company, Tulsa, OK (1991).
Rojey, A., Jaffret, C , Comot-Gandolph, S., Durand, B., JuUin, S.,
and Valais, M., "Natural Gas Production, Processing, Transport,"
Editions Technip, Paris, France (1997).
Skrebowski, C , Gas-to-liquids or LNG? Petroleum Rev. 38-39
(Jan. 1998).
Speight, J.G, "Gas Processing: Environmental Aspects and Methods,"
Butterworth Heinemann, Oxford, England (1993).
Speight, J.G, "Handbook of Petroleum Product Analysis," Wiley,
Hoboken, NJ (2002).
Standing, M. B., and Katz, D. L., Density of natural gases. Trans. AIME
142, 140-149 (1942).
Stenning, D.G, and Gran, J.A., "Coselle CNG Economics and Opportu-
nities: A New Way to Ship Natural Gas by Sea," Paper presented at
the Gastech 2000 Conference, Houston, TX (Nov. 14-17, 2000).
Sutton, R. P., "Compressibility Factor for High Molecular Weight Reser-
voir Gases," SPE 14265. Paper presented at the SPE Annual
Technical Conference and Exhibition, Las Vegas, NV (Sept. 22-25,
1985).
Thomas, M., Water into wine: Gas-to-liquids technology the key to
unlocking future reserves, Euroil (May 17-21, 1998).
Thomas, S., and Dawe, R.A., Review of ways to transport natural gas
energy from countries which do not need the gas for domestic use.
Energy Int. J. 28, \A6\~U11 (2003).
Whitson, C. H., and Brule, M. R., "Phase Behavior," SPE Monograph
No. 20, Richardson, TX (2000).
Wichert, E., and Aziz, K., Calculate Z's for sour gases. Hydrocarbon
Proc. 51, 119-122 (May 1972).