GE Energy Products – Europe

OPERATION AND MAINTENANCE MANUAL

COMPONENT AND SYSTEM LITERATURE

________________________________________________________________________

EQUIPMENT DEFINITION

GE DEVICE :

DESIGNATION : LIQUID AND SOLID COMPOUND CLEANING

RECOMMENDATIONS FOR DLN GAS
TURBINE

SUPPLIER :

TYPE : GEK 103623

LITERATURE REFERENCE : GEK 103623

________________________________________________________________________
All rights reserved Copyright – Droits de reproduction réservés
OMML_0442_01_Recommendations_EN_A Revision : A Date : 05/2006
 GEK 103623c
Revised September 2005

GE Energy

Gas Turbine Compressor Washing

Liquid Washing Recommendations for DLN Gas Turbines

These instructions do not purport to cover all details or variations in equipment nor to provide for
every possible contingency to be met in connection with installation, operation or maintenance. Should
further information be desired or should particular problems arise which are not covered sufficiently for
the purchaser's purposes the matter should be referred to the GE Company.
© 2005 General Electric Company
GEK 103623c Gas Turbine Compressor Washing

TABLE OF CONTENTS

I. SCOPE ............................................................................................................................................ 3

II. INTRODUCTION.......................................................................................................................... 3

III. TYPES OF FOULING................................................................................................................... 4

IV. METHODS OF DETECTION...................................................................................................... 4

A. Visual Inspection...................................................................................................................... 4
B. Performance Monitoring .......................................................................................................... 4

V. WATER AND WATER AND DETERGENT WASHING METHOD ....................................... 4

VI. ALLOWABLE CONDITIONS FOR WATER WASH ............................................................... 5

VII. WASHING AND RESTORATION OF PERFORMANCE ....................................................... 5

A. Water or Detergent Wash ......................................................................................................... 5
B. Results of Washing................................................................................................................... 13

APPENDIX 1 COMPRESSOR WASHING DETERGENT SPECIFICATION ............................. 15

I. SCOPE ............................................................................................................................................ 15

II. REQUIREMENTS......................................................................................................................... 15

III. MATERIAL COMPATIBILITY .................................................................................................. 15

IV. TESTS ............................................................................................................................................. 15

A. Ash Content: Preparation of Test Samples .............................................................................. 15
B. Accelerated Storage Stability (from MIL-C-85704A)............................................................. 15

LIST OF TABLES

Table 1. QUALITY SPECIFICATION................................................................................................. 14

Table 2. WATER AND/OR WATER AND DETERGENT SOLUTION INJECTION (FLOW)
RATES...................................................................................................................................... 14
Table 3. CHEMICAL CONTENT OF WASHING DETERGENT ....................................................... 16

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Gas Turbine Compressor Washing GEK 103623c

I. SCOPE

The scope of this document is to present the methods of compressor washing approved by GE. Two meth-
ods of liquid washing are employed — on line and off line. On-line washing is the process of injecting
water into the compressor while running at full speed and some percentage of load. Off-line washing is
the process of injecting cleaning solution into the compressor while it is being turned at cranking speed.
The advantage of on-line washing is that it can be done without having to shut down the machine. On-line
washing, however, is not as effective as off-line washing; therefore, on-line washing is used to supplement
off-line washing, not replace it.

This document applies to all gas turbine models offered by Gas Turbine Division and addresses units op-
erating with DLN systems.

NOTE

It is recommended that a unit-specific procedure and checklist be created by each

customer. The procedure and checklist should include configuring the unit for
water wash, performing water wash and restoration following water wash. These
procedures should conform to the enclosed general guidelines. Technical assis-
tance can be provided by General Electric in preparing the unit specific procedures
and checklists.

II. INTRODUCTION

A loss of gas turbine performance is indicated by a decrease in power output and an increase in heat rate.

Often a loss of performance is a direct result of fouling of the axial flow compressor. Fouled compressors
result in reduced air flow, lower compressor efficiency and a lower compressor pressure ratio.

Compressor washing will remove fouling deposits and restore performance. It should be noted that full
power may not always be regained once significant fouling occurs. Regular compressor washing will help
maintain performance. Specific intervals must be determined based on customer performance. Compressor
washing may also slow the progress of corrosion, thereby increasing blade life and reducing the contribu-
tion of corrosion products to the formation of fouling deposits.

III. TYPES OF FOULING

The type and rate of fouling of an axial compressor depends on the environment in which it operates and
the filtration present.

Experience has shown that fouling deposits consist of varying amounts of moisture, oil, soot, water-soluble
constituents, insoluble dirt and corrosion products of the compressor blading material. Fouling deposits are
probably held together by moisture and oil. If corrosion of the blading is occurring, the corrosion products
will promote and stabilize the deposit.

It is important to minimize fouling deposits by reducing oil leaks and the ingestion of oily constituents
(lube oil fumes). Good filtration may greatly reduce fouling. Moisture formation cannot be reduced in
humid environments. Moisture is formed in the compressor inlet when humid air is cooled below its dew
point as a result of being accelerated to about Mach = 0.5. GER 3601, “Gas Turbine Compressor Operating
Environment and Material Evaluation,” discusses the factors influencing compressor fouling and corrosion.

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GEK 103623c Gas Turbine Compressor Washing

IV. METHODS OF DETECTION

There are two basic methods for determining the cleanliness of the compressor. Visual inspection and
performance monitoring are described below.

A. Visual Inspection

Visual inspection involves shutting the unit down; removing the inlet plenum inspection hatch; and
visually inspecting the compressor inlet, bellmouth, inlet guide vanes and early stage blading.

If any deposits, including dust or filmy deposits, can be wiped or scraped off these areas, the compressor
is fouled sufficiently to affect performance. The initial inspection also reveals whether the deposits are
oily or dry. For oily deposits, a water-detergent wash is required. Location of the source of the oil and
correction should be accomplished before washing to prevent recurrence of the fouling.

If only dry deposits are found, water alone may be sufficient.

B. Performance Monitoring

A second method for detecting a fouled compressor is performance monitoring. Performance monitor-
ing involves obtaining gas turbine data on a routine basis, which in turn is compared to base line data
to monitor trends in the performance of the gas turbine.

The performance data is obtained by running the unit at steady-state BASE load and recording output,
exhaust temperature, inlet air temperature, barometric pressure, compressor discharge pressure and
temperature, and fuel consumption. The data should be taken carefully with the unit warmed up.

GEK 28166, “Field Performance Testing Procedure,” can be used as a guide for assessing machine per-
formance both before and after cleaning the compressor. The purpose of this particular document is to
establish the performance of generator drive machines. The appropriate portions can, however, also be
used for all machines, both generator drive and other applications, for assessing cleaning effectiveness.

Output and heat rate can be corrected to a standard condition using the turbine performance curves, and
an analysis can be made of compressor pressure ratio and efficiency. The current performance levels
can be compared to base line data and will aid in determining the problem area.

If performance analysis indicates compressor fouling, it should be verified by a visual inspection.

V. WATER AND WATER AND DETERGENT WASHING METHOD

It is recommended that on-line water washing be addressed in the facility's operating air permit. Regula-
tors may interpret this as an additional short-term emissions source, requiring an exemption similar to that
provided for start-up, shutdown and transient conditions.

The compressor is washed with water and/or water and detergent solution. This can be accomplished while
the turbine is on line or off line. As the on-line washing practice has been found to be most effective when
carried out daily, the specification on the liquid must be more restrictive for on-line washing than off-line
washing. The water specifications for off-line and on-line cleaning are given in Table 1.

It is recommended that on-line water washing be performed without the use of detergent. The detergent
effectiveness during on-line wash is limited as there is no soak time as there is for off-line wash.

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Gas Turbine Compressor Washing GEK 103623c

Except for the pH, the restrictions in these specifications are concerned with deposits and corrosion of the
hot gas path. The pH restriction is concerned with corrosion in the water-handling system. High-purity
demineralized water after contact with air will have a pH in the range of 5.0 to 6.0. Thus, allowance has
been made in the pH provided this is the reason for the low pH.

If a detergent is used, additional restrictions are required to ensure no harm will result to turbine compo-
nents.

In general, deposits will contain some water-soluble material and oils. The latter will be more amenable to
removal by detergent, but the deposit may be removable by water washing alone, depending on the amount
of water-soluble material present. Hot water at 150 to 200°F (66-93°C) is generally more effective than
cold water.

There are a number of detergents commercially available for this purpose, some of which, along with the
deposits that have been removed, may constitute a hazardous solid waste (as defined by the US Environ-
mental Protection Agency) when used for an off-line wash. Because of this possibility, local regulations
should be considered for the storage, handling and treatment of the water wash effluent when the drain and
containment system is designed.

VI. ALLOWABLE CONDITIONS FOR WATER WASH

For an on-line wash the compressor inlet temperature, CTIM from the Speedtronic panel, must be greater
than 50°F (10°C). CTIM must be measured with inlet bleed heat off. Refer to TIL1153-3 for guidance on
performing cold weather on-line washing.

On—line water washing should not be performed while inlet bleed heat is operating for any reason. Do not
force inlet bleed heat off to satisfy this restriction. If inlet bleed heat turns on for any reason while washing,
the water wash procedure should be suspended.

For off-line water wash the operator must take appropriate precautions to prevent freezing in the compressor
inlet, gas turbine, exhaust and drain system. Off-line water washing should not be done at compressor inlet
temperatures,CTIM, less than 40°F (4°C), measured while cranking.

VII. WASHING AND RESTORATION OF PERFORMANCE

A. Water or Detergent Wash

1. Off-Line Compressor Wash

The intention of this procedure is to isolate all air extraction points and drain all low points. It is
recognized that additional isolations and drains may be required depending on specific systems,
equipment and customer supplied equipment and interconnect piping.

It is recommended that the customer develop a customized checklist for the preparation and restora-
tion of the gas turbine for an off-line water wash.

Off-line compressor water wash is required if compressor performance degrades 8% due to fouling.

1. Preparation

a. Off-line washing solution must meet the requirements of Table 1.

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GEK 103623c Gas Turbine Compressor Washing

b. The cooldown procedure must be continued until the wheelspace temperatures are within
120°F (67°C) of the wash water temperature.

CAUTION

To prevent thermal shock, wheelspace temperature must be no more than 120°F

(67°C) greater than the wash water temperature. If cool water is used [50°F
(10°C)], the wheelspace temperature must not exceed 170°F (77°C). If hot water
[180°F (82°C)] is used, the wheelspace temperature must not exceed 300°F
(149°C).

c. If a unit is equipped with off-base atomizing air compressor, the compressor should be
deenergized during the wash and rinse cycles.

d. Open inlet guide vanes, if applicable.

e. Close flame detector valves or blank-off. Water will foul the flame scanners and make
starting difficult.

f. When regenerators are present, the gas-side face must be covered and kept dry during
compressor washing to prevent wetting regenerator deposits. These deposits may change
form when wet and become extremely difficult to remove. Leave access doors open while
cranking to provide an air exhaust path.

g. Fuel manifold drains are to remain closed during wash to prevent water from entering.
Open during dry cycle.

h. Manually ioslate systems, open drains and divert drains as follows:

a) The flow through the false start drain valves (VA17) must be diverted from the sludge
tank to a wash water effluent tank on turbines that operate on liquid fuel or have the
capability to.

NOTE

The false start drain flow or any flow that goes normally to the sludge tank must be
diverted from its “normal” path into the sludge tank, into the wash water effluent
drain to prevent an overflow of the sludge tank. In addition, the false start drain
effluent should be visible to evaluate the effectiveness of the wash cycle. On gas-
only machines, there will be no sludge tank; only a wash water effluent tank.

b) Arrange valves in the exhaust plenum drain piping to divert effluent from the sludge
tank to the waste water tank. Open the main wash water drain valve at the bottom of the
exhaust plenum.

c) Open the inlet plenum drain valve.

d) Close valve installed in the AD-2 line supplying compressor discharge air to the false
start drain valve and open downstream drain.

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Gas Turbine Compressor Washing GEK 103623c

e) Switch the motor controller for the turbine exhaust frame cooling fan motors, 88TK-1
and 88TK-2 in the manual “ON” position (if provided).

NOTE

This step is necessary to prevent water wash from entering the exhaust frame cool-
ing system during the wash cycle.

The atomizing air system (if provided) is isolated in the following manner:

f) Close valve on inlet side of atomizing air system from AD-8 line.

g) Open all low point drains in the atomizing air supply lines.

h) Open the atomizing air separator drain valve (if provided).

i) Open vent line on inlet side of CA2, booster atomizing air compressor (if provided).

j) Open switch at the motor control center for 88AB; the drive motor for the booster
atomizing air compressor, CA2.

The cooling and sealing air circuitry is isolated in the following manner:

k) Close valve in the bearing sealing air supply line AE-5 from extraction air (if provided).

l) Close valve in all compressor discharge pressure transducer supply lines (AD-4).

m) Close AD-1, AD-3 and if provided, AD-6, AD-7 and AD-10.

n) Close valve in the bleed air line (AE-##) from extraction air (if provided). If isolation
valve is not provided, isolate with a blank-off plate.

o) Open separator drain valve on bearing sealing air line, if provided.

p) Open needle valve upstream of WW9 connection for drainage during the wash cycle
(low point drain on AD-3), if provided.

q) Open low point drain on bearing sealing air line, if provided.

r) If the turbine has a self-cleaning inlet filter, close the block valve and open the drain
valve on the self-cleaning inlet filter air line.

The inlet air heating system is isolated in the following manner:

For all 7EA units. If a unit is equipped with a VM15–1 isolation valve, close the valve
and opent the low point drains. All other frame sizes will have VM15–1 isolation valves.

s) Close VM15-1 manually, or if motorized valve is provided, ensure it is closed.

t) Open all low point drains in the Inlet Air Heating System.

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GEK 103623c Gas Turbine Compressor Washing

2. Washing Procedure

Washing can be accomplished using a permanent system (a series of nozzles or a spray ring
mounted in the inlet plenum) or with a manual system (a hand-held hose and spray nozzle).
With either system, take care to cover the full circumference of the bellmouth. The inlet
plenum and bellmouth should be cleaned first to prevent these deposits from being washed
into the compressor during the cleaning.

Washing with water or detergent should be done at crank speed. Flow rates are given in Table
2.

Utilize the detergent wash procedures which follow:

a. Select the Water Wash control display on the turbine control panel CRT Select OFF-
LINE WATER WASH ON.

At this time, the turbine is prohibited from firing.

b. Place the Master Select Switch in the CRANK position.

c. Initiate a turbine START signal.

d. The turbine will accelerate to full continuous cranking speed. The cranking motor will
maintain the unit on crank until the stop signal is given.

e. Apply solution at the rate specified in Table 2.

f. Apply the solution at crank speed for three to five minutes, shut unit down, continue
spraying during coastdown until the solution is no longer drawn into the compressor inlet.

g. Allow the detergent to soak for 20 minutes and rinse with water at crank speed for 15 to
20 minutes following the recommended flow rates of Table 2.

3. Washing Effectiveness

The effectiveness of the wash and the rinse can most easily be evaluated by observing the
runoff from the drains during the rinse and visual inspection of the compressor inlet at the
end of a wash cycle.

a. The compressor should be rinsed until the drain water appears clean.

b. The runoff water may also be checked for the amount of impurities it contains by mea-
suring its electrolytic conductivity. The conductivity value will decrease as washing con-
tinues and the runoff water contains fewer dissolved impurities.

c. Another method of testing is to use an atomic absorption spectrometer if one is available

for checking the level of trace metals.

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Gas Turbine Compressor Washing GEK 103623c

NOTE

The detergent wash may need to be repeated depending on the amount of fouling
and detergent effectiveness. Multiple washes will be required if the compressor is
heavily fouled.

4. Draining and Drying Procedure

a. Allow the gas turbine to drain and dry for about 20 minutes including coasting down
time.

b. Open fuel manifold drains and open all low point drains in atomizing air system, fuel
system and purge system.

NOTE

The interconnecting piping is often the low point trap and this piping must be
drained by removing drain plugs or parting pipe flanges. The low point can be in
the interconnecting piping or the manifold itself depending on the piping design
and location of the gas valves. Additionally, lower combustion can flexible hoses
may trap water and may require flange disassembly to remove water at these lo-
cations.

Following water wash and rinse cycles, the dry-out crank cycle should continue
until no water is observed draining from any low point drain. Following restora-
tion of the piping, the subsequent turbine restart should be carefully monitored
and any operational abnormalities during restart that might indicate that all wash
water has not been drained should result in an operator trip of the unit and further
draining and purging of the piping to insure all water is removed.

c. After the turbine has stopped, and drying time is complete, initiate a turbine START
signal with the master operation selector switch in the CRANK position.

d. Allow the turbine to accelerate to crank speed.

e. Allow the turbine to dry for at least 20 minutes or until low point drains are dry at crank
speed.

f. Initiate a turbine STOP signal.

5. Restoration

a. If applicable, close inlet guide vanes.

b. If applicable, reenergize off-base atomizing air compressor and remove regenerator

cover.

c. Close fuel manifold drains.

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GEK 103623c Gas Turbine Compressor Washing

CAUTION

It is important that the line that allows waste fuel to drain to the sludge tank be
kept open after water washing and during normal turbine startup and operation, so
that fuel or water which may accumulate in the exhaust plenum can continuously
drain out of the plenum. Accumulation of waste fuel in the exhaust plenum is
potentially hazardous.

d. Open the hand valves or remove blank-off plates on flame detectors.

e. Return the following manual valves to their previous position in the order listed:

a) Return the three-way false start drain valve, combustion system and turbine shell valves
from water drain to fuel drain (if installed).

b) Rearrange valves installed in the exhaust plenum drain piping to divert effluent from
the wash water tank to the sludge tank (if applicable).

c) Close the inlet plenum drain valve (if provided).

NOTE

This is important to prevent intake of dirt etc., into the compressor.

d) Open valve installed in the AD-2 line supplying compressor discharge air to the false
start drain valves.

e) Switch the motor controller for the turbine exhaust frame cooling fan motors 88TK-1
and 88TK-2, into the “AUTO” mode (if provided).

The atomizing air system is reenergized in the following manner:

f) Open valve on inlet side of atomizing air system from AD-8 line.

CAUTION

It is critical that this valve be opened to prevent damage to the turbine.

g) Close all low point drains in the atomizing air lines.

h) Close the atomizing air separator drain valve (if provided).

i) Close vent line on inlet side of CA2, booster atomizing air compressor (if provided).

j) Close switch at the motor control center for 88AB; the drive motor for the booster
atomizing air compressor CA2.

The cooling and sealing air circuitry is reengaged in the following order:

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Gas Turbine Compressor Washing GEK 103623c

k) Open valve in the bearing sealing air supply line AE-5 from extraction air (if provided).

CAUTION

It is critical that this valve be opened to prevent damage to the turbine.

l) Open valves in all compressor discharge pressure transducer supply lines (AD-4).

CAUTION

It is critical that this valve be completely opened to prevent damage to the turbine.

m) Open AD-1, AD-3, AD-6, AD-7 and AD-10 (if provided).

CAUTION

In configurations where AD-6 is used to supply the purge air system, it is critical
that this valve be opened to prevent damage to the turbine.

n) Open valves or remove blank-off plate in the bleed air lines (AE-##) from extraction
air.

CAUTION

It is critical that these valves be opened to prevent damage to the turbine.

o) Close separator drain valve on bearing sealing air line (if provided).

p) Close needle valve upstream of WW9 connection (low-point drain on AD-3), if pro-
vided.

q) Close low-point drain on bearing sealing air line, if provided.

r) If the turbine has a self-cleaning inlet filter, open the block valve and close the drain
valve on the self-cleaning filter air line.

The inlet air heating system is reengaged in the following manner:

For all 7EA units. If a unit is equipped with a VM15–1 isolation valve, open the valve
and close the low point drains. All other frame sizes will have VM15–1 isolation valves.

s) Open VM15-1 manually, or if motorized valve is provided, ensure it is opened.

t) Close all low point drains in the Inlet Air Heating System.

f. Press the Off-Line Water Wash OFF softswitch on the water wash control display.

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GEK 103623c Gas Turbine Compressor Washing

NOTE

When the OFF-LINE WATER WASH OFF is selected, the permissive is in place
to allow the turbine to fire and the permissive is removed to allow the 20TW-1
valve to be opened.

2. On-Line Compressor Wash

The intent of on-line washing is to extend the period between off-line washes through frequent
washings of short duration. When the compressor is suspected of being heavily fouled, an off-line
wash should be performed.

On line water washing may result in a fogging over of flame detector lenses. For units operating
with DLN systems this has the potential of resulting in tripping the turbine off line. In order to
assure uninterrupted turbine operation the following set-up procedure should be followed for units
operating with DLN systems.

While observing Flame Detector Level Intensity on the Mark V display, start water wash with
throttled back flow, slowly increase until intensity is decreased to a comfortable margin above
drop out level or maximum flow (Table 2) is reached, which ever occurs first.

Adding water for wash will increase the compressor pressure ratio and thus reduce the surge mar-
gin. Under normal circumstances, there is ample surge margin to allow for washing and steam or
water injection for NOx control or power augmentation. However, the following steps are recom-
mended prior to performing an on-line wash.

1. Preparation

a. On-line washing solution must meet the requirements of both Table 1.

Turbine must be running at full speed and not in the process of shutting down.

b. Compressor inlet temperature, CTIM, must be greater than 50°F (10°C). Refer to
TIL1153-3 for information on cold weather on-line water wash. On-line water washing
should not be performed while inlet bleed heat is operating for any reason. Do not force
inlet bleed heat off to satisfy this restriction.

c. Set the inlet guide vanes to 81° or greater. For units operating with DLN systems, full
open position occurs only at base load.

d. Reduce load by 5% if operating at base load. Units operating with DLN systems need not
reduce load and must perform compressor wash at base load to achieve full open IGV's.

e. Units operating with water or steam injection for NOx control or power augmentation
must reduce water or steam injection to 3% maximum of compressor inlet flow.

f. For units operating with DLN systems, washing is to be conducted while in Extended
Lean-Lean or Premix combustion modes.

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Gas Turbine Compressor Washing GEK 103623c

NOTE

Operating in extended lean-lean will result in increased emissions over premix

operation.

2. Washing Procedure

a. Apply water at the rate specified in Table 2.

b. Continue to apply solution for 30 minutes.

c. On-line wash is most effective when performed on a regular basis.

d. If inlet bleed heat turns on for any reason while washing, the water wash procedure
should be suspended.

NOTE

If using a detergent solution for on-line washing, it is recommended that the wash
be followed by enough rinse water to remove the detergent residue from the wash
nozzles at the spray manifold. This will prevent the detergent solutions from dry-
ing and clogging the nozzles.

B. Results of Washing

After cleaning, there should be a noticeable increase in performance. Increase in performance is a

function of how fouled the compressor was initially. An increase in BASE load power of 10% is not
uncommon following an off-line wash. This can be confirmed by comparing restored performance data
to levels of performance before washing, utilizing the procedure in GEK 28166 for generator drive ma-
chines and the appropriate procedure for other applications as previously described under Performance
Monitoring. It should be noted that full power may not always be regained once significant fouling
occurs. Regular compressor washing will help maintain performance. Specific intervals must be de-
termined based on customer performance.

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GEK 103623c Gas Turbine Compressor Washing

Table 1. QUALITY SPECIFICATION

OFF-LINE WASHING
TOTAL SOLIDS (dissolved and undissolved) 100 ppm
TOTAL ALKALI METAL 25 ppm
OTHER METALS WHICH MAY PROMOTE 1.0 ppm
HOT CORROSION (i.e. lead, vanadium)
pH (determined by glass electrode) 6.5 to 7.5
ON-LINE WASHING
TOTAL SOLIDS (dissolved and undissolved) 5 ppm
TOTAL ALKALI AND OTHER METALS
0.5 ppm
WHICH
MAY PROMOTE HOT CORROSION
pH (determined by glass electrode) 6.5 to 7.5

Applies to water or water and detergent solution

Table 2. WATER AND/OR WATER AND DETERGENT SOLUTION INJECTION (FLOW)

RATES

Off Line(1) On Line(1)

Machine Flow (GPM)
Press (psig) Temp (°F) Flow (GPM) Press (psig) Temp (°F)
max.
MS3001,
115 150-180 15 100 50-180 3.5
3002
MS5001,
85 150-180 35 100 50-180 8
5002
MS6001 85 150-180 42 100 50-180 10
MS6001F/FA 85 150-180 45 100 50-180 13
MS7001EA 85 150-180 50 100 50-180 18
MS7001F/FA 85 150-180 81 100 50-180 26
MS9001E 85 150-180 72 100 50-180 26
MS9001F/FA 85 150-180 117 100 50-180 38
1 Mixed at manufacturer's suggested mix ratio.

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Gas Turbine Compressor Washing GEK 103623c

APPENDIX 1 COMPRESSOR WASHING DETERGENT SPECIFICATION

I. SCOPE

This specification is for cleaning compounds for use in compressor washing. It is required that these com-
pounds will not cause harm to gas turbine components. Thus, their purity and composition must be such
that they do not cause aqueous corrosion or stress corrosion of compressor materials. Also, it is required
that they do not cause hot corrosion in the turbine. Furthermore, they must not lead to compressor fouling.
With regard to the cleaning agents themselves, they must be chemically stable in themselves and in their
mixtures with water. Also, they must not form combustible mixtures and they should satisfy all local codes
relative to health and safety requirements. Compliance with this specification does not imply a cleaning
compound improves the cleaning of a compressor over and above what can be obtained from water alone.

II. REQUIREMENTS

The cleaning compound when mixed with water in the manufacturer’s prescribed concentration shall satisfy
the water washing specifications for on-line and off-line water quality given in Table 1. In the pure state it
shall satisfy the specification given in Table 3.

The residue or ash content of the cleaning compound shall not exceed 0.01%. See test 4.1.

The storage stability of the cleaning compound shall show no marked color change, shall not separate and
shall not corrode or stain the steel specimen when tested as specified in test 4.5.16 of MIL-C-85704A. This
test is given in 4.2.

The cleaner and its mixtures with water shall not form gums under compressor conditions.

The Pensky-Martens flash point of the cleaning compound shall be above 140°F (60°C) (ASTM D93).

III. MATERIAL COMPATIBILITY

Use of the cleaning compound shall not have adverse effects on engine system materials such as compressor
or turbine materials.

IV. TESTS

A. Ash Content: Preparation of Test Samples

Approximately 10 g of cleaning compound shall be weighed to the nearest 0.1 mg in a tared porcelain
crucible. The crucible shall be heated at 221° ± 2°F (105° ± 1°C) for 24 hours, then heated at 464° ±
4°F (240° ± 2°C) for the next 24 hours. Following this, the crucible and its contents shall be carefully
ignited over a Bunsen-type gas burner. The crucible shall then be placed in a muffle furnace at 1,900°F
(1,040°C) for 2 hours. The crucible shall be transferred to a desiccator, cooled and weighed until con-
stant weight. The ash content shall be calculated as the percentage of the initial weight of cleaning
compound.

B. Accelerated Storage Stability (from MIL-C-85704A)

Preparation of test sample. A 150-ml portion of a well-shaken cleaning compound shall be poured into
each of two chemically clean 250-ml pressure-resistant clear glass bottles which shall be approximately
9.5 inches (24.1 cm) in height and 2.5 inches (6.4 cm) in outside diameter. One bottle shall be capped

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GEK 103623c Gas Turbine Compressor Washing

and stored in the dark for at least six days at room temperature. A strip of steel 6 by 0.5 by 0.02 inches
(15.2 x 1.3 x 0.05 cm) conforming to MIL-S-7952 shall be polished to remove surface contamination
and then cleaned by boiling for one minute in chemically pure isopropyl alcohol and one minute in
mineral spirits. The steel strip shall be placed in the other test bottle and the bottle shall be capped.
The capped bottle containing the steel strip shall be thoroughly shaken for one minute.

Procedure. The capped bottle containing the steel strip shall be placed in a water bath and heated at a
uniform rate to a temperature of 140° ± 4°F (60° ± 2°C) over a period of five hours. It shall be held
at this temperature for three hours. No heat shall be applied to the bath overnight. The above heating
procedure shall be repeated each day for five days. (This test need not necessarily be attended if an
interval time is used to regulate the temperature automatically. The test may be started on a Wednesday,
Thursday or Friday and still have the pressure bottle removed on a normal workday.) On the morning
of the sixth day, the bottle shall be removed from the bath, uncapped, examined for separation and the
steel strip carefully withdrawn from the cleaning compound. Separation into layers shall be cause for
rejection. The portion of the steel strip which had been immersed in the compound shall be examined
for evidence of pitting, corrosion and uneven darkening. The open bottle shall be capped and the two
bottles shall be thoroughly shaken for one minute, then allowed to remain undisturbed for one hour
at room temperature and then examined. Any marked change in the color and uniformity of the aged
sample shall be considered as showing unsatisfactory stability properties.

Table 3.
CHEMICAL CONTENT OF WASHING DETERGENT

Total alkali metals 25 ppm max

Magnesium + calcium 5 ppm max
Vanadium 0.1 ppm max
Lead 0.1 ppm max
Tin + copper 10 ppm max
Sulfur 50 ppm max
Chlorine 40 ppm max

GE Energy
General Electric Company
www.gepower.com

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