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Sato 2010

The document discusses the thermal cycloreversion of 4H-1,3-dioxine-4-thiones to acyl thioketenes. This reaction generates reactive intermediates that can be trapped with nucleophiles to form β-ketothioic O-acid derivatives and related products.

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Raúl Aponte
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17 views1 page

Sato 2010

The document discusses the thermal cycloreversion of 4H-1,3-dioxine-4-thiones to acyl thioketenes. This reaction generates reactive intermediates that can be trapped with nucleophiles to form β-ketothioic O-acid derivatives and related products.

Uploaded by

Raúl Aponte
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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1996 thio compounds

thio compounds (acyclic compounds)


P 0440 Thermal Cycloreversion of 4H-1,3-Dioxine-4-thiones to Acyl
36 - 072 Thioketenes: A General Synthesis of β-Ketothioic O-Acid Deriva-
tives. — Thermal cycloreversion of the title thiones such as (I) gives acyl
thioketenes as reactive intermediates. Trapping of these intermediates with
nucleophiles leads to β-ketothioic O-acid derivatives such as (III) or (VI) and
some related products. — (SATO, M.; BAN, H.; UEHARA, F.; KANEKO, C.;
Chem. Commun. (Cambridge) (1996) 6, 775-776; Pharm. Inst., Tohoku Univ.,
Sendai 980-77, Japan; EN)

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