Quantum Mechanics Notes
Quantum Mechanics Notes
Kieran O’Rourke
March 28th, 2018
Contents
1 Gauge Theory – 2
1.0.1 Gauge Gravity . . . . . . . . . . . . . . . . . . . . . . 4
2 Rambling Thoughts 4
3 kor Thoughts 4
4 Spin 5
5 Marvin Chester QM 6
6 Snippets 7
1
Abstract
Aucune grâce extérieure n’est complète si la beauté intérieure ne la
vivifie. La beauté de l’âme se répand comme une lumière mystérieuse
sur la beauté du corps. (Victor Hugo)
Gauss-Bonnet
“If in the first act you have hung
a pistol on the wall, then in the
following one it should be fired.”
Anton Chekhov’s rule on writing
is a good one.
1 Gauge Theory –
“Most people are other people.
Their thoughts are someone else’s
opinions, their lives a mimicry,
their passions a quotation.”
Oscar Wilde
User Luke Pritchett has already given a good answer. For completeness,
I want to mention that there is an alternative way to think about this, one
2
that I learnt very recently and that I found to be fascinating. I cannot help
but recommend the book *Quantum Gauge Theories: A True Ghost Story*,
by G. Scharf. It is short, concise and to the point. I read it a couple of days
ago, and I loved every page of it.
In its first chapter, the book introduces free fields. Here, the author argues
that the unphysical (longitudinal) polarisation of a spin j = 1 field is in fact
a gradient: Aµ = Aphysical
µ + ∂µ Λ. This determines the gauge transformation
for free fields to be Aµ → Aµ + ∂µ λ. So far, so good: this is just standard
gauge theory.
The key point is that, as the author shows, the gauge invariance of free
fields is in fact restrictive enough to determine the gauge transformation of
interacting fields. For example, the author does not introduce the (ad-hoc)
postulate that gauge fields are to transform according a Lie algebra: this is
in fact a conclusion rather than an axiom.
Furthermore, the author does not introduce the (ad-hoc) Higgs mechanism,
but rather derives it from the gauge invariance for free fields. All in all, in this
book there are (almost) no unjustified ingredients: no covariant derivatives,
no Lie Groups, no spontaneous symmetry breaking, etc. The only working
principle is the gauge invariance of free fields, Aµ → Aµ + ∂µ λ, which is
perfectly well-motivated. Everything else is derived as a consequence of this
simple principle.
Finally, and concerning OP’s main question, the author argues that the
theory is unitary if and only if it is gauge invariant, so this constitutes a proof
that unitarity requires the Higgs field to exist.
If this is not enough for me to convince the reader to read the book,
let me mention that the author does not introduce negative norm states
(which is also a rather unconvincing aspect of gauge theories), but he doesn’t
introduce non-covariant (Coulomb, axial) gauges either. Moreover, the author
explains from first principles how General Relativity emerges from a spin
j = 2 field, using only the gauge transformation for free fields (which is, as
before, completely natural from the point of view of unphysical polarisations).
Finally, the book follows the Epstein-Glaser formulation of QFT, so there are
no divergences nor counter-terms anywhere.
Needless to say, it is impossible for me to explain how this works in
practice: doing so would require for me to rewrite the whole book here. Let
me nevertheless quote a paragraph from the introduction that I hope will
pique the reader’s interest.
> In Chapter 4 the same method is applied to massive gauge fields. These
are the incoming and outgoing free fields which appear in the expansion of the
S-matrix (corresponding to the W ± - and Z-bosons in the electroweak theory).
We have no generation of mass by spontaneous symmetry breaking; instead,
3
perturbative gauge invariance does the job. It forces us to introduce an
unphysical (Goldstone-like) and physical (Higgs) scalar fields and determines
their coupling. For example, the so-called Higgs potential need not be put in
by hand but follows naturally from third-order gauge invariance. humanity
iz da
1.0.1 Gauge Gravity pitz.
2 Rambling Thoughts
KOR: If two energy levels in an atom are separated by ~ω then any photon
of frequency different from ω won’t be absorbed. Absorption implies a spread
in ω, therefore a finite photon production time, as squeezing time spreads ω.
3 kor Thoughts
In dealing with equations in physics, think about what the terms encode;
referring to geometry, co-ordinates? Space? Also, relate all understanding to
symmetries.
4
4 Spin
A system is only in an eigenstate of spin around an axis if a rotation about
the axis doesn’t change the system. Take z to be the direction of travel, then
for a spin 1 system the Sz = 0 state would be symmetric to a rotation about
an axis normal to the direction of travel. But this can only be the case if
the momentum is zero i.e. in the rest frame. If the system has a non-zero
momentum any rotation will change the direction of the momentum so it
won’t leave the system unchanged.
For a massive particle we can always find a rest frame, but for a massless
particle there is no rest frame and therefore it is impossible to find a spin
eigenfunction about any axis other than along the direction of travel. This
applies to all massless particles e.g. gravitons also have only two spin states.
In the first approximation, spin degree of freedom can be separated from or-
bital degrees of freedom, so that the wavefunction becomes χ(s1 , s2 )φ(x1 , x2 ),
where si is spin of ith electron, and xi is position of ith electron. Here χ is spin
part of wavefunction, and φ is orbital part. To preserve total antisymmetry
of the wavefunction, χ and φ can be either symmetric, or antisymmetric. If
one is symmetric, the other must be antisymmetric.
* ↑↑ * ↓↓ * ↓↑ + ↑↓
* ↓↑ − ↑↓
5
From here we can see that symmetric spin part of wavefunction gives rise
to three different states — these are triplet states. If spin part of wavefunction
is antisymmetric, there’s only one such state — it’s the singlet state.
When one makes spectroscopic measurements with not very high resolu-
tion, states with different spins but same orbitals will appear to have the same
energies, so the spectral lines will appear the same. But if you put your system
in magnetic field, you’ll see that the spectral lines split according to spin
multiplicities: spin-singlet states will remain single lines, while spin-triplets
will split into three different spectral lines. This is the origin of such naming.
5 Marvin Chester QM
I propose that, as used to describe the physical world, symmetry is so ele-
mental that it coincides with the concept of identity itself. The theory of
symmetry is the mathematical expression of the notion of identification and
that is why it is so effective as the basis of science. By identity is meant the
end result of identification. We know objects by their properties. Constitution
is what "confers to the carrier of a set of properties the dignity of an object",
says Elena Castellani (1998, p. 182). She ’constitutes’ an elementary object
of physics - electron, nucleon - from group theory by showing that invariance
under the spatio-temporal transformation group yields as characterization of
the object its energy, its linear momentum, its angular momentum and its
mass. To constitute something, then, is to assign to it labels of significance.
The significance arises from invariance properties.
The logic of group theory is the logic of scientific inquiry so that the
mathematics we use to describe nature is a carefully coded expression of our
6
experience.
6 Snippets
In an effective field theory, all but the first few of the infinite set of parameters
in a nonrenormalizable theory are suppressed by huge energy scales and hence
can be neglected when computing low-energy effects.
7
same collective behavior.
The strange logic is that you cannot find an Action Principle for the
EM field using E and B + positions and velocities. You must introduce the
auxilliary potentials and Gauge Invariance is a property of the potentials.