20ME403 Engineering Materials and Metallurgy Unit - IV Digital Material
20ME403 Engineering Materials and Metallurgy Unit - IV Digital Material
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20ME403 - ENGINEERING MATERIALS AND
METALLURGY
UNIT –IV- NON METALLIC MATERIALS
Date: 26.02.2022
1. CONTENTS
S.NO CONTENTS
1 Course Objectives
2 Pre Requisites
3 Syllabus
4 Course outcomes
6 Lecture Plan
8 Lecture Notes
9 Assignments
10 Part A Q & A
11 Part B Qs
14 Assessment Schedule
20ME403 - ENGINEERING
MATERIALS AND
METALLURGY (IV SEM)
20ME206 -
FUNDAMENTALS OF
MANUFACTURING
PROCESSES (II SEM)
4. SYLLABUS
ME8491 ENGINEERING METALLURGY LTPC
3003
OBJECTIVE:
• Students completing this course are expected to:
● Explain the principles of constitution of alloys, phase diagrams, and Iron carbide Equilibrium Diagram.
● Classify various types of Heat treatment process and its applications.
● Discuss the properties and applications of Ferrous and Nonferrous metals.
● Summarize the properties of Non-metallic materials and applications.
● Select the suitable materials for various Engineering applications.
UNIT I : CONSTITUTION OF ALLOYS AND PHASE DIAGRAMS 9
Constitution of alloys – Solid solutions, substitutional and interstitial – Gibbs phase rule– binary phase
diagrams - lever rule - Isomorphous, eutectic, eutectoid, peritectic, and peritectoid reactions, Iron – carbon
equilibrium diagram. Classification of steel and cast Iron microstructure, properties and application.
UNIT II : HEAT TREATMENT 9
Annealing – Full annealing, stress relief, recrystallization and spheroidising – normalizing, hardening and
Tempering of steel. Isothermal transformation diagrams for eutectoid steel – cooling curves superimposed on I.T.
diagram, CCT diagram – Hardenability, Jominy end quench test - Austempering, martempering – case hardening-
carburizing, Nitriding, cyaniding, carbonitriding – Flame and Induction hardening –strain hardening - Vacuum and
Plasma hardening.
UNIT III FERROUS AND NON-FERROUS METALS 9
Effect of alloying additions on steel- Properties and applications of Carbon steel, Alloy steel - stainless
and tool steels – HSLA, Maraging steels – Copper and copper alloys – Brass, Bronze and Cupronickel – Aluminium
and Al-Cu – precipitation strengthening treatment – Bearing alloys, Super Alloys, Titanium and Titanium alloys,
Alpha, Beta, Alpha – Beta Ti alloys, Ni and Nickel alloys, Monel and Mg-alloys.
UNIT IV NON-METALLIC MATERIALS 9
Polymers – types of polymer, commodity and engineering polymers – Properties and applications of various
thermosetting and thermoplastic polymers (PP, PS, PVC, PMMA, PET,PC, PA, ABS, PI, PAI, PPO, PPS, PEEK, PTFE,
Polymers – Urea and Phenol formaldehydes)- Engineering Ceramics – Properties and applications of Al2O3, SiC,
Si3N4, PSZ and SIALON – Composites - Classifications - MMC - FRP – CMC – hybrid composites Applications of
Composites.
UNIT V MATERIAL CHARACTERIZATION 9
Types of fracture – Testing of materials under tension, compression and shear loads – Hardness tests (Brinell, Vickers
and Rockwell), Impact test lzod and charpy, fatigue and creep failure mechanisms. Introduction to NDT
techniques such as X-ray radiography, Dye penetration test, Magnetic particle test and Ultrasonic test.
TOTAL: 45 PERIODS
TEXT BOOKS:
1. Avner, S.H., “Introduction to Physical Metallurgy”, McGraw Hill Book Company, 2017.
2. Williams D Callister, “Material Science and Engineering” Wiley India Pvt Ltd, Revised Indian 10th Edition, 2017
REFERENCES:
1. Kenneth G. Budinski and Michael K. Budinski, “Engineering Materials”, Prentice Hall of India Private Limited, 2012.
2. Van Vlack L.H., ‘Elements of Materials Science and Engineering’, 6th Edition, AddisonWesley, 2011
3. Raghavan.V, “Materials Science and Engineering”, Prentice Hall of India Pvt. Ltd., 2017.
4. U.C.Jindal : Material Science and Metallurgy, "Engineering Materials and Metallurgy", First Edition, Dorling
Kindersley, 2012
5. Upadhyay. G.S. and Anish Upadhyay, “Materials Science and Engineering”, Viva Books Pvt. Ltd., New Delhi, 2006.
6. Dieter George E., “Mechanical Metallurgy”, 3rd Edition, McGraw-Hill, New York, 2014
7. J. Prasad and C. G. K. Nair, Non-Destructive Test and Evaluation of Materials, Tata McGraw-Hill Education, 2nd
edition (2011).
5. Course Outcomes
HIGHEST
CO No. CO Course Outcomes COGINITIVE
LEVEL
Explain various binary alloy systems with K2
C405.1 respective invariant reaction.
CO1
CO2 Classify various heat treatment process and its K2
C405.2
significance
CO3 Discuss various Ferrous and non-ferrous metals K2
C405.3
with its application
Summarize the various non-metallic materials with K2
C405.4
CO4 its applications
Compute the material properties by various K2
C405.5 material testing techniques
CO5
CO6 Apply the knowledge of material science on K3
C405.6
material selection for specific requirements
Knowledge level:
K1 – Remembering; K2 - Understanding; K3 – Applying; K4 –Analyzing;
K5 – Evaluating; K6 - Creating
6. CO- PO/PSO Mapping
POs PO PO PO PO PO
COs PO1 PO 4 PO 5 PO 6 PO 7 PO 8 PO 9
2 3 10 11 12
C405.1 CO1 3 2 2 2 2 2 3 3
C405.2 CO2 3 2 2 2 2 2 3 3
C405.3 CO3 3 2 2 2 2 2 3 3
C405.4 CO4 3 2 2 2 2 2 3 3
C405.5 CO5 3 2 2 2 2 2 3 3
C405.6 CO6 3 2 2 2 2 2 3 3
C405
PSOs
COs PSO 1 PSO 2 PSO 3
C405.1 CO1 2
C405.2 CO2 2
C405.3 CO3 2
C405.4 CO4 2
C405.5 CO5 2
C405.6 CO6 2
C405 - - 2
6. CO- PO/PSO Mapping
POs PO PO PO PO PO
COs PO1 PO 4 PO 5 PO 6 PO 7 PO 8 PO 9
2 3 10 11 12
C405.1 CO1 2 2
C405.2 CO2 3 2 1 2
C405.3 CO3 2 1 2
C405.4 CO4 2 1 2
C405.5 CO5 2 2 2
C405.6 CO6 3 2 2 2 2 2
C405 2 2 1 1 2 2 2 2
PSOs
COs PSO 1 PSO 2 PSO 3
C405.1 CO1
C405.2 CO2
C405.3 CO3
C405.4 CO4
C405.5 CO5
C405.6 CO6 2
C405 - - 2
UNIT IV NON METALLIC MATERIALS
S. No. of K Mode of
Topics CO
No. Periods Level Delivery
K2 CO4
Introduction to Polymers, types of Board &
1 1
polymer Chalk, PPT
Commodity and engineering CO4 Board &
2 polymersProperties and applications 1 K2
Chalk, PPT
of various thermosetting
K2 CO4
thermoplastic polymers -PP, PS, PVC, Board &
3 1
PMMA, PET,PC, PA Chalk, PPT
K2 CO4
Properties and applications of ABS, Board &
4 1
PI, PAI, PPO, PPS, PEEK, PTFE Chalk, PPT
Polymenr- Urea and Phenol K2 CO4 Board &
5 formaldehydes, Introduction to 1
Chalk, PPT
Engineering Ceramics
K2 CO4
Properties and applications of Al2O3, Board &
6 1
SiC, Si3N4, PSZ and SIALON Chalk, PPT
CO4
K2 Board &
7 Composites classifications- MMC 1
Chalk, PPT
These subunits are typically connected by covalent chemical bonds. Although the
term polymer is sometimes taken to refer to plastics, it actually encompasses a large
class of natural and synthetic materials with a wide variety of properties.
Natural polymeric materials such as shellac, amber, and natural rubber have been
used for centuries. A variety of other natural polymers exist, such as cellulose, which
is the main constituent of wood and paper. The list of synthetic polymers includes
synthetic rubber, Bakelite, neoprene, nylon, PVC, polystyrene, polyethylene,
polypropylene, polyacrylonitrile, PVB, silicone, and many more.
➢ Light weight
➢ Easy to fabricate
➢ Low cost.
Structure of polymer:
Organic polymer:
Branched polymer:
Copolymer
Graft copolymer:
Graft copolymer is a kind of branch polymer, side chains of which are made of
monomers differing from the monomer of the main chain.
Polymerisation: Polymerization is a process through which a large number of
monomer molecules react together to form a polymer. The macromolecules produced
from a polymerization may have a linear or a branched structure. They can also
assume the shape of a complex, three-dimensional network. There exist several
different categories of polymerization reactions, the most notable of which being step-
growth polymerization, chain-growth polymerization (both of which fall under the
category of addition polymerization), and condensation polymerization.
A polymer is a substance that is made up very large molecules that are, in turn, made
up of many repeating units called monomers. Polymerization is the process through
which these monomers come together to form the macromolecules that constitute
polymers. An illustration detailing the polymerization of the monomer styrene into the
polymer known as polystyrene is provided below.
Depending on the functional groups present in the reacting monomers, the complexity
of the mechanism of the polymerization reaction may vary. The most simple
polymerization reactions involve the formation of polymers from alkenes via free-
radical reaction. Polyethylene, which is one of the most commercially important
polymers, is prepared via such a polymerization process (the reactant monomer used
here is ethylene).
Types of Polymerization:
➢ Molecular weight
➢ Chain shape
➢ Type of mers
Classification of polymers: Polymers are classified into two groups. Thermo plastic
and Thermo setting based on their response to elevated temperature.
Ex: Epoxies (EP), Unsaturated Polyesters (UP), Phenolics (PF), Urea Formaldehyde (UF),
Melamine Formaldehyde (MF)
Commodity polymers: The light weight polymers with low strength and stiffness and
not suitable for high temperature uses are brought under this category. These polymers
are inexpensive and can be readily formed into a variety of shapes ranging from plastic
bags to bath tubs. They are most widely used polymers.
Ex: Polyethylene (PE), Polypropylene (PP), Polyvinyl Chloride (PVC), Polystyrene (PS) etc.
Engineering polymers: The polymers which are designed to give improved strength,
greater environmental resistance, better performance at elevated temperatures (as high
as 350 C) are called engineering polymers. These materials are produced relatively in
small quantities and are often expensive.
Poly Ethylene
Applications: Flexible bottles, toys, battery parts, ice trays, film wrapping materials
Polypropylene (PP): Properties: Light-weight material, about 95% air and has very
good insulation properties , Chemical resistance in most circumstances, Elasticity,
Electrical insulation properties, Fatigue resistance, Low density, Low friction, Toughness,
Transmissivity.
Applications: Packaging and foodservice products, automotive parts, toys, house
wares, appliance parts, wall tiles, radio and TV housings, furniture, floats, and
luggage
Polystyrene
Applications: Wall tile, battery cases, toys, lighting , panels, housing appliances,
disposable food containers
Polyvinylchloride
Applications: Pipes, valves, fittings, floor tiles, wire insulation, phonograph records,
Guards, ducts, tanks, gaskets etc.
Polymethyl methacrylate (PMMA): Properties: They are hard , rigid and high
impact strength thermoplastic, They are highly transparent to light, It can be easily
formed, readily colored, excellent decorative property. Good chemical and weather
resistance.
Polymethyl methacrylate
Applications: Camera lenses, Flash lights, safety glasses, Instrument panels, window
glazing, display signs , Weather proof coatings etc.
Polyethylene tetraphthalate
Polycarbonate
Applications: Electrical and electronic applications, Helmets, face shields, window
glazing, cams and gears, automotive parts such as dashboards, boat propellers,
housing for hand-held power tools, electrical connectors.
Polyamide (PA): Properties: Very strong and tough, good abrasion resistance,
Flexible and high impact strength, High softening temperature so molding is difficult,
Tend to absorb water.
Polyamide
Applications: Films are used for circuit board types of applications where operating
temperatures are high, In resin form, they are used as adhesives, Composite with
polyimide matrix are used in space shuttle applications.
Polyamide-Imide
Applications: Valves made from PAI are used in hot water systems, high
temperature electrical applications, spark ignition engines etc.
Polyphenylene oxide
Applications: Electrical and electronic applications, automotive parts, Computer
housings, T.V. tuners etc.
Polyphenylene sulphide
Polyetherether Ketone
Polytetra Fluroethylene
Applications: High and low temperature electrical and electronic insulation , Bearings
Wear resistant, low friction surfaces , Chemical process equipment's, Valves, Pump
impellers, Gaskets, Non-stick cookware’s.
Urea Formaldehyde
Applications: Electrical and electronic products- switches, circuit breakers, knobs and
handles, decorative products, laminates, and chemically resistant coatings.
Engineering Ceramics:
Ceramic materials are inorganic, nonmetallic materials. Most ceramics are compounds
between metallic and nonmetallic elements for which the interatomic bonds are either
totally ionic or predominantly ionic but having some covalent character. The term
ceramic comes from the Greek word keramikos, which means burnt stuff, indicating
that desirable properties of these materials are normally achieved through a high-
temperature heat treatment process called firing.
Characteristics of ceramics :
➢ Brittleness
Classification of ceramics:
Advanced Ceramics
Alumina(Al2O3): It is the most widely use oxide ceramic, either in the pure form
or as a raw material mixed with other ceramics. Alumina is available in nature but it
contains unknown amounts of impurities. So it possesses non-uniform properties
and as a result its behavior is not reliable. Synthetic alumina is obtained by the
fusion of molten bauxite, iron fillings, coke in electric furnaces. The cooled product is
crushed and then graded in to various sizes. Alumina parts are manufactured from
these powders by cold pressing and sintering. Their properties are improved by
minor additions of other ceramics such as titanium oxide and titanium carbide.
Alumina has a hexagonal structure with a very strong ionic and covalent bonding.
Properties:
➢ Hard, wear-resistant
➢ Resists strong acid and alkali attack at elevated temperatures Good thermal
conductivity
➢ High Hardness (1600 HV) and moderate tensile strength (206 MPa).
➢ Compressive strength (2620 Mpa) of alumina is higher than hardened tool steels.
Applications:
➢ Alumina makes an excellent high voltage insulator. Insulators in spark plugs and in
insulating substrates to support integrated circuits.
➢ Alumina based ceramic tools have high abrasion resistance, hot hardness and are
chemically stable than high speed steels. So they are used in cutting cast irons,
and steels to obtain good surface finish.
➢ It is used for pump liners, pump impellers, check valves and nozzles subjected to
erosion.
➢ Some unique application found in medical use that include restoration of teeth,
bone filler and orthopedic implants.
Silicon Carbide (SiC): Synthetic silicon carbide is made from silica sand, coke, small
amounts of sodium chloride and saw dust. When the mixture is fired at a high
temperature in an electric arc furnace for a long time, the carbon from coke diffuses
into the sand and silicon carbide is formed. After the furnace has cooled, the silicon
carbide mass is removed, crushed and then graded into various desired sizes.
Two types of silicon carbides – hexagonal alpha and cubic beta. Structural parts are
commonly made from alpha Sic by the sintering process.
Properties:
Applications:
➢ Silicon carbide works well in high stress, high temperature applications such as
turbine blades and automotive engines.
Properties:
➢ High strength over a wide temperature range
➢ High fracture toughness
➢ High hardness
➢ Outstanding wear resistance, both impingement and frictional modes
➢ Good thermal shock resistance
➢ Good chemical resistance
Applications:
➢ Rotating bearing balls and rollers
➢ Cutting tools
➢ Engine moving parts — valves, turbocharger rotors
➢ Engine wear parts — cam followers, tappet shims
➢ Turbine blades, vanes, buckets
➢ Metal tube forming rolls and dies
➢ Precision shafts and axles in high wear environments
➢ Weld positioners
Partially stabilized Zirconia (PSZ): Zirconia has a monoclinic structure at room
temperature and a tetragonal structure at elevated temperature, during the
transformation of monoclinic to tetragonal structure, there is a volume expansion. If
this volume expansion is allowed to occur during hot pressing or sintering, it fractures
the part. This is avoided by stabilization of zirconia. Stabilization is obtained by doping
Zirconia with oxides of magnesium, calcium or yttrium. This process forms a material
called partially stabilized zirconia(PSZ).
Properties:
Applications:
➢ Oxygen sensors
Properties:
➢ High strength
Applications:
➢ Ceramics and glasses: Ceramics- Silicon carbide, silicon nitride, Alminium oxide.
➢ Carbon
➢ Fibres
➢ Whiskers
➢ Particulates
Fibre reinforced composites consist of fibres of high strength and modulus, embedded
in a matrix. The properties of fibre reinforced composites depend on
The strength of the composite improves when the aspect ratio of the fibre is large. A
greater volume fraction of fibre increases the strength and stiffness of the composite.
Short, randomly oriented fibres are easily introduced in the matrix and give a relatively
isotropic behavior in the composite. But continuous fibres with unidirectional orientation
produce anisotropic properties, with good strength and stiffness along the length
direction.
In this case, fibres are aligned with the direction of the applied load. However,
unidirectional orientation provides poor properties when the load is perpendicular to
the fibres. If the composite is subjected to forces in different direction, then the fibres
can be introduced in several directions within the matrix. Fibres can also be arranged in
a three dimensional pattern. The three dimensional reinforcement occurs when the
woven fabrics are stitched together and injected into the matrix material.
The fibres are the primary load carrying members. So the fibres have to be strong,
stiff and of light weight. These properties are decided by the two ratios, specific
strength and specific modulus. The higher values of these two ratios are desirable.
The matrix binds and support the fibres. The matrix distributes the stress to the
fibres and protects them from any environmental damage. The matrix also control over
electrical properties, chemical behaviour and elevated temperature use. A good bonding
must be obtained between the matrix and fibres to transmit the load properly from the
matrix to fibres.
Because of their low density, improved strength, stiffness, fatigue resistance and
strength to weight ratio, fibre reinforced composites are superior to those of metallic
materials.
Coefficient of thermal expansion for many fibre reinforced composites are much lower
and as a result , they exhibit better dimensional stability over a wide temperature
range. Another unique characteristic of many fibre reinforced composites is their high
damping capacity.
GFRP composites have very high specific strength. But they are not rigid and are limited
to service temperature below 2000 C.
Applications: Used in Automotive and marine bodies, leaf springs, pipes, storage
containers, sporting goods and industrial floorings.
Carbon Reinforced plastics: Carbon fibre composites have much lower densities,
higher strength, higher stiffness to weight ratio. It has low coefficient of thermal
expansion and this give better dimensional stability. The commonly used matrix materials
are epoxy, polyester, PEEK, PPS.
Applications: Used in sport and recreational equipment, filament wound rocket motor
cases, pressure vessels, commercial and military aircraft, helicopter structure, satelites.
The melting point, physical and mechanical properties of the composite at various
temperatures determine the service temperature of composites. Most metals,
ceramics and compounds can be used with matrices of low melting point alloys. The
choice of reinforcements becomes more stunted with increase in the melting
temperature of matrix materials.
Applications:
➢ Aluminium reinforced with alumina fibres has been used in automotive connecting
rods and pistons.
➢ Aluminium reinforced with boron fibres has been used in aerospace applications,
including struts for the space shuttle.
➢ Aluminium reinforced with SiC whiskers are used in aircraft wing planes.
➢ Copper based alloys reinforced with sic fibres are used for producing high
strength propellers for ships.
➢ Super alloys reinforced with tungsten maintain their strength at high temperature.
They are used in Jet engines and turbine blades.
Hybrid Composites:
Assignment
S. Question K CO
N Le
o vel
1 A glass fibre of 5 micron diameter is subjected to a tensile stress of K3 CO4
20 MPa. The surface energy and elastic modulus of this material are
0.3 Jm-2 and 70 GPa, respectively. Pick the correct answer based on
the information provided above:
Note: The glass fibre contains a population of flaws of different
lengths. (Gate- 2018)
(A) The fibre will undergo brittle fracture
(B) The fibre will undergo plastic deformation, but not fracture
(C) The fibre will undergo elastic deformation, but not fracture
(D) The fibre will undergo buckling
2 Point out the non metallic materials suitable for the following articles K3 CO4
with justification.
II. Coursera :
Material Behavior
https://www.coursera.org/learn/material-behavior#syllabus
https://www.udemy.com/course/introduction-to-engineering-materials-
and-testing-procedures/
Real time Applications in day to day life and to Industry
Application of thermo plastics and Thermo setting plastics:
Polystyrene (PS):Wall tile, battery cases, toys, lighting , panels, housing appliances,
disposable food containers
1. Unit Test – I
2. Unit Test – II
5. Model Examination
16. PRESCRIBED TEXT BOOKS & REFERENCE BOOKS
TEXT BOOKS:
1. Avner, S.H., “Introduction to Physical Metallurgy”, McGraw Hill
Book Company, 2017.
2. Williams D Callister, “Material Science and Engineering” Wiley India
Pvt Ltd, Revised Indian 10th Edition, 2017
REFERENCES:
1. Kenneth G. Budinski and Michael K. Budinski, “Engineering
Materials”, Prentice Hall of India Private Limited, 2012.
2. Van Vlack L.H., ‘Elements of Materials Science and Engineering’, 6th
Edition, AddisonWesley, 2011
3. Raghavan.V, “Materials Science and Engineering”, Prentice Hall of
India Pvt. Ltd., 2017.
4. U.C.Jindal : Material Science and Metallurgy, "Engineering Materials
and Metallurgy", First Edition, Dorling Kindersley, 2012
5. Upadhyay. G.S. and Anish Upadhyay, “Materials Science and
Engineering”, Viva Books Pvt. Ltd., New Delhi, 2006.
6. Dieter George E., “Mechanical Metallurgy”, 3rd Edition, McGraw-Hill,
New York, 2014
7. J. Prasad and C. G. K. Nair, Non-Destructive Test and Evaluation of
Materials, Tata McGraw-Hill Education, 2nd edition (2011).
Mini Project suggestions
➢ To design and fabricate the bicycle frame using fiber reinforced composites.
composites.
Thank you
Disclaimer:
This document is confidential and intended solely for the educational purpose of RMK Group of
Educational Institutions. If you have received this document through email in error, please notify the
system manager. This document contains proprietary information and is intended only to the
respective group / learning community as intended. If you are not the addressee you should not
disseminate, distribute or copy through e-mail. Please notify the sender immediately by e-mail if you
have received this document by mistake and delete this document from your system. If you are not
the intended recipient you are notified that disclosing, copying, distributing or taking any action in
reliance on the contents of this information is strictly prohibited.