MATERIAL SAFETY DATA SHEET

Last changed: 11/Dec/1998 Internal no.: :rev LdV-2 Replaces date: 07/Aug/1998

MAR - 71
1. PRODUCT AND COMPANY

TRADE NAME MAR - 71

APPLICATION Bactericides (disinfection)

ART-NO 653 613809 (5 liter)

Producer/Importer UNITOR CHEMICALS, Kjemi-Service AS

Address P.O.Box 49
Zipcode & City 3163 Borgheim
Country Norway
Telephone + 47 33 35 15 00
Fax + 47 33 35 15 05
Issued by Leen de Visser (+31 6 538 63736)
Emergency number Int. +44 1865 407333

Int. +1 703 5273887

USA (800) 424-9300
Greece Int. +30 1 7793777

2. COMPOSITION OF PRODUCT
No Ingredients name CAS-NO Cons.(weight%) Classification
1 N,N-Methylene-bis-(5-methyl-oxazolidine) 66204-44-2 >95 Xn,22-36/37/38
2 Components which do not contribute to the classification of the 1 - 10
product.

Legend T+=Very toxic, T=Toxic, C=Corrosive, Xn=Harmful, Xi=Irritant, IK=No classification required, E=Explosive, O=Oxidising,
F+=Extremely flammable, F=Very flammable, Fo=Flammable, N=Dang. to the environment, Mut=Genetoxic,
Sens=Sensitizing, Carc=Carcinogen, Repr=Causes birth defects

3. HAZARD IDENTIFICATION

Harmful
Liquid.Colourless.Completely soluble in water.
Irritating to eyes, respiratory system and skin.
Harmful if swallowed.

4. FIRST AID
GENERAL
Seek medical attention if any signs of unconsciousness or discomfort develop.Show this safety data sheet to the
physician present.

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INHALATION
In case of accidental inhalation of vapours or decomposition products, move to fresh air.Get medical advice if
discomfort develops.
SKIN CONTACT
Wash skin thoroughly with soap and water for several minutes.Get medical attention if irritation persists after
washing.Remove contaminated clothing immediately.Wash contaminated clothing before reuse.
EYE CONTACT
After splashes in the eyes: Flush with large amounts of water for at least 15 minutes.Keep eye wide open while
flushing.Get medical advice.
INGESTION
DO NOT INDUCE VOMITING! Get medical advice immediately.
If vomiting occurs, keep the head low to prevent obstruction of airways.Drink a couple of glasses of water or milk.Too
much water increases the danger of vomiting, which makes the damage worse.
MEDICAL INFORMATION
High risk of chemical pneumonia (pneumonitis) if aspirated during and after ingestion.If necessary, perform gastric
lavage after intubation.The product has moderate acute toxicity.

5. FIRE FIGHTING MEASURES

PROPER FIREFIGHTING EQUIPMENT
Water spray, fog or mist, alcohol-resistant foam, dry chemical, carbon dioxide (CO2).
IMPROPER FIREFIGHTING EQUIPMENT
Not known.
PERSONAL PROTECTION WHEN FIREFIGHTING
S-210 Wear self-contained breathing apparatus or supplied-air respirator in confined spaces.
OTHER INFORMATION
Containers close to fire should be removed immediately or cooled with water.

6. ACCIDENTAL RELEASE MEASURES

SAFETY MEASUREMENTS TO PROTECT PERSONS
Clean-up personnel should use respiratory protection and/or protection against liquid contact.Use personal protective
equipment as specified in section 8.
SAFETY MEASUREMENTS TO PROTECT ENVIRONMENT
Do not contaminate lakes, canals or ditches with the chemical or its container.Dike with absorbent material and prevent
spreading and release to water sources and sewers.
PROPER METHODS FOR DAMAGE LIMITATION AND CLEANUP
Remove spill with absorbent materials and/or mechanical equipment, and dispose of in accordance with section
13.Flush with large amounts of water to clean the area.Ventilate well.

7. HANDLING AND STORAGE

HANDLING ADVICE
Use personal protective equipment as specified in section 8.Avoid contact with skin and eyes.Eyewash facilities should
be available at the workplace.
STORAGE
S-3/9/49 Keep only in the original container in a cool, well ventilated place.S-3/9/49 Containers must be kept tightly

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closed.

8. EXPOSURE CONTROL AND PERSONAL PROTECTION

Ingredients name CAS-no TLV value TLV Year

N,N-Methylene-bis-(5-methyl-oxazolidine) 66204-44-2 0.0

EXPOSURE CONTROL
Arrange working conditions and methods to avoid prolonged contact with the product.Do not inhale aerosol.
RESP. PROTECTION
Normally not necessary in ordinary use.Use respiratory protection for operations which generate gas, fumes, vapour or
mist, e.g. gas mask with combination cartridge A2/P2.
EYE PROTECTION
Wear eye protection if there is a possibility of direct contact or splashes.
HAND PROTECTION
Use protective gloves of impervious material, e.g.:Neoprene, nitrile, polyethylene or PVC.
SKIN PROTECTION
Protective clothing should be worn if there is a possibility of direct contact or splashes.
OTHER INFORMATION
Do not smoke in work area.

9. PHYSICAL AND CHEMICAL PROPERTIES

Form Liquid.
Colour Colourless./Pale yellow.
Odour Strong.Irritating.Ammonia-like.
Solubility Completely soluble in water.
Melting point/range N/E Density 1.06 @ 20 ºC
Expl. limit LEL-UEL., %-%: 0.6 - 6.0 Solubility in water 100 %
Vapor pressure < 1 hPa Saturation conc. N/A
Decomposition temp. N/A Rel. density sat. air (air=1) N/A
pH Solution 10 (1.5 g/l) Boiling point/range 116 ºC (760 mm Hg)
Flash point > 100 ºC pH konsentrat: N/A
Molecular weight N/A Viscosity < 15 sec
Ignition temp N/A Smelling limits lo-hi N/A
Rel. vapor density (air=1) >1 Rel. evap. velocity N/E
Air reactive N/A Water reactive N/A

OTHER INFORMATION
N/A = Not applicable.
N/E = Not established.

10. STABILITY AND REACTIVITY

STABILITY
Stable under normal conditions.Avoid intense heating.Decomposes when exposed to heat.
MATERIALS TO AVOID
Reacts violently with acids.
HAZARDOUS DECOMPOSITION PRODUCTS
No decomposition if stored and used as directed.

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11. TOXICOLOGICAL INFORMATION
OTHER TOX. INFORMATION
LD50/oral/rat =900 mg/kg
GENERAL
As for all other chemicals, the product should be handled with care.
INHALATION
Inhalation may cause irritation to the respiratory system, coughing and shortness of breath.
SKIN CONTACT
Prolonged or repeated contact may cause irritation.
EYE CONTACT
Vapour or splashes in the eyes may cause irritation and smarting.
INGESTION
The product will be difficult to swallow.Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.
SESITATION
Sensitizing properties are not known.
CANCER

Not regulated.

12. ECOLOGICAL INFORMATION

MOBILITY
Dissolves in water .
BREAKDOWN
Readily biodegradable, according to appropriate OECD test.
ACCUMULATION
Has the potential to bioaccumulate.
ECOTOXITY
LC50 (Br.rerio, mg/litre):57.7
EC50/48h/Daphnia =37.9 mg/l
OTHER INFORMATION
No environmental problems are expected if the product is handled/used correctly.
In its intended use the product will not be released into the environment.

13. DISPOSAL
S-35 This material and its container must be disposed of in a safe way.S-35 In accordance with local and national
regulations.

14. TRANSPORT INFORMATION

GENERAL
Goods classified for transport : NO
PROPER SHIPPING NAME : Not regulated.
Flash point : > 100 ºC

Label information:

ADR

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Class : Not regulated.

IMDG-CODE
Class : Not regulated.

IATA-DGR
Class : Not regulated.

US DOT
Class : Not regulated.

GENERAL
Not considered as dangerous goods under UN, IMO, ADR/RID or IATA/ICAO regulations.

15. REGULATORY INFORMATION

Classification

Harmful

COMPOSITION
N,N-Methylene-bis-(5-methyl-oxazolidine) (>95)

R-PHRASES
R-22 Harmful if swallowed.
R-36/37/38 Irritating to eyes, respiratory system and skin.
S-PHRASES
S-26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S-28 S-28 After contact with skin, wash immediately with plenty of Water.
REFERENCES
Classified according to European directive on classification of dangerous preparations 90/492/EEC.
OTHER INFORMATION

The product is labelled in accordance with EU directive 88/379.

16. OTHER INFORMATION

ISSUED: 11/Dec/1998

VENDOR NOTES
The safety data sheet fulfills requirements specified in Directive 93/112/EEC.The safety data sheet has been prepared
on the basis of information given by our suppliers and our present knowledge.Information given is intented to present
guidelines for safe handling, use, processing, storage, transport, disposal and discharge; it is not intended to be a
guarantee or quality specification.The intent of this safety data sheet is to give a description of the product with regard to
safe storage, handling and use.Information given applies only to the product itself, and not in combination with other
products or in any processed form, unless this is specified in the text.We believe that all information in this safety data
sheet (which replaces all previous versions) was correct at the date of issue.It is the responsibility of the recipient of
this safety data sheet to ensure that information given here is read and understood by all who use, handle, dispose of or
in any way come in contact with the product.

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