Compressed Gas Cylinder Safety SOP
Compressed Gas Cylinder Safety SOP
Definition
A compressed gas is defined as any single gas or mixture of gases in a container with a pressure exceeding
40 psi at 70°F/21°C, 104 psi at 130°F/55°C, or any flammable liquid with an absolute vapor pressure
exceeding 40 psi at 100°F/38°C.
Hazards
Cylinders of compressed gases can pose a chemical hazard as well as a physical hazard. If the valve were
to break off a cylinder, the amount of force present could propel the cylinder through a brick wall. For
example, a cylinder of compressed breathing air used by SCUBA divers has the explosive force of 1 ½
pounds of TNT.
Container Requirements for Compressed Gases
1. All compressed gas cylinders or containers delivered to or shipped from the University must be
marked, labeled, stored, and handled in accordance with all applicable rules and regulations,
including DOT, OSHA, and NFPA standards.
2. The contents of each cylinder and container must be clearly identified by tag or stamp on the
cylinder.
3. University faculty, staff, and students must not remove or alter any identification on a compressed
gas cylinder.
4. Do not purchase a larger cylinder size than necessary. Only gases in returnable containers should be
selected for purchase—lecture bottles are an exception.
Storage of Compressed Gas Cylinders
1. Storage areas for compressed gas cylinders must be designed to accommodate the gases used and
provide adequate spacing and/or segregation in accordance with applicable building codes and
regulations. Compressed gas cylinder storage areas must be segregated from exit corridors and
egress paths.
2. Storage areas should be designated by hazard class and marked clearly with appropriate warning
signs that restrict access.
3. Consideration must be given to separate storage of full and empty containers. Incompatible gases
must be separated by at least 20-feet or separated by using appropriate fire rated barriers.
4. The cylinder storage area should be dry, free of combustible materials and debris (e.g. timber, card
board, packaging materials) to prevent flame impingement on gas cylinders in a fire, well-ventilated,
and be of fire-resistant construction when necessitated by the gas in storage.
5. Compressed gas cylinders must not be stored near sources of heat and ignition or near corrosive
chemicals or fumes.
9. All compressed gas cylinders must be fitted with a protective valve cap or guard while in storage.
10. If the use of small non-refillable cylinders (lecture bottles) is unavoidable, they should be secured in a
device, cage, or box designed for cylinders 18-inches or smaller.
11. Toxic gases (such as F2, CO, and H2S) should be stored and used in a chemical fume hood. If this is
not feasible, the area of use must be equipped with a detection system specific to the toxic gas or
inhalation hazard.
12. Oxygen should be stored in an area that is at least 20-feet away from any flammable or combustible
materials, or separated from them by a noncombustible barrier at least 5-feet high and having a fire-
resistance rating of at least 1/2 hour.
13. Position all cylinders so that the main valve is always accessible.
Safe Handling of Compressed Gas Cylinders
1. Persons handling compressed gas cylinders must:
• Be familiar with the hazards of the compressed gas.
• Always use a cylinder cart or other transport device to move cylinders in a secured fashion.
Never drag a cylinder by valves or caps or roll a cylinder in a horizontal position. Compressed
gas cylinders should be transported with the cylinder cap securely fastened.
• Never use a compressed gas cylinder as a support or door stop.
• Keep caps on cylinders unless connected to dispensing equipment systems.
• Never expose cylinders to temperature extremes, direct flame, or heat.
2. Never use a gas cylinder that cannot be positively identified. Color-coding is not a reliable way of
identifying a gas cylinder because the colors can vary from supplier to supplier.
3. Empty compressed gas cylinders must be:
• Closed
• Secured at all times
• Labeled to indicate “empty”
4. Regulators control the rate at which gas is delivered from the cylinder so the gas may be used safely.
Never discharge a gas without the use of a regulator. Compressed gas piping, regulators, and flow
control equipment must be:
• Installed and operated by trained and qualified persons familiar with the specific hazards of the
gases in use.
• Grounded to minimize sparks due to static discharge when using flammable gas.
• Provided with a means for safely purging the system and devices to prevent backflow of gases
or liquids into the gas storage cylinders when using hygroscopic corrosive gases, such as
anhydrous HCl.
5. Always use the appropriate regulator on a cylinder.
• If a regulator will not fit a cylinder's valve, replace the cylinder, not the regulator.
• Do not ever attempt to adapt or modify a regulator to fit a cylinder for which it was not
designed. Regulators are designed to fit only specific cylinder valves to avoid improper use.
6. Inspect regulators, pressure relief devices, valves, cylinder connections, and hose lines frequently for
damage.
7. Do not use oil or grease on any cylinder component of an oxidizing gas because a fire or explosion
can result.
8. Never transfer gases from one cylinder to another.
• The gas may be incompatible with the residual gas remaining in the other cylinder.
• The gas may be incompatible with the material of which the cylinder is made.
9. Never completely empty cylinders.
• Leave approximately 25 psi of pressure.
• This will prevent any residual gas in the cylinder from becoming contaminated.
Emergency Procedures for Compressed Gas Cylinders
1. Personnel should be aware of common emergency situations involving compressed gases and their
associated hazards, such as:
• An unsecured cylinder may tip and become damaged in a manner that the release of internal
pressure can cause the cylinder to become a dangerous high-speed projectile.
• A fire threatening the cylinder can cause a rupture or explosion.
• A flammable gas leak can cause a buildup of explosive gases.
• A leak can cause high concentrations of gas that exceed safe breathing levels or an inert gas
leak can cause an oxygen-deficient atmosphere that is a threat to life safety.
• An unplanned chemical reaction may cause a cylinder rupture or explosion of apparatus.
2. Fires involving compressed gas cylinders should be handled with extreme caution.