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Atomicstructure
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10. ML. 2. 13, 4 15. 16. 1. 18, ‘The time period of revolution of electron in its ground state orbit in a hydrogen atom is 1.6 x 10-! s. The frequency of revolution of the electron in its first excited state (in sis: [7 Jan. 2020 1] (@) 16x10" (b) 78x10" (©) 62x10" (@)—5.6x 10" An excited He" ion emits two photons in succession, with wavelengths 108.5 nm and 30.4 nm, in makinga transition to ground state, The quantum number n, corresponding, to its initial excited state is (for photon of wavelength », __ 12aver ener E= 5 Gommy {12 Aprit 2019 14 (a) n=4 (by () n=7 (@) n=6 ‘The electron in a hydrogen atom first jumps from the third excited state tothe second excited state and subsequently to the first excited state, The ratio of the respective wavelengths, 2,/,, ofthe photons emitted in this process is: [12 Aprit2019 11) @ 207 wm OW m9 ‘Consider an eleetron in a hydrogen atom, revolving in its second excited state (having radius 4.65 A), The de-Brogl wavelength ofthiselectron is: [12 April 2019 (@) 35A (6) 66A (©) 129A) 97A In Li’ electron in first Bohr orbit is excited toa level bya radiation of wavelength 2. When the ion gets deexcited to the ground state in all possible ways (including intermediate emissions), a total of six spectral lines are observed. What is the value of? [10 April 2019 II] (Given : h= 6.6310" Js; ¢=3 * 108s!) (@) Hanm (6) 94nm (6) 123m @) 108nm ‘Taking the wavelength of first Balmer line in hydrogen spectrum (n=3 ton =2)as660 nm, the wavelength of the 2" Balmer line(n=4ton=2) will be; [9 April 20191] (@) 8892nm (©) 4889nm (©) 642.71 (@) 3889nm ‘A He' ion isin it first excited state. Its ionization energy is [9 April 2019 11] (a) 4836eV (b) S440ev (©) 13.60eV (@) 604eV Radiation coming from transitions n = 2 to n= 1 of hydrogen atoms fall on He® ions in n= Land n=2 states. ‘The possible transition of helium ions as they absorb ‘energy from the radiation is [8 April 20191) (@) n=29n=3 () n=tona4 (©) n=2ones (@) n=2>ne4 A hydrogen atom, initially in the ground state is excited ‘byabsorbing a photon of wavelength 980A. The radius of the atom in the excited state, in terms of Bohr radius ay, willbe: [11 Jan 2019 1] (@) 254) (@) 4a) (b) 9% ©) 16a 19. 20. 21. 22. 23. 24. Ina hydrogen like atom, when an electron jumps from the Meshell o the L-shell, the wavelength of emitted radiation is 1 Ifan electron jumps from N-shell to the L-shell, the wavelength of emitted radiation will be: [11 Jan 2019 11] 20 © 5 OF ‘An electron from various excited states of hydrogen atom, emit radiation to come to the ground state. Let hy, hy be the de Broglie wavelength ofthe electron in the n state and the ground state respectively. Let A,, be the wavelength ofthe emitted photon in the transition from the n!® state to the ground state. For large n, (A, B are z 16 @ 59% 95) constants) {2018} () A,=A+BA, (©) AzsA+BA2 @ Area Ifthe series limit frequency of the Lyman series is v;, then the series limit frequency of the P-fund series is : 2018) @ By &) 16y, © y/6 @ vy25 The de-Broglie wavelength (2,,) associated with the electron orbiting in the second excited state of hydrogen atom is related to that in the ground state (i) by [Online April 16,2018], () p= hes (©) Ag han (©) yng @ Age Ihg The energy required to remove the electron from asingly ionized Helium atom is 2.2 times the energy required to remove an electron from Helium atom. The total energy required to ionize the Helium atom completely is: [Online April 15,2018], (© 19ev (a) Mev (@) eV (b) 79eV Muon (1!) is negatively charged (lq|=[el) with a mass 1m, =200m,), where m. isthe mass ofthe electron and eis, theelectronic charge. If"! is bound toa proton to forma hydrogen like atom, identify the eorrect statements, [Online April 15, 2018] (A) Radius ofthe muonie orbit is 200 times smaller than that ofthe electron 1 Spy times 1e speed of the w~! in the nth orbit is (B) the speed of the 4 in the nth orbit is 35 that of the election in the nth orbit (©) The lonization energy of muonie atom is 200 times ‘more than that ofan hydrogen atom. (D) The momentum of the muon in the nth orbit is 200 times more than that of the electron @ B.D) ©) ®.0) © © @ A.O,O)25, 2. 29. Somccnergy levels ofa molecule aeshown nthe figure. The ratio of the wavelengths r=), is given by (20171 al ro? w®r=s oO @ =F ‘The acceleration of an electron in the first orbit of the hydrogen atom (= 1) is: [Online April 9, 2017], eat OR According to Bohr’s theory, the time averaged magnetic field atthe centre (i.e, nucleus) of hydrogen atom duc to the motion ofelectrons in the n** orbit is proportional to (a principal quantum number) [Online April 8, 2017] Or © Or wer A hydrogen atom makesa transition fromn=2ton= | and, emits photon. Thisphoton strikes. a doubly onized lithium atom (2 3) in excited state and completely removes the “orbiting electron The least quantum number for the excited state of the ion for the process is [Online 44 (@ 2 ®4 @5 @3 Asan electron makes transition from an excited state to the ground state ofa hydrogen - like atonvion 2016) 12015) (@) kinetic energy decreases, potential energy inereases but total energy remains same (b) kinetic energy and total energy decrease but potential (©) ts kinetic energy increases but potential energy and total enerey decrease (@) kineticenery, potential energy and total energy decrease ‘The de-Broglie wavelength associated with the electron in the n = 4 level is [Online April 11, 2015] (@) th ofthe de-Broglie wavelength of the electron in the ground stat. (b) fourtimes the de-Broglie wavelength of the electron in the ground sate (©) to times the de-Broglie wavelength ofthe eletron ‘the ground state (a) hatF ofthe de-Broglie wavelength ofthe letron in the ground state 31. 32. 33. M4 fone were to apply Bohr model to a particle of mass ‘m" and charge ‘q" moving in a plane under the influence of a ‘magnetic field “B’, the energy of the charged particle in then level will be: [Online April 10, 2015] o (R) 0 o(%) o *(35) «0 o( 24) ‘The radiation corresponding to 3 > 2 transition of hhydrogen atom falls on a metal surface to produce photoelectrons. These electrons are made to enter a ‘magnetic field of 3 « 107. Ifthe radius of the largest, circular path followed by these electrons is 10.0 mm, the ‘work fimetion ofthe metal iscloseto: [2014] (a) 18eV (b) Liev (©) 08ev (@) L6ev Hydrogen (11, Deuterium (,F?), ingly inised Helium (.He')' and doubly ionised lithium (,Li*)" all have one electton around the nucleus. Consider an electron ‘ansition fom n=2 ton = 1. Ifthe wavelengths of emitted radiation are 2,2,23 and hy respectively then approximately whieh one ofthe following is correct? (2014) (@) =a Match List - 1 (Experiment performed) with List-II (Phenomena discovered/associated) and select the correct ‘option from the options given below the lists: [Online April 19, 2014] Shy =A List-1 List-It () JPavisson and Genner| @ ]Wave nature of experiment electrons (@)[Millkan’s oil drop [Gi [Charge ofan electron esperiment © [Ruthertont (i [Quantisation of experiment lencray levels @ |Franck-Henz iv) |iSistence of nucleus experiment (a) (OH, QL, Gli), HG) 0) CHD, BH), 44) © (MG. 2HiY.GHi.4>4) (@) (+6), CHG. BHD. 4D)37. 29. a, ‘The binding energy of the electron ina hydrogen atom is 13.6eV, the eneray’required to remove the electron from the ist excited state of Li"*is: [Online April9, 2014] @ I224eV (6) 306eV (©) 136eV (@) 34eV Ina hydrogen like atom electron make transition from an energy level with quantum number n to another with quantum number (n ~ 1). If n>>1, the frequency of radiation emitted is proportional to [2013] @+ ‘A125 eV electron beam is used to bombard gaseous, Inydrogen at room temperature. [twill emit [Online April 25, 2013], (a) 2 lines in the Lyman series and 1 Tine in the Balmar (b) 3inesin the Lyman series (6) Linein the -yman series and 2 lines in the Balmar series (@) 3linesin the Balmer series In the Bobr's model of hydrogen-like atom the force between the nucleus and the electron is modified as efi (45) wet iseonam fri the radius of the a orbit in terms of the Bohr radius (3 [Online April 23, 2013] fa) r= agn—B (b) r= ag? +B ©) r= ay—B @) rym agntB Orbits ofa particle moving in a circle are such thatthe perimeter of the orbit equals an integer number of de- Broglie wavelengths of the particle. For a charged particle moving in a plane perpendicular to a magnetic field, the radius of the a orbital will therefore be proportional to [Online April 22, 2013} Oe Oa Om? Mat Inthe Bobr model an electron meves in acitcular orbitaround the proton, Considering the orbiting electron to bea circular current loop, the magnetie moment ofthe hydrogen atom, ‘when the electron isin n excited state, is: [Online April 9, 2013] © (SIR e wh o (3%) enh »(S Hydrogen atom is excited ftom ground state to another state with principal quantum number equal to 4. Then the ‘number of spectral lines in the emission spectra will be (2012) @ 6 (2 3 oS 2. 4B. 44, 46, 47. 48, A diatomic molecule is made of two masses m, and my which are separated by a distance r, If we calculate its rotational energy by applying Bohr's rule of angular ‘momentum quantization, its energy will be given by: (nis an integer) (2012) (ray my)??? ne omarmyene he a ) ann Blom my 2h? gy (mena? Gay + may (@) omyigr ‘Which of the plots shown in the figure represents speed (»,) ofthe electron in ahyerogen atom as. function ofthe principal quantum number (n)? [Online May 26, 2012] oe @B (OD Oc. Or A doubly ionised Li atom is excited from its ground state (a= 1)ton=3 state. The wavelengths ofthe spectral lines fen by hype Ay and Ay. The ratio Ayala) and [Online May 12, 2012] pith ae, espetively (a) 81,067 () 81,12 © 6412 (@ 64,067 A hypothetical atom has only three energy levels. The ground level has energy, E, = ~ 8 eV, The two excited states have energies, E = — 6eV and £,=~2 eV. Then which of the following Wavelengths will not be present in the emission spectrum of this atom? [Online May 12, 2012] (@) 207 om (b) 465 om (©) 310mm (@) 620nm ‘The electron ofa hydrogen atom makes atransition from the (n + 1)" orbit to the n! orbit. For large n the wavelength ofthe emitted radiation is proportional to {Online May 7, 2012] (@ n Om Om — @r Energy required forthe electron excitation in Li™* from the first to the third Bohe orbit is 201) (a) 363eV. (b) 108.80 (©) 1224ev @ 121ev ‘The transition from the state n= 4 to n=3 ina hydrogen like atom results in ultraviolet radiation. Infrared ‘radiation will be obtained in the transition from : [2009] @ 352 492 © 554 W2519. sh. Suppose an electron is attracted towards the origin by a force £ where is constant and ‘7 is the distance of the electron from the origin, By applying Bobr model to this system, the radius of the n" orbital ofthe electron. is found to be ‘r,” and the kinetic energy of the electron, tobe ‘7,". Then which ofthe following is true? [2008] () Tres 52. (b) 7, independent of nr, o¢ © 1, 1 (d) Th Which ofthe following transitions in hydrogen atoms emit, photons of highest frequency? [2007] G@) n=1ton=2 0) ton=6 53. (©) n=6ton=2 (d)—-n=2ton=1 The diagram shows the energy levels for an electron in a certain atom. Which transition shown represents the emission of a photon with the most energy? [20085] a TW @Vv om on @1 ‘The wavelengths involved in the spectrum of deuterium (30) are slighty aiterent fom that of hydrogen spectrum, because (2003) (a) the size ofthe two nuclei are different (b) the nuclear forces are diferent in the two cases (6) the masses ofthe 0 nuclei are diferent (4) the attration between the electron and the nucleus is diferent in the nwo cases 1136eV energy required to onze thehyrogen for, then the eneray required to remove an electron from n= 2is [2002] (@) 1020V (©) 34eV (b) OeV (0) 68eV
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