SAFETY DATA SHEET

Revision Date 17-Apr-2018 Version 8

1. IDENTIFICATION
Product identifier
Product Name Spray Nine Grez-Off® 1 gal

Other means of identification

Product Code 22701

Recommended use of the chemical and restrictions on use

Recommended Use Degreaser - General Purpose - Non-Aerosol.
Uses advised against No information available

Details of the supplier of the safety data sheet

Manufacturer Address May Also Be Distributed by:
ITW Permatex ITW Permatex Canada
6875 Parkland Blvd. 101-2360 Bristol Circle
Solon, OH 44139 USA Oakville, ON Canada L6H 6M5
Telephone: (800) 924-6994

24-hour emergency phone number Chem-Tel: 800-255-3924

International Emergency:
00+1+ 813-248-0585
Contract Number: MIS0003453

E-mail address [email protected]

2. HAZARDS IDENTIFICATION
Classification

OSHA Regulatory Status

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Skin corrosion/irritation Category 2A

Serious eye damage/eye irritation Category 2A

Label elements

Emergency Overview
Signal word
Warning

Causes skin irritation

Causes serious eye irritation

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Appearance Orange Physical state Liquid Odor Citrus

Precautionary Statements - Prevention

Wash face, hands and any exposed skin thoroughly after handling
Wear protective gloves/protective clothing/eye protection/face protection

Precautionary Statements - Response

Specific treatment (see supplemental first aid instructions on this label)
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
IF ON SKIN: Wash with plenty of soap and water
If skin irritation occurs: Get medical advice/attention
Take off contaminated clothing and wash before reuse

Precautionary Statements - Storage

Store in a well-ventilated place. Keep cool

Precautionary Statements - Disposal

Dispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC)

Not applicable

Other Information
- Not applicable

Unknown acute toxicity 1.4708 % of the mixture consists of ingredient(s) of unknown toxicity

3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance(s)

Chemical Name CAS No Weight-%

SODIUM METASILICATE 6834-92-0 1-5
Any concentration shown as a range is due to batch variation.

4. FIRST AID MEASURES

Description of first aid measures

General advice Get medical advice/attention if you feel unwell.

Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention.

Skin contact IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician.
Take off contaminated clothing and wash before reuse.

Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. If symptoms persist, call a physician.

Ingestion IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an

unconscious person. Call a physician.

Self-protection of the first aider Use personal protective equipment as required.

Most important symptoms and effects, both acute and delayed

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Symptoms See section 2 for more information.

Indication of any immediate medical attention and special treatment needed

Note to physicians Treat symptomatically.

5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Carbon dioxide (CO2), Dry chemical, Foam

Unsuitable extinguishing media

None.

Specific hazards arising from the chemical

None in particular.

Explosion data
Sensitivity to Mechanical Impact None.
Sensitivity to Static Discharge None.

Protective equipment and precautions for firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin.
Use personal protective equipment as required.

Environmental precautions

Environmental precautions See Section 12 for additional Ecological Information.

Methods and material for containment and cleaning up

Methods for containment Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel
into suitable containers for disposal.

Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.

7. HANDLING AND STORAGE

Precautions for safe handling

Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing
vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling.
Wash contaminated clothing before reuse. Use personal protective equipment as required.

Conditions for safe storage, including any incompatibilities

Storage Conditions Keep container tightly closed in a dry and well-ventilated place. Keep from freezing.

Incompatible materials Strong oxidizing agents

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters
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Appropriate engineering controls

Engineering Controls Showers

Eyewash stations
Ventilation systems

Individual protection measures, such as personal protective equipment

Eye/face protection Tight sealing safety goggles.

Skin and body protection Wearpr

otect
i
venat
uralr
ubber
,ni
t
ril
erubber
,Neopr
ene™ orPVCgl
oves.

Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as
appropriate.

General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of
equipment, work area and clothing is recommended.

9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Physical state Liquid

Appearance Orange
Odor Citrus
Odor threshold No information available

Property Values Remar

ks •Met
hod
pH 8-11
Melting point / freezing point No information available
Boiling point / boiling range 100 °C / 212 °F
Flash point > 93 °C / > 200 °F Tag Closed Cup
Evaporation rate < 1 Butyl acetate = 1
Flammability (solid, gas) No information available
Flammability Limit in Air
Upper flammability limit: No information available
Lower flammability limit: No information available
Vapor pressure 18 mm Hg
Vapor density >1 Air = 1
Relative density ~1.013 g/ml
Water solubility Soluble in water
Solubility in other solvents No information available
Partition coefficient No information available
Autoignition temperature No information available
Decomposition temperature No information available
Kinematic viscosity No information available
Dynamic viscosity No information available
Explosive properties No information available
Oxidizing properties No information available

Other Information

Softening point No information available

Molecular weight No information available
VOC Content (%) <1%
Density No information available
Bulk density No information available

10. STABILITY AND REACTIVITY

Reactivity
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Stable under normal conditions

Chemical stability
Stable under recommended storage conditions

Possibility of Hazardous Reactions

None under normal processing.

Conditions to avoid
Keep from freezing.

Incompatible materials
Strong oxidizing agents

Hazardous Decomposition Products

Carbon oxides
Nitrogen oxides (NOx)

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Inhalation May cause irritation of respiratory tract.

Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes.

Skin contact May cause skin irritation and/or dermatitis.

Ingestion Ingestion may cause irritation to mucous membranes.

Chemical Name Oral LD50 Dermal LD50 Inhalation LC50

SODIUM METASILICATE = 1153 mg/kg ( Rat ) - -
6834-92-0

Information on toxicological effects

Symptoms No information available.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Sensitization No information available.

Germ cell mutagenicity No information available.
Carcinogenicity No information available.

The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral) 17322 mg/kg
ATEmix (dermal) 75518 mg/kg

12. ECOLOGICAL INFORMATION

Ecotoxicity

3.2241 % of the mixture consists of component(s) of unknown hazards to the aquatic environment

Persistence and degradability

No information available.

Bioaccumulation
No information available.

Mobility
No information available.

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Other adverse effects

No information available

13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and
regulations.

Contaminated packaging Do not reuse container.

US EPA Waste Number Not applicable

14. TRANSPORT INFORMATION

DOT
Proper shipping name: Not regulated

IATA
Proper shipping name: Not regulated

IMDG
Proper shipping name: Not regulated

15. REGULATORY INFORMATION

International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Not determined
ENCS Not determined
IECSC Complies
KECL Complies
PICCS Not determined
AICS Complies

Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances

US Federal Regulations

SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

SARA 311/312 Hazard Categories

Acute health hazard Yes
Chronic Health Hazard No
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Fire hazard No
Sudden release of pressure hazard No
Reactive Hazard No

CWA (Clean Water Act)

This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)

CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material

US State Regulations

California Proposition 65
This product does not intentionally contain any chemicals known by the State of California to cause cancer and/or birth defects
U.S. State Right-to-Know Regulations

U.S. EPA Label Information

EPA Pesticide Registration Number Not applicable

WHMIS Hazard Class

D2B - Toxic materials

16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION

NFPA Health hazards 1 Flammability 1 Instability 0 -
HMIS Health hazards 1 Flammability 1 Physical hazards 0 Personal protection B

NFPA (National Fire Protection Association)

HMIS (Hazardous Material Information System)

Revision Date 17-Apr-2018

Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

End of Safety Data Sheet

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