Revision date: 02/10/2020 Revision: 04 Supersedes date: 28/07/2015

SAFETY DATA SHEET

UNISOFT KHD
According to Regulation (EC) No 1907/2006, Annex II, as amended. Commission Regulation (EU) No 2015/830
of 28 May 2015.

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name UNISOFT KHD

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses Textile Auxiliaries

Uses advised against No specific uses advised against are identified.

1.3. Details of the supplier of the safety data sheet

Supplier Eksoy Kimya Sanayi ve Ticaret A.Ş.

Acıdereosb Mah. Zübeyde Hanım Cad. No:4 P.K.: 01410
SARIÇAM / ADANA / TÜRKİYE
Telephone : +90 (322) 441 11 80
Fax : +90 (322) 441 03 72
e-mail : [email protected]

1.4. Emergency telephone number

Emergency telephone Eksoy Kimya: +90 322 441 11 80 (office hours)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Not Classified

Health hazards Skin Corr. 1B - H314 Eye Dam. 1 - H318

Environmental hazards Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410

2.2. Label elements

Hazard pictograms

Signal word Danger

Hazard statements H314 Causes severe skin burns and eye damage.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary statements P405 Store locked up.

P270 Do not eat, drink or smoke when using this product.
P260 Do not breathe dust.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water or shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing.

Contains 1H-Imidazole-1-ethanol, 4,5-dihydro-, 2-nortall-oil alkyl derivs.

2.3. Other hazards

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UNISOFT KHD
According to Regulation (EC) No 1907/2006, Annex II, as amended. Commission Regulation (EU) No 2015/830
of 28 May 2015.

This product does not contain any substances classified as PBT or vPvB.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

1H-Imidazole-1-ethanol, 4,5-dihydro-, 2-nortall-oil alkyl derivs. 25-40%

CAS number: 61791-39-7

M factor (Acute) = 1 M factor (Chronic) = 1

Classification
Skin Corr. 1B - H314
Eye Dam. 1 - H318
Aquatic Acute 1 - H400
Aquatic Chronic 1 - H410

The full text for all hazard statements is displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

General information Get medical attention immediately. Show this Safety Data Sheet to the medical personnel. Chemical
burns must be treated by a physician.

Inhalation Remove affected person from source of contamination. Move affected person to fresh air and keep warm
and at rest in a position comfortable for breathing. Maintain an open airway. Loosen tight clothing such as
collar, tie or belt. When breathing is difficult, properly trained personnel may assist affected person by
administering oxygen. Place unconscious person on their side in the recovery position and ensure
breathing can take place.

Ingestion Rinse mouth thoroughly with water. Stop if the affected person feels sick as vomiting may be dangerous.
Do not induce vomiting unless under the direction of medical personnel. If vomiting occurs, the head
should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. Move affected person to fresh air and keep warm and at rest in a position
comfortable for breathing. Place unconscious person on their side in the recovery position and ensure
breathing can take place. Maintain an open airway. Loosen tight clothing such as collar, tie or belt.

Skin contact It is important to remove the substance from the skin immediately. Take off immediately all contaminated
clothing. Rinse immediately with plenty of water. Continue to rinse for at least 15 minutes and get medical
attention. Chemical burns must be treated by a physician.

Eye contact Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide apart.
Continue to rinse for at least 10 minutes.

Protection of first aiders First aid personnel should wear appropriate protective equipment during any rescue. Wash contaminated
clothing thoroughly with water before removing it from the affected person, or wear gloves. It may be
dangerous for first aid personnel to carry out mouth-to-mouth resuscitation.

4.2. Most important symptoms and effects, both acute and delayed

General information See Section 11 for additional information on health hazards. The severity of the symptoms described will
vary dependent on the concentration and the length of exposure.

Inhalation A single exposure may cause the following adverse effects: Severe irritation of nose and throat.
Symptoms following overexposure may include the following: Corrosive to the respiratory tract.

Ingestion May cause chemical burns in mouth, oesophagus and stomach. Symptoms following overexposure may
include the following: Severe stomach pain. Nausea, vomiting.

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UNISOFT KHD
According to Regulation (EC) No 1907/2006, Annex II, as amended. Commission Regulation (EU) No 2015/830
of 28 May 2015.

Skin contact Causes severe burns. Symptoms following overexposure may include the following: Pain or irritation.
Redness. Blistering may occur.

Eye contact Causes serious eye damage. Symptoms following overexposure may include the following: Pain. Profuse
watering of the eyes. Redness.

4.3. Indication of any immediate medical attention and special treatment needed

Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media The product is not flammable. Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water
fog. Use fire-extinguishing media suitable for the surrounding fire.

Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire.

5.2. Special hazards arising from the substance or mixture

Specific hazards Severe corrosive hazard. Water used for fire extinguishing, which has been in contact with the product,
may be corrosive.

Hazardous combustion products Thermal decomposition or combustion products may include the following substances: Very toxic or
corrosive gases or vapours.

5.3. Advice for firefighters

Protective actions during Avoid breathing fire gases or vapours. Evacuate area. Keep upwind to avoid inhalation of gases, vapours,
firefighting fumes and smoke. Cool containers exposed to heat with water spray and remove them from the fire area
if it can be done without risk. Cool containers exposed to flames with water until well after the fire is out.
Avoid discharge to the aquatic environment. Control run-off water by containing and keeping it out of
sewers and watercourses. If risk of water pollution occurs, notify appropriate authorities.

Special protective equipment for Regular protection may not be safe. Wear chemical protective suit. Wear positive-pressure self-contained
firefighters breathing apparatus (SCBA) and appropriate protective clothing. Firefighter's clothing conforming to
European standard EN469 (including helmets, protective boots and gloves) will provide a basic level of
protection for chemical incidents.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions No action shall be taken without appropriate training or involving any personal risk. Keep unnecessary
and unprotected personnel away from the spillage. Wear protective clothing as described in Section 8 of
this safety data sheet. Follow precautions for safe handling described in this safety data sheet. Wash
thoroughly after dealing with a spillage. Ensure procedures and training for emergency decontamination
and disposal are in place. Do not touch or walk into spilled material. Avoid inhalation of dust. Use suitable
respiratory protection if ventilation is inadequate. Avoid contact with skin and eyes. Avoid contact with
contaminated tools and objects.

6.2. Environmental precautions

Environmental precautions Avoid discharge into drains or watercourses or onto the ground. Avoid discharge to the aquatic
environment. Large Spillages: Inform the relevant authorities if environmental pollution occurs (sewers,
waterways, soil or air).

6.3. Methods and material for containment and cleaning up

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UNISOFT KHD
According to Regulation (EC) No 1907/2006, Annex II, as amended. Commission Regulation (EU) No 2015/830
of 28 May 2015.

Methods for cleaning up Wear protective clothing as described in Section 8 of this safety data sheet. Clear up spills immediately
and dispose of waste safely. This product is corrosive. Approach the spillage from upwind. Collect spillage
with a shovel and broom, or similar and reuse, if possible. Collect and place in suitable waste disposal
containers and seal securely. Flush contaminated area with plenty of water. Wash thoroughly after
dealing with a spillage. Neutralise with alkali. Caution. May generate heat. Dangerous for the
environment. Do not empty into drains. Dispose of waste to licensed waste disposal site in accordance
with the requirements of the local Waste Disposal Authority.

6.4. Reference to other sections

Reference to other sections For personal protection, see Section 8. See Section 11 for additional information on health hazards. See
Section 12 for additional information on ecological hazards. For waste disposal, see Section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Read and follow manufacturer's recommendations. Wear protective clothing as described in Section 8 of
this safety data sheet. Keep away from food, drink and animal feeding stuffs. Keep container tightly
sealed when not in use. This product is corrosive. Immediate first aid is imperative. Avoid discharge to the
aquatic environment. Do not handle until all safety precautions have been read and understood. Do not
handle broken packages without protective equipment. Do not reuse empty containers.

Advice on general occupational Wash promptly if skin becomes contaminated. Take off contaminated clothing. Wash contaminated
hygiene clothing before reuse. Do not eat, drink or smoke when using this product. Wash at the end of each work
shift and before eating, smoking and using the toilet. Change work clothing daily before leaving
workplace.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store away from incompatible materials (see Section 10). Store in accordance with local regulations.
Store away from the following materials: Alkalis. Keep only in the original container. Keep container tightly
closed, in a cool, well ventilated place. Keep containers upright. Protect containers from damage. Bund
storage facilities to prevent soil and water pollution in the event of spillage. The storage area floor should
be leak-tight, jointless and not absorbent.

Storage class Corrosive storage.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

DNEL No information available.

PNEC No information available.

8.2. Exposure controls

Protective equipment

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UNISOFT KHD
According to Regulation (EC) No 1907/2006, Annex II, as amended. Commission Regulation (EU) No 2015/830
of 28 May 2015.

Appropriate engineering controls Provide adequate ventilation. Personal, workplace environment or biological monitoring may be required
to determine the effectiveness of the ventilation or other control measures and/or the necessity to use
respiratory protective equipment. Use process enclosures, local exhaust ventilation or other engineering
controls as the primary means to minimise worker exposure. Personal protective equipment should only
be used if worker exposure cannot be controlled adequately by the engineering control measures. Ensure
control measures are regularly inspected and maintained. Ensure operatives are trained to minimise
exposure.

Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicates eye contact
is possible. Personal protective equipment for eye and face protection should comply with European
Standard EN166. Wear tight-fitting, chemical splash goggles or face shield. If inhalation hazards exist, a
full-face respirator may be required instead.

Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn if a risk
assessment indicates skin contact is possible. The most suitable glove should be chosen in consultation
with the glove supplier/manufacturer, who can provide information about the breakthrough time of the
glove material. To protect hands from chemicals, gloves should comply with European Standard EN374.
Considering the data specified by the glove manufacturer, check during use that the gloves are retaining
their protective properties and change them as soon as any deterioration is detected. Frequent changes
are recommended.

Other skin and body protection Appropriate footwear and additional protective clothing complying with an approved standard should be
worn if a risk assessment indicates skin contamination is possible.

Hygiene measures Provide eyewash station and safety shower. Contaminated work clothing should not be allowed out of the
workplace. Wash contaminated clothing before reuse. Clean equipment and the work area every day.
Good personal hygiene procedures should be implemented. Wash at the end of each work shift and
before eating, smoking and using the toilet. When using do not eat, drink or smoke. Preventive industrial
medical examinations should be carried out. Warn cleaning personnel of any hazardous properties of the
product.

Respiratory protection Respiratory protection complying with an approved standard should be worn if a risk assessment
indicates inhalation of contaminants is possible. Ensure all respiratory protective equipment is suitable for
its intended use and is ‘CE’-marked. Check that the respirator fits tightly and the filter is changed
regularly. Gas and combination filter cartridges should comply with European Standard EN14387. Full
face mask respirators with replaceable filter cartridges should comply with European Standard EN136.
Half mask and quarter mask respirators with replaceable filter cartridges should comply with European
Standard EN140.

Environmental exposure controls Keep container tightly sealed when not in use. Emissions from ventilation or work process equipment
should be checked to ensure they comply with the requirements of environmental protection legislation. In
some cases, fume scrubbers, filters or engineering modifications to the process equipment will be
necessary to reduce emissions to acceptable levels. Store in a demarcated bunded area to prevent
release to drains and/or watercourses.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Paste.

Colour No information available.

Odour No information available.

Odour threshold No information available.

pH ~ 3,5 - 4,5 @ 25°C

Freezing point No information available.

Initial boiling point and range No information available.

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UNISOFT KHD
According to Regulation (EC) No 1907/2006, Annex II, as amended. Commission Regulation (EU) No 2015/830
of 28 May 2015.

Flash point No information available.

Evaporation rate No information available.

Evaporation factor No information available.

Flammability (solid, gas) No information available.

Upper/lower flammability or No information available.

explosive limits

Other flammability No information available.

Vapour pressure No information available.

Vapour density No information available.

Relative density No information available.

Bulk density No information available.

Solubility(ies) No information available.

Partition coefficient No information available.

Auto-ignition temperature No information available.

Decomposition Temperature No information available.

Viscosity No information available.

Explosive properties No information available.

Explosive under the influence of a No information available.

flame

Oxidising properties No information available.

9.2. Other information

Other information No information required.

SECTION 10: Stability and reactivity

10.1. Reactivity

Reactivity See the other subsections of this section for further details.

10.2. Chemical stability

Stability Stable at normal ambient temperatures and when used as recommended. Stable under the prescribed
storage conditions.

10.3. Possibility of hazardous reactions

Possibility of hazardous reactions No potentially hazardous reactions known.

10.4. Conditions to avoid

Conditions to avoid There are no known conditions that are likely to result in a hazardous situation.

10.5. Incompatible materials

Materials to avoid Alkalis. Amines.

10.6. Hazardous decomposition products

Hazardous decomposition Does not decompose when used and stored as recommended. Thermal decomposition or combustion
products products may include the following substances: Corrosive gases or vapours.

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UNISOFT KHD
According to Regulation (EC) No 1907/2006, Annex II, as amended. Commission Regulation (EU) No 2015/830
of 28 May 2015.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity - oral
Summary Based on available data the classification criteria are not met.

ATE oral (mg/kg) 6,720.0

Acute toxicity - dermal

Summary Based on available data the classification criteria are not met.

Acute toxicity - inhalation

Summary Based on available data the classification criteria are not met.

Skin corrosion/irritation
Summary Causes severe skin burns and eye damage.

Extreme pH Moderate pH ( > 2 and < 11.5).

Serious eye damage/irritation

Summary Causes serious eye damage.

Respiratory sensitisation
Summary Based on available data the classification criteria are not met.

Skin sensitisation
Summary Based on available data the classification criteria are not met.

Germ cell mutagenicity

Summary Based on available data the classification criteria are not met.

Carcinogenicity
Summary Based on available data the classification criteria are not met.

IARC carcinogenicity None of the ingredients are listed or exempt.

Reproductive toxicity
Summary Based on available data the classification criteria are not met.

Specific target organ toxicity - single exposure

Summary Based on available data the classification criteria are not met.

Specific target organ toxicity - repeated exposure

Summary Based on available data the classification criteria are not met.

Aspiration hazard
Summary Not relevant. Solid.

General information The severity of the symptoms described will vary dependent on the concentration and the length of
exposure.

Inhalation Corrosive to the respiratory tract. Symptoms following overexposure may include the following: Severe
irritation of nose and throat.

Ingestion May cause chemical burns in mouth, oesophagus and stomach. Symptoms following overexposure may
include the following: Severe stomach pain. Nausea, vomiting.

Skin contact Causes severe burns. Symptoms following overexposure may include the following: Pain or irritation.
Redness. Blistering may occur.

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UNISOFT KHD
According to Regulation (EC) No 1907/2006, Annex II, as amended. Commission Regulation (EU) No 2015/830
of 28 May 2015.

Eye contact Causes serious eye damage. Symptoms following overexposure may include the following: Pain. Profuse
watering of the eyes. Redness.

Route of exposure Ingestion Inhalation Skin and/or eye contact

Target organs No specific target organs known.

SECTION 12: Ecological information

12.1. Toxicity
Acute aquatic toxicity
Summary Very toxic to aquatic life.

Acute toxicity - fish LC₅₀, 96 hour: < 1 mg/l, (based on GHS classification)

Acute toxicity - aquatic EC₅₀, 48 hour: < 1 mg/l, (based on GHS classification)
invertebrates

Acute toxicity - microorganisms IC₅₀, 3 hour: < 1 mg/l, (based on GHS classification)

Chronic aquatic toxicity

Summary Very toxic to aquatic life with long lasting effects.

12.2. Persistence and degradability

Persistence and degradability The degradability of the product is not known.

Biological oxygen demand ~ 0,203 mg/g

Chemical oxygen demand ~ 0,597 mg/g

BOD5/COD 0,34

12.3. Bioaccumulative potential

Bioaccumulative potential No data available on bioaccumulation.

Partition coefficient No information available.

12.4. Mobility in soil

Mobility No data available.

12.5. Results of PBT and vPvB assessment

12.6. Other adverse effects

Other adverse effects None known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information The generation of waste should be minimised or avoided wherever possible. Reuse or recycle products
wherever possible. This material and its container must be disposed of in a safe way. Disposal of this
product, process solutions, residues and by-products should at all times comply with the requirements of
environmental protection and waste disposal legislation and any local authority requirements. When
handling waste, the safety precautions applying to handling of the product should be considered. Care
should be taken when handling emptied containers that have not been thoroughly cleaned or rinsed out.
Empty containers or liners may retain some product residues and hence be potentially hazardous.

Disposal methods Do not empty into drains. Dispose of surplus products and those that cannot be recycled via a licensed
waste disposal contractor. Waste, residues, empty containers, discarded work clothes and contaminated
cleaning materials should be collected in designated containers, labelled with their contents. Incineration
or landfill should only be considered when recycling is not feasible.

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UNISOFT KHD
According to Regulation (EC) No 1907/2006, Annex II, as amended. Commission Regulation (EU) No 2015/830
of 28 May 2015.

SECTION 14: Transport information

14.1. UN number

UN No. (ADR/RID) 1759

UN No. (IMDG) 1759

UN No. (ICAO) 1759

UN No. (ADN) 1759

14.2. UN proper shipping name

Proper shipping name (ADR/RID) CORROSIVE SOLID, N.O.S. (CONTAİNS 1H-Imidazole-1-ethanol, 4,5-dihydro-, 2-nortall-oil alkyl derivs.)

Proper shipping name (IMDG) CORROSIVE SOLID, N.O.S. (CONTAİNS 1H-Imidazole-1-ethanol, 4,5-dihydro-, 2-nortall-oil alkyl derivs.)

Proper shipping name (ICAO) CORROSIVE SOLID, N.O.S. (CONTAİNS 1H-Imidazole-1-ethanol, 4,5-dihydro-, 2-nortall-oil alkyl derivs.)

Proper shipping name (ADN) CORROSIVE SOLID, N.O.S. (CONTAİNS 1H-Imidazole-1-ethanol, 4,5-dihydro-, 2-nortall-oil alkyl derivs.)

14.3. Transport hazard class(es)

ADR/RID class 8

ADR/RID classification code C10

ADR/RID label 8

IMDG class 8

ICAO class/division 8

ADN class 8

Transport labels

14.4. Packing group

ADR/RID packing group II

IMDG packing group II

ICAO packing group II

ADN packing group II

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

14.6. Special precautions for user

EmS F-A, S-B

ADR transport category 2

Emergency Action Code 2X

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UNISOFT KHD
According to Regulation (EC) No 1907/2006, Annex II, as amended. Commission Regulation (EU) No 2015/830
of 28 May 2015.

Hazard Identification Number 80

(ADR/RID)

Tunnel restriction code (E)

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code

Transport in bulk according to Not applicable.

Annex II of MARPOL 73/78 and
the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

National regulations Health and Safety at Work etc. Act 1974 (as amended).
The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations 2009 (SI
2009 No. 1348) (as amended) ["CDG 2009"].
EH40/2005 Workplace exposure limits.

EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006
concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) (as
amended).
Commission Regulation (EU) No 2015/830 of 28 May 2015.
Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on
classification, labelling and packaging of substances and mixtures (as amended).

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

Inventories
EU - EINECS/ELINCS
None of the ingredients are listed or exempt.

SECTION 16: Other information

Abbreviations and acronyms used ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road.
in the safety data sheet ADN: European Agreement concerning the International Carriage of Dangerous Goods by Inland
Waterways.
RID: European Agreement concerning the International Carriage of Dangerous Goods by Rail.
IATA: International Air Transport Association.
ICAO: Technical Instructions for the Safe Transport of Dangerous Goods by Air.
IMDG: International Maritime Dangerous Goods.
CAS: Chemical Abstracts Service.
ATE: Acute Toxicity Estimate.
LC₅₀: Lethal Concentration to 50 % of a test population.
LD₅₀: Lethal Dose to 50% of a test population (Median Lethal Dose).
EC₅₀: 50% of maximal Effective Concentration.
PBT: Persistent, Bioaccumulative and Toxic substance.
vPvB: Very Persistent and Very Bioaccumulative.

Classification abbreviations and Eye Dam. = Serious eye damage

acronyms Skin Corr. = Skin corrosion
Aquatic Acute = Hazardous to the aquatic environment (acute)
Aquatic Chronic = Hazardous to the aquatic environment (chronic)

Classification procedures Eye Dam. 1 - H318: Skin Corr. 1B - H314: : Calculation method. Aquatic Acute 1 - H400: Aquatic Chronic
according to Regulation (EC) 1 - H410: : Calculation method.
1272/2008

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UNISOFT KHD
According to Regulation (EC) No 1907/2006, Annex II, as amended. Commission Regulation (EU) No 2015/830
of 28 May 2015.

Training advice Read and follow manufacturer's recommendations. Only trained personnel should use this material.

Issued by SEVLER GOKCE AVCIOGLU - [email protected]

Revision date 02/10/2020

Revision 04

Supersedes date 28/07/2015

SDS number 108

Hazard statements in full H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This information relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date
indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility
to satisfy himself as to the suitability of such information for his own particular use.

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