iotopy

Tnfrored (TR)Speut
du)
o tadtonn) spe UV Xobuelina.Unh
ibr oHona)
TR Fundbnal qTo

TR Region
2.u IS e

69
TR Spedtum

AbBorrnee T t a ltante

Freqaeny

Pirdplt-
TR Ubrattona) RotedHorad eneqy Charqes

Enegy Chorq deperden -

moJecude.
() MaA othe adomg pre3e in a

( Asa emen oaom oithin 0 molede.

(3) the stverqth abond.

Airger pirt 4 Fundiora qhoup Tegion

Aingen

Tolal ronge Negior) TK 8petrum 4uoo-667 Cn

TR Spet vum
FuncHona qoyp toon

PHnt rtaton
 Funtiona qop ion firq hint rtgon
ange
oo 1oc

. i a e fu for donKfitation . t ig uyef for idertificadon

o funchiona ghoup peufic com peund

gun
Compawnd

Cornounds haoina same fontiorad LornOoundk roulnq samne

q oup houo imilan chsonption ncHonad qoqP Shous
dift exent abiovpion bond
bond in thi TeGion in tha g o n

3trekhing vibraion
Sending uibration

-( 145o-666c)
OH
C H O

to idenHfy ditfeence

we
We
B
4
A
bl
inqen p i t r e i o n

linean- diatomic meJeude and qru df

(3n-Sfundommk
abSorborte
band
diadomic moJtule to IdanH Gnl4
non-in eawn
C3n-<) fundamtn
absor banre SuntHonad qoyp
loane
wse fundhonal qoop
 dinHadT6
TR 8petrum
OJNj(al
sped ,e Xtpt enonjUmUy
mpounds
ho
No too de nat aborb
diatomde
molewles Auch aj Ha O
unce
tince hoe
hoe
Homonudêo Inadia
I - A Inacfi ),
h
ate R-
TR adiahon moment in th
th maet ule
moetue .

oue1all eleehie (Oipale)

No dipalt
po T R acdiue
mome Hd, 0 ,

Piniple o SpedrostoPy he Dond

infro- Ted radiaion produces
The absoYpHon a also called
Called
uibraton hich d alo
strething bond orgle

bond angle bonding

The Strealching
bond CoTepordA

to a chaqe (poiHue negathue) in bond diaBonce

the
betoeen bondu with no clisplate ment vom
indetm oleulah Oxi8

O-O -0
Bond Stse kcing

Typu oberdínq uibiaton

Bord anale
Scitsoving bending

Aocking

aqgi oppodie up
down)

bothup@deon)
 U braora equendue

here MM2

Teduced mous
forte Conen

he ualuu o vibationa Teguency i

Oropostionato the bond trtnqth ohich
d diretly
expreged n K
popogtonal to the veduced ma .
invotlu
facdor influendng Ulbraional frequ eney
)Elecronic ttfeda T h e electronici effect such a induciue
inrducHue and
and

Tesonore e
Tnduciue etted- The Indudi o the qroyp paesent in
the vicirtity o the CaHbony 9roup
deuble bond may be eithey T ettect Celedhon 7deasina)
- I effect Celecdon aithdrauaing)
Tefted and their pxegence tend to reduce the
the vdue
uadue a
a
force Cen&Bond. Thexefore, The oberpHon shifta to leuey
wau number when uth qtoup ane
prtkent.
H
CH o CHco
(17So e) CI71oco CL71 s )
I cthed ond her premte incTeae he vadu
The
o r ce totant-
Thorfo, obsorption 8hi to hhe wauo ndmbei.

CH Co
cH Ch
17S en
Relonont e eftec
The Conjugaton ohethe in the unsabutat ed hdrocaibona

Or In the aHoMatHG Mhg tendA to decreaye he

magnitude t h e Corte con&tond Their
abBorpHon aloa
SNttR to loude wau umbe.
aloa
for ex CH--CHg

CH-C-CH =CH AbsosbHon shiftA {rom 171S>

696

R
C-H

bsorbHon &hih rom (71-> 1693a?

Hydroqen bondirg
Tn the
organic CompoundA Auch ou
phen.l, CaHboxylic acid
ominu wNch Bhoo
forte Consen
hydrocen Dondinq he valu
qentnallh decrea becae
atd pochion ond hi 8hft towand Joud u wau numbei.
 Appllaton Info-ed Spedoktop
Tdentiicadton Su btoncejThe 3R Studie help in frding out
whethe a giuen om pl organic
Substonce idenli cal toth ongtheN not
9 be noted thad 4h technique fails to dizinguith
betten two enontiormeu a Subante ne he TR
for th enandiomey ayn adly 4he some.

2. 0edenminadon moletulat }rucksteThe IR

Sperokiopy
quiquite helpfu in establishing h sucne a
he uno on ovganic tompound by hooi n the fun dHonal
gaoups nd the nadune o CtoCbondi i t h he hdp
the hep
d tdteent bondu peapea

3 Stadying the proqte a a teachon Proqres aChernical

radion Con be reodily olloaed by exominng Spedra
Amall porHon& reacHon xtuune oithdraon ftom
time o ime.

DetecHon a puat a Compound The R pecthoktopy

4
Prouid-ya mean to heck he
pwity a n organic Com pourdby compauna i
3pecdrum with that he pune compeund.
 Momplh
CH3
340 popy dcoh -64
CH
H

3200 3tHo cm
O-H 6rekching
2 So-29 SO c
-H Stretehi nq
C-0 6sett n

( Oimethye th
CH-O-CH3
C-&relching lo6o-IIS6 Cm
C-H Sretching 28S0 29 SOCm

Toluene CH

C-H
SheMNq thy qvoyp »20o-29So cCm
H Stiinq a atonaiC Hnq 3o 31ooo(M
C-C Shdchin a aomoi t ing ISoI6ootn

Ho do he 4 Specra o
Floina
heolosinq padra
(in Acetone ond ahy altoha

> CH-C-CH Ceo Shetehing

e abou 710cm

CH- CH0-H H re lehing o 3200 -

34oo Cm
 Arehe acid ond m thy aloho

CH- -OH 0-H 8hretthing od Jasen fsequeney (3 Ooscs

Co Stsedchi n at abo 72Sm

2) CH-OH -H StTebching eu aboud (33oocm

Ethy methy 4 kotone and mdhyl viny kelone

)CH-CHa--tH3-(o 8hrelehinq (Aubenated I71cm

2CH C-CH =CH Co reBchine unatmoaled) 68otm

CH CH,OH and CHgoCH

) CHCH0H due to ptimany altoked CC-o) losocm
O-H sTetcHng 2e0-26oo Lm

2) HOtH Aly& etheu shoo absorpHon at (lo-e Cm

CH CH -CH and th=CH-CH2- o-CH3

) CHCH-d-CH- Satunaded eone will gie absorpHon band
a 73S - 176S cm C=o)

2) CH=H- CH,oCH CC) Cal Kene pwut) wil gi a bior bhian band
o3o fo-3oloo) and du to alkyl ethei
 Lonefe
and

Loul g absorpHon lband at 172S- 17oS c bei ng

Sakunated cycic kebne Com pound

An unsahuraded d-3 Retone Con

tainJa onugsdion
wil AhoLD absorpHon aat bout
a
695-166SC
CCH CHCH,CooH and tH o tH CH,Cou

CCHCH,CH CooH toil u abterption bond at

o o - 6o6 cm Cdu te &atunahed

Caxbe xylt oid)
CHbtHH,tod du to al th ltoocm d
to aud
chlovide 179 SC

CHCH--cH2 and CH--tH=cH

Bot 8heo C-o steleh

Satuotedl etone CHCH,-t-Ch appea at ahout hlo

wile chy-c tH2 C,B-unatnaed
cH--H= ) xetone wi
obou