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Prarancangan Pabrik Tetrachlorosilane (Sicl) Dari Purified Rice Husk

This document discusses the design of a tetrachlorosilane (SiCl4) plant with a capacity of 18,000 tons per year using purified rice husk ash as raw material. There are two main stages: combusting rice husk ash to produce silica and carbon, and reacting the silica with chlorine gas to produce gaseous tetrachlorosilane. Five utility units are required: water, electricity, fuel, instrument air and nitrogen, and waste treatment. An economic evaluation found the project has a 46.06% return on investment before tax and would be profitable.

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0% found this document useful (0 votes)
55 views2 pages

Prarancangan Pabrik Tetrachlorosilane (Sicl) Dari Purified Rice Husk

This document discusses the design of a tetrachlorosilane (SiCl4) plant with a capacity of 18,000 tons per year using purified rice husk ash as raw material. There are two main stages: combusting rice husk ash to produce silica and carbon, and reacting the silica with chlorine gas to produce gaseous tetrachlorosilane. Five utility units are required: water, electricity, fuel, instrument air and nitrogen, and waste treatment. An economic evaluation found the project has a 46.06% return on investment before tax and would be profitable.

Uploaded by

Tanti Nabella24
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Prarancangan Pabrik Tetrachlorosilane (SiCl4) dari Purified Rice Husk Ash dengan Kapasitas 18.

000
Ton/Tahun
Prarancangan Pabrik Tetrachlorosilane (SiCl4) dari Purified Rice Husk
DWIANA AYU KIRANTI N, Chandra Wahyu Purnomo, S.T., M.E., M.Eng., D.Eng.
Ash dengan Kapasitas 18.000 Ton/Tahun
Universitas Gadjah Mada, 2020 | Diunduh dari http://etd.repository.ugm.ac.id/

ABSTRACT

Indonesia is a country which is rich in natural resources. Rice farming


produces a lot of biomass waste that includes rice husk. One of the largest
components contained in rice husk is silica (SiO2) that is equal to 86,9% - 97,3%
(w/w). Silica can be used in a variety of industries and can also be used as raw
material to produce tetrachlorosilane (SiCl4).
There are two main stages in designing tetrachlorosilane (SiCl4) plant from
rice husk. The first stage is the combustion of rice husk to produce ash that contains
silica (SiO2) and carbon. The second stage is the reaction between silica ash with
chlorine (Cl2) gas to produce gaseous tetrachlorosilane (SiCl4) with carbon
monoxide (CO) as side product. Then, the gaseous tetrachlorosilane (SiCl4) is
condensed to get the aqueous tetrachlorosilane (SiCl4) with 99% (w/w) purity.
There are five utility units used in tetrachlorosilane (SiCl4) plant design.
The first unit is water supply and processing unit which produces 10.653 kg/hour
water for general uses and 6.050 kg/hour cooling water. The second unit is
electricity supply unit which produces 211 kW electricity. The third unit is fuel
supply unit which supplies 48 lb/hour natural gas and 107 kg/hour diesel. The fourth
unit is instrument air and nitrogen (N2) unit. The fifth unit is a waste treatment unit
which processes solid, liquid, and gas waste.
The location for tetrachlorosilane plant is in Cilegon and requires 150
employees. Required fixed capital for tetrachlorosilane (SiCl4) plant establishment is
$10.818.642,41 + Rp366.559.053.918,79 and the working capital is $6.224.513,91 +
Rp12.708.891.714,21. From the calculations, the return of investment (ROI) before
tax is 46,069%, return of investment (ROI) after tax is 29,94%, pay out time (POT)
before tax is 1,78 years, pay out time (POT) after tax is 2,50 years, break even point
(BEP) is 42,10%, shut down point (SDP) is 19,16%, and discounted cash flow rate of
return (DCFRR) is 43,96%. Based on the economic evaluation, the establishment of
tetrachlorosilane (SiCl4) plant from rice husk ash with a capacity of 18.000 tons/year
is interesting to be assessed further.

Catherine (16/395178/TK/44470)
Dwiana Ayu Kiranti N. (16/395182/TK/44474) xi
Prarancangan Pabrik Tetrachlorosilane (SiCl4) dari Purified Rice Husk Ash dengan Kapasitas 18.000
Ton/Tahun
Prarancangan Pabrik Tetrachlorosilane (SiCl4) dari Purified Rice Husk
DWIANA AYU KIRANTI N, Chandra Wahyu Purnomo, S.T., M.E., M.Eng., D.Eng.
Ash dengan Kapasitas 18.000 Ton/Tahun
Universitas Gadjah Mada, 2020 | Diunduh dari http://etd.repository.ugm.ac.id/

INTISARI

Indonesia merupakan negara yang kaya akan sumber daya alam. Produksi
padi menghasilkan biomassa, seperti sekam padi. Salah satu komponen terbesar yang
terkandung dalam sekam padi adalah silika (SiO2), yaitu sebesar 86,9% - 97,3%
berat. Silika dapat digunakan untuk berbagai industri dan dapat dipakai sebagai
bahan baku produksi tetrachlorosilane.
Ada dua tahap utama dalam prarancangan tetrachlorosilane (SiCl4) dari
sekam padi. Tahap pertama adalah pembakaran sekam padi untuk menghasilkan abu
yang mengandung SiO2 dan karbon. Tahap kedua adalah mereaksikan abu dengan
gas klorin (Cl2) untuk menghasilkan tetrachlorosilane (SiCl4) dalam wujud gas
dengan hasil samping berupa karbon monoksida (CO). Gas tetrachlorosilane (SiCl4)
kemudian dikondensasi untuk mendapatkan tetrachlorosilane (SiCl4) cair dengan
kemurnian 99% berat.
Ada lima unit utilitas yang digunakan dalam perancangan pabrik
tetrachlorosilane (SiCl4). Unit pertama adalah unit penyediaan dan pengolahan air,
berupa air untuk keperluan umum sebesar 10.653 kg/jam dan air untuk pendingin
sebesar 6.050 kg/jam. Unit kedua adalah unit penyedia tenaga listrik sebesar 211 kW.
Unit ketiga adalah unit penyedia bahan bakar berupa gas alam sebesar 48 lb/jam dan
solar sebesar 107 kg/jam. Unit keempat adalah unit penyedia udara instrumentasi dan
nitrogen (N2). Unit kelima adalah unit pengolahan limbah padat, cair, dan gas.
Pabrik tetrachlorosilane berlokasi di Cilegon dan membutuhkan karyawan
sebanyak 150 orang. Modal tetap yang dibutuhkan untuk pendirian pabrik
tetrachlorosilane (SiCl4) adalah sebesar $10.818.642,41 + Rp366.559.053.918,79
dan modal kerja sebesar $6.224.513,91 + Rp12.708.891.714,21. Dari hasil
perhitungan, diperoleh return of investment (ROI) sebelum pajak sebesar 46,06% dan
sesudah pajak sebesar 29,84%, pay out time (POT) sebelum pajak sebesar 1,78 tahun
dan sesudah pajak sebesar 2,50 tahun, break even point (BEP) sebesar 42,10%, shut
down point (SDP) sebesar 19,16%, dan discounted cash flow rate of return (DCFRR)
sebesar 43,96%. Berdasarkan hasil perhitungan evaluasi ekonomi tersebut, pabrik
tetrachlorosilane (SiCl4) dari purified rice husk ash dengan kapasitas 18.000
ton/tahun menarik untuk dikaji lebih lanjut.

Catherine (16/395178/TK/44470)
Dwiana Ayu Kiranti N. (16/395182/TK/44474) xii

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