EDMT- 013

JEE -Advance- 2022

MOCK TEST
ANSWER KEY (04.08.2022)
Paper-I
Code: 108467
PHYSICS CHEMISTRY MATHEMATICS
1 AC 1 ABC 1 ABCD
2 BD 2 ABD 2 ABCD
3 ACD 3 ABD 3 ABC
4 ACD 4 BCD 4 AC
5 AC 5 BC 5 C
6 ABCD 6 BCD 6 ABCD
7 BC 7 BC 7 BCD
8 ABC 8 B 8 ACD
9 ACD 9 D 9 AC
10 AD 10 BC 10 AC
1 A – p, r 1 A –r 1 A – p, q
B – q, s B–s B–s
C – p, r C–q C – p, q, r
D – q, s D–p D–q
2 A–p 2 A–q 2 A–q
B – r, s B–p B–r
C–p C–p, q,r,s C–p
D–r D – p, q, r D–s
1 1 1 8 1 0
2 5 2 9 2 7
3 4 3 5 3 1
4 5 4 5 4 7
5 4 5 8 5 5
6 4 6 3 6 2
7 1 7 4 7 5
8 1 8 5 8 3

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 Physics
PART-A
1. At equilibrium position Fb  mg

R
2. C  Cv 
1 x

3. A, C, D Fr Ft
Decrease in gravitational PE = Increase in rotational KE
A
 1 1  m2  2
mg cos30   A 2    30°
2 2 2 3 
1/2
ar
 3 3g 
Or    
 2  at
  m  3 3g mg3 3 mg
Centripetal force of COM  m 2    
2  2  2 4 B’
3 3 mg 5 3
Fr – mg cos 30°  mg  Fr 
4 4
mg
mgsin30  Ft  ma t  Ft 
8
F is the force exerted by rod on hinge  Fr2  Ft2

1 T
4. f
2L 

 kq
5. E  2 rˆ
r

6. Electric field inside conductor is zero

V2
7. P
R
  
8. 
F  q v B 
2
9. sin C 
1

PART-C
1 2  1
1.  R  Z  1 1  2 
k  2 

2. Pav  Vrms rms cos 

T
3. P
R th

4. Apply Bernoull’s theorem

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5. 4
P  0.003 0.005 0.06 
 = M/(r2)   100%       100%
P  0.3 0.5 6 

7. F  ma
5  mg  ma

u2 sin2 usin  2eusin 

8.  eucos    eucos  
2g g g

Chemistry

Part  A

1. (A)
+ - - +
O N N O N N O N N O N N

O O
N N Bond order 1 2 3 3
(B) Due to nonbonding electron pair repulsion F  F bonds is weaker than ClCl bond
(C) In between F2O and H2O bond pair’s lie more nearer to F than H as F is more
electronegative than H. So bond pairbond pair repulsion in more in H2O than F2O
So, HOH > FOF
Cl2O has highest bond angle due to large size of Cl which develops more repulsion

(D) PCl5 is sp3d hybridized. Equatorial bonds are formed by sp2 orbitals in xy plane and axial
bonds are formed by p z dz2 orbitals in zdirection

2. ‘A’ is total no of collisions per unit time. ‘P’ is probability factor which indicates the fractions
of total collisions per unit time having perfect orientation
Ea/RT is the fraction of P.A having energy  Ea
At T OK, all collisions will be converted to products

3. In salt bridge, cations and anions have nearly same speed to minimize liquids junction
potential

4. If Ssystem = Ssurrounding, the process in reversible.

Here Ssystem=8 J/K
3.6 100
Ssurr   J / K  6 J / K
600

5. Diamond has zinc Blende structure. In Schottky defect density decreases

6. C (sp3 hybridized) of conjugated keto form must contain hydrogen to show tautomerism

O    carbon

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 CH3 CH3 CH3 CH3 CH3 CHO
7. Br I CH3
NaI  I2 O3 ,(CH3 )2 S
CHO 
OH CHO 

  
     
acetone
CHO H
Br I
OH
O
CH3 CH3 O

 H
 
CHO

CHO

8. Neural structure is more stable than charged structure. More electronegative atom should
possess ve charge not +ve charge
More the no of covalent bonds in charged structure more is its stability

9. More the no of Natoms more is the basic strength. So III is most basic. IV shows steric
inhibition of resonance

10. (A) No. of angular nodes = l

No. of radial model = nl1
(B) Fe3+ 1s22s2sp63s23p23d5
No. of e,s having ml = 0 in 1s2 = 2
2s2=2
2p6=2
3s2=2
3p6=2
3d5=1
Total = 11

h
(C) &(D) orbital angular momentum = l(l  1)
2
Part  B

1. OH

Zn
  (B) SOCl2
R  OH   R  Cl
(A) 

H2O2
(C) CH2=CHCH3   Br  CH2  CH2  CH3
HBr

Br
|
HBr
(D) CH2=CHCH3   CH3  CH CH3

h
2. (A) Orbital angular momentum = l(l  1)
2
nh
(B) Orbit angular momentum =
2
(C) Electron wave function  = Rn,l (r) l,ml ( ) ml ( )
(D) n represents energy and size of orbital
l represents shape of orbital and energy of orbital in multi electron system
ml represents the orientation of orbital

Part  C

1. CaC2O4 + KMnO4 + H2SO4  CaSO4 + K2SO4 + CO2

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 n= 2 n=5 + MnSO4 + H2O
meq of CaC2O4 = meq of KMnO4
 100N (CaC2O4) = 4103 5
 NCaC2O 4  2  10 4
2
MCaC2O 4   10 4  10 4 (M)
2
K 
sp CaC O
2 4
 S2  10 4  10 4  10 8

2. In insulated container, q = 0
q = U  w  U = w = 100 (99100) = 100 bar ml
H = U + P2V2P1V1 = 100 + 100099  1100 = 9900 bar ml

3. OH COOH ONa COONa

H3C H3C
NaNH2
HO Br   NaO
7 mole

O 2N Br O 2N CH
OHSO 3H NaO SO 3Na
1 mole

2 mole NaHCO 3

OH COONa
H3C

HO Br

O 2N Br
OHSO 3Na

 OH   O OH  O
 |   || |  ||
4. Hemiacetal   C  OR  , Benzoin  Ph  C  CH Ph  , HCOOH, OHCH2  C  can repond
 |   
 H   
   
to Tollen’s reagent test

5. D C D C
A C A D A C A D
Co Co Co Co
B E B E B F B F
F F E E
Interchanging A & B to get another 4 isomers

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6. H2C CH3

KMnO4 ( 1 mole)
CH3

O
||
H2O  CO2  CH3  C  CH2  COOH  HOOC  CH2  COOH  CH3COOH
 

O
|| CO2  CH3COOH
CO2  CH3  C  CH3

7. It is fcc lattice

8. Cl

CH2 CH3 CH3 CH3 CH3

Cl H Cl Cl Cl H Cl H Cl H

H Cl H Cl Cl Cl H Cl H Cl
CH2 CH2 CH2 HC Cl CH2

CH3 CH3 CH3 CH3 H2 C Cl

MATHEMATICS
1. A,B,C,D
(AB)n((AB)n)T = (AB)(AB) …..(AB) (AB)T(AB)T ….(AB)T
= (AB) (AB) ….(AB) (BTAT) (BTAT) …(BT AT)
=I nN
|AB| = 1 [ |A| =  1, |B| =  1]
||AB| B| = | B| =  1
||AB|A| = | A| =  1

2. A,B,C,D
Find h(x) in terms of f(x–1) & differentiate to get critical point & also take help by plotting the
graph of f(x)

3. A,B,C
Use the argument & find locus which would give you centre & radius

2/3

–1 1

/3

4. AC

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 x(x 4  1)(x  1)  x10  2x
f(x) 
x 2  2x  3
Dr > 0  x. Just analyse the behaviour of Nr is f(x) and f(x) come from – & goes to +
 Finite min exist at same critical point
 f(x) is may one & into

5. A,C,D
n
C1 n1 C2  n 2 C3  ....  nm1 Cm
= n Cn 1  n1Cn1  n 2 Cn1  ...  n m 1Cn1
= Coefficient of xn1 in (1+x)n+(1+x)n+1+(1+x)n+2+….+(1+x)n+m1
 (1  x)m  1
=Coefficient of xn1 in (1  x)n  
 (1  x)  1 
(1  x)m n  (1  x)n
= Coefficient of xn1 in
x
= Coefficient of x in (1  x)  (1  x)n  mn Cn  1
n mn

Similarly, we can prove m C1 m 1 C2  m 2 C3  .... m n1 Cn

6. ABCD
   
 
f1(x)  sin1 cos(sin2 x)  sin1 sin   sin2 x     sin2 x
 2  2
Similarly f2(x), f3(x) & f4(x) could be written.

7. BCD
Given conic is an ellipse, h2 –abc < 0
Manor axis will be largest chord and mirror axis will be chord of minimum length, centre of
ellipse is (0, 0), now we can take (r cos , r sin )
On ellipse 3r 2 cos2   2r 2 sin  cos   3r 2 sin2   1
1
3r 2  r 2 sin 2  1  r 2 
3  sin2 
2 1 2 1 
rmax  rmin  
2 4 4


4
1 1
a b
2 2
1
2 4 1 1
2a  2 2b = 1 e  1   e 
1 2 2
2
y – 0 = –1 (x – 0) Equation of mirror axis is x = y
y = –x
Equation of major axis is x + y = 0

8. ACD
We can write the equation of parabola in normal form

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 2
xy  x y4
   2 
 2   2 
Now compare it with y2 = 4ax
4a  2 (Length of latus rectum)
1
a
2 2
Put (0, 0) and (–1, 1) in the equation of parabola we get same sign
a
4a2 1
Now to calculate area 2 a xdx   
0
3 6

9. AC
Case I
f(i) = i f(1) = 1, f(2) = 2, f(3) = 3, f(4) = 4, f(5) = 5 only one function is possible.
Case II Example
5
C2 f(1) = 1, f(4) = 4, f(5) = 5, f(2) = 3, f(3) = 2
Case III
5
C1  3 f(1) = 1, f(2) = 3, f(3) = 2, f(4) = 5, f(5) = 4
OR
f(1) = 1 f(2) = 4, f(4) = 2
f(3) = 5, f(5) = 3
OR
f(2) = 5, f(5) = 2
f(3) = 4, f(4) = 3
total 15 + 10 + 1 = 26

10. AC
1 x2  1  x
 x2  1  x

x2  1  x
dx

x2  1  x
 1
dx   x  
x 2  1 dx

Matrix Match
1. A – p, q ;B – s;C – p, q, r;D – q
(A) 5 6  67  ....(30)31 , A zero required the factors of 5 and 2
So just find total 5 in this product
(5)6  (10)11  (15)16  (20)21  (25)26  (30)31
56 + 11 + 16 + 21 + 52 + 31
2P = 274
(B) Let y = n, 1  x  n – 1 0  z  n (total n + 1)
2n9 total n – 1
9
So total numbers  (n  1)(n  1)  276
n 2
(C) Girls can sit in 4 × 4! Ways = 96
(D) _ _ 7 = 72, _ 7 _ = 72 7 _ _ = 81
R = 72 + 72 + 81 = 225

2. A – q ;B – r; C – p; D – s

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 2
(A) Probability of success = P(>4) = =p
6
2
 Prob. Of failure = 1  p 
3
Required prob. = P(FS) + P(FFFS) + P(FFFFFS)
3 5
2 1  2 1 7 1
           ....
3 3 3 3 3 3
2
9 2 9 2
   
4 9 5 5
1
9
(B) P(i)  i2 ,i  1,2,3,...,6
  32 9
Required prob. = 2 2 2

  1  3    5 35
(C) Number of ways getting sum 15
= coefficient of x15 in (x + x2 + x3 + ….+x6)4
= coefficient of x11 in (1 + x +… + x5)4
= coefficient of x11 in (1 – x6)4 (1–x)–4
= coefficient of x11 in (1 –4x6)
(1  4 C1x  5 C2 x 2  ....)
14
 C11  4  8 C5  28  5
28  5 35
Req. prob.  
64 324
A
  P(A  B) 1
(D) P    
B P(B) 6
n(A  B)  1
n(B)  6

INTEGER
  3 
1. 1  sin 2x  cos2 x  cos x   x 2 in  , 
2 2 
Draw graph of L.H.S. & R.H.S

2. 7
Let chord of conic passes through the origin y = mx
Chord y = mx and conic solving then quadratic in x is (1 + m + m2)x2 – 1 = 0
x1  x 2  0
Similarly y1  y 2  0
Mid point be (p, q) = (0,0)
p+q+7=7

3. 1

2 sin
7 cos 2  cos 4  cos    1
 7 7 7 
2 sin 
7
1 3
 1
2 2
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  | k |  1
1 2n2  2n  1  2n2  2n  1
4. 
an 4
20
1 1
a
i1 i

4
841  1  7


5. 5

6. f(x)2  1 x  [0, 4]
At x = 1, 2, 3 if f(x) is cont. when L = R = V  3 ×3 –3 = 6 cases
At x = 0, 4 V = R at x = 0, V = L at x = 4
4 cases  total 10 cases = 2 ×5  2 prime number.

7. f(x) = 3x2 – 7x +c, x > 7/6

3x2 – 7x + c = x
64
D=0 c  [c]  5
12

8. A  cos2 .(cos2   1)  2 sin2 

2
 1 7
  sin2    
 2 4
7 
 A   ,2 
4 
7 15
 2 [A] = 3
4 4

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