Page: 1

SAFETY DATA SHEET Revision Date: 22.10.2019

Print Date: 10.12.2019
SDS Number: R0402443
Derakane™ 411-45 epoxy vinyl ester resin Version: 1.3
™ Trademark, INEOS or its subsidiaries, registered
in various countries
123349

Conforms to EU Regulation 1907/2006/EC as amended. - SDSGHS_RW

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Trade name : Derakane™ 411-45
epoxy vinyl ester resin
™ Trademark, INEOS or its subsidiaries, registered in
various countries

1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended use : Reserved for industrial and professional use.

Restrictions on use :
Consumer use

1.3 Details of the supplier of the safety data 1.4 Emergency telephone number
sheet 00-888-284-6367-3/001-571-444-1840, or contact
INEOS Composites Hispania S.L. your local emergency telephone number at 111 -
Carretera Reial 137-139 ENG, SCO, CYM and 0808 808 8000 - NIE (Mo -
08960 Sant Just Desvern - Barcelona Fr, 08.00 - 18.00)
Spain
+34 93 206 51 20 (in Spain)
Regulatory Information Number
+34 93 206 51 2 (in Spain), or contact your local
CSR contact person
[email protected]
Product Information
+34 93 206 51 20 (in Spain)

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

Flammable liquids, Category 3 H226: Flammable liquid and vapour.

Skin irritation, Category 2 H315: Causes skin irritation.

Eye irritation, Category 2 H319: Causes serious eye irritation.

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SAFETY DATA SHEET Revision Date: 22.10.2019

Print Date: 10.12.2019
SDS Number: R0402443
Derakane™ 411-45 epoxy vinyl ester resin Version: 1.3
™ Trademark, INEOS or its subsidiaries, registered
in various countries
123349

Reproductive toxicity, Category 2 H361d: Suspected of damaging the unborn child.

Specific target organ toxicity - single H335: May cause respiratory irritation.
exposure, Category 3, Respiratory
system

Specific target organ toxicity - repeated H372: Causes damage to organs through
exposure, Category 1, Auditory organs prolonged or repeated exposure if inhaled.

Long-term (chronic) aquatic hazard, H412: Harmful to aquatic life with long lasting
Category 3 effects.

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)

Hazard pictograms :

Signal word : Danger

Hazard statements : H226 Flammable liquid and vapour.

H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H361d Suspected of damaging the unborn child.
H372 Causes damage to organs (Auditory
organs) through prolonged or repeated
exposure if inhaled.
H412 Harmful to aquatic life with long lasting
effects.

Precautionary statements : Prevention:

P201 Obtain special instructions before use.
P210 Keep away from heat, hot surfaces, sparks,
open flames and other ignition sources. No
smoking.
P260 Do not breathe dust/ fume/ gas/ mist/
vapours/ spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/
eye protection/ face protection.
Response:
P370 + P378 In case of fire: Use dry sand, dry chemical
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SAFETY DATA SHEET Revision Date: 22.10.2019

Print Date: 10.12.2019
SDS Number: R0402443
Derakane™ 411-45 epoxy vinyl ester resin Version: 1.3
™ Trademark, INEOS or its subsidiaries, registered
in various countries
123349

or alcohol-resistant foam to extinguish.

Hazardous components which must be listed on the label:

Styrene
2.3 Other hazards
Additional advice
No information available.

SECTION 3: Composition/information on ingredients

3.2 Mixtures

Hazardous components
Chemical name CAS-No. Classification Concentration
EC-No. (REGULATION (EC) (%)
Registration number No 1272/2008)
Styrene 100-42-5 Flam. Liq.3; H226 >= 40,00 - <
202-851-5 Acute Tox.4; H332 50,00
01-2119457861-32-xxxx Skin Irrit.2; H315
Eye Irrit.2; H319
Repr.2; H361d
STOT SE3; H335
STOT RE1; H372
Asp. Tox.1; H304
Aquatic Chronic3;
H412
methacrylic acid 79-41-4 Acute Tox.4; H302 >= 0,50 - <
201-204-4 Acute Tox.4; H332 1,00
Acute Tox.3; H311
Skin Corr.1A; H314
Eye Dam.1; H318
STOT SE3; H335
For explanation of abbreviations see section 16.

SECTION 4: First aid measures

4.1 Description of first aid measures

General advice : Move out of dangerous area.

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SAFETY DATA SHEET Revision Date: 22.10.2019

Print Date: 10.12.2019
SDS Number: R0402443
Derakane™ 411-45 epoxy vinyl ester resin Version: 1.3
™ Trademark, INEOS or its subsidiaries, registered
in various countries
123349

Call a POISON CENTRE or doctor/physician if exposed or

you feel unwell.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.

If inhaled : Move to fresh air.

IF INHALED: Call a POISON CENTER/ doctor if you feel
unwell.
Keep patient warm and at rest.
If unconscious, place in recovery position and seek medical
advice.

In case of skin contact : Remove contaminated clothing. If irritation develops, get

medical attention.
If on skin, rinse well with water.
Wash contaminated clothing before re-use.
If on clothes, remove clothes.

In case of eye contact : Immediately flush eye(s) with plenty of water.

Remove contact lenses.
Protect unharmed eye.

If swallowed : Obtain medical attention.

Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.

4.2 Most important symptoms and effects, both acute and delayed
Symptoms : Signs and symptoms of exposure to this material through
breathing, swallowing, and/or passage of the material through
the skin may include:
stomach or intestinal upset (nausea, vomiting, diarrhea)
irritation (nose, throat, airways)
confusion

Risks : Causes skin irritation.

Causes serious eye irritation.
May cause respiratory irritation.
Suspected of damaging the unborn child.
Causes damage to organs through prolonged or repeated
exposure if inhaled.

4.3 Indication of any immediate medical attention and special treatment needed
Treatment : No hazards which require special first aid measures.
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SAFETY DATA SHEET Revision Date: 22.10.2019

Print Date: 10.12.2019
SDS Number: R0402443
Derakane™ 411-45 epoxy vinyl ester resin Version: 1.3
™ Trademark, INEOS or its subsidiaries, registered
in various countries
123349

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Water spray
Foam
Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical

Unsuitable extinguishing : High volume water jet

media

5.2 Special hazards arising from the substance or mixture

Specific hazards during : Organic dusts at sufficient concentration can form explosive
firefighting mixtures in air.
Never use welding or cutting torch on or near drum (even
empty) because product (even just residue) can ignite
explosively.
Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.
Do not allow run-off from fire fighting to enter drains or water
courses.

Hazardous combustion : carbon dioxide and carbon monoxide

products toxic fumes
Hydrocarbons

5.3 Advice for firefighters

Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for firefighters

Specific extinguishing : Product is compatible with standard fire-fighting agents.

methods

Further information : Do not use a solid water stream as it may scatter and spread
fire.
Fire residues and contaminated fire extinguishing water must

5 / 25
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SAFETY DATA SHEET Revision Date: 22.10.2019

Print Date: 10.12.2019
SDS Number: R0402443
Derakane™ 411-45 epoxy vinyl ester resin Version: 1.3
™ Trademark, INEOS or its subsidiaries, registered
in various countries
123349

be disposed of in accordance with local regulations.

Use a water spray to cool fully closed containers.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Evacuate personnel to safe areas.
Remove all sources of ignition.
Use personal protective equipment.
Ensure adequate ventilation.
Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.
Persons not wearing protective equipment should be excluded
from area of spill until clean-up has been completed.
Comply with all applicable federal, state, and local regulations.
Suppress (knock down) gases/vapours/mists with a water
spray jet.

6.2 Environmental precautions

Environmental precautions : Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up : Contain spillage, and then collect with non-combustible
absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and place in container for disposal according to
local / national regulations (see section 13).

6.4 Reference to other sections

For further information see Section 8 and Section 13 of the safety data sheet.

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Advice on safe handling : Open drum carefully as content may be under pressure.
Avoid formation of aerosol.
6 / 25
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SAFETY DATA SHEET Revision Date: 22.10.2019

Print Date: 10.12.2019
SDS Number: R0402443
Derakane™ 411-45 epoxy vinyl ester resin Version: 1.3
™ Trademark, INEOS or its subsidiaries, registered
in various countries
123349

Provide sufficient air exchange and/or exhaust in work rooms.

Do not breathe vapours/dust.
Do not smoke.
Container hazardous when empty.
Take precautionary measures against static discharges.
Avoid exposure - obtain special instructions before use.
Avoid contact with skin and eyes.
Smoking, eating and drinking should be prohibited in the
application area.
For personal protection see section 8.
Dispose of rinse water in accordance with local and national
regulations.
Secondary operations, such as grinding and sanding, may
produce dust.
Maintain good housekeeping. Do not permit dust layers to
accumulate, for example, on floors, ledges, and equipment, in
order to avoid any potential for dust explosion hazards.

Advice on protection against : Take necessary action to avoid static electricity discharge
fire and explosion (which might cause ignition of organic vapours). No sparking
tools should be used. Keep away from open flames, hot
surfaces and sources of ignition. Use only explosion-proof
equipment.

Hygiene measures : Wash hands before breaks and at the end of workday. When
using do not eat or drink. When using do not smoke.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage : Keep container tightly closed in a dry and well-ventilated
areas and containers place. Containers which are opened must be carefully
resealed and kept upright to prevent leakage. Observe label
precautions. No smoking.

Other data : No decomposition if stored and applied as directed.

7.3 Specific end use(s)

Specific use(s) : No data available

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SAFETY DATA SHEET Revision Date: 22.10.2019

Print Date: 10.12.2019
SDS Number: R0402443
Derakane™ 411-45 epoxy vinyl ester resin Version: 1.3
™ Trademark, INEOS or its subsidiaries, registered
in various countries
123349

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure Limits

Components CAS-No. Value type (Form Control parameters Basis
of exposure)
Styrene 100-42-5 TWA 100 ppm GB EH40
430 mg/m3
STEL 250 ppm GB EH40
1.080 mg/m3
methacrylic acid 79-41-4 TWA 20 ppm GB EH40
72 mg/m3
STEL 40 ppm GB EH40
143 mg/m3
Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006:
Styrene : End Use: Workers
Exposure routes: Inhalation
Potential health effects: Short-term exposure, Systemic effects
Value: 289 mg/m3
End Use: Workers
Exposure routes: Inhalation
Potential health effects: Short-term exposure, Local effects
Value: 306 mg/m3
End Use: Workers
Exposure routes: Inhalation
Potential health effects: Long-term exposure, Systemic effects
Value: 85 mg/m3
End Use: Workers
Exposure routes: Skin contact
Potential health effects: Long-term exposure, Systemic effects
Value: 406 mg/kg
End Use: Consumers
Exposure routes: Inhalation
Potential health effects: Short-term exposure, Systemic effects
Value: 174,25 mg/m3
End Use: Consumers
Exposure routes: Inhalation
Potential health effects: Short-term exposure, Local effects
Value: 182,75 mg/m3
End Use: Consumers
Exposure routes: Skin contact
8 / 25
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SAFETY DATA SHEET Revision Date: 22.10.2019

Print Date: 10.12.2019
SDS Number: R0402443
Derakane™ 411-45 epoxy vinyl ester resin Version: 1.3
™ Trademark, INEOS or its subsidiaries, registered
in various countries
123349

Potential health effects: Long-term exposure, Systemic effects

Value: 343 mg/kg
End Use: Consumers
Exposure routes: Ingestion
Potential health effects: Long-term exposure, Systemic effects
Value: 2,1 mg/kg
End Use: Consumers
Exposure routes: Inhalation
Potential health effects: Long-term exposure, Systemic effects
Value: 10,2 mg/m3

Predicted No Effect Concentration (PNEC) according to Regulation (EC) No. 1907/2006:

Styrene : Fresh water
Value: 0,028 mg/l
Fresh water
Value: 0,04 mg/lIntermittent use/release

Marine water
Value: 0,014 mg/l
Sewage treatment plant
Value: 5 mg/l
Fresh water sediment
Value: 0,614 mg/kg
Marine sediment
Value: 0,307 mg/kg
Soil
Value: 0,2 mg/kg
8.2 Exposure controls

Engineering measures
Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below
exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse
effects.
Provide appropriate exhaust ventilation at places where dust is formed.
Personal protective equipment
Eye protection : Wear chemical splash goggles when there is the potential for
exposure of the eyes to liquid, vapor or mist.

Use eye protection according to EN 166.

Hand protection
Material : Laminate (Barrier© or Silvershield©)
Break through time : 480 min

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SAFETY DATA SHEET Revision Date: 22.10.2019

Print Date: 10.12.2019
SDS Number: R0402443
Derakane™ 411-45 epoxy vinyl ester resin Version: 1.3
™ Trademark, INEOS or its subsidiaries, registered
in various countries
123349

Glove thickness : > 0,5 mm

Remarks : The exact break through time can be obtained from the
protective glove producer and this has to be observed. Gloves
should be discarded and replaced if there is any indication of
degradation or chemical breakthrough.

The selected protective gloves have to satisfy the

specifications of Regulation (EU) 2016/425 and the standard
EN 374 derived from it.

Skin and body protection : Wear as appropriate:

Impervious clothing
Safety shoes
Flame-resistant clothing
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.
Discard gloves that show tears, pinholes, or signs of wear.

Protective clothing complying with EN 13688.

Safety shoes complying with EN ISO 20345.

Respiratory protection : In the case of vapour formation use a respirator with an

approved filter.

Filter type : Organic vapour type (A)

Respiratory protection complying with EN 136.

Respiratory protection complying with EN 140.
Respiratory protection complying with EN 14387.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance : liquid

Odour : pungent

Odour Threshold : No data available

pH :
No data available

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SAFETY DATA SHEET Revision Date: 22.10.2019

Print Date: 10.12.2019
SDS Number: R0402443
Derakane™ 411-45 epoxy vinyl ester resin Version: 1.3
™ Trademark, INEOS or its subsidiaries, registered
in various countries
123349

Melting point/freezing point : No data available

Boiling point/boiling range : 145 °C

Flash point : 26,1 °C

Method: Pensky-Martens closed cup

Evaporation rate : No data available

Upper explosion limit : 6,1 %(V)

Lower explosion limit : 1,1 %(V)

Vapour pressure : 8,53248 hPa (25 °C)

Calculated Vapor Pressure

Relative vapour density : >1

(Air = 1.0)

Relative density : No data available

Density : 1,078 g/cm3 (25 °C)

Solubility(ies)
Water solubility : insoluble

Solubility in other solvents : No data available

Partition coefficient: n- : No data available

octanol/water

Decomposition temperature : No data available

Viscosity
Viscosity, dynamic : No data available

Viscosity, kinematic : > 20,5 mm2/s (40 °C)

Oxidizing properties : No data available

9.2 Other information

No data available

11 / 25
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SAFETY DATA SHEET Revision Date: 22.10.2019

Print Date: 10.12.2019
SDS Number: R0402443
Derakane™ 411-45 epoxy vinyl ester resin Version: 1.3
™ Trademark, INEOS or its subsidiaries, registered
in various countries
123349

SECTION 10: Stability and reactivity

10.1 Reactivity
No decomposition if stored and applied as directed.
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
Hazardous reactions : Hazardous polymerisation may occur.
Vapours may form explosive mixture with air.
This product does not present a dust explosion hazard as
delivered. However, fine dust dispersed in air in sufficient
concentrations, and in the presence of an ignition source, is a
potential dust explosion hazard.

10.4 Conditions to avoid

Conditions to avoid : Exposure to air.
Exposure to sunlight.

Heat, flames and sparks.

10.5 Incompatible materials

Materials to avoid : Acids
aluminum
aluminum chloride
Bases
Copper
Copper alloys
halogens
iron chloride
metal salts
strong bases
Strong oxidizing agents
Peroxides

10.6 Hazardous decomposition products

Hazardous decomposition : carbon dioxide and carbon monoxide
products Hydrocarbons

12 / 25
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SAFETY DATA SHEET Revision Date: 22.10.2019

Print Date: 10.12.2019
SDS Number: R0402443
Derakane™ 411-45 epoxy vinyl ester resin Version: 1.3
™ Trademark, INEOS or its subsidiaries, registered
in various countries
123349

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Information on likely routes of : Inhalation
exposure Skin contact
Eye Contact
Ingestion

Acute toxicity
Not classified based on available information.
Components:
Styrene
Acute oral toxicity : LD50 Oral (Rat): > 2.000 mg/kg

Acute inhalation toxicity : LC50 (Rat): 11,8 mg/l, 2770 ppm

Exposure time: 4 h
Test atmosphere: vapour

No observed adverse effect level (Humans): 100 ppm

Exposure time: 7 h
Test atmosphere: vapour

Acute dermal toxicity : LD50 (Rat): > 2.000 mg/kg

Method: OECD Test Guideline 402
Assessment: No adverse effect has been observed in acute
dermal toxicity tests.

Components:
methacrylic acid
Acute oral toxicity : LD50 (Mouse): 1.250 mg/kg

LD50 (Rat, male): 1.320 mg/kg

Method: OECD Test Guideline 401

Acute inhalation toxicity : LC50 (Rat): 7,1 mg/l

Exposure time: 4 h
Test atmosphere: vapour
Method: OECD Test Guideline 403
Assessment: The component/mixture is classified as acute
inhalation toxicity, category 4.

Acute dermal toxicity : LD50 (Rabbit): 500 - 1.000 mg/kg

Skin corrosion/irritation

13 / 25
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SAFETY DATA SHEET Revision Date: 22.10.2019

Print Date: 10.12.2019
SDS Number: R0402443
Derakane™ 411-45 epoxy vinyl ester resin Version: 1.3
™ Trademark, INEOS or its subsidiaries, registered
in various countries
123349

Causes skin irritation.

Product:
Remarks: May cause skin irritation and/or dermatitis.

Result: Repeated exposure may cause skin dryness or cracking.

Components:
Styrene
Species: Rabbit
Result: Irritating to skin.

Species: human skin

Result: No skin irritation

methacrylic acid
Method: OECD Test Guideline 404
Result: Corrosive after 3 minutes or less of exposure

Serious eye damage/eye irritation

Causes serious eye irritation.
Product:
Remarks: Vapours may cause irritation to the eyes, respiratory system and the skin., Causes
serious eye irritation.

Components:
Styrene
Result: Irritating to eyes.
Remarks: Vapour during processing may be irritating to the respiratory tract and to the eyes.

methacrylic acid
Result: Corrosive

Respiratory or skin sensitisation

Skin sensitisation: Not classified based on available information.
Respiratory sensitisation: Not classified based on available information.
Components:
Styrene
Exposure routes: Skin contact
Species: Guinea pig
Assessment: Does not cause skin sensitisation.

Exposure routes: inhalation (vapour)

Species: Humans
Assessment: Does not cause respiratory sensitisation.

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SAFETY DATA SHEET Revision Date: 22.10.2019

Print Date: 10.12.2019
SDS Number: R0402443
Derakane™ 411-45 epoxy vinyl ester resin Version: 1.3
™ Trademark, INEOS or its subsidiaries, registered
in various countries
123349

methacrylic acid
Test Type: Buehler Test
Species: Guinea pig
Assessment: Did not cause sensitisation on laboratory animals.
Method: OECD Test Guideline 406

Germ cell mutagenicity

Not classified based on available information.
Components:
methacrylic acid
Genotoxicity in vitro : Test Type: Ames test
Method: OECD Test Guideline 471
Result: negative

: Test Type: Chromosome aberration test in vitro

Method: OECD Test Guideline 487
Result: negative

Genotoxicity in vivo : Test Type: Mammalian bone marrow sister chromatid

exchange
Test species: Rat (male)
Cell type: Bone marrow
Method: OECD Test Guideline 475
Result: negative

Test Type: chromosome aberration assay

Test species: Mouse (male)
Method: OECD Test Guideline 478
Result: negative

Test Type: chromosome aberration assay

Test species: Mouse (male)
Cell type: peripheral blood cells
Method: OECD Test Guideline 474
Result: negative

Carcinogenicity
Not classified based on available information.
Reproductive toxicity
Suspected of damaging the unborn child.
Components:
Styrene
Reproductive toxicity - : Some evidence of adverse effects on development, based on
Assessment animal experiments.

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SAFETY DATA SHEET Revision Date: 22.10.2019

Print Date: 10.12.2019
SDS Number: R0402443
Derakane™ 411-45 epoxy vinyl ester resin Version: 1.3
™ Trademark, INEOS or its subsidiaries, registered
in various countries
123349

methacrylic acid
Effects on fertility : Species: Rat
Application Route: Oral
Fertility: No observed adverse effect level (Mating/Fertility):
400 mg/kg body weight
Symptoms: No effects on fertility No effects on reproduction
parameters
Method: OECD Test Guideline 416

Effects on foetal : Species: Rabbit

development Application Route: Oral
Developmental Toxicity: No observed adverse effect level F1:
450 mg/kg body weight
Symptoms: No specific developmental abnormalities
Method: OECD Test Guideline 414

STOT - single exposure

May cause respiratory irritation.
Components:
Styrene
Assessment: May cause respiratory irritation.

methacrylic acid
Exposure routes: Inhalation
Target Organs: Respiratory Tract
Assessment: May cause respiratory irritation.

STOT - repeated exposure

Causes damage to organs (Auditory organs) through prolonged or repeated exposure if inhaled.
Components:
Styrene
Exposure routes: inhalation (vapour)
Target Organs: Auditory system
Assessment: Causes damage to organs through prolonged or repeated exposure.

Repeated dose toxicity

Components:
Styrene
Species: Human
85 mg/m3
Application Route: inhalation (vapour)

Species: Human
615 mg/kg
Application Route: Skin contact

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SAFETY DATA SHEET Revision Date: 22.10.2019

Print Date: 10.12.2019
SDS Number: R0402443
Derakane™ 411-45 epoxy vinyl ester resin Version: 1.3
™ Trademark, INEOS or its subsidiaries, registered
in various countries
123349

methacrylic acid
Species: Rat, male and female
NOAEC: 352 mg/m3
Application Route: inhalation (dust/mist/fume)
Exposure time: 90 Days
Group: yes
Symptoms: Local irritation, Reduced body weight

Aspiration toxicity
Not classified based on available information.
Components:
Styrene
May be fatal if swallowed and enters airways.

Further information
Product:
Remarks: Solvents may degrease the skin.

SECTION 12: Ecological information

12.1 Toxicity

Components:
Styrene
Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 4,02 mg/l
Exposure time: 96 h

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 4,7 mg/l
aquatic invertebrates Exposure time: 48 h

Toxicity to algae : ErC50 (Pseudokirchneriella subcapitata (green algae)): 4,9

mg/l
Exposure time: 72 h

EC10 (Pseudokirchneriella subcapitata (green algae)): 0,28

mg/l
Exposure time: 96 h

Toxicity to bacteria : EC50 (activated sludge): ca. 500 mg/l

Exposure time: 0,5 h

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SAFETY DATA SHEET Revision Date: 22.10.2019

Print Date: 10.12.2019
SDS Number: R0402443
Derakane™ 411-45 epoxy vinyl ester resin Version: 1.3
™ Trademark, INEOS or its subsidiaries, registered
in various countries
123349

Toxicity to daphnia and other : NOEC: 1,01 mg/l

aquatic invertebrates Exposure time: 21 d
(Chronic toxicity) Species: Daphnia magna (Water flea)

Toxicity to soil dwelling : NOEC: 34 mg/kg

organisms Exposure time: 14 d
Species: Eisenia fetida (earthworms)
Method: OECD Test Guideline 207

methacrylic acid
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 85 mg/l
Exposure time: 96 h
Test Type: flow-through test

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 130 mg/l
aquatic invertebrates Exposure time: 48 h
Test Type: flow-through test

Toxicity to algae : EC50 (Pseudokirchneriella subcapitata (green algae)): 20 mg/l

End point: Biomass
Exposure time: 72 h
Test Type: flow-through test
Method: OECD Test Guideline 201

Toxicity to fish (Chronic : NOEC: 10 mg/l

toxicity) Exposure time: 35 d
Species: Danio rerio (zebra fish)
Test Type: flow-through test
Method: OECD Test Guideline 210

Toxicity to daphnia and other : NOEC: 53 mg/l

aquatic invertebrates Exposure time: 21 d
(Chronic toxicity) Species: Daphnia magna (Water flea)
Test Type: flow-through test
Method: OECD Test Guideline 211

12.2 Persistence and degradability

Components:
Styrene
Biodegradability : Result: Readily biodegradable.
Biodegradation: > 60 %
Exposure time: 10 d

methacrylic acid
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SAFETY DATA SHEET Revision Date: 22.10.2019

Print Date: 10.12.2019
SDS Number: R0402443
Derakane™ 411-45 epoxy vinyl ester resin Version: 1.3
™ Trademark, INEOS or its subsidiaries, registered
in various countries
123349

Biodegradability : Inoculum: activated sludge

Result: Readily biodegradable.
Biodegradation: 87 %
Exposure time: 28 d

12.3 Bioaccumulative potential

Components:
Styrene
Bioaccumulation : Bioconcentration factor (BCF): < 100

Partition coefficient: n- : log Pow: 2,96 (25 °C)

octanol/water

methacrylic acid
Bioaccumulation : Bioconcentration factor (BCF): 1,0
Remarks: Bioaccumulation is unlikely.

Partition coefficient: n- : log Pow: 0,93

octanol/water

12.4 Mobility in soil

Components:
Styrene
Distribution among : Koc: 352
environmental compartments

12.5 Results of PBT and vPvB assessment

Components:
Styrene
Assessment : This substance is not considered to be persistent,
bioaccumulating and toxic (PBT).. This substance is not
considered to be very persistent and very bioaccumulating
(vPvB)..

12.6 Other adverse effects

Product:
Additional ecological : An environmental hazard cannot be excluded in the event of
information unprofessional handling or disposal., Toxic to aquatic life.

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SAFETY DATA SHEET Revision Date: 22.10.2019

Print Date: 10.12.2019
SDS Number: R0402443
Derakane™ 411-45 epoxy vinyl ester resin Version: 1.3
™ Trademark, INEOS or its subsidiaries, registered
in various countries
123349

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Product : The product should not be allowed to enter drains, water
courses or the soil.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Send to a licensed waste management company.

Contaminated packaging : Empty remaining contents.

Dispose of as unused product.
Empty containers should be taken to an approved waste
handling site for recycling or disposal.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.

SECTION 14: Transport information

SECTION 14: Transport information

14.1 UN number

ADN: UN1866
ADR: UN1866
INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO: UN1866
INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER: UN1866
INTERNATIONAL MARITIME DANGEROUS GOODS: UN1866
RID: UN1866

14.2 UN proper shipping name

ADN: RESIN SOLUTION

ADR: RESIN SOLUTION
INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO: Resin solution
INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER: Resin solution
INTERNATIONAL MARITIME DANGEROUS GOODS: RESIN SOLUTION
RID: RESIN SOLUTION

14.3 Transport hazard class(es)

ADN: 3
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SAFETY DATA SHEET Revision Date: 22.10.2019

Print Date: 10.12.2019
SDS Number: R0402443
Derakane™ 411-45 epoxy vinyl ester resin Version: 1.3
™ Trademark, INEOS or its subsidiaries, registered
in various countries
123349

ADR: 3
INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO: 3
INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER: 3
INTERNATIONAL MARITIME DANGEROUS GOODS: 3
RID: 3

14.4 Packing group

ADN: III
ADR: III
INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO: III
INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER: III
INTERNATIONAL MARITIME DANGEROUS GOODS: III
RID: III

14.5 Environmental hazards

ADN: Not applicable

ADR: Not applicable
INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO: Not applicable
INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER: Not applicable
INTERNATIONAL MARITIME DANGEROUS GOODS: Not applicable
RID: Not applicable

14.6 Special precautions for user

Not applicable

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Ship Type: Not applicable

Hazard code(s): Not applicable
Pollutant Category: Not applicable

Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific
exceptions that can be applied. Consult shipping documents for descriptions that are specific to the
shipment.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
REACH - Candidate List of Substances of Very High : Not applicable
Concern for Authorisation (Article 59).

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SAFETY DATA SHEET Revision Date: 22.10.2019

Print Date: 10.12.2019
SDS Number: R0402443
Derakane™ 411-45 epoxy vinyl ester resin Version: 1.3
™ Trademark, INEOS or its subsidiaries, registered
in various countries
123349

REACH - List of substances subject to authorisation : Not applicable

(Annex XIV)

Regulation (EC) No 1005/2009 on substances that : Not applicable

deplete the ozone layer

Regulation (EC) No 850/2004 on persistent organic : Not applicable

pollutants

Regulation (EC) No 649/2012 of the European : Not applicable

Parliament and the Council concerning the export and
import of dangerous chemicals

REACH - Restrictions on the manufacture, placing on :Conditions of restriction for the

the market and use of certain dangerous substances, following entries should be
preparations and articles (Annex XVII) considered:
(3)
Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of
major-accident hazards involving dangerous substances.
Quantity 1 Quantity 2
P5c FLAMMABLE LIQUIDS 5.000 t 50.000 t

Other regulations : Take note of Directive 92/85/EEC regarding maternity

protection or stricter national regulations, where applicable.

Take note of Directive 94/33/EC on the protection of young

people at work or stricter national regulations, where
applicable.

The components of this product are reported in the following inventories:

DSL : This product contains one or several components that are not
on the Canadian DSL and have annual quantity limits.

AICS On the inventory, or in compliance with the inventory

ENCS On the inventory, or in compliance with the inventory

KECI Not in compliance with the inventory

PICCS Not in compliance with the inventory

IECSC On the inventory, or in compliance with the inventory

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SAFETY DATA SHEET Revision Date: 22.10.2019

Print Date: 10.12.2019
SDS Number: R0402443
Derakane™ 411-45 epoxy vinyl ester resin Version: 1.3
™ Trademark, INEOS or its subsidiaries, registered
in various countries
123349

TCSI On the inventory, or in compliance with the inventory

TSCA On TSCA Inventory

Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL
(Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA) On
or in compliance with the active portion of the TSCA inventory

15.2 Chemical safety assessment

No data available

SECTION 16: Other information

Further information
Revision Date: 22.10.2019

Classification procedure:
H226 Flammable liquid and vapour. Based on product data or assessment
H315 Causes skin irritation. Calculation method
H319 Causes serious eye irritation. Calculation method
H361d Suspected of damaging the unborn Calculation method
child.
H335 May cause respiratory irritation. Calculation method
H372 Causes damage to organs through Calculation method
prolonged or repeated exposure if
inhaled.
H412 Harmful to aquatic life with long Calculation method
lasting effects.

Full text of H-Statements

H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.

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SAFETY DATA SHEET Revision Date: 22.10.2019

Print Date: 10.12.2019
SDS Number: R0402443
Derakane™ 411-45 epoxy vinyl ester resin Version: 1.3
™ Trademark, INEOS or its subsidiaries, registered
in various countries
123349

H315 Causes skin irritation.

H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H361d Suspected of damaging the unborn child.
H372 Causes damage to organs through prolonged or repeated exposure if
inhaled.
H412 Harmful to aquatic life with long lasting effects.

Other information : The information accumulated herein is believed to be accurate

but is not warranted to be whether originating with the
company or not. Recipients are advised to confirm in advance
of need that the information is current, applicable, and suitable
to their circumstances. This SDS has been prepared by
INEOS's Environmental Health and Safety Department (+34
93 206 51 20 (in Spain)).

Sources of key data used to compile the Safety Data Sheet

INEOS internal data including own and sponsored test reports
The UNECE administers regional agreements implementing harmonised classification for labelling
(GHS) and transport.

List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data
sheet :
ACGIH : American Conference of Industrial Hygienists
BEI : Biological Exposure Index
CAS : Chemical Abstracts Service (Division of the American Chemical Society).
CMR : Carcinogenic, Mutagenic or Toxic for Reproduction
FG : Food grade
GHS : Globally Harmonized System of Classification and Labeling of Chemicals.
H-statement : Hazard Statement
IATA : International Air Transport Association.
IATA-DGR : Dangerous Goods Regulation by the “International Air Transport Association” (IATA).

ICAO : International Civil Aviation Organization

ICAO-TI (ICAO) : Technical Instructions by the “International Civil Aviation Organization”
IMDG : International Maritime Code for Dangerous Goods
ISO : International Organization for Standardization

24 / 25
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SAFETY DATA SHEET Revision Date: 22.10.2019

Print Date: 10.12.2019
SDS Number: R0402443
Derakane™ 411-45 epoxy vinyl ester resin Version: 1.3
™ Trademark, INEOS or its subsidiaries, registered
in various countries
123349

logPow : octanol-water partition coefficient

LCxx : Lethal Concentration, for xx percent of test population
LDxx : Lethal Dose, for xx percent of test population.
ICxx : Inhibitory Concentration for xx of a substance
Ecxx : Effective Concentration of xx
N.O.S.: Not Otherwise Specified
OECD : Organization for Economic Co-operation and Development
OEL : Occupational Exposure Limit
P-Statement : Precautionary Statement
PBT : Persistent , Bioaccumulative and Toxic
PPE : Personal Protective Equipment
STEL : Short-term exposure limit
STOT : Specific Target Organ Toxicity
TLV : Threshold Limit Value
TWA : Time-weighted average
vPvB : Very Persistent and Very Bioaccumulative
WEL : Workplace Exposure Level
GAM : Water Hazard Class for the Netherlands
ADR : Agreement concerning the International Carriage of Dangerous Goods by Road.
ADNR: Regulation for the Carriage of Dangerous Substances on the Rhine
CLP : Classification, Labelling and Packaging
CSA : Chemical Safety Assessment
CSR : Chemical Safety Report
DNEL : Derived No Effect Level.
EINECS : European Inventory of Existing Commercial Chemical Substances.
ELINCS : European List of Notified Chemical Substances
GV: Exposure limits (DK)
PEC : Predicted Effect Concentration
PEL : Permissible Exposure Limits
PNEC : Predicted No Effect Concentration
REACH : Registration, Evaluation, Authorisation and Restriction of Chemicals
RID : Regulation Concerning the International Transport of Dangerous Goods by Rail
WGK : German Water Hazard Class
GB / EN

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