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CSS Past Paper Css Chemistry Paper 2021

This document contains an exam for recruitment to BS-17 posts in the federal government of Pakistan. The exam contains two parts: (1) a 30-minute multiple choice question section with 20 marks, and (2) a three hour written answer section worth 80 marks. Candidates must answer 4 questions from Part II, with each question worth 20 marks. The questions cover topics in organic chemistry, including reaction mechanisms, spectroscopy, and biochemical processes.

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Ali Tara
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© © All Rights Reserved
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Download as PDF, TXT or read online on Scribd
142 views

CSS Past Paper Css Chemistry Paper 2021

This document contains an exam for recruitment to BS-17 posts in the federal government of Pakistan. The exam contains two parts: (1) a 30-minute multiple choice question section with 20 marks, and (2) a three hour written answer section worth 80 marks. Candidates must answer 4 questions from Part II, with each question worth 20 marks. The questions cover topics in organic chemistry, including reaction mechanisms, spectroscopy, and biochemical processes.

Uploaded by

Ali Tara
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
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FEDERAL PUBLIC SERVICE COMMISSION Roll Number

COMPETITIVE EXAMINATION-2021 FOR RECRUITMENT TO


POSTS IN BS-17 UNDER THE FEDERAL GOVERNMENT
CHEMISTRY, PAPER-II
TIME ALLOWED: THREE HOURS PART-I (MCQS) MAXIMUM MARKS = 20
PART-I(MCQS): MAXIMUM 30 MINUTES PART-II MAXIMUM MARKS = 80
NOTE: (i) Part-II is to be attempted on the separate Answer Book.
(ii) Attempt ONLY FOUR questions from PART-II. ALL questions carry EQUAL marks.
(iii) All the parts (if any) of each Question must be attempted at one place instead of at different places.
(iv) Candidate must write Q. No. in the Answer Book in accordance with Q. No. in the Q.Paper.
(v) No Page/Space be left blank between the answers. All the blank pages of Answer Book must be crossed.
(vi) Extra attempt of any question or any part of the attempted question will not be considered.
PART-II
Q. 2. (a) Describe factors that influence keto-enol tautomerization. Elaborate the statement with the (10)
help of examples.
(b) Assign “R” or “S” configuration on each of the chiral centers of the given compounds. (10) (20)

Q. 3. (a) Give the products expected (if any) when ethylbenzene reacts under following conditions:
(i) Br2 in CCl4 (dark) (02 marks each) (10)
(ii) HNO 3 ,H2 SO 4
(iii) Conc. H2 SO 4

(iv)

(v) Alkaline KMnO 4


(b) Account for the following: (05 marks each) (10) (20)
(i) Intramolecular H-bonding is stronger than intermolecular H-bonding
(ii) Control of nucleophilic substitution reaction over elimination reactions

Q. 4. (a) Write down reagents, reaction conditions and important steps for the following (10)
conversions:
(i) Chlorobenzene to 2,4-dinitrophenyl hydrazine
(ii) Pyridine to 2-amino pyridine
(b) Write a note that substituents on aromatic rings dictate reactivity and orientation of the (10) (20)
incoming electrophile in electrophilic aromatic substitution reactions.

Q. 5. Draw detailed mechanisms for: (04 marks each) (20)

(i)

(ii)

(iii)

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CHEMISTRY, PAPER-II

(iv)

(v)

Q. 6. Account for the following: (05 marks each) (20)


(i) In DNA, a guanine residue reacts with electrophiles predominantly at the 7 and 3
positions of the ring system (see below). Suggest an explanation for this.

(ii) Outline the synthesis of following compound:

(iii) A Grignard reagent that is a key intermediate in an industrial synthesis of vitamin


A can be synthesized in the following way:

Wh
at
are
the
stru
ctu
res
of compounds A and C? The acid catalysed rearrangement of A to B takes p1.
(iv) What are compounds A and B in the reaction given below? Compound B has a
strong IR absorption band in the 1650–1730 cm−1 region and a broad strong band
in the 3200–3550 cm−1 region.

1. OsO4 CrO3
1-Methylcyclohexene A (C7H 14O2) B (C7H 12O2)
2. NaHSO3 CH3CO2H

Q. 7. Explain the following: (04 marks each) (20)


(i) How can IR be used to help interpret NMR spectra?
(ii) What are diastereotopic protons? Explain with examples.
(iii) Determine the structure for a compound with formula C 6 H4 N2 O4 with following
1
H-NMR data:
  8.76 t (1H), 8.38 dd (2H), 7.97 t (1H)
(iv) Assign chemical shifts of each proton in the above structure.
(v) Why 13 C-NMR is less sensitive than 1 H-NMR?

Q. 8. Answer following questions: (04 marks each) (20)


(i) Comment if glycogenesis is anabolic or catabolic. Write down all steps involve in
glycogenesis.
(ii) Describe endergonic and exergonic reactions
(iii) Write a note on anionic and cationic surfactants.
(iv) Comment if waste glass can be used for cement production.
(v) What is the chemical composition of nucleic acids and their biological significance?
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