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ChE 210 Lecture 5 Material Balance With Chemical Reaction and Problems Involving Multiple Units

This lecture discusses material balances for chemical processes involving chemical reactions, including determining extent of reaction, fractional conversion, selectivity, and solving example problems. It also covers general and mole balances for chemical reactors, rate expressions, batch and continuous reactors, and analytical solutions for simple rate laws including first and second order reactions. Multiple examples are provided to illustrate applications of these concepts to problems involving single and multiple reactions, yields, selectivity, limiting reactants, and elemental and molecular balancing.

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May May Magluyan
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222 views97 pages

ChE 210 Lecture 5 Material Balance With Chemical Reaction and Problems Involving Multiple Units

This lecture discusses material balances for chemical processes involving chemical reactions, including determining extent of reaction, fractional conversion, selectivity, and solving example problems. It also covers general and mole balances for chemical reactors, rate expressions, batch and continuous reactors, and analytical solutions for simple rate laws including first and second order reactions. Multiple examples are provided to illustrate applications of these concepts to problems involving single and multiple reactions, yields, selectivity, limiting reactants, and elemental and molecular balancing.

Uploaded by

May May Magluyan
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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MATH 2073: DIFFERENTIAL CALCULUS

LECTURE 5:
Material Balance With Chemical
Reaction and Problems Involving
Multiple Units
Selectivity

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Extent

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Material Balance for Processes Involving
Chemical Reaction

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Think About This:
What terms in the General Material Balance
can be removed if:

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Fraction(al) conversion to extend of reaction:

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Example 1:

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Conclusion:

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Example 2:

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Example 3:

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Example 4:

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Material Balance for Chemical Reactors

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General Mole Balance

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Rate Expressions

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The Batch Reactor

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Reactor Volume

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Analytical Solutions for Simple Rate Laws

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First-Order, Irreversible

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First-Order, Irreversible

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First-Order, Irreversible

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First-Order, Irreversible

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First-Order, Reversible

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First-Order, Reversible

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First-Order, Reversible

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First-Order, Reversible

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First-Order, Reversible

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First-Order, Reversible

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Non-Zero Steady-State

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Stoichiometry, Limiting, and
Excess Reactants

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Example 5:

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Example 6:

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Example 7:

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Fractional Conversions, Extent of Reaction,
and Chemical Equilibrium

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Example 8:

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Example 9:

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Example 10:

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Example 11:

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Processes Involving Multiple Reactions

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Example 12: Two Simultaneous Reactions Occur

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Example 13: Analysis of a Bioreactor

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Multiple Reactions, Yield, and Selectivity

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Example 14:

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Example 15: Yield and Selectivity
in a Dehydrogenation Reactor

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Elemental Balance

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Example 16: Elemental Balance

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Example 17: Element Balances

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Example 18: Use of Element balances to
Solve a Hydrocracking Problem

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Atomic and Molecular Balances

▷ In a chemical process, molecules are either generated


(produced) or consumed
▷ Therefore, one should take into account the amounts
(moles) generated, consumed, fed and remaining in
molecular balances

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Example 19:

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Example 20:

Perform Atomic Balance.

q1 = 60 moles q2 = 40 moles

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Answer the following questions in at least five (5)
sentences each. Do not forget to cite your
Development
references. Activity 4
1. Define: (a) Extent of Reaction, (b) Fractional Submit your answers in this
Conversion, (c) Limiting Reaction, (d) Excess form. Scan the QR code.
Reactant, (e) Chemical Reaction, (f) Equilibrium,
(g) Percentage Yield, (h) Selectivity, (i) Efficacy,
(j) Efficiency
2. Compare and differentiate mass balance, mole
balance, atomic balance, molecular balance,
material balance, elemental balance, and
component balance. Note that some are just
synonymous.

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