The Chemical Elements of a Smartphone

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click to enlarge

There are an isolated few graphics online that look at elements involved in the
manufacture of a smartphone – for example, this ‘Periodic Table of iPhones’ – but
there’s actually remarkably little easily accessible information out there that details the
specific compounds used for specific purposes in mobile phones. This probably isn’t
surprising since these details are probably kept under the lock and key of patent laws
and the like; however, I tried my best with this graphic to provide a little more detail
about specific uses, an undertaking that took a lot more effort than I initially expected!

The Screen

Details on the elements and compounds involved in the manufacture of touch screens
were in fact the easiest to track down. These are manufactured mainly from
aluminosilicate glass, a mixture of aluminium oxide and silicon dioxide, which is then
placed in a hot bath of molten salt. The purpose of this is to allow smaller sodium ions
to leave the glass and larger potassium ions to take their place; these take up more room
and are pressed together when the glass cools, producing a layer of compressive stress
on the glass and increasing its strength and resistance to mechanical damage.

A thin, transparent, conductive layer of indium tin oxide is deposited on the glass in
order to allow it to function as a touch screen – you can read more on how exactly touch
screens function here. Several of the rare earth elements are also present in very small
quantities, and have a hand in producing the colours displayed on the screen.

The Battery
The majority of today’s phones use lithium ion batteries. These batteries tend to use
lithium cobalt oxide as the positive electrode in the battery (though other transition
metals are sometimes used in place of cobalt), whilst the negative electrode is formed
from carbon in the form of graphite. It will also have an organic solvent to act as the
electrolytic fluid. The lithium in the positive electrode is ionised during charging of the
battery, and moves into the layers of the graphite electrode. During discharge, the ions
move back to the positive electrode. The battery itself is usually housed in an
aluminium casing.

The Electronics

A wide range of elements and compounds are used in the electronics of a phone. The
chip, the processor of the phone, is made from pure silicon, which is then exposed to
oxygen and heat in order to produce a film of silicon dioxide on its surface. Parts of this
silicon dioxide layer are then removed where current will be required to flow. Silicon
does not conduct electricity without being ‘doped’ with other elements; this process
involves the silicon being bombarded with a variety of different elements, which can
include phosphorus, antimony, arsenic, boron, indium or gallium. Different types of
semiconductor (P or N) are produced depending on the element used, with boron being
the most common type of P-type dopant.

The micro-electrical components and wiring in the phone are composed mainly of
copper, gold, and silver. Tantalum is also used, being the main component of micro-
capacitors. A range of other elements, including platinum and palladium are also used,
but detail on the specific applications of these was a little tricker to track down! Solder
is used to join electrical components together – this was, in years past, usually
composed of tin and lead, but in recent years lead-free alternatives have been sought,
many of which use a combination of tin, silver and copper.

The microphone and speaker of the phone both contain magnets, which are usually
neodymium-iron-boron alloys, though dysprosium and praseodymium are often also
present in the alloy. These are also found in the vibration unit of the phone.

The Casing

The elements present in the phone casing will depend on whether the case is metal or
plastic, or a mix of the two. Metal casings can be made of magnesium alloys, whilst
plastic casings will, of course, be carbon based. The casing will often also contain flame
retardant compounds – brominated flame retardants are still often used, but efforts are
being made to minimise the use of these, and so other organic compounds that do not
contain bromine are now more frequently employed.

There is, I’m sure, a plethora of further information out there which goes into more
specific detail about the different chemical compounds used in phones, but this was all I
was able to easily track down. If anyone has information that’s more specific, then it’d
be great to know!

EDIT: Thanks to  @acheronviper on twitter, here’s a little more information on the
elements used in semiconductors within a phone:
As noted above, the silicon dioxide layer on the semi-conductor device prevents current
from flowing in areas of the semiconductor where this is not desired, namely between
the transistors (essentially a form of switches) and the silicon. Transistors are constantly
getting smaller and smaller, and as they do so, there is also a requirement for the
insulating layer between them and the silicon to become thinner. However, this is
limited by the size of silicon atoms, and the fact that, once down to about 5 atoms thick,
the layer leaks current and becomes inefficient.

To combat this, hafnium based layers were utilised instead; this also requires use of a
different material for the transistors, with both titanium nitride and titanium aluminium
nitride being employed. To connect the transistors with the interconnecting copper
layers in the semi-conductor, tungsten is used as a contact. Tungsten also finds use
outside the semiconductor device, as weights for the vibrating motors within the phone.

Of course, the strive to improve the semiconductor devices still further is ongoing, and
the possibility of introducing group III-V element compounds into the transistor
structure, such as GaAs, InP and InAs, is a possibility that could allow electron mobility
to improve, and in turn allow semiconductors to become smaller still.

The graphic in this article is licensed under a  Creative Commons Attribution-

References & Further Reading

 ‘What’s in my smartphone?’ – E. Levonas, Mineral Information Institute.

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Categories: Materials Chemistry